CN102398894A - Preparation of deuterium-depleted water, and application thereof - Google Patents
Preparation of deuterium-depleted water, and application thereof Download PDFInfo
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Abstract
The invention relates to an apparatus system, wherein water electrolysis, hydrogen-oxygen recombination and a rectification technology are combined into the integration by the apparatus system, and deuterium-containing water in purified water and protium-containing water in purified water are separated by using the apparatus system. With adopting the apparatus system, the main protium-containing water can be effectively separated from the purified water, and the deuterium-containing water content in the purified water can be reduced to less than 100 ppm from 150 ppm after the separation. According to the present invention, the prepared deuterium-depleted water can be adopted for preparation of deuterium-depleted water wine, deuterium-depleted water beverages, deuterium-depleted water cosmetics and deuterium-depleted water physiological saline.
Description
Technical field
The present invention relates to the distribution of hydrogen isotopes in the rectifying tower different temperature fields in the compound and water of electrolysis, hydrogen-oxygen of water, belong to isotopic chemical separation field.
Background technology
Separating of light-water and heavy water is the separation of hydrogen isotopes after all, and wherein mainly is separating of protium and deuterium.As far back as nineteen sixty-eight USP 3411884 just adopted a kind of two warm hydrogen sulfide method to come the separation of hydrogen isotropic substance; It is that water and hydrogen sulfide are carried out convection current under catalyst action; Utilize the partition ratio of hydrogen isotopes between liquid and vapor capacity to change with variation of temperature; Realize containing the enrichment of deuterium hydrate in liquid phase, reach isolating effect.04035475 pair of this technology of USP in 1977 expands, and has improved certain efficiency, this technology to today also in extensive utilization.
Electrolytic process is to separate protium deuterium tritium one of effective means the most at present in the world, mainly contains alkaline electrolytic bath and solid polymer electrolyte (SPE) electrolyzer.People have carried out more research [Matsushima H, Nohira T, ItoY.Electrochim Acta [J], 2004,49 (24): 4181] to alkaline electrolytic bath separation of hydrogen isotropic substance.USP 04225402 in 1980 has proposed a kind of combined electrolysis-catalytic exchange technology and has extracted heavy water; It is that the hydrogen that water and electrolysis and non-electrolysis produce is exchanged; Deuterium enriched in liquid phase water with in the hydrogen; Again this water is carried out electrolysis and produce hydrogen, multistage cyclic electrolysis and exchange are able to concentrate heavy water.
SPE water electrolysis technology adopts PEM to substitute traditional alkaline water electrolytic matter and asbestos diaphragm; The more traditional alkaline electrolytic bath of its electrolyzer has that volume is littler, current density and advantage such as electrolytic efficiency is higher, gas purity is higher, longer service life, system process are also simpler, thereby has obtained increasing application [Cristescu I, Cristescu I-R in the electrolyzer in modern times; D.L; GluglaM, Murdoch D, Welte S.Fusion Eng andDesign [J]; 2006,81 (1-7): 839].
Except the method enrichment deuterium that adopts chemistry, aspect concentrated heavy water, also has the method for some physics; For example USP 5084181 has just adopted a kind of half to pass through the hydrophobic membrane diffusion process, according to the difference of light-water and heavy water spread coefficient in film, under certain temperature and pressure; Let light-water see through semi-permeable membranes; And the velocity of diffusion of heavy water is slower, and the amount that sees through is few, has so just to a certain degree concentrated heavy water.Other can also utilize difference of specific gravity, the heat content difference of light-water and heavy water to wait to separate heavy water.
Generally speaking, separating of light-water and heavy water perhaps mainly is separating of protium and deuterium, utilizes the difference of the physicochemical property between them exactly, mainly is the difference of kinetics aspect, realizes under suitable condition.But problems such as current all technologies all exist cost high, and separation factor is little, so these technology are all in constantly improving.Up to now, the technology that also is difficult to see is efficiently come directly from common pure water or deionized water, to obtain low deuterium-oxide or is claimed depleted water, and obtains another by product, and promptly higher concentration contains deuterium-oxide.
The present invention is directed to this target, designed a covering device, realize separating continuously of low deuterium-oxide and high deuterium-oxide, this device has much lower relatively energy consumption simultaneously.
In low deuterium-oxide application facet, formed some patents now, like low deuterium-oxide soymilk (Chinese patent CN101589787A), low-deuterium biscuit (Chinese patent CN101589732A), low deuterium shampoo (CN101589998A), low deuterium-oxide wine (CN101348757A) etc.This is because the special efficacy of low deuterium-oxide determines; Result of study according to extensively and profoundly shows, and though in the water content of deuterium what, all be deleterious to life entity; Deuterium damage dna, repair enzyme and even whole health, high-load deuterium has detrimentally affect to heredity, metabolism and the enzyme system etc. of human body.And viable organism has no defensive ability/resistance ability to deuterium, just is difficult to metabolism in the life entity and goes out in case get into.Low deuterium-oxide (or title " depleted water ") has active effect to organism metabolism, cells multiply, and is good for health and long-lived, therefore also is called as in " life holy water ".The present invention utilizes resulting low deuterium-oxide, has also developed a lot of purposes in fields such as wine, beverage, makeup, medical salines.
Summary of the invention
The present invention is through adopting devices such as electrolysis-recombiner, rectifying tower, with the deionized water electrolysis, hydrogen-oxygen is carried out compound again, utilizes rectifying tower that high deuterium-oxide is partly separated simultaneously.Owing to made full use of the electric energy of the compound generation of hydrogen-oxygen, also waste heat to be generated electricity simultaneously, therefore whole energy consumption significantly reduces.The structure of total system is also more simplified than other electrolysis and exchange system.
In the present invention, physics and the difference of chemical property aspect between hydrogen isotopes protium and the deuterium have been made full use of.
In electrolysis and recombination process, because the weight of protium element has only the half the of deuterium, so protium has higher activity than deuterium on kinetics.When the ion-exchange membrane that adopts in the electrolysis system was PEM, on the anode catalyst surface, protium element water was preferentially by electrolysis, and the protium proton arrives negative electrode through PEM.In addition, protium in film translational speed also much larger than the speed of deuterium, arrive anode simultaneously after; Protium also can reduce than deuterium more easily; Overall effect is exactly that deuterium element water is left on anode more, and the more protium of its initial proportion is by electrolytic reduction relatively, so-called isotopic effect that Here it is.The hydrogen that arrives negative electrode after the electrolysis generates target water with oxygen generation electrochemical reaction again, promptly low deuterium-oxide, and the electric energy that produces therebetween then is used.When electrolysis system was the alkali ion membrane electrode, then water was decomposed at negative electrode, releasing hydrogen gas, and hydroxide ion arrives anode through film, emits oxygen, the compound again target water that obtains of hydrogen and oxygen.The present invention with compound associating, makes electrolysis-recombiner with electrolysis.In such recombiner; Input is water with output; Just the glassware for drinking water of output has lower deuterium content, in addition, owing to can the electric energy of the compound generation of hydrogen-oxygen be used; So the better simply electrolytic process of the energy that whole process consumed has lacked near half the, thereby production cost greatly descends.
At the anode export of electrolysis-recombiner, insert a rectifying tower, the oxygen that comes out from anode and not the intact water of electrolysis get into rectifying tower through a vacuum breaker.In rectifying tower, be filled with solid and/or liquid catalyst; Effect by means of catalyzer; The water that in rectifying tower, rises is gentle will to carry out energy with the water that descends and exchange with element, and whole structure is a light element as containing the liter waterborne of protium and 16 oxygen, and contains falling of deuterium and 18 oxygen under water.Because the temperature contrast of rectifier and bottom, this separation trend is strengthened.Like this, the water of higher deuterium content flows out through the rectifying tower lower end relatively, and the water of low deuterium concentration then gets into the heat exchanger that connects with it with oxygen.
Heat exchanger will cool off from water and the oxygen that rectifying tower comes out, and the water that the while heat make-up is come in makes that like this energy is used effectively.Water and the oxygen that gets off that is cooled gets into vapour liquid separator, and water is retained, and oxygen then is discharged from.The water that remains gets into electrolysis-recombiner through adapting pipe again, accepts electrolysis.In addition, the oxygen that anode is discharged also gets into electrolysis-recombiner through another pipeline, and to carry out electrochemistry compound with hydrogen.
When this process was constantly carried out, low deuterium-oxide just constantly flowed out from electrolysis-recombiner, and high deuterium-oxide then constantly flows out from the rectifying tower lower end, has so just realized that protium and the continuous of deuterium separate, and has obtained required low deuterium-oxide, and high deuterium-oxide is then as by product.
When a plurality of such electrolysis-recombiner units are united a time-out; For example; First unit is decomposed the high deuterium-oxide that obtains import next electrolysis-recombiner unit, high deuterium-oxide is accepted further electrolysis, so just can further concentrate; Obtain the deuterium-oxide that contains of greater concn, the deuterium-oxide that contains of the low concentration that comes out from this unit then returns upper level electrolysis-recombiner unit.Like this, when obtaining low deuterium-oxide, also can obtain the deuterium-oxide that contains of high density.After electrolysis recombination process was each time accomplished, if resulting high deuterium-oxide concentration doubles, and initial heavy water concentration was made as 150ppm, then through 12 times concentrated after, the concentration of high deuterium-oxide will reach near 61%.And, then only need can reach same deuterium concentration 6 times if electrolysis recombination process deuterium-oxide concentration improves 4 times each time.
At each electrolysis-recombiner unit, owing to enter and what come out all is water, most consumption all become heat energy and mechanical energy, and this mainly is that consumption by system's internal resistance and utility appliance causes.And available energy is to be used for ability with deuterium-oxide and protium water sepn, and it equals to contain deuterium-oxide and the mixing energy that contains protium water, and this energy can be ignored with respect to chemical energy basically.Therefore, the utilization of heat energy has determined the level of overall power consumption.In order to make full use of energy, introducing a cogeneration machine is a well selection.When taking appropriate methods to reduce, estimate that the capacity usage ratio more than 90% can reach to energy that environment distributes as far as possible.Like this, the energy expenditure of unit product can drop to very low stage, and under the ideal situation, this energy consumption is equivalent to containing deuterium-oxide and containing the mixing energy of emitting when protium water mixes.In fact because various auxiliary elements such as pump, computer, motor etc. all need consumed energy, the also heat radiation of oriented environment etc. should be an efficient system so can reach the system of the capacity usage ratio more than 90%.
In system's operational process, in order to keep stable, need monitor and control, when occurring to report to the police, cut off operation, securing system timely when unusual to the temperature of each parts, pressure, liquid level, voltage and current etc.So just need to introduce relevant equipment,, when adopting appropriate control software and disposing appropriate hardware, can carry out visualized operation the operation of total system like computerized control system.
After low deuterium-oxide is produced, can blend with grain wine and brewage, make low deuterium-oxide wine, as described in the low deuterium-oxide wine (CN101348757A) of patent, the deuterium oxide content of this wine is lower than 135ppm; Also can make grape wine according to Wine-making technique, make low deuterium-oxide wine, the deuterium oxide content of this wine is lower than 140ppm; Also can mix with various essential oils hanging down deuterium-oxide, make the low deuterium-oxide makeup of different flavor, the deuterium oxide content of these makeup is lower than 140ppm, and essential oil content is greater than 1ppm, less than 99.5%; Perhaps this low deuterium-oxide is made low deuterium-oxide saline water according to the ME of medical saline, the deuterium oxide content of gained saline water is lower than 140ppm; Also can this low deuterium-oxide be cooperated with various fruit according to beverage production process and make beverage corresponding, the deuterium oxide content of this beverage is lower than 140ppm.Generally speaking, all relate to the product of water now, and like various beverages, skin care item, makeup, plaster, medical injection agent, common tap water, wine or the like, all available low deuterium-oxide substitutes, and the product after substituting all can produce the effect more useful to human body.
Description of drawings:
Fig. 1: protium deuterium-oxide separating unit system, among the figure: 1, rectifying tower, 2, heat exchanger, 3, vapour liquid separator; 4, electrolysis-recombiner, 5, high deuterium-oxide container, 6, vapour liquid separator, 7, low deuterium-oxide hopper; 8, deionized water inlet, 9, computer control system, 10, the cogeneration machine, 11, liquor pump; 12, gas pump, 13, vacuum breaker, 14, electrolysis power, 15, switch-valve.
Fig. 2 is SPE combined electrolysis technology of the present invention and the contrast of common SPE electrolysis process energy consumption.1 is SPE combined electrolysis technology of the present invention among the figure, and 2 is common SPE electrolysis process.
Fig. 1 is a kind of combination water electrolysis provided by the invention and hydrogen-oxygen is compound and rectifying is the water separating system unit of one; Total water separating system can be made up of a plurality of such unit, and each grade unit all comprises like lower member: hopper, rectifying tower, vapour liquid separator, heat exchanger, electrolysis-recombiner, vacuum breaker, switch-valve, computer control center, electrolysis power, cogeneration machine, water pump, heat pump, connecting tube.In system's operational process, by water pump deionized water is injected electrolysis-recombiner, carry out electrolysis, and with the hydrogen of generation and the water of the low deuterium content of the compound generation of oxygen, promptly low deuterium-oxide is also claimed depleted water.Oxygen that electrolysis produces and surplus water get into rectifying tower; Part water and oxygen get into vapour liquid separator recycling through rectifier and get into electrolysis-recombiner; The water of the high deuterium content of another part flows out through the rectifying tower bottom, thereby realizes separating of low deuterium-oxide and high deuterium-oxide.When system comprised a plurality of unit, each unit can a shared computerized control system, cogeneration machine and electrolysis power, carries out the intensive style management.
Electrolysis-recombiner among Fig. 1 is one of core component of the present invention, and it can carry out electrolysis with the water that conveying is come in, and hydrogen that generates and oxygen are carried out the water that deuterium content is hanged down in compound acquisition.This electrolysis-recombiner includes by ion-exchange membrane, the membrane electrode that the yin, yang catalysis electrode is formed and for membrane electrode fluming water and gas and derive the flow-field plate of electronics.
Hopper among Fig. 1 is used to deposit the deionized water before and after separating, and it can be pottery, stainless steel or plastics manufacturing, can have various forms and size, and the most basic requirement is the water that does not pollute input and produce.
Rectifying tower among Fig. 1 is used for the not electrolytic water that comes out from electrolysis-recombiner is separated once more; Wherein the lighter water of a part is emitted from the top with oxygen with liquid and/or gas form; Get into vapour liquid separator again through heat exchanger; The water that another part is heavier is emitted from the bottom, becomes the water of high deuterium content.The top of rectifying tower is different with the temperature of bottom.Contain solid and/or liquid catalyst in the tower, can carry out the exchange of protium water and deuterium-oxide.Rectifying tower can be by pottery, stainless steel or plastics manufacturing.
Vapour liquid separator among Fig. 1 is used for gas and liquid separation; The liquid water that comes out from rectifying tower gets into electrolysis-recombiner once more after separating; The water that is combined to generate by hydrogen and oxygen that comes out from electrolysis-recombiner is after vapour liquid separator separates; The promptly low deuterium-oxide of its liquid portion is stored by hopper, gets into bulking system again.
Cogeneration machine among Fig. 1 is used for the waste heat that production process produces is used again, to reduce the unit consumption of energy of product.
Embodiment:
The present invention will be described below in conjunction with Fig. 1.
Embodiment 1: as shown in Figure 1, deionized water is input to electrolysis-recombiner 4 by liquor pump 11, and simultaneously oxygen is input to electrolysis-recombiner 4 by gas pump 12, carry out electrolysis and compound.The water that anode is left during electrolysis gets into rectifying tower 1 with the oxygen of generation through vacuum breaker 13, and the water that electrolysis generates then gets into vapour liquid separator 6 with not used up oxygen.Under the effect of water catalyzer in rectifying tower of entering rectifying tower 1; Separation to a certain degree will take place in two temperature fields; Wherein heavy partly is that the high part of deuterium and oxygen 18 content outputs to high deuterium-oxide container 5 at the bottom of by tower, and the water that lightweight partly promptly mainly is made up of oxygen 16 and protium will rise with oxygen, and exchanges with the water that is input to rectifying tower 1 from heat exchanger 2; Water after the exchange and vapour get into heat exchanger 2 by cat head; The cooling back gets into vapour liquid separator 3, and the liquid water after the separation is input to electrolysis-recombiner 4 by liquor pump 11, realizes the circulation of liquid; Oxygen after the separation gets into vapour liquid separator 6 again, is input to electrolysis-recombiner 4 with the oxygen that replenishes into by gas pump 12, realizes the circulation of gas.The water that gets into the electrolysis generation of vapour liquid separator 6 then outputs to low deuterium-oxide hopper 7, gets into following one technology.In process of production, by the running status of computer control system 9 monitor control systems, and the heat that system produces will be generated electricity by cogeneration machine 10.After once such separation; The deuterium content of the liquid water in low deuterium-oxide hopper 7 will be dropped to by initial 150ppm below the 100ppm; Good catalytic separation ability can drop to deuterium content below the 50ppm, and better separating power can drop to deuterium content below the 30ppm; Simultaneously, the deuterium content of the water that in high deuterium-oxide container, obtains will be increased to more than the 200ppm, and good catalytic separation ability can be brought up to deuterium content more than the 400ppm, and better separating power can be brought up to deuterium content more than the 600ppm.
Unit consumption of energy that this embodiment consumed and common electrolysis-catalytic exchange technology promptly can not be compared the technology that the hydrogen-oxygen recombination energy is converted into electric energy, and the result is as shown in Figure 2.Can find out that it is half that the energy consumption of the simple electrolysis-catalytic exchange of ability loss-rate of combined electrolysis is almost little, and if waste heat is made full use of, then the energy consumption of combined electrolysis also will decline to a great extent.
Embodiment 2: connected by embodiment 1 described separation system a plurality of, the deionized water inlet 8 of next system connects the high deuterium-oxide container 5 of a system, can realize the enrichment of deuterium like this, and the multiplying power of each enrichment is 2～10 times.After 6～12 enrichments, the content of the deuterium-oxide or the water of weighing will reach more than 60%.
Embodiment 3: connected by embodiment 1 described separation system a plurality of, the deionized water inlet 8 of next system connects the low deuterium-oxide hopper 7 of a system, can realize the further purifying of low deuterium-oxide like this, and the multiplying power of each purifying is 1.5 to 5 times.Through behind 2～6 purifying, the deuterium content in its water can be reduced to below the 10ppm.
Embodiment 4: will be blent by embodiment 1 or 3 resulting low deuterium-oxides and grain wine and brewage, and make low deuterium-oxide wine, the deuterium oxide content of this wine is lower than 140ppm.Concrete as be that the low deuterium-oxide of 80ppm is blent in 7: 3 ratio with the grain wine more than 90% concentration and brewageed with deuterium content, obtain the low deuterium-oxide wine of about 30 degree, wherein total deuterium-oxide or title deuterium oxide content are 80～100ppm.
When the low deuterium-oxide of taking different concns is blent in different ratios with grain wine; Can obtain a series of embodiment, wherein the content of deuterium oxide changes with proportioning is different, total but deuterium oxide content should be lower than 140ppm; If be higher than 140ppm, can think this wine and common grain wine indifference.The content of deuterium is low more, and the mouthfeel of wine is good more, and is bigger to the benefit of human body.Can certainly use the direct and grain brewing spirit of low deuterium-oxide, but cost is too high, will not recommend at this.
Embodiment 5: will be made grape wine according to Wine-making technique by embodiment 1 or 3 resulting low deuterium-oxides, and make low deuterium-oxide wine, the deuterium oxide content of this wine is lower than 140ppm.Because Wine-making technique has been maturation process, do not add description here in addition, but as need make the wine of lower concentration very such as 50ppm deuterium content, should select for use raisin and low deuterium-oxide to brewage.
When the low deuterium-oxide of taking different concns is brewageed in different ratios with grape; Can obtain a series of embodiment; Wherein the content of deuterium-oxide changes with proportioning is different; But total deuterium oxide content should be lower than 140ppm, if be higher than 140ppm, can think this wine and vin ordinaire indifference.The content of deuterium is low more, and the mouthfeel of wine is good more, and is bigger to the benefit of human body.
Embodiment 6: will be mixed with various volatile oil by embodiment 1 or 3 resulting low deuterium-oxides, and make the low deuterium-oxide makeup of different flavor.Concrete as the low deuterium-oxide of 100ml is mixed with 1ml rose sesame oil, make rose water.
When the volatile oil of the low deuterium-oxide that adopts different concns and different varieties or their mixing oil cooperate; Can obtain countless embodiment; The volatile oil that is adopted can be made up of fresh material of one or more fragrant natural plant leaves, stem, skin, flower or fruit or the extracting solution that siccative is raw material; As said among the patent CN02151058.X, concrete raw material like leaf of Cortex cinnamomi camphorae, peppermint base of leaf, Chinese ilex base of leaf, pine tree base of leaf, rose base of leaf, green grass, Flos Rosae Chinensis or the like.Volatile oil also can be various synthetic essence, like synthetic musk, sandenol etc.Such volatile oil can find in a lot of monographs, does not describe in addition at this.But in various low deuterium-oxide makeup, deuterium oxide content wherein should be lower than 140ppm, and essential oil content less than 99.5%, otherwise can be considered common makeup greater than 1ppm.
Embodiment 7: will make low deuterium-oxide saline water according to the ME of medical saline by embodiment 1 or 3 resulting low deuterium-oxides.Because the ME of saline water has become standard production technology, does not add description in addition at this.But the deuterium oxide content of gained saline water should be lower than 140ppm, otherwise can be considered generic physiological salt solution.In this saline water, deuterium content is low more, absorption by human body is also good more, also big more to the benefit of human body.
Embodiment 8: will be cooperated with various fruit according to beverage production process by embodiment 1 or 3 resulting low deuterium-oxides and can make beverage corresponding, and specifically mix in 20: 1 ratio with the orange juice powder as hanging down deuterium-oxide, and can obtain the low deuterium-oxide beverage of orange juice.Because drink manufacturing technology has been maturation process, do not add description in addition at this, but the deuterium oxide content of gained beverage should be lower than 140ppm, otherwise can be considered common beverages.In this beverage, deuterium content is low more, and is also big more to the beneficial effect of human body.
Because it is almost countless to relate to the fishery products of drinking and keeping healthy; So low deuterium-oxide is as the substitute of water in these articles for use; Also has countless operational feasibilities; Anyly relate to the expert who drinks with healthcare products exploitations and all can not all these application be enumerated one by one at this easily with hanging down the product that deuterium-oxide is used for them.Above embodiment is a drop in the ocean, is a kind of tangible elaboration to spirit of the present invention.
Claims (10)
1. a combination water electrolysis and hydrogen-oxygen is compound and distillation system is the water separating system of one; This system is made up of one or more levels structure; Each level structure all comprises like lower member: hopper, rectifying tower, vapour liquid separator, heat exchanger, electrolysis-recombiner, vacuum breaker, switch-valve, computer control center, electrolysis power, cogeneration machine, water pump, heat pump, connecting tube; In system's operational process, by water pump deionized water is injected electrolysis-recombiner, carry out electrolysis; And with the hydrogen of generation and the water of the low deuterium content of the compound generation of oxygen, i.e. depleted water; Oxygen that electrolysis produces and surplus water get into rectifying tower, and the top of rectifying tower is different with the temperature of bottom, contains solid and/or liquid catalyst in the tower, can carry out the exchange of protium water and deuterium-oxide, and rectifying tower can be by pottery, stainless steel or plastics manufacturing; After the rectifying tower exchange; Wherein the lighter water of a part is emitted from the top with oxygen with liquid and/or gas form; Get into vapour liquid separator again through heat exchanger, this vapour liquid separator is used for gas and liquid separation, and water after the separation and oxygen get into electrolysis-recombiner more respectively; Generate electricity through the cogeneration machine through resulting waste heat after the heat exchange; The water of the high deuterium content of another part flows out through the rectifying tower bottom, thereby realizes separating of low deuterium-oxide and high deuterium-oxide.
2. the said combination water electrolysis of claim 1 and hydrogen-oxygen is compound and distillation system is the water separating system of one; It is characterized in that; Electrolysis-recombiner can be with carrying the water of coming in to carry out electrolysis; And hydrogen that generates and oxygen carried out the water of the low deuterium content of compound acquisition, this electrolysis-recombiner includes the membrane electrode of being made up of ion-exchange membrane, negative electrode, anode and is membrane electrode fluming water and gas and derives the flow-field plate of electronics.
3. the said combination water electrolysis of claim 1 and hydrogen-oxygen is compound and distillation system is the water separating system of one; It is characterized in that; Vapour liquid separator is used for gas and liquid separation, and the liquid water that comes out from rectifying tower gets into electrolysis-recombiner once more after separating, and the water that combines generation by hydrogen and oxygen that comes out from electrolysis-recombiner is after vapour liquid separator separates; The promptly low deuterium-oxide of its liquid portion is stored by hopper, gets into next stage equipment again.
4. the said combination water electrolysis of claim 1 and hydrogen-oxygen is compound and distillation system is the water separating system of one; It is characterized in that; Computerized control system will be used for controlling the operation etc. of unlatching, water pump and heat pump of voltage, electric current, temperature, pressure, the valve of production process; Normally carry out with what guarantee to produce, and when accident occurring, system is protected.
5. the said combination water electrolysis of claim 1 and hydrogen-oxygen is compound and distillation system is the water separating system of one; It is characterized in that; The low deuterium-oxide that the upper level unit is produced can offer the next stage unit further to be separated, and obtains the depleted water of lower deuterium content.
6. the said combination water electrolysis of claim 1 and hydrogen-oxygen is compound and distillation system is the water separating system of one; It is characterized in that; The high deuterium-oxide that the upper level unit is produced can offer the next stage unit to carry out further concentrating, and obtains the high deuterium-oxide of higher deuterium content.
7. will make grape wine according to Wine-making technique according to the low deuterium-oxide that the said scheme of claim 1 is produced, make low deuterium-oxide wine, it is characterized in that this deuterium oxide content vinous is lower than 140ppm.
8. will mix with various volatile oil according to the low deuterium-oxide that the said scheme of claim 1 is produced; Make the low deuterium-oxide makeup of different flavor, it is characterized in that, the deuterium oxide content of these makeup is lower than 140ppm; Volatile oil content is greater than 1ppm; Less than 99.5%, volatile oil can be made up of fresh material of one or more fragrant natural plant leaves, stem, skin, flower or fruit or the extracting solution that siccative is raw material, also can be various compound essences.
9. the low deuterium-oxide that will produce according to the said scheme of claim 1 makes low deuterium-oxide saline water according to the ME of medical saline, it is characterized in that the deuterium oxide content of this saline water is lower than 140ppm.
10. will cooperate with various fruit according to beverage production process according to the low deuterium-oxide that the said scheme of claim 1 is produced and to make beverage corresponding, it is characterized in that the deuterium oxide content of this beverage is lower than 140ppm.
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Cited By (27)
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| CN103848399A (en) * | 2012-11-28 | 2014-06-11 | 柯香文 | Method and equipment for preparing deuterium depleted water by light water |
| CN103849884A (en) * | 2012-11-28 | 2014-06-11 | 柯香文 | Equipment for preparing deuterium depleted water by light-water electrolytic method |
| CN103979495A (en) * | 2014-05-26 | 2014-08-13 | 刘宏建 | Technology for producing deuterium-depleted water and method for producing deuterium-depleted water thereby |
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| CN105314597A (en) * | 2015-11-26 | 2016-02-10 | 辽宁科技大学 | Deuterium depleted water preparation method |
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| WO2019174659A1 (en) | 2018-03-15 | 2019-09-19 | Karl Bau Gmbh | Method and assembly for producing water having reduced deuterium content |
| CN109077203A (en) * | 2018-08-18 | 2018-12-25 | 安徽国科生物科技有限公司 | Micro- drinks of a kind of low deuterium-oxide richness and preparation method thereof |
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