CN102417337B - Polyurethane modified epoxy resin grouting material - Google Patents

Polyurethane modified epoxy resin grouting material Download PDF

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Publication number
CN102417337B
CN102417337B CN 201110270206 CN201110270206A CN102417337B CN 102417337 B CN102417337 B CN 102417337B CN 201110270206 CN201110270206 CN 201110270206 CN 201110270206 A CN201110270206 A CN 201110270206A CN 102417337 B CN102417337 B CN 102417337B
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Prior art keywords
epoxy resin
modified epoxy
grouting material
polyurethane modified
solid
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CN 201110270206
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CN102417337A (en
Inventor
王耀东
段勤
蔡卫民
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SHANGHAI BAOSAI BUILDING MATERIALS FACTORY
China Petroleum and Chemical Corp
Sinopec Ningbo Engineering Co Ltd
Sinopec Ningbo Technology Research Institute
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SHANGHAI BAOSAI BUILDING MATERIALS FACTORY
China Petroleum and Chemical Corp
Sinopec Ningbo Engineering Co Ltd
Sinopec Ningbo Technology Research Institute
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Priority to CN 201110270206 priority Critical patent/CN102417337B/en
Publication of CN102417337A publication Critical patent/CN102417337A/en
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Abstract

The invention relates to a polyurethane modified epoxy resin grouting material. The grouting material is characterized in that: the grouting material comprises an adhesive and a solid material according to a weight ratio of 1:4-8, wherein the solid material comprises coarse quartz sand, high aluminum cement, middle quartz sand, a pigment and fine quartz sand; and the adhesive comprises a polyurethane modified epoxy resin, a curing agent, an epoxy-based reactive diluent, a leveling agent, a defoamer and a dispersant. Compared with grouting materials prepared with the prior art, the polyurethane modified epoxy resin grouting material provided by the invention allows the toughness and the strength of the grouting material to be improved, the impact and the shock of mobile equipment to the base to be effectively reduced, the service life of the equipment and the base to be prolonged, better water resistance and oil resistance to be possessed and the cost to be reduced by about 50%.

Description

A kind of polyurethane modified epoxy resin grouting material
Technical field
The present invention relates to building material technical field, specifically refer to a kind of polyurethane modified epoxy resin grouting material.
Background technology
Along with the development of technology, the measure of precision of some moving equipment is more and more higher, and is also more and more higher to the requirement on basis, and especially the anti-seismic performance to the basis has proposed stricter requirement.For example use that the epoxy resin grouting material can effectively reduce the destruction of equipment vibrations to the basis between moving equipment and basis; simultaneously; because the epoxy resin grouting material is the chemical grouting material, it also has certain resistivity to acid-basicity, and equipment is played a very good protection.
But,, frangible during sharp pounding because the fragility of Resins, epoxy is big, to moving equipment more high-power and/or big speed, existing epoxy resin grouting material can not satisfy the more and more higher freedom from vibration and the requirement of shock resistance, and simultaneously, the cost of epoxy resin grouting material is also higher.Therefore, be badly in need of a kind of resistance to compression of exploitation and folding strength is higher and cost is low chemical grouting material, resonance that bridge is produced the destruction of travelling of vibrations that produced when avoiding moving equipment operation and vehicle to the basis.
Summary of the invention
Technical problem to be solved by this invention is that the present situation at prior art provides a kind of compressive resistance, shock resistance and freedom from vibration good polyurethane modified epoxy resin grouting material, to reach the purpose that improves polyurethane modified epoxy resin grouting material over-all properties.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: this polyurethane modified epoxy resin grouting material, and it is characterized in that comprising tackiness agent and solid-state material, tackiness agent: the weight ratio of solid-state material is 1: 4~8;
Wherein, the weight of described solid-state material consists of:
Figure BSA00000572877800011
The weight of described tackiness agent consists of:
Polyurethane modified epoxy resin 100%
Solidifying agent 40~50%
Epoxy group(ing) reactive thinner: 10%~18%
Flow agent: 1%~3%
Defoamer: 1%~3%
Dispersion agent: 1%~3%
Preferably, the preferred fluorine-carbon modified polypropylene esters of gallic acid of above-mentioned flow agent, 3777 types of for example Dutch Fu Ka company; 510 types that 660 types that the preferred Shanghai Resin Factory of described epoxy group(ing) reactive thinner produces or Yixing three wooden groups produce.
Described defoamer can be selected for use and contain silicon defoamer, 2722 types that for example Dutch Fu Ka company produces; The preferred high score subclass of described dispersion agent dispersion agent, for example Dutch Fu Ka company 4010 types.
The preferred low-expansion coefficient of described solidifying agent, low heat-generation system and the good solidifying agent of toughening effect, better, the C-1 type solidifying agent that can select for use Suzhou tannery to produce.
The preparation method of above-mentioned polyurethane modified epoxy resin grouting material, it is characterized in that comprising earlier described polyurethane modified epoxy resin and described solidifying agent poured in the agitation vat and mix, and then described solid-state material poured in the agitation vat, be stirred well to solid-state material and all soak into, promptly obtain polyurethane modified epoxy resin grouting material.
Compared with prior art, polyurethane modified epoxy resin grouting material provided by the present invention not only has epoxide group, has urethano and hydroxyl, phenolic group isoreactivity group simultaneously, gives the grouting material higher bonding strength and toughness; And the alicyclic ring ammonia and the polyetheramine that are adopted in the solidifying agent, the toughness and the intensity of grouting material have then further been improved, make the ultimate compression strength (28 days) of grouting material can reach 120MPa, folding strength (28 days) can reach about 32MPa, and the maximum compressive strength (28 days) of high-quality grouting material only is 110MPa in the prior art, maximum folding strength (28 days) only is about 25MPa, has effectively reduced impact and the vibrations of moving equipment to the basis, has prolonged the work-ing life on equipment and basis; Simultaneously, because polyurethane modified epoxy resin has the dual performance of Resins, epoxy and urethane simultaneously, so have better water tolerance and oil-proofness; Compare with the epoxy resin grouting material, its cost has reduced about 50%.The present invention is particularly suitable for the technical formula of dry mortar.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Prepare solid-state material by following weight ratio:
The thick quartz sand 50% of 4~6 orders
High-alumina cement: 3%
Quartz sand 25% in 70~100 orders
Pigment: 2%
400~600 order fine quartz sands 20%
Above-mentioned pigment can be selected shades of colour as required for use, uses primary colors can not add pigment.
Prepare tackiness agent by following weight ratio:
Polyurethane modified epoxy resin: 100%
The C-1 type that solidifying agent 45% Hunan supernatural power bell Manufacturing Co., Ltd produces
660 types that epoxy group(ing) thinner 14% Shanghai Resin Factory produces
3777 of the Dutch Fu Ka of flow agent 2% company
The Dutch Fu Ka of defoamer 2% company 2722 types
The Dutch Fu Ka of dispersion agent 2% company 4010 types
The SK190 that above-mentioned polyurethane modified epoxy resin adopts Hunan supernatural power bell Manufacturing Co., Ltd to produce.
Above-mentioned solidifying agent can also adopt the low coefficient of expansion, low heat-generation system, other products that toughening effect is good.
The material of forming tackiness agent is poured in the agitation vat, with 550rpm stir about 3 minutes,, obtained tackiness agent to mixing with portable agitator.In agitation vat, pour solid-state material then into,, solid-state material is all soaked into, promptly obtain polyurethane modified epoxy resin grouting material with 550rpm stir about 6 minutes.
The performance perameter of this polyurethane modified epoxy resin grouting material is as shown in table 1.
Table 1
Figure BSA00000572877800031
Table 2 has been listed the performance perameter of grouting material in the prior art.
Table 2
Figure BSA00000572877800041

Claims (5)

1. a polyurethane modified epoxy resin grouting expects that it is characterized in that forming tackiness agent by tackiness agent and solid-state material: the weight ratio of solid-state material is 1: 4~8;
Wherein, the weight of described solid-state material consists of:
Figure FSB00001087090200011
The weight of described tackiness agent consists of:
2. polyurethane modified epoxy resin grouting material according to claim 1 is characterized in that described flow agent is fluorine-carbon modified polypropylene esters of gallic acid flow agent.
3. polyurethane modified epoxy resin grouting material according to claim 1 is characterized in that described defoamer is for containing silicon defoamer.
4. polyurethane modified epoxy resin grouting material according to claim 1 is characterized in that described dispersion agent is a high score subclass dispersion agent.
5. the preparation method of a polyurethane modified epoxy resin as claimed in claim 1 grouting material, it is characterized in that comprising that the material that will form described tackiness agent is earlier poured in the agitation vat mixes, and then described solid-state material poured in the agitation vat, be stirred well to solid-state material and all soak into, promptly obtain polyurethane modified epoxy resin grouting material.
CN 201110270206 2011-09-02 2011-09-02 Polyurethane modified epoxy resin grouting material Active CN102417337B (en)

Priority Applications (1)

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CN102417337B true CN102417337B (en) 2013-07-31

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103145375B (en) * 2012-12-17 2015-02-25 刘占峰 High-strength moisture curing epoxy resin grouting material and preparation method
CN103554843B (en) * 2013-10-14 2016-05-11 北京联合荣大建材有限公司 Track is filled, preparation and the construction method of epoxy grouting material for back-grouting
CN105350564B (en) * 2015-12-07 2017-09-01 湖南皓诺工程有限公司 A kind of adhesive structure and construction method of blower foundation steel loop and concrete
CN105645834B (en) * 2015-12-30 2017-07-18 福建江夏学院 It is a kind of for additive of concrete toughness reinforcing and preparation method thereof
CN105541202B (en) * 2015-12-30 2017-06-23 福建省东霖建设工程有限公司 A kind of Grouting Cement mortar of composite toughening and preparation method thereof
CN105621990B (en) * 2015-12-30 2017-07-18 福建省东霖建设工程有限公司 A kind of high tenacity cracking resistance Grouting Cement mortar and preparation method thereof
CN106366995A (en) * 2016-08-30 2017-02-01 张为凤 High-elasticity high-heat-dissipation adhesive
CN106318303A (en) * 2016-08-30 2017-01-11 张为凤 Method for preparing silica gel modified adhesive
CN107721309A (en) * 2017-10-25 2018-02-23 中科院广州化灌工程有限公司 Aqueous polyurethane epoxy interpenetrating networks superfine cement composite grouting material and preparation method and application
CN111234172A (en) * 2020-01-17 2020-06-05 阳泉煤业(集团)有限责任公司 Epoxy resin/water glass/polyurethane composite reinforced material and preparation method thereof

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CN101423358A (en) * 2008-11-20 2009-05-06 同济大学 Method for preparing high impact resistant epoxy resin mortar
CN101684041A (en) * 2009-08-07 2010-03-31 宜昌鹏搏镁橄榄石有限公司 Forsterite grouting material

Patent Citations (2)

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CN101423358A (en) * 2008-11-20 2009-05-06 同济大学 Method for preparing high impact resistant epoxy resin mortar
CN101684041A (en) * 2009-08-07 2010-03-31 宜昌鹏搏镁橄榄石有限公司 Forsterite grouting material

Non-Patent Citations (2)

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Address after: 100728 Beijing, Chaoyangmen, North Street, No. 22, No.

Applicant after: Sinopec Corp.

Applicant after: SINOPEC Ningbo Engineering Company Limited

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