CN102367362B - Polyamide resin capacitor aluminium shell film mulching paint and its preparation method - Google Patents

Polyamide resin capacitor aluminium shell film mulching paint and its preparation method Download PDF

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Publication number
CN102367362B
CN102367362B CN2011103297105A CN201110329710A CN102367362B CN 102367362 B CN102367362 B CN 102367362B CN 2011103297105 A CN2011103297105 A CN 2011103297105A CN 201110329710 A CN201110329710 A CN 201110329710A CN 102367362 B CN102367362 B CN 102367362B
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China
Prior art keywords
composition
polyamide resin
paint
aluminium shell
film mulching
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Expired - Fee Related
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CN2011103297105A
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Chinese (zh)
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CN102367362A (en
Inventor
孔祥新
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TONGLING XINTAI ELECTRIC APPARATUS AND CAPACITOR CO Ltd
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TONGLING XINTAI ELECTRIC APPARATUS AND CAPACITOR CO Ltd
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Abstract

The invention discloses a polyamide resin capacitor aluminium shell film mulching paint and its preparation method. The polyamide resin capacitor aluminium shell film mulching paint is mainly prepared by mixing raw materials of a composition A and a composition B, wherein the composition A is composed of polyamide resin, ketone, polyethylene wax, nanometer powdered carbon, ethanol, glycerol and attapulgite; and the composition B is composed of an acrylic acid ester copolymer modifier, a silane coupling agent, graphite and tetramethylsilane. The formulation provided by the invention is reasonable and the preparation method is simple. The film mulching paint has a good curing effect on the capacitor aluminium shell and has heat-resistant and wear-resistant performance, and can be used to effectively protect the capacitor and increase the service life of the capacitor.

Description

A kind of polyamide resin capacitor aluminium shell film mulching paint and preparation method thereof
Technical field
The present invention relates to capacitor case and chemical composition, be specifically related to a kind of polyamide resin capacitor aluminium shell film mulching paint and preparation method thereof.
Background technology
Progress along with the electron trade technology, the manufacturing technology of electronic circuit board also has greatly improved, for volume and the reduction of dwindling electronic product consumes, electrolytic condenser is as one of universal component on the electronic circuit board, it is more and more higher not only its heatproof, anti-puncture being required, and to require its footprints also be the smaller the better.The electrolytic condenser footprints is little, at first is that aluminium shell of capacitor will have high length-to-diameter ratio, and electrical condenser diameter reduced dimension area is just little; Next is that capacitor case will have high air heat resistance, otherwise in asking, damages and reduction of service life easily in the sky of compactness, traditional aluminium shell of capacitor is that subpunch is made shape, and one deck insulating material is sealed up in rear pyrocondensation, and insulating material tightly is rolled on the capacitor case after heating.This its shortcoming of red shortness's plastic film electrical condenser is that the anti-air themperature of insulating material of heat-sealing is not high enough, also can produce a lot of plastic film waste materials in the process of heat-seal process.The coating method that the disclosed a kind of insulation film on aluminum body of electrolytic capacitor of TaiWan, China Yabo Company is also arranged, Chinese invention patent application publication number CNl944704, the method mainly is to take 1000~20000 volts high potential gradient, make gaseous ion bump teflon tetrafluoroethylene (polytetrafluoroethylene), clash into fluorine atom, simultaneous oxidation generates fluorine oxide, fluorine oxide namely can produce powerful tackiness under high temperature action, and is deposited on the aluminum enclosure surface glutinous covering and forms the insulated hull rete of fluorine oxide.This method in fact only is the chloride secondary pollution of covering material that has reduced, but exists the problem that temperature tolerance is poor, production cost is higher.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art; the object of the present invention is to provide a kind of polyamide resin capacitor aluminium shell film mulching paint and preparation method thereof; the present invention fills a prescription rationally; the preparation method is simple; solidification effect is good on aluminium shell of capacitor; effectively carry out protective condenser, the coating paint that makes has the heat-resistant antifriction performance, has increased the work-ing life of electrical condenser.
The present invention adopts following technical scheme to achieve these goals:
Polyamide resin capacitor aluminium shell film mulching paint, the weight part that it is characterized in that its constitutive material is: comprise composition A and composition B, described composition A: polyamide resin 60-70 part, ketone 20-30 part, polyethylene wax 5-10 part, nano-carbon powder 15-25 part, ethanol 5-15 part, glycerol 15-25 part and attapulgite 10-15 part; Described composition B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, silane coupling agent 5-10 part, Graphite Powder 99 5-10 part and tetramethylsilane 5-10 part.
The preparation method of described polyamide resin capacitor aluminium shell film mulching paint is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, glycerol and attapulgite are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition A, again acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and tetramethylsilane are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition B;
(2) composition A and composition B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
Beneficial effect of the present invention:
The present invention fills a prescription rationally, and the preparation method is simple, and solidification effect is good on aluminium shell of capacitor, effectively carries out protective condenser, and the coating paint that makes has the heat-resistant antifriction performance, increased the work-ing life of electrical condenser.
Embodiment
Embodiment 1:Polyamide resin capacitor aluminium shell film mulching paint, the weight part of its constitutive material is: comprise composition A and composition B, described composition A: 10 parts of 60 parts of polyamide resins, 20 parts of ketones, 5 parts of polyethylene waxs, 15 parts of nano-carbon powders, 5 parts of ethanol, 15 parts of glycerol and attapulgites; Described composition B: 5 parts of 20 parts of acrylic acid esters co-polymer properties-correcting agent, 5 parts of silane coupling agents, 5 parts of Graphite Powder 99s and tetramethylsilanes.
The preparation method of polyamide resin capacitor aluminium shell film mulching paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, glycerol and attapulgite are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition A, again acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and tetramethylsilane are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition B;
(2) composition A and composition B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull, aluminum hull need to clean with the hot water that adds NaOH, NaOH concentration is 4-6%, place after cleaning 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned polyamide resin capacitor aluminium shell film mulching paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate, then aluminium sheet is placed under 210-220 ℃ the environment and solidified, solidified at least 1 minute.
Embodiment 2:Polyamide resin capacitor aluminium shell film mulching paint, the weight part of its constitutive material is: comprise composition A and composition B, described composition A: 15 parts of 70 parts of polyamide resins, 30 parts of ketones, 10 parts of polyethylene waxs, 25 parts of nano-carbon powders, 15 parts of ethanol, 25 parts of glycerol and attapulgites; Described composition B: 10 parts of 30 parts of acrylic acid esters co-polymer properties-correcting agent, 10 parts of silane coupling agents, 10 parts of Graphite Powder 99s and tetramethylsilanes.
The preparation method of polyamide resin capacitor aluminium shell film mulching paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, glycerol and attapulgite are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition A, again acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and tetramethylsilane are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition B;
(2) composition A and composition B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull, aluminum hull need to clean with the hot water that adds NaOH, NaOH concentration is 4-6%, place after cleaning 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned polyamide resin capacitor aluminium shell film mulching paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate, then aluminium sheet is placed under 210-220 ℃ the environment and solidified, solidified at least 1 minute.
Embodiment 3:Scribble the polyamide resin capacitor aluminium shell film mulching paint of embodiment 1 and embodiment 2, the electrical condenser overlay film aluminum hull technical indicator that solidification value wherein, time and gained overlay film aluminum hull are made is:
? Embodiment 1 Embodiment 2
Solidification value (℃) 198 216
Set time (s) 60 60
Require index Meet Meet
Length-to-diameter ratio 2.6:1 3.2:1

Claims (2)

1. polyamide resin capacitor aluminium shell film mulching paint, the weight part that it is characterized in that its constitutive material is: composition A and composition B, described composition A: polyamide resin 60-70 part, ketone 20-30 part, polyethylene wax 5-10 part, nano-carbon powder 15-25 part, ethanol 5-15 part, glycerol 15-25 part and attapulgite 10-15 part; Described composition B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, silane coupling agent 5-10 part, Graphite Powder 99 5-10 part and tetramethylsilane 5-10 part.
2. the preparation method of a polyamide resin capacitor aluminium shell film mulching paint as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, glycerol and attapulgite are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition A, again acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and tetramethylsilane are added in the stirrer, stirred 30-45 minute under the normal temperature, mix and obtain composition B;
(2) composition A and composition B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
CN2011103297105A 2011-10-27 2011-10-27 Polyamide resin capacitor aluminium shell film mulching paint and its preparation method Expired - Fee Related CN102367362B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106543857A (en) * 2016-10-26 2017-03-29 安徽飞达电气科技有限公司 A kind of aluminium shell of capacitor heatproof coating paint
CN106634112A (en) * 2016-12-13 2017-05-10 宁国市大荣电器有限公司 Capacitor aluminum shell heat-resisting coating paint
CN108165068A (en) * 2017-11-24 2018-06-15 安徽江南泵阀有限公司 A kind of preparation process of the filler of chemical pump coating
CN113121770A (en) * 2019-12-31 2021-07-16 都江堰市天兴硅业有限责任公司 Polyamide 1.1, preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2242430A (en) * 1990-03-27 1991-10-02 Intevep Sa Anticorrosive coating composition
CN101358106A (en) * 2008-09-25 2009-02-04 武汉工程大学 Anti-icing nano composite paint and application

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6162568A (en) * 1984-09-03 1986-03-31 Nippon Paint Co Ltd Method of preventing steel material corrosion

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2242430A (en) * 1990-03-27 1991-10-02 Intevep Sa Anticorrosive coating composition
CN101358106A (en) * 2008-09-25 2009-02-04 武汉工程大学 Anti-icing nano composite paint and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP昭61-62568A 1986.03.31

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