CN102430199A - Preparation method of electrochemical treatment sensing element - Google Patents
Preparation method of electrochemical treatment sensing element Download PDFInfo
- Publication number
- CN102430199A CN102430199A CN2011103943757A CN201110394375A CN102430199A CN 102430199 A CN102430199 A CN 102430199A CN 2011103943757 A CN2011103943757 A CN 2011103943757A CN 201110394375 A CN201110394375 A CN 201110394375A CN 102430199 A CN102430199 A CN 102430199A
- Authority
- CN
- China
- Prior art keywords
- titanium
- platinum
- sensing element
- electrode
- tinsel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 34
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 18
- 239000010936 titanium Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000007747 plating Methods 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- 238000009713 electroplating Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- 239000012153 distilled water Substances 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 238000013461 design Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 238000005282 brightening Methods 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000011010 flushing procedure Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 229910001200 Ferrotitanium Inorganic materials 0.000 claims description 2
- 229910000914 Mn alloy Inorganic materials 0.000 claims description 2
- 229910000756 V alloy Inorganic materials 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- MECMQNITHCOSAF-UHFFFAOYSA-N manganese titanium Chemical compound [Ti].[Mn] MECMQNITHCOSAF-UHFFFAOYSA-N 0.000 claims description 2
- GFNGCDBZVSLSFT-UHFFFAOYSA-N titanium vanadium Chemical compound [Ti].[V] GFNGCDBZVSLSFT-UHFFFAOYSA-N 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 abstract description 4
- 238000006701 autoxidation reaction Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 239000007772 electrode material Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 206010028980 Neoplasm Diseases 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 208000030507 AIDS Diseases 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FCUFAHVIZMPWGD-UHFFFAOYSA-N [O-][N+](=O)[Pt](N)(N)[N+]([O-])=O Chemical compound [O-][N+](=O)[Pt](N)(N)[N+]([O-])=O FCUFAHVIZMPWGD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical group 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- -1 long service life Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The invention relates to a preparation method of an electrochemical treatment sensing element, which adopts the technology of plating platinum on the outer layer of titanium or titanium alloy, greatly reduces the production cost of an electrode, and simultaneously, titanium is a matrix of metal elements acceptable to human bodies, so that the electrode has the advantage of organism tissue compatibility. The electrode prepared by the method disclosed by the invention is plated with platinum on the surface layer of the electrode, and the electrode is stored in absolute ethyl alcohol after being processed, cleaned and deoiled, so that the autoxidation of a matrix is well avoided.
Description
Technical field
The invention belongs to the medical apparatus field, relate in particular to a kind of method for preparing that is used for a kind of electrochemotherapy sensing element of electrochemotherapy cancer.
Background technology
Electrode material for being used to treat human tumor has a lot of requirements; These electrode materials require that satisfactory electrical conductivity is arranged, the tissue electrode reaction do not produce burn into not frangible, do not introduce other supervoltage that material, long service life, hydrogen are arranged little, have good catalytic, requiring product simultaneously is bronsted lowry acids and bases bronsted lowry.And platinum is optimal electrode material.
Once adopted me to invent pure platinum electrode at electrochemotherapy; Introduced the pure platinum electrode of this kind among the Chinese patent CN89207791.3; But the kind electrode cost is high and exist dislocation of electrode, electrode tip to collide and the monolateral effect of electric current, and the contaminated operation platform also is easy to generate and hands over justice to infect; Cause pathophoresis, especially the passage of the transmission of infection of AIDS.
Give birth to for stopping this type of incident, many research worker attempt adopting stainless steel electrode, copper electrode; Nickel electrodes etc. are used for medical-therapeutic treatment of human body, but owing to often mix poisonous elements such as nickel, chromium in these electrode materials, electrochemical reaction produces corrosion; Follow electrode corrosion can not accept big coulomb electric charge, electrode fractures easily, has an accident; Therefore these materials are not suitable for using as electrode material, and reaction condition requires comparatively, and harshness is not suitable for use of large-scale production.The scientific research personnel in this field is lower in the development cost of making great efforts at present, is fit to the novel electrode material that the treatment human body uses again.
Summary of the invention
The present invention has prepared a kind of electrochemotherapy sensing element, and it has solved pure platinum electrode cost height, has existed dislocation of electrode, electrode tip to collide and the monolateral effect of electric current, contaminated operation platform and the problem that is easy to generate the infection of friendship justice.
In order to solve the technical problem of above-mentioned existence, the present invention has adopted following scheme:
A kind of method for preparing of electrochemotherapy sensing element is characterized in that may further comprise the steps:
Step 1: draw materials
Get titanium alloy wires or titanium silk, the diameter wiry of getting is 0.3mm-1.5mm, and is getting tinsel is stretching, cut out, and an end wiry is worn into sharp head;
Step 2: oil removing
2.1 the tinsel of cutting out in the step 1 is cleaned with detergent earlier, and reuse gasoline cleans, room temperature dries;
2.2 the tinsel after will drying is put in sodium carbonate liquor or the sodium bicarbonate solution of 0.5mol/L-1.0mol/L and boils 10min-60min, guarantees that temperature is 60 ℃-90 ℃, boils to wire surface to become the woven design shape;
Step 3: flash
The tinsel of handling in the step 2 is carried out flash, and the time is 0.1min-0.5min, the easy platinum plating of wire surface behind the flash;
Step 4: the tinsel of surface-brightening is kept in the dehydrated alcohol for use, this bright metal silk is a negative electrode;
Step 5: platinum plating
Anode adopts platinized platinum, and electroplate liquid is the dinitro diamino platinum (NH of 20g/L-50 g/L
3)
2Pt (NO
2)
2, 40 g/L-80 g/L sulfamic acid H
2OSO
2.NH
2, the mixed solution of 1000ml-4000ml distilled water preparation, the pH value of electroplate liquid is 1-2, is reflected in 60 ℃-75 ℃ the water-bath to carry out, the electric current density in the electroplating process is 1.5A-2.5A/m
2, electroplating time is 1min-40min, per 6 minutes generation 1 μ m thickness;
Step 6: the cathodic metal silk electrode after the platinum plating is put into boiling water boil 5min-60min, the reuse distilled water flushing is promptly accomplished the preparation of this electrochemotherapy sensing element.
Said titanium comprises a kind of in the titanium of titanium or unannealed processing after the annealing in process, and said titanium alloy is a kind of in titanium vanadium alloy, titanium maxter alloy, titanium manganese alloy, the ferro-titanium; Impurity content in said titanium alloy wires or the titanium silk is 10
-6Below the mol.
Said abluent is a kind of in sodium bicarbonate solution, sodium carbonate liquor, sodium hydroxide solution, the ammonia.
When deposition occurring in the described electroplate liquid of step 5, to the dinitroso diammonia platinum that wherein adds 20g/L-50 g/L, guarantee that the quality percentage composition of the dinitroso diammonia platinum in the electroplate liquid is no less than 40%, add amino sulfonic acid H
2OSO
2.NH
2Guarantee the pH value of solution, eliminate deposition or muddy.
This electrochemotherapy sensing element has following beneficial effect:
(1) the electrochemotherapy sensing element of the present invention's preparation adopts titanium or the outer platinized technology of titanium alloy, greatly reduces the cost of electrode production, and titanium also is that human body can be accepted the metallic element matrix simultaneously, makes this electrode have body tissue intermiscibility advantage.
(2) the electrochemotherapy sensing element top layer platinum plating of the present invention's preparation, and after oil removing is cleaned in processing, electrode is kept in the dehydrated alcohol, the matrix autoxidation well avoided.
(3) preparation flow of electrochemotherapy sensing element of the present invention is simple, and is easy to operate, is easy to processing.
The specific embodiment
Below in conjunction with specific embodiment, the present invention is further specified:
Embodiment 1
Step 1: draw materials
Get the qualified titanium silk of impurity content, the diameter wiry of getting is 0.3mm, and is getting tinsel is stretching, cut out, and an end wiry is worn into sharp head;
Step 2: oil removing
The tinsel of cutting out in the step 1 is cleaned with sodium hydroxide solution earlier, and reuse gasoline cleans, and room temperature dries; Tinsel after will drying is put in the sodium carbonate liquor of 0.5mol/L and boils 30min, guarantees that temperature is 85 ℃, boils to wire surface to become the woven design shape;
Step 3: flash
The tinsel of handling in the step 2 is carried out flash, and the time is 0.5min, the easy platinum plating of wire surface behind the flash;
Step 4: the tinsel of surface-brightening is kept in the dehydrated alcohol for use, this bright metal silk is a negative electrode;
Step 5: platinum plating
Anode adopts platinized platinum, and electroplate liquid is the dinitroso diammonia platinum of 20g/L, the sulfamic acid of 50 g/L, the mixed solution of 1000ml distilled water preparation, and the pH value of electroplate liquid is 2, is reflected in 75 ℃ the water-bath to carry out, the electric current density in the electroplating process is 1.5A/m
2, electroplating time is 18min, per 6 minutes generation 1 μ m thickness;
Step 6: the cathodic metal silk electrode after the platinum plating is put into boiling water boil 40min, the reuse distilled water flushing is promptly accomplished the preparation of this electrochemotherapy sensing element.
In electroplating process, when deposition occurring in the electroplate liquid,, guarantee that the quality percentage composition of the dinitroso diammonia platinum in the electroplate liquid is no less than 40% to the dinitroso diammonia platinum that wherein adds 20g/L.
Embodiment 2
Step 1: draw materials
Get the qualified titanium maxter alloy tinsel of impurity content, the diameter wiry of getting is 1.2mm, and is getting tinsel is stretching, cut out, and an end wiry is worn into sharp head;
Step 2: oil removing
The tinsel of cutting out is cleaned with ammonia spirit earlier, and reuse gasoline cleans, and room temperature dries; Tinsel after will drying is put in the sodium bicarbonate solution of 1.0mol/L and boils 50min, guarantees that temperature is 75 ℃, boils to wire surface to become the woven design shape;
Step 3: flash
The tinsel of handling in the step 2 is carried out flash, and the time is 0.3min, the easy platinum plating of wire surface behind the flash;
Step 4: the tinsel of surface-brightening is kept in the dehydrated alcohol for use, this bright metal silk is a negative electrode;
Step 5: platinum plating
Anode adopts platinized platinum, and electroplate liquid is the dinitroso diammonia platinum of 35g/L, the sulfamic acid of 60 g/L, the mixed solution of 2000ml distilled water preparation, and the pH value of electroplate liquid is 1, and reaction constant temperature carries out in 70 ℃ water-bath, and the electric current density in the electroplating process is 2.5A/m
2, electroplating time is 30min, per 6 minutes generation 1 μ m thickness;
Step 6: the cathodic metal silk electrode after the platinum plating is put into boiling water boil 50min, the reuse distilled water flushing is promptly accomplished the preparation of this electrochemotherapy sensing element.
When deposition occurring in the electroplate liquid,, guarantee that the quality percentage composition of the dinitroso diammonia platinum in the electroplate liquid is no less than 40% in the electroplating process to the dinitroso diammonia platinum that wherein adds 35g/L.
In conjunction with specific embodiments the present invention has been carried out exemplary description above; Obvious realization of the present invention is not subjected to the restriction of aforesaid way; As long as the various improvement of having adopted method design of the present invention and technical scheme to carry out; Or design of the present invention and technical scheme are directly applied to other occasion without improving, all in protection scope of the present invention.
Claims (4)
1. the method for preparing of an electrochemotherapy sensing element is characterized in that may further comprise the steps:
Step 1: draw materials
Get titanium alloy wires or titanium silk, the diameter wiry of getting is 0.3mm-1.5mm, and is getting tinsel is stretching, cut out, and an end wiry is worn into sharp head;
Step 2: oil removing
2.1 the tinsel of cutting out in the step 1 is cleaned with detergent earlier, and reuse gasoline cleans, room temperature dries;
2.2 the tinsel after will drying is put in sodium carbonate liquor or the sodium bicarbonate solution of 0.5mol/L-1.0mol/L and boils 10min-60min, guarantees that temperature is 60 ℃-90 ℃, boils to wire surface to become the woven design shape;
Step 3: flash
The tinsel of handling in the step 2 is carried out flash, and the time is 0.1min-0.5min, the easy platinum plating of wire surface behind the flash;
Step 4: the tinsel of surface-brightening is kept in the dehydrated alcohol for use, this bright metal silk is a negative electrode;
Step 5: platinum plating
Anode adopts platinized platinum, and electroplate liquid is the dinitroso diammonia platinum (NH of 20g/L-50 g/L
3)
2Pt (NO
2)
2The sulfamic acid H of 40 g/L-80 g/L
2OSO
2.NH
2, the mixed solution of 1000ml-4000ml distilled water preparation, the pH value of electroplate liquid is 1-2, is reflected in 60 ℃-75 ℃ the water-bath to carry out, the electric current density in the electroplating process is 1.5A-2.5A/m
2, electroplating time is 1min-40min, per 6 minutes generation 1 μ m thickness;
Step 6: the cathodic metal silk electrode after the platinum plating is put into boiling water boil 5in-60min, the reuse distilled water flushing is promptly accomplished the preparation of this electrochemotherapy sensing element.
2. according to the method for preparing of the said a kind of electrochemotherapy sensing element of claim 1; It is characterized in that: the silk of titanium described in the step 1 comprises a kind of in the titanium silk of titanium silk or unannealed processing after the annealing in process, and said titanium alloy is a kind of in titanium vanadium alloy, titanium maxter alloy, titanium manganese alloy, the ferro-titanium; Impurity content in said titanium alloy wires or the titanium silk is 10
-6Below the mol.
3. according to the method for preparing of the said a kind of electrochemotherapy sensing element of claim 1, it is characterized in that: abluent described in the step 2 is a kind of in sodium bicarbonate solution, sodium carbonate liquor, sodium hydroxide solution, the ammonia.
4. according to the method for preparing of the said a kind of electrochemotherapy sensing element of claim 1; It is characterized in that: when deposition occurring in the described electroplate liquid of step 5; To the dinitroso diammonia platinum that wherein adds 20g/L-50 g/L, guarantee that the quality percentage composition of the dinitroso diammonia platinum in the electroplate liquid is no less than 40%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103943757A CN102430199A (en) | 2011-12-02 | 2011-12-02 | Preparation method of electrochemical treatment sensing element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103943757A CN102430199A (en) | 2011-12-02 | 2011-12-02 | Preparation method of electrochemical treatment sensing element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102430199A true CN102430199A (en) | 2012-05-02 |
Family
ID=45978774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103943757A Pending CN102430199A (en) | 2011-12-02 | 2011-12-02 | Preparation method of electrochemical treatment sensing element |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102430199A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112955A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Dinitrodiammineplatinum ammoniacal electroplating solution for acidic platinum plating and electroplating method adopting dinitrodiammineplatinum ammoniacal electroplating solution |
| CN105112956A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Acidic dinitrodiammineplatinum ammoniacal plating solution and plating method of Pt |
| CN105112957A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Platinum electroplating solution containing dipotassium tetrakis(nitrito-N)platinate and electroplating method adopting platinum electroplating solution |
| CN105154931A (en) * | 2015-09-21 | 2015-12-16 | 无锡清杨机械制造有限公司 | Platinum electroplating solution comprising dihydrogen dinitrosulfatoplatinate and electroplating method adopting platinum electroplating solution |
| CN113755913A (en) * | 2021-09-30 | 2021-12-07 | 励福(江门)环保科技股份有限公司 | Acidic P salt plating solution for electroplating platinum and electroplating method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101713087A (en) * | 2009-11-24 | 2010-05-26 | 北京有色金属研究总院 | Electroplating method of Ti-Ni based memory alloy |
-
2011
- 2011-12-02 CN CN2011103943757A patent/CN102430199A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101713087A (en) * | 2009-11-24 | 2010-05-26 | 北京有色金属研究总院 | Electroplating method of Ti-Ni based memory alloy |
Non-Patent Citations (2)
| Title |
|---|
| 杨升红: "钛基镀铂工艺研究", 《稀有金属材料与工程》 * |
| 栾永勤等: "不溶性阳极-钛网镀铂的研制", 《电镀与精饰》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112955A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Dinitrodiammineplatinum ammoniacal electroplating solution for acidic platinum plating and electroplating method adopting dinitrodiammineplatinum ammoniacal electroplating solution |
| CN105112956A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Acidic dinitrodiammineplatinum ammoniacal plating solution and plating method of Pt |
| CN105112957A (en) * | 2015-09-21 | 2015-12-02 | 无锡清杨机械制造有限公司 | Platinum electroplating solution containing dipotassium tetrakis(nitrito-N)platinate and electroplating method adopting platinum electroplating solution |
| CN105154931A (en) * | 2015-09-21 | 2015-12-16 | 无锡清杨机械制造有限公司 | Platinum electroplating solution comprising dihydrogen dinitrosulfatoplatinate and electroplating method adopting platinum electroplating solution |
| CN113755913A (en) * | 2021-09-30 | 2021-12-07 | 励福(江门)环保科技股份有限公司 | Acidic P salt plating solution for electroplating platinum and electroplating method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102430199A (en) | Preparation method of electrochemical treatment sensing element | |
| CA3076561C (en) | Method of producing an electrocatalyst | |
| CN103014755B (en) | Fabrication method of long-life titanium base electrode | |
| CN103014751B (en) | Active cathode and preparation method thereof | |
| CN102191513B (en) | Preparation method of insoluble titanium-based catalytic electrode | |
| CN103147093A (en) | Preparation method of long-life DSA electrode | |
| CN102560571A (en) | Cyanide-free silver plating stable electroplating solution and preparation method thereof, and silver plating method | |
| WO2006030685A1 (en) | Electrolysis electrode and method for producing aqueous quaternary ammonium hydroxide solution using such electrolysis electrode | |
| CN102787340A (en) | Aluminium alloy hard anodizing electrolyte | |
| US5407550A (en) | Electrode structure for ozone production and process for producing the same | |
| CN102703928B (en) | Method for extracting gallium through ultrasonic-assisted intensified electrolysis | |
| CN101545113B (en) | An activating treatment process for the production of electrolytic manganese dioxide with anodic | |
| CN109234757B (en) | Preparation method of uniform and stable ruthenium-iridium bimetallic doped titanium electrode | |
| CN102425000A (en) | Preparation method of bioactive titanium oxide film layer on NiTi alloy surface | |
| CN102560561A (en) | DSA (Dimensionally Stable Anode) electrode and manufacturing method thereof | |
| CN102534717A (en) | Method for preparing lead dioxide electrode plate on engineering plastic substrate | |
| CN114684847A (en) | Copper hydroxide, preparation method and application thereof, and bactericide | |
| CN114836783B (en) | A preparation method and application based on nanoruthenium dioxide/carbon composite array | |
| CN114959812A (en) | Nickel-tungsten alloy electroplating solution and insoluble anode system | |
| CN102899684A (en) | Preparation method for cathodic porous supported catalytic electrode used in electrolysis and hydro-liquefaction of coal | |
| CN105274560A (en) | Preparation of a Novel Ce-La Co-doped Highly Catalytic Activity Ti/Ce-Lanano-TiO2 Modified Electrode and Its Electrocatalytic Reduction of L-Cystine | |
| CN102899678A (en) | Preparation process for silver potassium cyanide based on diaphragm electrolysis | |
| CN115537883B (en) | IrO for electrolytic copper foil production 2 -Ta 2 O 5 Method for reducing oxygen evolution potential of Ti electrode | |
| CN115537905A (en) | NiTi alloy root canal file and surface modification method thereof | |
| CN101638795A (en) | Method for transferring electrically-deposited Co-P catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120502 |