CN102417767A - Organic-inorganic laminating coating for aluminum capacitor shell and preparation method thereof - Google Patents

Organic-inorganic laminating coating for aluminum capacitor shell and preparation method thereof Download PDF

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Publication number
CN102417767A
CN102417767A CN2011103297247A CN201110329724A CN102417767A CN 102417767 A CN102417767 A CN 102417767A CN 2011103297247 A CN2011103297247 A CN 2011103297247A CN 201110329724 A CN201110329724 A CN 201110329724A CN 102417767 A CN102417767 A CN 102417767A
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compsn
organic
stirrer
composition
inorganic
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CN2011103297247A
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CN102417767B (en
Inventor
孔祥新
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TONGLING XINTAI ELECTRIC APPARATUS AND CAPACITOR CO Ltd
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TONGLING XINTAI ELECTRIC APPARATUS AND CAPACITOR CO Ltd
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Priority to CN2011103297247A priority Critical patent/CN102417767B/en
Publication of CN102417767A publication Critical patent/CN102417767A/en
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Publication of CN102417767B publication Critical patent/CN102417767B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses an organic-inorganic laminating coating for an aluminum capacitor shell and a preparation method thereof. The organic-inorganic laminating coating is mainly obtained by mixing and stirring a composition A and a composition B in composition raw materials in part by weight, wherein the composition A consists of polyvinyl chloride resin, polyamide resin, ketone, sodium carbonate, nanometer carbon powder, ethyl acetate and attapulgite; and the composition B consists of an acrylic ester copolymer modifier, organosiloxane, sodium silicate and straw ash. The organic-inorganic laminating coating has a reasonable formula, a simple preparation method and a good curing effect on the aluminum capacitor shell; a capacitor is protected effectively; and the obtained laminating coating has heat resistance performance and wear resistance performance, and contributes to prolonging the service life of the capacitor.

Description

A kind of organic-inorganic capacitor aluminum housing coating paint and preparation method thereof
Technical field
The present invention relates to capacitor case and chemical compsn, be specifically related to a kind of organic-inorganic capacitor aluminum housing coating paint and preparation method thereof.
Background technology
Along with the electron trade development of technology; The manufacturing technology of electronic circuit board also has greatly improved; For the volume that dwindles electronic product consumes with reducing; Electrolytic condenser is as one of universal component on the electronic circuit board, and it is increasingly high not only its heatproof, anti-puncture being required, and to require its footprints also be more little good more.The electrolytic condenser footprints is little, at first is that aluminium shell of capacitor will have high length-to-diameter ratio, and electrical condenser diameter reduced dimension area is just little; Next is that capacitor case will have high air heat resistance; Otherwise, damages and reduction of service life easily in the sky of compactness in asking; Traditional aluminium shell of capacitor is that subpunch is processed shape, and one deck insulating material is sealed up in back pyrocondensation, and insulating material tightly is rolled on the capacitor case after heating.This its shortcoming of red shortness's plastic film electrical condenser is that the anti-AT of insulating material of heat-sealing is not high enough, in the process of heat-seal process, also can produce a lot of plastic film waste materials.The coating method that the disclosed a kind of insulation film on aluminum body of electrolytic capacitor of TaiWan, China Yabo Company is also arranged; Chinese invention patent application publication number CNl944704; This method mainly is to take 1000~20000 volts high potential gradient; Make gaseous ion bump ZX 21 tetrafluoroethylene (polytetrafluoroethylene), clash into fluorine atom, simultaneous oxidation generates fluorine oxide; Fluorine oxide promptly can produce powerful tackiness under high temperature action, and is deposited on the aluminum enclosure surface glutinous covering and forms the insulated hull rete of fluorine oxide.This method in fact only is the chloride secondary pollution of covering material that has reduced, and temperature tolerance is poor, the production cost problem of higher but exist.
Summary of the invention
For deficiency and the defective of alleviating prior art; The object of the present invention is to provide a kind of organic-inorganic capacitor aluminum housing coating paint and preparation method thereof; The present invention fills a prescription rationally, and the preparation method is simple, and solidification effect is good on aluminium shell of capacitor; Effectively carry out protective condenser, the coating paint that makes has the heat-resistant antifriction performance, has increased the work-ing life of electrical condenser.
The present invention adopts following technical scheme to achieve these goals:
The organic-inorganic capacitor aluminum housing coating paint; The weight part that it is characterized in that its constitutive material is: comprise compsn A and compsn B, described compsn A: PVC RESINS 40-50 part, polyamide resin 40-50 part, ketone 20-30 part, yellow soda ash 15-25 part, nano-carbon powder 15-25 part, ETHYLE ACETATE 20-30 part and attapulgite 10-15 part; Described compsn B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, organo-siloxane 5-10 part, water glass 5-10 part and stalk ashes 5-10 part.
The preparation method of described organic-inorganic capacitor aluminum housing coating paint is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; PVC RESINS, polyamide resin, ketone, yellow soda ash, nano-carbon powder, ETHYLE ACETATE and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, organo-siloxane, water glass and stalk ashes was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
Beneficial effect of the present invention:
The present invention fills a prescription rationally, and the preparation method is simple, and solidification effect is good on aluminium shell of capacitor, effectively carries out protective condenser, and the coating paint that makes has the heat-resistant antifriction performance, increased the work-ing life of electrical condenser.
Embodiment
Embodiment 1:The organic-inorganic capacitor aluminum housing coating paint; The weight part of its constitutive material is: comprise compsn A and compsn B, described compsn A: 10 parts of 40 parts of PVC RESINSs, 40 parts of polyamide resins, 20 parts of ketones, 15 parts in yellow soda ash, 15 parts of nano-carbon powders, 20 parts in ETHYLE ACETATE and attapulgites; Described compsn B: 5 parts in 20 parts of acrylic acid esters co-polymer properties-correcting agent, 5 parts of organo-siloxanes, 5 parts of water glass and stalk ashes.
The preparation method of organic-inorganic capacitor aluminum housing coating paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; PVC RESINS, polyamide resin, ketone, yellow soda ash, nano-carbon powder, ETHYLE ACETATE and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, organo-siloxane, water glass and stalk ashes was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull; Aluminum hull need use the hot water that adds NaOH to clean; NaOH concentration is 4-6%, clean the back place 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned organic-inorganic capacitor aluminum housing coating paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate; Then aluminium sheet is placed 210-220 ℃ environment curing down, solidified at least 1 minute.
Embodiment 2:The organic-inorganic capacitor aluminum housing coating paint; The weight part of its constitutive material is: comprise compsn A and compsn B, described compsn A: 15 parts of 50 parts of PVC RESINSs, 50 parts of polyamide resins, 30 parts of ketones, 25 parts in yellow soda ash, 25 parts of nano-carbon powders, 30 parts in ETHYLE ACETATE and attapulgites; Described compsn B: 10 parts in 30 parts of acrylic acid esters co-polymer properties-correcting agent, 10 parts of organo-siloxanes, 10 parts of water glass and stalk ashes.
The preparation method of organic-inorganic capacitor aluminum housing coating paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; PVC RESINS, polyamide resin, ketone, yellow soda ash, nano-carbon powder, ETHYLE ACETATE and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, organo-siloxane, water glass and stalk ashes was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull; Aluminum hull need use the hot water that adds NaOH to clean; NaOH concentration is 4-6%, clean the back place 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned organic-inorganic capacitor aluminum housing coating paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate; Then aluminium sheet is placed 210-220 ℃ environment curing down, solidified at least 1 minute.
Embodiment 3:Scribble the organic-inorganic capacitor aluminum housing coating paint of embodiment 1 and embodiment 2, the electrical condenser overlay film aluminum hull technical indicator that solidification value wherein, time and gained overlay film aluminum hull are processed is:
? Embodiment 1 Embodiment 2
Solidification value (℃) 203 212
Set time (s) 60 60
Require index Meet Meet
Length-to-diameter ratio 2.8:1 3.3:1

Claims (2)

1. organic-inorganic capacitor aluminum housing coating paint; The weight part that it is characterized in that its constitutive material is: comprise compsn A and compsn B, described compsn A: PVC RESINS 40-50 part, polyamide resin 40-50 part, ketone 20-30 part, yellow soda ash 15-25 part, nano-carbon powder 15-25 part, ETHYLE ACETATE 20-30 part and attapulgite 10-15 part; Described compsn B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, organo-siloxane 5-10 part, water glass 5-10 part and stalk ashes 5-10 part.
2. the preparation method of an organic-inorganic capacitor aluminum housing coating paint as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; PVC RESINS, polyamide resin, ketone, yellow soda ash, nano-carbon powder, ETHYLE ACETATE and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, organo-siloxane, water glass and stalk ashes was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
CN2011103297247A 2011-10-27 2011-10-27 Organic-inorganic laminating coating for aluminum capacitor shell and preparation method thereof Expired - Fee Related CN102417767B (en)

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Application Number Priority Date Filing Date Title
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CN102417767A true CN102417767A (en) 2012-04-18
CN102417767B CN102417767B (en) 2013-05-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497360A (en) * 2016-10-26 2017-03-15 安徽飞达电气科技有限公司 A kind of organic-inorganic aluminium shell of capacitor high-quality coating paint

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5039731A (en) * 1986-10-20 1991-08-13 Lord Corporation Metal coating compositions including linear polyester polyurethane
JP2006052295A (en) * 2004-08-11 2006-02-23 Kansai Paint Co Ltd Method for producing aqueous resin dispersion
CN1986711A (en) * 2006-12-12 2007-06-27 溧阳市溧竹环境工程有限公司 Acid-proof wear-proof anticorrosive paint and its preparing method
CN101550315A (en) * 2009-05-15 2009-10-07 泰州市四联化工有限公司 Black organic-silicon heat-resisting paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5039731A (en) * 1986-10-20 1991-08-13 Lord Corporation Metal coating compositions including linear polyester polyurethane
JP2006052295A (en) * 2004-08-11 2006-02-23 Kansai Paint Co Ltd Method for producing aqueous resin dispersion
CN1986711A (en) * 2006-12-12 2007-06-27 溧阳市溧竹环境工程有限公司 Acid-proof wear-proof anticorrosive paint and its preparing method
CN101550315A (en) * 2009-05-15 2009-10-07 泰州市四联化工有限公司 Black organic-silicon heat-resisting paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497360A (en) * 2016-10-26 2017-03-15 安徽飞达电气科技有限公司 A kind of organic-inorganic aluminium shell of capacitor high-quality coating paint

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