CN102406549A

CN102406549A - Device and method for efficiently producing stable ozone (O3) ointment

Info

Publication number: CN102406549A
Application number: CN2011102650496A
Authority: CN
Inventors: 范书振; 王云鹏
Original assignee: 李明利
Priority date: 2011-09-08
Filing date: 2011-09-08
Publication date: 2012-04-11

Abstract

The invention relates to a production process for efficiently transforming vegetable oil (such as olive oil, coconut oil, sunflower seed oil and the like) into stable ointment containing ozone (O3). In the production process, two-stage reaction kettles in series connection and a residual gas recovery technology are adopted and the temperature of the reaction kettles can be controlled so that efficiency and O3 utilization ratio are improved and stability of O3 oil is strengthened. The production process can be used for producing the stable O3 ointment in large quantity; and the obtained O3 ointment can be applied to treatment of skin diseases and skin beauty and has good sterilizing effect.

Description

A kind ofly efficiently produce stable ozone (O 3) ointment process units and method

Technical field

The present invention relates to a kind of will (like olive oil, Oleum Cocois, the sunflower seed wet goods) effective conversion is the production process of stable ozone ointment.Use through the series connection of two-stage reaction still, reactor temperature is controlled at 15 ℃ times and the residual air recovery technology has improved efficient, and the present invention can produce stable ozone (O in batches ₃) ointment, be used for the treatment of dermatosis and the beauty treatment of skin.The ozone ointment has the good sterilization effect.

Background technology

Ozone (O ₃) be a kind of gas with hyperoxia voltinism, be widely used in the multiple application demands such as sterilization, bleaching, antibacterial, deodorization, water treatment.In the medical domain; Ozone have good bactericidal effect, induce and regulate the immunologic mechanism effect because of it and also have no side effect, safe noresidue, in multiple diseases such as treatment dermatosis, acne, decubital ulcer, various organ inflammation, have a very wide range of applications [1-6].But ozone gas itself is extremely unstable, is very easy to resolve into common oxygen, therefore is difficult to store and transportation.Make that the patient uses very inconvenience of ozone therapy at home, have to hospital treatment or the expensive ozone generation device of purchase.Treat the patient of inner inflammation (such as gastritis) for needs, can't oneself operate especially.The appearance of ozone carburetion has solved this problem, and when temperature was lower than 15 ℃, the ozone carburetion can be kept at ozone wherein and surpass 10 years, and when temperature surpassed 25 ℃, ozone then can discharge [7] in the ozone oil, very convenient storage and application [1].Ozonisation vegetable oil pure natural, have no side effect, do not have hazard residue, but external also can take orally, very convenient treatment is used.As far back as 1890, Nikola Tesla just pushed the medical ozone olive oil to market.He is blown into ozone gas to make the ozonisation olive oil with the time in 8 weeks in olive oil under the action of a magnetic field.1904 ozonisation olive oil have begun in medical literature, to occur [8].And nearest report has also been affirmed the outstanding curative effect [9,10] of ozone carburetion.

But making the ozone carburetion is a process more slowly, and document is mentioned in [7], generally makes the ozonisation oil require time in about 3 weeks, and according to the difference of the ozonator that uses, this time is also different.Manufacture method generally is exactly directly ozone gas to be imported vegetable oil (like the Fructus Canarii albi wet goods) with conduit to react, and can intuitively be referred to as bubbling method [7,11].This mode is produced the ozone carburetion, and gas and vegetable oil contact area are little, and gas can't effectively react with vegetable oil, responseless ozone pollution air, and also making also can reduce production efficiency under the room temperature.

The present invention provides a kind of equipment and method of fast effective production ozonisation ointment.Through the appropriate design layout, increase contact area and the time of gas with vegetable oil, increase response speed.Use agitating device and the series connection of two-stage reaction still at a slow speed, make ozone gas in motor process, effectively contact and reaction take place, efficiently utilize ozone gas with vegetable oil.Simultaneously, the control temperature of reaction kettle makes the Direction of Reaction carry out to the direction that helps the generation of ozone carburetion at low temperature state, prevents that the ozone oil that has generated from discharging gas, raises the efficiency.At last, use vent gas treatment and retracting device, eliminate residual ozone, and can carry out recycle to residual air, practice thrift cost, the protection environment guarantees that producers' is healthy and safe.Use equipment provided by the invention and method, can effectively improve input-output ratio, effectively improve speed of production, can efficiently in batches produce the ozone ointment fast.

List of references:

1, " three oxygen composite treatments treatment pressure ulcer ", Luo Qihua etc., the nursing magazine, Vol.25 (2), p.47,2010

2, " the colpitic clinical observation of ozone therapy ", Li Xiaoqing, China and foreign countries' medical treatment, Vol.30, p.41,2010

3, " the CT guiding is the ozone therapy prolapse of lumbar intervertebral disc down ", Zhang Zhicai etc., Chinese minimally invasive surgery magazine, Vol.10 (9), p.802,2010

4, " the B ultrasonic guiding is triple therapy treatment knee joint osseous arthritis observation of curative effect down " once resolved, the new traditional Chinese medical science, and Vol.42 (7), p.95,2010

5, " effect observation of ozone therapy dermatomycosis ", Ling Zhixiong etc., Guangdong Medical College's journal, Vol.25 (4), p.437,2007

6, " ozone associating adefovir ester capsule for treating hepatitis B observation of curative effect ", it is quick to pacify the good etc., China's Contemporary medicine, Vol.16 (4), p.13,2009

7, " Wound Care Treatment Product ", Vandeputte; Jan; (Varsenare, BE), the novel patent of u. s. utility, 20090291122,2007

8、″The?Medical?Uses?of?Hydrozone?and?Glycozone″，9th?Edition，by?New?York?Chemist?Charles?Marchland.

Summary of the invention

The object of the invention is exactly can only use small-sized medical ozone generator to what prior art existed; Produce the ozone ointment on a small quantity; And the time is long, and ozone content is unstable, the defective that ozone and oxygen utilization rate are low; The apparatus and method that provide a kind of ozone ointment to produce in batches can efficiently be produced stable ozone (O ₃) ointment.Make the ozone content of ozone ointment stable, improved ozone and oxygen utilization rate.

Its technical scheme is: the series connection of two-stage reaction still, divide one, two (front and back) two-stage.The responseless ozone of one-level gets into the second level and utilizes.Back level residual air reclaims again, and the control of course of reaction temperature strengthens the oily degree of stability of ozone.Increase low-speed agitator, make ozone oil uniformity.The present invention has the efficient height compared with prior art, and is energy-conservation, pollution-free, the advantage that ozone ointment degree of stability is high.

Description of drawings

As shown in Figure 11 is oilless air compressor, the 2nd, and air cooling driers, the 3rd, molecular sieve pressure swing adsorption oxygen, 4 check valves, the 5th, air pump, the 6th, effusion meter, the 7th, ball valve, the 8th, check valve; The 9th, ozonator, the 10th, check valve, 11,12,13,14,15,16; 17,18,21,22,23, be duty conversion valve (ball valve), 19,20; Be agitator motor, 24 is agitated reactors, and 25 is No. two agitated reactors, the 26th, and ozone eliminator, 27 relief valve, 28 gasbag-type air accumulators, 29 cooling water tanks, 30 cooling water pumps.

Fig. 1 is the sketch map of an embodiment of the present invention;

Fig. 2 is that an agitated reactor is the working reaction still, the beginning exhaust phase flow graph that No. two agitated reactors are the absorption reaction still.

Fig. 3 is that No. two agitated reactors are the working reaction still, the beginning exhaust phase flow graph that agitated reactor is the absorption reaction still.

Shown in Figure 4 is that an agitated reactor is the working reaction still, the Gas Recovery stage flow graph that No. two agitated reactors are the absorption reaction still.

Fig. 5 is that No. two agitated reactors are the working reaction still, the Gas Recovery stage flow graph that agitated reactor is the absorption reaction still.

The specific embodiment

With reference to Fig. 1, a kind ofly efficiently produce stable ozone (O ₃) ointment process units and method.

One: close

duty conversion valve

12,17,18,23,14, open

duty conversion valve

11,13,15,16,21, vegetable oil (like olive oil, Oleum Cocois, sunflower seed wet goods) is added an agitated reactor and No. two agitated reactors respectively.Open venting valve 22, start cooling water pump 21.

Two: open the air cooling driers after 10 minutes, open oilless air compressor 1, air pump 5 and ozonator 9,

agitator motor

19,20, (duty is seen Fig. 2)

After three: 20 minutes, open ball valve 7, close venting valve 22.(duty is seen Fig. 4)

Four: venting valve 22 is closed back residual air through oxygen recovery check valve 8, is recovered in the gasbag-type air accumulator 28.

Five: the start-stop of controlling oilless air compressor according to the pressure of gasbag-type air accumulator.

Six: the vegetable oil pH value 4-5 in agitated reactor, ozone content reaches 8%, and producing finishes emits through conversion valve 12, again to an agitated reactor charging.

Seven: through closing

duty conversion valve

11,12,17,15,21, open

duty conversion valve

13,14,16,18,23, the exchange of ozone turnover gas circuit makes ozone be introduced into No. two agitated reactors and reacts.Getting into an agitated reactor again absorbs.Initial state after the exchange is seen Fig. 3.Duty is seen Fig. 5.(the exchange back is because No. two agitated reactor implants oil have absorbed certain ozone, and the working time will be less than preceding batch.)

Eight: comprehensively above-mentioned: like Fig. 2; Fig. 3 is 20 fens clock times of beginning; Carrying out aerofluxus makes in the agitated reactor (oxygen+ozone) content greater than after 80%; Convert to like Fig. 4, the hermetically sealed mode of operation of entering shown in Figure 5 no longer discharged ozone and oxygen in up to a hundred hours afterwards to the production process of hundreds of hour.

Claims

1. efficiently produce stable ozone (O for one kind ₃) ointment process units and method comprise: use through the series connection of two-stage reaction still, temperature of reaction kettle control and residual air recovery technology add high-concentrated ozone and carry out aeration, and stable (O is produced in slow-speed of revolution stirring ₃) the ozone ointment.

2. two-stage reaction temperature in the kettle according to claim 1 is controlled under 15 ℃.

According to the said adding oxygen purity of claim 1 greater than 90%.

According to the said adding ozone concentration of claim 1 greater than 50mg/L.

5. agitator speed 5-15 cycle per minute clock in the two-stage reaction still according to claim 1.

6. (oxygen+ozone) content reclaimed greater than 80% o'clock in level (the absorption still after the conversion) agitated reactor of back according to claim 1.

7. agitated reactor pop off valve controlled pressure according to claim 1 is 1kg/cm2.

8. gasbag-type air accumulator pressure according to claim 1 is less than 0.5kg/cm2.

9. ozone according to claim 1 carried out aeration 180---300 hour, and the vegetable oil in the first order reaction still becomes paste, and paste vegetable oil pH value is less than or equal to 5.

10. vegetable oil addition according to claim 1 (volume) should be less than 60% of reactor volume.