CN102424358A - Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition - Google Patents
Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition Download PDFInfo
- Publication number
- CN102424358A CN102424358A CN2011102661452A CN201110266145A CN102424358A CN 102424358 A CN102424358 A CN 102424358A CN 2011102661452 A CN2011102661452 A CN 2011102661452A CN 201110266145 A CN201110266145 A CN 201110266145A CN 102424358 A CN102424358 A CN 102424358A
- Authority
- CN
- China
- Prior art keywords
- salt
- hydrogen
- deuterium
- water
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Catalysts (AREA)
Abstract
The invention relates to a method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition. Three components of rich metal/water or alcohol with its general formula being R(OH)n, or heavy water/ a catalyst and the like form a ternarysystem. In the system at normal temperature of 10-60 DEG C, rich metal is used for water or alcohol decomposition so as to prepare hydrogen, or rich metal is used for heavy water decomposition so as to prepare deuterium.
Description
Technical field
The present invention relates to the preparation method of a kind of hydrogen or deuterium, the method for particularly iron, manganese, aluminium, four kinds of rich metals such as zinc decomposition water or pure hydrogen of heavy water system or deuterium under normal temperature (10-60 ℃) condition.Prepared hydrogen does not contain any impurity, need not to purify, and can directly supply with the combustion of fuel cell or hydrogen and draw the energy of pulling.
Background technology
Many of the world urban air pollution is a pressing problem, especially in the population of these dense or airflow cities, the problem is more sudden Chu.The source of polluting mainly is the traffic exhaust emissions.For example during the 2008 Olympic Games, Beijing takes vehicle to restrict driving, and replenishes the combustion of part hydrogen again and hands over car altogether, gets instant result, and Beijing sky presents blue sky and white cloud.
Hydrogen combustion power is universally acknowledged high-level efficiency, the low emission transportation and energy.Current, oneself becomes ripe hydrogen combustion automotive engineering, yet the high manufacturing cost of hydrogen needs to be resolved hurrily with storage transportation problem.These two problems can't resolve, and hydrogen car can only rest on the trial period.
The preparation method of hydrogen has multiple, comparatively speaking, has only hydrogen production by water decomposition just both economical and sustainable.But the method for existing hydrogen production by water decomposition is like the sun power thermochemical cycle; Utilize Wood Adhesives from Biomass hydrogen production process etc. all to have some defectives.So so far, the hydrogen on the market is still with water electrolysis hydrogen production and the hydrogen manufacturing of decomposition natural gas.The former current consumption is higher; The latter except that consuming petrochemical industry resource and emission greenhouse gas still, the ME complicacy, equipment is huge, should not disperse miniaturized hydrogen manufacturing.Thus, preclude the use of the existing industrial hydrogen production, hydrogen storage problem is still not resolved.
Summary of the invention
Technical problem to be solved by this invention is; The method of a kind of rich metal normal temperature water of decomposition or heavy water hydrogen manufacturing or deuterium is provided, and according to certain ternary system compatibility, at room temperature safety is produced hydrogen; Make it possess the sudden or title instantaneity of the hydrogen of producing, and improve the transformation efficiency of rich metal.
Technical scheme of the present invention is following:
The method of rich metal normal temperature water of decomposition or heavy water hydrogen manufacturing or deuterium is characterized in that: under the normal temperature, with A, three kinds of components of B and C stir in container according to the ratio of mol ratio A:B:C=1:50 ~ 10000:0.01 ~ 0.9 and make hydrogen or deuterium;
Wherein, A component: manganese, iron, aluminium, one of zinc or its two or more mixtures with arbitrary proportion;
B component: the alcohol that during hydrogen manufacturing is water or general formula R (OH) n; During the system deuterium is heavy water;
C component: catalyzer;
Said catalyst is two or more mixtures with arbitrary proportion among the salt of one of salt of following 15 metal ion species or said metal ion: copper, iron, tin, chromium, molybdenum, titanium, vanadium, niobium, nickel, cobalt, zirconium, manganese, zinc, indium, aluminium; Or sodium molybdate; Or ammonium molybdate.
Positively effect of the present invention is:
The first, the iron that the present invention selected for use, manganese, aluminium, and four kinds of rich metals such as zinc, both very fast with the water speed of response, it is high to produce hydrogen speed, again to environment with human friendly, and the abundance in the earth's crust is higher and be easy to obtain.Ternary hydrogen system of the present invention has the characteristic of under normal temperature (10-60 ℃) condition, producing hydrogen.
The second, ternary hydrogen system of the present invention has the characteristic of rich metal high conversion, and is for example anti-in 30 ℃ of beginnings of room temperature hydrogen manufacturing
Should, because exothermic heat of reaction, system can heat up automatically under good heat-retaining condition.For rhythmic reaction, have only to last stage reaction, for needing the external world, the transformation efficiency that improves rich metal gives some heats slightly, transform to promote remaining a small amount of rich metal.
Three, ternary hydrogen system of the present invention has the sudden of product hydrogen.Under the A/B/C proportioning situation that is fit to, control rhythmic reaction temperature is 60 ℃, and the transformation efficiency of two minutes rich metals of reaction can reach 45-50%.
Four, the hydrogen of ternary hydrogen system generation of the present invention is not for containing the pure hydrogen of any impurity.Neither need purify CO or CO2, also needn't hydrogen-oxygen separate, the energy of the battery that can directly be used to act as a fuel.
Five, ternary hydrogen system of the present invention has process for making hydrogen and equipment is simple; Processing ease; Pollution-free; Industrial scale is changeable, and the characteristics of less investment.Can build the device of the production hydrogen of hydrogen production process of the present invention in be scattered in various places hydrogenation station, help being implemented in hydrogen manufacturing limit, limit, hydrogenation station and fill hydrogen to automobile.Thereby the technical problem that hydrogen transportation and the hydrogenation station from the hydrogen manufacturing head factory hydrogenation station to various places that have solved the prior art existence must store a large amount of high pressure hydrogens reaches the purpose that reduces the hydrogen manufacturing cost.
Six, ternary hydrogen system of the present invention has the insensitive characteristics of reaction pressure, can reduce the occupation of land of device for producing hydrogen, for technical foundation has been laid in the follow-up research and development of the device for producing hydrogen of hydrogen production process of the present invention being brought up to automobile.
The mat woven of fine bamboo strips seven, ternary system compsn of the present invention is used the heavy water place of water, can make deuterium at normal temperatures equally.
Description of drawings
FigureThe 1st, the embodiment of the invention one, the gas chromatogram (the GC-950 gas chromatogram of hydrogen) of the gaseous product that Mn/H2O/Fe3+ ternary system water of decomposition generates.Visible by Fig. 1: RT is that 1.511 minutes peak is a hydrogen; It is oxygen that hydrogen richness reaches 2.990 minutes persons of 98.1%. RT; RT is that 3.182 minutes persons are nitrogen; Press peak area ratio O2:N2=1; 4.6.
Fig. 2 is the embodiment of the invention three, and Mn/H2O/Na2MoO4 ternary system water of decomposition generates the gas chromatogram (the GC-950 gas chromatogram of hydrogen) of gaseous product.Visible by Fig. 2: 0.990 minute peak of RT is a hydrogen, and content is 88.22%; 2.482 minutes persons of RT are oxygen; 2.673 minutes persons of RT are nitrogen; O2:N2=1:4.2.
Embodiment
Further specify the present invention below in conjunction with accompanying drawing and embodiment.
Embodiment one
Get a glass there-necked flask that TM and induction stirring are housed, add 1.2 gram purity 99.8% manganese powder (21.89 mmole) and 90 milliliters of deionized waters.Get a reinforced bottle again, add 0.81 gram (5.0 mmole) FERRIC CHLORIDE ANHYDROUS and 10 milliliters of deionized waters, under 30 ℃ of room temperatures, in the aqueous solution adding there-necked flask with FeCl3, start stirring and produce great amount of bubbles immediately.Reaction is fierce, and temperature of reaction rises to some extent.Temperature of reaction remains on < in 60 ℃ the scope.Adopt draining water gathering of gas law to capture the gas that generates, with the gas that the gas chromatograph analysis is collected, hydrogen content reaches 98. 1%, and analytical results is seen Fig. 1, and 1.511 minutes chromatographic peak of RT is a hydrogen, and 3.182 minutes persons are nitrogen; 2.990 minute person is an oxygen; N2:O2=4.6:1, thus have reason to think the air that carries when nitrogen and oxygen in the sample is for analytical sampling, so the hydrogen of generation is pure hydrogen (as follows).Reaction result is following:
Reaction time (min) Reaction temperature (℃) Generation of hydrogen (ml) Manganese conversion (JP Mi%)
2 58 225 45.01
4 60 267 53.41
6 60 287 57.42
8 60 307 61.42
10 60 320 64.28
15 60 346 69.25
20 60 361 72.27
30 60 386 77.27
60 60 405 81.02
Embodiment two
Equipment is identical with embodiment one with operation and proportioning, only replaces manganese powder with aluminium wire (4.5 gram), generates hydrogen richness 97.7% in the gas, and reaction result is following:
Reaction times (minute) temperature of reaction (℃) generates the transformation efficiency (mole %) of amounts of hydrogen (milliliter) aluminium
70 25 25 0.58
260 35 73 1.92
430 40 117 3.06
700 60 226 5.93
Embodiment three
Equipment is identical with embodiment one Bi Zhuo with operation and feed molar Pei, only uses Sodium orthomolybdate (1.16 mmole) to replace iron trichloride (5.0 mmole), and experimental result is following: generate hydrogen richness 88.22% in the gas, see Fig. 2.
Reaction times (minute) temperature of reaction (℃) generates the transformation efficiency (mole %) of amounts of hydrogen (milliliter) manganese
12 40 10 1.80
20 45 20 3.60
42 50 30 5.40
60 60 40 7.20
Embodiment four
To the three-necked 1.33 g (purity 98%) of zinc dust (20 mmol Mi) and 90 ml tap water, 0.67 g of anhydrous nickel chloride take (5,0 mmole) was dissolved with 10 ml of tap water.Under 25 ℃ of room temperatures, this solution is joined in the there-necked flask, produce great amount of bubbles immediately, collect the gas that generates with draining water gathering of gas law, it is 96.9% that gas chromatograph is analyzed hydrogen content, and reaction result is following:
Reaction times (minute) temperature of reaction (℃) generates the transformation efficiency (mole %) of gas vol (milliliter) zinc
0 25 0 0
10 45 17 3.67
20 60 46 9.85
30 60 64 13.79
60 60 79 17.08
Embodiment five
The iron powder (20 mmole) and 90 ml tap waters that add 1.13 gram purity 99% in the there-necked flask restrain the aluminum trichloride (anhydrous) of purity 98.5% with 10 ml tap waters dissolving 0.68, under 29 ℃ of room temperatures with this solution adding there-necked flask in.Immediately produce large bubbles, fitted with a drain gas gathering occasionally and collect the gas generated by gas chromatograph analysis of hydrogen gas samples accounted for 94.9%, the other for sampling carried atmospheric nitrogen and oxygen.Reaction was carried out 120 minutes, and the result is following:
Reaction times (minute) temperature of reaction (℃) gas generating amount (milliliter) iron powder transformation efficiency (mole %)
0 29 0 0
10 45 57 12.07
20 60 94 19.91
30 60 123 26.05
60 60 179 37.91
90 60 222 47.02
120 59 250 52.95
Embodiment six
Device and operation and proportioning are same as embodiment one, only with the hydrogen manufacturing of aluminum chloride replacement iron trichloride, react 55 minutes, and the transformation efficiency of manganese reaches 72.23%.
Embodiment seven
Device and operation and proportioning are same as embodiment one, just substitute iron trichloride with chromium trioxide, react 60 minutes, and the transformation efficiency of manganese reaches 77.08%.
Embodiment eight
Apparatus and the operation and the ratio of the same as first embodiment, only the substitution of anhydrous indium trichloride, trichloride, Shi, 70 minutes reaction, the conversion rate was 75.79% manganese.
Embodiment nine
Apparatus and the operation and the ratio of the same as first embodiment, only the ferric iron into sulfuric Ami, 60 min, the conversion rate was 40.78% manganese.
Embodiment ten
Device and operation and proportioning are same as embodiment one, only iron trichloride are changed to Xiao Suangu, react 70 minutes, and the manganese transformation efficiency reaches 35.87%.
Embodiment 11
Device and operation and proportioning are same as embodiment one, only replace iron trichloride with Nickel Chloride, react 60 minutes, and the manganese transformation efficiency reaches 17.08%.
Embodiment 12
Device and operation and proportioning are same as embodiment one, only replace iron trichloride with copper sulfate, react 70 minutes, and the manganese transformation efficiency is 47.56%.
Embodiment 13
Device and operation and proportioning are same as embodiment one, only with Er Lvization the replacement iron trichloride, reacted 80 minutes, the manganese transformation efficiency is 21.70%.
Embodiment 14
Device and operation and proportioning are same as embodiment one, only change iron trichloride into manganous chloride, react 90 minutes, and the manganese transformation efficiency is 4..72%.
Device and operation and proportioning are same as embodiment one, only substitute iron trichloride with ammonium molybdate, react 60 minutes, and the manganese transformation efficiency is 6.70%.
Embodiment 16
The aluminium powder (20 mmole) of claiming 0.55 gram purity 98%; Put in the there-necked flask that 90 ml tap waters are housed; Loseing has bubble to produce. and the anhydrous chlorides of rase nickel (5.0 mmole) of 0.68 gram purity 98% is dissolved in 10 ml tap waters, and loseing has bubble to generate. and under room temperature (30 ℃), both are mixed in the there-necked flask and stir, produce great amount of bubbles at once; Be mixed with temperature rise; Temperature of reaction remains on 60 ℃. capture the gas that generates with draining water gathering of gas law. and with the composition of gas chromatographic analysis gas-phase product, hydrogen content is 95%. reactions 60 minutes, and the transformation efficiency of aluminium is 10.77%.
Embodiment 17
Device and operation and proportioning are same as embodiment 16, only substitute nickelous chloride with Sodium orthomolybdate, react 60 minutes, and the aluminium transformation efficiency is 7.43%.
Embodiment 18
Device and operation and proportioning are same as embodiment 16, only nickelous chloride are changed to aluminum chloride, react 60 minutes, and the transformation efficiency of aluminium reaches 27.47%.
Embodiment 19
Device and operation and proportioning are same as embodiment 16, only substitute nickelous chloride with chromium trichloride, react 50 minutes, and the aluminium transformation efficiency is 32.73%.
Device and operation and proportioning are same as embodiment 16, only substitute nickel chloride with indium trichloride, react 60 minutes, and the aluminium conversion ratio is 30.70%.
Embodiment 21
Apparatus and the operation and the same ratio as in Example XVI Conversion only nickel chloride iron sulfate Ami, the reaction 70 minutes the conversion was 20.47% aluminum.
Embodiment 22
Device and operation and proportioning are same as embodiment 16, substitute nickelous chloride with NSC 51149, react 60 minutes, and the transformation efficiency of aluminium is 12.71%.
Embodiment 23
Device and operation and proportioning are same as embodiment 16, only change nickelous chloride into ammonium molybdate, react 60 minutes, and the transformation efficiency of aluminium is 9.07%.
Embodiment 24
Device and operation and proportioning are same as embodiment 16, only replace nickelous chloride with copper sulfate, react 60 minutes, and the transformation efficiency of aluminium reaches 13.67%.
Device and operation and proportioning are same as embodiment 16, only substitute nickelous chloride with zinc chloride, react 70 minutes, and the transformation efficiency of aluminium is 9.78%.
Embodiment 26
Device and operation and proportioning are same as embodiment 16, only change nickelous chloride into manganous sulfate, react 90 minutes, and the transformation efficiency of aluminium is 3.75%.
Embodiment 27
Device and operation and proportioning are same as embodiment four, only change nickelous chloride into copper sulfate, react 60 minutes, and the transformation efficiency of zinc is 28.79%.
Embodiment 28
Device and operation and proportioning are same as embodiment four, only replace nickelous chloride with NSC 51149, react 70 minutes, and the transformation efficiency of zinc is 25.00%.
Embodiment 29
Apparatus and the operation and the ratio of the same as the fourth embodiment, only the conversion of nickel chloride, iron sulfate Ami, the reaction 70 minutes the conversion was 27.98% zinc.
Device and operation and proportioning are same as embodiment four, only replace nickelous chloride with Indium-111 chloride, react 50 minutes, and the transformation efficiency of zinc is 40.77%.
The embodiment hentriaconta-
Device and operation and proportioning are same as embodiment four, only change nickelous chloride into chromium trichloride, react 60 minutes, and the transformation efficiency of zinc is 43.07%.
Embodiment 32
Device and operation and proportioning are same as embodiment four, only nickelous chloride are changed to aluminum chloride, react 60 minutes, and the transformation efficiency of zinc is 38.70%.
Embodiment 33
Device and operation and proportioning are same as embodiment four, only replace nickelous chloride with iron trichloride, react 50 minutes, and the transformation efficiency of zinc is 47.28%.
Embodiment 34
Device and operation and proportioning are same as embodiment four, only change nickelous chloride into ammonium molybdate, react 60 minutes, and the transformation efficiency of zinc is 6.78%.
Device and operation and proportioning are same as embodiment four, only nickelous chloride are changed to Sodium orthomolybdate.Reacted 60 minutes, the transformation efficiency of zinc is 6.17%.
Embodiment 36
Device and operation and proportioning are same as embodiment four, only substitute nickelous chloride with manganous chloride, react 90 minutes, and the transformation efficiency of zinc is 2.71%.
Embodiment 37
Device and operation and proportioning are same as embodiment five, only change aluminum chloride into iron trichloride, react 50 minutes, and the transformation efficiency of iron reaches 37.02%.
Embodiment 38
Apparatus and the operation and the ratio of the same as the fifth embodiment, only the aluminum trichloride into Ami iron sulfate, 60 min, the conversion was 21.71% iron.
Embodiment 39
Device is identical with embodiment five with operation and proportioning, only aluminum chloride is changed to chromium trichloride, reacts 70 minutes, and the transformation efficiency of iron is 41.87%.
Device and operation and proportioning are same as embodiment five, only substitute aluminum chloride with Indium-111 chloride, react 60 minutes, and the transformation efficiency of iron is 37.68%.
Embodiment 41
Device and operation and proportioning are same as embodiment five, only change aluminum chloride into ammonium molybdate, react 90 minutes, and the transformation efficiency of iron is 7.89%.
Embodiment 42
Device and operation and proportioning are same as embodiment five, only replace aluminum chloride with Sodium orthomolybdate, react 90 minutes, and the transformation efficiency of iron is 7.55%.
Embodiment 43
Device and operation and proportioning are same as embodiment five, only aluminum chloride are changed to copper sulfate, react 60 minutes, and the transformation efficiency of iron is 17.88%.
Embodiment 44
Device and operation and proportioning are same as embodiment five, only aluminum chloride are changed to NSC 51149, react 70 minutes, and the transformation efficiency of iron is 10.07%.
Device and operation and proportioning are same as embodiment five, only aluminum chloride are changed to nickelous chloride, react 60 minutes, and the transformation efficiency of iron is 9.78%.
Embodiment 46
Device and operation and proportioning are same as embodiment five, only substitute aluminum chloride with zinc chloride, react 80 minutes, and the transformation efficiency of iron is 3.27%.
Embodiment 47
Get a glass there-necked flask that thermometer and electromagnetic agitation are housed, add the manganese powder (9.0 mM) of 0.5 gram purity 99.8% and the anhydrous indium chloride (2.5 mM) of 0.56 gram purity 98%, there-necked flask and atmospheric isolation; Open gas bottle and cut down door, under 30 ℃ of room temperatures, 50 milliliters of heavy water are added in the there-necked flask with liquid-feeding tube; Start stirring; Indium trichloride dissolves very soon, the bubble generation is arranged simultaneously and with temperature rise, maintain the temperature at 50 ℃; Reacted 180 minutes. capture the gas that generates, generate the composition and the content of gas with the analysis of look-matter coupling method (GC-MS). the conversion ratio of manganese reaches 47.85%.
Embodiment 48
Device and operation and proportioning are same as embodiment 47, only Indium-111 chloride are changed to iron trichloride, reacted 90 minutes,
The transformation efficiency of manganese is 43.75%.
Embodiment 49
Device and operation and proportioning are same as embodiment 48, only only change manganese powder into aluminium powder, react 9.0 minutes, and the transformation efficiency of aluminium is 17.88%.
Device and operation and proportioning are same as embodiment 49, only aluminium powder are changed to iron powder, and replace iron trichloride with aluminum chloride, react 180 minutes, and the transformation efficiency of iron is 14.75%.
Embodiment 51
Device and operation and proportioning are same as embodiment 50, only iron powder are changed into zinc powder and substitute aluminum chloride with nickelous chloride, react 90 minutes, and the zinc powder transformation efficiency is 7.98%.
Embodiment 52
Device and operation and proportioning are same as embodiment one, change deionized water into methyl alcohol, and temperature of reaction is 40 ℃, react 70 minutes, and the transformation efficiency of manganese reaches 57.85%.
Embodiment 53
The aluminium powder (20 mmole) of claiming 0.55 gram purity 98%; In there-necked flask, be dissolved in 70 milliliters of absolute ethyl alcohols; Loseing has bubble to produce. and 0.81 gram (5.0 mmole) iron trichloride is dissolved in 30 milliliters of absolute ethyl alcohols, and also loseing has bubble to generate. and under room temperature (30 ℃), both are mixed in the there-necked flask and stir, produce great amount of bubbles at once; Be mixed with temperature rise, temperature of reaction remains on 40 ℃.Capture the gas that generates with draining water gathering of gas law, with the composition of gas chromatographic analysis gas-phase product, hydrogen content is 94%. reactions 60 minutes, and the transformation efficiency of aluminium is 26.77%.
Embodiment 54
Device and operation and proportioning are same as embodiment four, only water are changed to butyleneglycol, react 90 minutes, and the transformation efficiency of zinc is 18.72%.
Embodiment 55
Device and operation and proportioning are same as embodiment five, only change water into terepthaloyl moietie, react 60 minutes, and the transformation efficiency of iron is 33.27%.
Claims (4)
1. the method for rich metal normal temperature water of decomposition or heavy water hydrogen manufacturing or deuterium is characterized in that: under the normal temperature, with A, three kinds of components of B and C stir in container according to the ratio of mol ratio A:B:C=1:50 ~ 10000:0.01 ~ 0.9 and make hydrogen or deuterium;
Wherein, A component: manganese, iron, aluminium, one of zinc or its two or more mixtures with arbitrary proportion;
B component: the alcohol that during hydrogen manufacturing is water or general formula R (OH) n; During the system deuterium is heavy water;
C component: catalyzer;
Said catalyst is two or more mixtures with arbitrary proportion among the salt of one of salt of following 15 metal ion species or said metal ion: copper, iron, tin, chromium, molybdenum, titanium, vanadium, niobium, nickel, cobalt, zirconium, manganese, zinc, indium, aluminium; Or sodium molybdate; Or ammonium molybdate.
(2) as claimed in claim 1, wherein the abundance of water or heavy metal temperature decomposition of hydrogen or deuterium, characterized in that: said catalyst is a metal salt anions include: sulfate, Ami sulfate, hydrochloric roots, hydrobromic root, hydrofluoric acid, chlorate, phosphate, sulfonate, oxalate, molybdate, phosphorus molybdate, phosphorus tungstate and nitrate.
3. the method for rich metal normal temperature water of decomposition as claimed in claim 1 or heavy water hydrogen manufacturing or deuterium is characterized in that: the alcohol of said general formula R (OH) n comprises: methyl alcohol, ethanol, n-propyl alcohol; Virahol, propyl carbinol, terepthaloyl moietie; Ucar 35, butyleneglycol, pinakon and tetramethylolmethane.
4. like the method for claim 1 or 2 or 3 described rich metal normal temperature water of decomposition or heavy water hydrogen manufacturing or deuterium, its characteristic is being done: A, and B, the compatibility of the system that three kinds of components of C are formed is selected to comprise: Mn/H2O/Fe3+; Mn/H2O/Al3+; Mn/H2O/Cr3+; Mn/H2O/In3+; Mn/H2O/Fe2+; Mn/H2O/Co2+; Mn/H2O/Ni2+; Mn/H2O/Cu2+; Mn/H2O/Zn2+; Mn/H2O/Mn2+; Mn/H2O/ (NH4) 2MoO4; Mn/H2O/Na2MoO4; Al/H2O/Fe3+; Al/H2O/Ni2+; Al/H2O/Na2MoO4; Al/H2O/Al3+; Al/H2O/Cr3+; Al/H2O/In3+; Al/H2O/Fe2+; Al/H2O/Co2+; Al/H2O/ (NH4) 2MoO4; Al/H2O/Cu2+; Al/H2O/Zn2+; Al/H2O/Mn2+; Zn/H2O/Ni2+; Zn/H2O/Cu2+; Zn/H2O/Co2+; Zn/H2O/Fe2+; Zn/H2O/In3+; Zn/H2O/Cr3+; Zn/H2O/Al3+; Zn/H2O/Fe3+; Zn/H2O/ (NH4) 2MoO4; Zn/H2O/Na2MoO4; Zn/H2O/Mn2+; Fe/H2O/Al3+; Fe/H2O/Fe2+; Fe/H2O/Fe3+; Fe/H2O/Cr3+; Fe/H2O/In3+; Fe/H2O/ (NH4) 2MoO4; Fe/H2O/Na2MoO4; Fe/H2O/Cu2+; Fe/H2O/Co2+; Fe/H2O/Ni2+; Fe/H2O/Zn2+; Mn/D2O/In3+; Mn/D2O/Fe3+; Al/D2O/Fe3+; Fe/D2O/Al3+; Zn/D2O/Ni2+; Mn/CH3OH/Fe3+; Al/C2H5OH/Fe3+; Zn/HOC4H8OH/Ni2+; Fe/HOC2H4OH/Al3+;
Wherein, Fe3+ represents ferric salt; Al3+ represents the salt of trivalent aluminium; Cr3+ represents chromic salt; In3+ represents the salt of trivalent indium; Fe2+ represents ferrous salt; Co2+ represents cobaltous salt; Ni2+ represents the salt of nickelous; Cu2+ represents cupric salt; Zn2+ represents the salt of divalent zinc; Mn2+ represents the salt of bivalent manganese.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110266145 CN102424358B (en) | 2011-09-09 | 2011-09-09 | Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110266145 CN102424358B (en) | 2011-09-09 | 2011-09-09 | Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102424358A true CN102424358A (en) | 2012-04-25 |
| CN102424358B CN102424358B (en) | 2013-06-12 |
Family
ID=45958402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110266145 Expired - Fee Related CN102424358B (en) | 2011-09-09 | 2011-09-09 | Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102424358B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109093129A (en) * | 2018-07-10 | 2018-12-28 | 氢电中科（广州）新能源设备有限公司 | A kind of the hydrogen manufacturing alloy and intelligent road-lamp of alumal dopen Nano Zero-valent Iron |
| WO2022160390A1 (en) * | 2021-01-27 | 2022-08-04 | 苏州大学 | Method for preparing deuterium gas and deuteration reaction using same as deuterium source |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117209A (en) * | 2007-07-11 | 2008-02-06 | 李达刚 | Method for preparing pure hydrogen or deuterium by metalloid near room-temperature water decomposition |
-
2011
- 2011-09-09 CN CN 201110266145 patent/CN102424358B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117209A (en) * | 2007-07-11 | 2008-02-06 | 李达刚 | Method for preparing pure hydrogen or deuterium by metalloid near room-temperature water decomposition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109093129A (en) * | 2018-07-10 | 2018-12-28 | 氢电中科（广州）新能源设备有限公司 | A kind of the hydrogen manufacturing alloy and intelligent road-lamp of alumal dopen Nano Zero-valent Iron |
| WO2022160390A1 (en) * | 2021-01-27 | 2022-08-04 | 苏州大学 | Method for preparing deuterium gas and deuteration reaction using same as deuterium source |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102424358B (en) | 2013-06-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105061776A (en) | Metal organic framework material of Fe porphyrin ligand, preparation method therefor and application thereof | |
| CN106669743B (en) | A kind of reforming hydrogen-production catalyst and preparation method thereof | |
| CN105498756B (en) | The catalyst of hydrogenation of carbon dioxide methanol | |
| CN103316691B (en) | Magnetic solid acid and preparation method thereof | |
| CN104787721A (en) | Hydrolysis hydrogen production agent | |
| CN103599790A (en) | Cobalt rare earth composite oxide catalyst for efficiently catalyzing complete oxidation of methane at low temperature | |
| CN109999878A (en) | For photo catalytic reduction CO2Nonmetal doping Co3O4-CeO2Composite catalyst and preparation method thereof | |
| CN102424358A (en) | Method for preparing hydrogen or deuterium by metal-rich normal-temperature water or heavy water decomposition | |
| CN103664192A (en) | Preparation method of pure-phase pyrochlore structure Ce2Zr2O7 | |
| CN103613483A (en) | Application of layered loading catalyst in preparation of lower alcohol by using synthesis gas | |
| CN113145113A (en) | Carbon dioxide hydrogenation catalyst, preparation method and application thereof | |
| CN108484383A (en) | A method of preparing hydroxyacetic acid compound | |
| CN108855158B (en) | Preparation method and application of cobalt-ruthenium bimetallic heterogeneous catalyst | |
| CN114229792B (en) | Method and device for preparing hydrogen by catalyzing hydrazine decomposition by nickel-iridium-based supported catalyst | |
| CN104355987B (en) | A kind of hydrogen peroxide catalytic oxidation prepares the method for octafluoro valeric acid | |
| CN102553408A (en) | Method and device for thermo chemolysis of CO2 and H2O based on reaction substance circulation | |
| CN103709204A (en) | Cobalt complex, preparation method and application thereof | |
| CN101822976A (en) | A kind of with combustion synthesis nanometer La 2O 3/ La 2O 2CO 3The method of composite | |
| CN104926596B (en) | A kind of method that micro passage reaction continuously prepares bromomethane | |
| CN101259415A (en) | Preparation of CO hydrogenation synthesizing low carbon mixed alcohol catalyst | |
| CN103480379A (en) | Method for preparing and synthetizing methanol catalyst from copper-based waste methanol catalyst recovered solution | |
| CN102151571B (en) | Catalyst for synthesizing ethylene diamine via dichloroethane method, preparation method thereof and method for synthesizing ethylene diamine by using same | |
| CN112657514A (en) | Photocatalyst filled with porous nano ZnS @ ZnO hollow spheres and preparation method thereof | |
| CN101406795A (en) | Aluminum oxide-base defluorination agent for nitrogen trifluoride anhydrous decomposition reaction and method of use thereof | |
| CN101380576B (en) | Catalyst for hydrogenolysis of rare glycerol to produce diatomic alcohol and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130612 Termination date: 20170909 |