Summary of the invention
It is raw material that a technical problem to be solved by this invention is to provide a kind of poly-lactic acid material of take blending and modifying, can improve the tow heat distortion temperature, can not cause at cigarette smoking near the standby filter tip of this tow preparing the time, filter tip can be because flue-gas temperature be too high the cigarette-filter tow of generation moment drop-head;
Another technical problem that the present invention will solve is to provide a kind of by improvement tow moisture pick-up properties with improve tow get damp rate, adsorptivity and compatibility, reduce the harmful substances such as tar, carbon monoxide, alkyl diradical, alkoxy free group and heavy metal element that contain in flue gas, meet the New Set of " Framework Convention on Tobacco Control ", can avoid in addition producing the cigarette-filter tow preparation method of stiffization of nodositas in curly course.
The present invention solves the technical scheme that above-mentioned first technical problem adopts: a kind of cigarette-filter tow, and its main component is the blending and modifying poly-lactic acid material, each component that described blending and modifying poly-lactic acid material comprises following parts by weight:
Described temperature-resistant polylactic acid polyester mixture is the mixture of polylactic acid poly ester polymer and heatproof additive, the molecular weight of described polylactic acid poly ester polymer is 30,000~250,000, the parts by weight of described polylactic acid poly ester polymer are 95~98, described heatproof additive is the Biomax Tnerma1300 type heatproof additive that du pont company is produced, and the parts by weight of described heatproof additive are 2~5;
The mixture that perhaps described temperature-resistant polylactic acid polyester mixture is polylactic acid poly ester polymer and nucleating agent in polylactic acid production, the molecular weight of described polylactic acid poly ester polymer is 30,000~250,000, the parts by weight of described polylactic acid poly ester polymer are 99.5~99.8, and the parts by weight of described nucleating agent in polylactic acid production are 0.2~0.5.
Each component that the mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
Each component that perhaps mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
Each component that perhaps mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
Described adsorbent is selected from wherein a kind of of diatomite, zeolite powder and sepiolite powder; Described diatomaceous parts by weight are 0.3~0.7 part; The parts by weight of described zeolite powder are 0.3~0.7 part; The parts by weight of described sepiolite powder are 0.3~0.7 part.
The present invention solves the technical scheme that above-mentioned another technical problem adopts: a kind of preparation method of cigarette-filter tow, and it comprises the following steps:
1. prepare material according to the described each component of technique scheme;
2. by step 1. in the mixture of temperature-resistant polylactic acid polyester mixture and polyhydroxyalkanoate, polyethylene glycol and heat stabilizer and anti-oxidant auxiliary agent put into the container with dynamic agitating device, after heating container to 30 ℃~40 ℃ dissolves to polyethylene glycol, mix, obtain the first mixture, again by adsorbent with by 80~100 purpose vibrating screens, evenly be sieved in above-mentioned the first mixture after titanium dioxide mixes, mix, obtain the blending and modifying poly-lactic acid material;
3. the blending and modifying poly-lactic acid material 2. step obtained carries out melt spinning, spinning temperature is: the extruded segment temperature is 220 ℃~230 ℃, 230 ℃~245 ℃ of metering section temperature, and the receiver section temperature is 240 ℃~255 ℃, the Melting pump temperature is 240 ℃~250 ℃, obtains as-spun fibre;
4. by as-spun fibre by being placed with the antistatic groove of antistatic additive, apply antistatic additive on as-spun fibre surface by drum process, synthetic a branch of, obtain fibre bundle;
5. anlistatig fibre bundle is carried out to the tonicity drawing-off after by the water of 55 ℃~80 ℃ in tank;
6. the fibre bundle after drawing-off being carried out to the processing of tonicity HEAT SETTING with the speed of 60m~180m/ minute by the curling steam chest be arranged on before crimping machine, is wherein wet-hot steam in steam chest, and setting temperature is 97 ℃~103 ℃;
7. after the fibre bundle after typing being sprayed by cold water spray device with the speed of 60m~180m/ minute, enter crimping machine curling after, again with the speed of 60m~180m/ minute by being arranged at the spray equipment that is placed with anti-cigarette poison solution after doctor blade, spray processing;
The tow that 8. will spray after processing is dried by drying plant, 50 ℃~60 ℃ of bake out temperatures, and drying time is 8~16 minutes, obtains the cigarette-filter tow product.
The adsorbent of described step in 2. is selected from wherein a kind of of diatomite, zeolite powder and sepiolite powder, and described diatomaceous parts by weight are 0.3~0.7 part; The parts by weight of described zeolite powder are 0.3~0.7 part; The parts by weight of described sepiolite powder are 0.3~0.7 part.
Each component that the mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
Each component that perhaps mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
Each component that perhaps mixture of described heat stabilizer and anti-oxidant auxiliary agent comprises following parts by weight:
When 3. described step is used single-screw bar extruder or Double-screw extruder to carry out melt spinning, described step 2. after, 3. described step increases the operation that dewaters, and makes the moisture of described blending and modifying poly-lactic acid material be not more than 0.005%(weight).
Described step 3. after, the described step barrel operation that increases before 4..
The antistatic additive of described step in 4. is: the mixed aqueous solution that the aqueous solution of the TNB-1 finish that a kind of aqueous solution in the polyoxyethylene fatty acid ester LAE-9 that weight content is 1.0%~2.0%, cithrol PEG, cithrol MC, cithrol PEG400PS, cithrol EGMS and cithrol EGDS or weight content are 1%~2.7% and weight content are 1.0%~2.0% water-soluble silicon oil solution.
At least one in the n-propyl gallate aqueous solution that the low chitosan aqueous solution that described anti-cigarette poison solution is 0.1%~1% for low chitosan mass degree, the sodium alginate aqueous solution that the sodium alginate mass percentage content is 0.1%~1%, the Tea Polyphenols aqueous solution that the Tea Polyphenols mass percentage content is 0.08%~0.7% and n-propyl gallate degree are 0.06%~0.08%.
Compared with prior art, the invention has the advantages that: the mixture of the heatproof additive added in poly-lactic acid material or nucleating agent in polylactic acid production and heat stabilizer and anti-oxidant auxiliary agent, heat resistance and the thermal stability of poly-lactic acid material have been improved, avoid cigarette to be pumped to while approaching filter tip, filter tip can, due to flue-gas temperature too high and moment drop-head, affect filter-tip resistance to suction; The vapours case that is 97 ℃~103 ℃ by Temperature Setting by the fibre bundle by after drawing-off carries out that the tonicity HEAT SETTING is processed and uses the cold water spray to carry out the tonicity cooling and shaping to the fibre bundle entered before crimping machine, on the one hand fiber bundle structure is changed, avoid on the other hand the violent friction of curling wheel face and doctor blade actinal surface and the tow band passed through at a high speed to produce high thermal deformation, and cause the tow generated to produce stiffization of nodositas, improve product percent of pass, reduced cost; To the tow that obtains after curling by being arranged at the spray equipment that is placed with anti-cigarette poison solution after doctor blade, spray processing, can improve compatibility and the adsorptivity of filter filament, the raising of filter filament compatibility and adsorptivity has improved the regain of filter filament on the one hand, has improved on the other hand the absorption property of filter filament to the alkoxy free group, alkyl diradical, carbon monoxide, tar and the heavy metal substance that contain in flue gas.
The specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
The screw rod extruder that in the present invention, melt spinning is used can be single-screw bar extruder, the Double-screw extruder, triple helical bar extruder or many screw rods extruder, wherein triple helical bar extruder and many screw rods extruder are owing to having exhaust siphon function and special screw-rod structure, moisture to material does not require, can directly carry out melt spinning, other screw rod extruder need remove water treatment by material, makes moisture just can enter the screw rod extruder lower than 0.005% and carries out melt spinning later.
The present invention has two kinds of embodiments, a kind of is a step spin processes, another kind is two step spin processes, the whole tow preparation process of one step spin processes is used a production line, from melt spinning until tow products occurs it being continuous process, do not interrupt, all equipment exhaustings are on a production line; And in two step spin processes, there is barrel operation that falls in as-spun fibre before entering the drawing machine drawing-off, i.e. storage is deposited, its tow preparation process is used two production lines, i.e. operation before drawing-off is used a production line, and the subsequent handling started from drawing-off is used another production line, the device fabrication line length, investment is large, and output is high, in addition wherein during an equipment fault, whole piece produces line all to be stopped, and the tow loss is large; Two step spin processes are with respect to a step spin processes, and the Whole Equipment production line is short, and fiber falls the bucket amount greatly; once equipment fault, the faulty equipment shutdown maintenance gets final product, and miscellaneous equipment still works; the tow loss is little, can arrange flexibly equipment according to productive target in addition, has promoted the utilization rate of equipment.
Umber in following embodiment is all parts by weight; The adsorbent used is selected from wherein a kind of of diatomite, zeolite powder and sepiolite powder, and wherein the diatomite loose thickness is 0.2~0.5g/cm
3, proportion 0.5~0.8g/cm
3, specific area 15~17cm
2/ g, porosity>=90%, whiteness>=90%, particle size range is 2500 orders~3500 orders, activity degree>=75, the zeolite powder loose thickness is 0.6~0.8g/cm
3, proportion 0.7~0.9g/cm
3, whiteness>=90%, granulometric range is 2500 orders~3000 orders, activity degree>=80, the sepiolite powder loose thickness is 0.558~0.7g/cm
3, proportion 0.7~0.9g/cm
3, whiteness>=85%, granulometric range is 2500 orders~3000 orders, activity degree>=80, the fiber aperture is 10~50 μ m;
The antistatic additive used is: the mixed aqueous solution that the aqueous solution of the TNB-1 finish that a kind of aqueous solution in the polyoxyethylene fatty acid ester LAE-9 that weight content is 1.0%~2.0%, cithrol PEG, cithrol MC, cithrol PEG400PS, cithrol EGMS and cithrol EGDS or weight content are 1%~2.7% and weight content are 1.0%~2.0% water-soluble silicon oil solution.
Embodiment mono-: many screw rods of MRS-70 extruder that the present embodiment is used two German Berstorffs (Berstorff) company to produce carries out melt spinning, every many screw rods of MRS-70 extruder has 6 spinneretss, each spinnerets 1.2 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 98 parts of polylactic acid poly ester polymers, the Biomax Tnerma1300 heatproof additive of 2 parts of du pont company productions mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 1 part of polyethylene glycol, the mixture of 1 part of polyhydroxyalkanoate and 2.53 parts of heat stabilizers and anti-oxidant auxiliary agent is put into the mixer of drive agitating device, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is the anti-oxidant auxiliary agent of SONOX215/225 of being produced by 0.03 part of Shandong Province Linyi City Sanfeng Chemical Industry Co., Ltd., 2.079 part polypropylene, 0.021 the mixture containing oxygen plastic additive and 0.4 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.5 part of zeolite powder and 0.5 part of titanium dioxide being mixed, by 90 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that many screw rods of MRS-70 type extruder is set is 220 ℃~230 ℃, 230 ℃~240 ℃ of metering section temperature, the receiver section temperature is 240 ℃~250 ℃, the Melting pump temperature is 240 ℃~250 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of many screw rods of MRS-70 type extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 100m/ minute, as-spun fibre is by after being arranged at many screw rods of MRS-70 type extruder, air-conditioned room before drawing machine, air-conditioned room keeps 23 ℃~26 ℃ of constant temperature, in the air-conditioned room porch, use ring blowing mode to carry out cooling to as-spun fibre simultaneously, cooled as-spun fibre is by that arrange and the antistatic groove that is placed with antistatic additive with the roller spinnerets quantity Matching, every 1.2 ten thousand as-spun fibres are synthetic a branch of, 12 bundle fiber bundles enter in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 80 ℃ by temperature again collects again, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 180m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 97 ℃, after spraying by cold water spray device again, enter crimping machine curling after, spray processing by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is the low chitosan aqueous solution that low chitosan mass degree that molecular weight is 5000~20,000 is 0.1%~1%, tow after spray is processed is dried by drying plant, 50 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.67dtex, total silk density 4.33ktex, single wire fracture intensity 1.8 ± 0.3CN/dtex, elongation at break 6.5 ± 1%, the rate 5.6% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11mg, nicotine content is 1.1mg, and alkoxy free group and alkyl diradical content are 11.5mg, and carbon monoxide content is 11mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment bis-: many screw rods of MRS-70 extruder that the present embodiment is used two German Berstorffs (Berstorff) company to produce carries out melt spinning, every many screw rods of MRS-70 extruder has 6 spinneretss, each spinnerets 1.06 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 95 parts of polylactic acid poly ester polymers, the Biomax Tnerma1300 heatproof additive of 5 parts of du pont company productions mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.5 part of polyethylene glycol, 1.2 the mixture of part polyhydroxyalkanoate and 2.75 parts of heat stabilizers and anti-oxidant auxiliary agent is put into the mixer of drive agitating device, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is by 0.05 part of Tea Polyphenols, 2.178 part polypropylene, 0.022 the mixture containing oxygen plastic additive and 0.5 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.3 part of zeolite powder and 0.7 part of titanium dioxide being mixed, by 80 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that many screw rods of MRS-70 type extruder is set is 220 ℃~230 ℃, 230 ℃~240 ℃ of metering section temperature, the receiver section temperature is 240 ℃~250 ℃, the Melting pump temperature is 240 ℃~250 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of many screw rods of MRS-70 type extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 90m/ minute, as-spun fibre is by after being arranged at many screw rods of MRS-70 type extruder, air-conditioned room before drawing machine, air-conditioned room keeps 23 ℃~26 ℃ of constant temperature, in the air-conditioned room porch, use ring blowing mode to carry out cooling to as-spun fibre simultaneously, cooled as-spun fibre is by that arrange and the antistatic groove that is placed with antistatic additive with the roller spinnerets quantity Matching, every 1.06 ten thousand as-spun fibres are synthetic a branch of, 12 bundle fiber bundles enter in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 70 ℃ by temperature again collects again, speed is 160m/ minute, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 160m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 103 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 160m/ minute, enter crimping machine curling after, spray processing with the speed of 160m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is the sodium alginate aqueous solution that the sodium alginate mass percentage content is 0.1%~1%, tow after spray is processed is dried by drying plant, 60 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.8dtex, total silk density 4.00ktex, single wire fracture intensity 1.9 ± 0.3CN/dtex, elongation at break 6.3 ± 1%, the rate 6 ± 1% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.2mg, nicotine content is 1.13mg, and alkoxy free group and alkyl diradical content are 11.6mg, and carbon monoxide content is 11.37mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment tri-: many screw rods of MRS-90 extruder that the present embodiment is used a German Berstorff (Berstorff) company to produce carries out melt spinning, every many screw rods of MRS-90 extruder has 12 spinneretss, each spinnerets 1.04 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 99.5 parts of polylactic acid poly ester polymers, 0.5 part TMC300 nucleating agent in polylactic acid production that Shanxi Province chemical research institute produces mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 1.2 parts of polyethylene glycol, 1.2 the mixture of part polyhydroxyalkanoate and 2.36 parts of heat stabilizers and anti-oxidant auxiliary agent is put into the mixer of drive agitating device, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is by 0.06 portion of n-propyl gallate, 1.98 part polypropylene, 0.02 the mixture containing oxygen plastic additive and 0.3 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.7 part of zeolite powder and 0.3 part of titanium dioxide being mixed, by 100 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that many screw rods of MRS-90 type extruder is set is 220 ℃~230 ℃, 230 ℃~240 ℃ of metering section temperature, the receiver section temperature is 240 ℃~250 ℃, the Melting pump temperature is 240 ℃~250 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of many screw rods of MRS-90 type extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 80m/ minute, as-spun fibre is by after being arranged at many screw rods of MRS-90 type extruder, air-conditioned room before drawing machine, air-conditioned room keeps 23 ℃~26 ℃ of constant temperature, in the air-conditioned room porch, use ring blowing mode to carry out cooling to as-spun fibre simultaneously, cooled as-spun fibre is by that arrange and the antistatic groove that is placed with antistatic additive with the roller spinnerets quantity Matching, every 1.04 ten thousand as-spun fibres are synthetic a branch of, 12 bundle fiber bundles enter in first seven rollers drawing machine after drawing-off, draft speed is 80m/ minute, entering drawing-off in second seven roller drawing machine after the water-soaked that is 75 ℃ by temperature again collects again, speed is 160m/ minute, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 80m~160m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 103 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 80m~160m/ minute, enter crimping machine curling after, spray processing with the speed of 150m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is that the Tea Polyphenols mass percentage content is 0.08%~0.7% Tea Polyphenols aqueous solution, tow after spray is processed is dried by drying plant, 55 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 4.0dtex, total silk density 4.16ktex, single wire fracture intensity 1.7 ± 0.3CN/dtex, elongation at break 5.8 ± 1%, the rate 5.9 ± 1% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 12mg, nicotine content is 1.12mg, and alkoxy free group and alkyl diradical content are 11.7mg, and carbon monoxide content is 11.3mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment tetra-: many screw rods of MRS-90 extruder that the present embodiment is used a German Berstorff (Berstorff) company to produce carries out melt spinning, every many screw rods of MRS-90 extruder has 12 spinneretss, each spinnerets 1.12 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 99.8 parts of polylactic acid poly ester polymers, 0.2 part nucleating agent in polylactic acid production TMC328 that Shanxi Province chemical research institute produces mixes the temperature-resistant polylactic acid polyester mixture that obtains 100 parts, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.8 part of polyethylene glycol, 0.8 the mixture of part polyhydroxyalkanoate and 2.36 parts of heat stabilizers and anti-oxidant auxiliary agent is put into the mixer of drive agitating device, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is by 0.06 portion of n-propyl gallate, 1.98 part polypropylene, 0.02 the mixture containing oxygen plastic additive and 0.3 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.3 part of diatomite and 0.4 part of titanium dioxide being mixed, by 100 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that many screw rods of MRS-90 type extruder is set is 220 ℃~230 ℃, 230 ℃~240 ℃ of metering section temperature, the receiver section temperature is 240 ℃~250 ℃, the Melting pump temperature is 240 ℃~250 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of many screw rods of MRS-90 type extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 80m/ minute, as-spun fibre is by after being arranged at many screw rods of MRS-90 type extruder, air-conditioned room before drawing machine, air-conditioned room keeps 23 ℃~26 ℃ of constant temperature, in the air-conditioned room porch, use ring blowing mode to carry out cooling to as-spun fibre simultaneously, cooled as-spun fibre is by that arrange and the antistatic groove that is placed with antistatic additive with the roller spinnerets quantity Matching, every 1.12 ten thousand as-spun fibres are synthetic a branch of, 12 bundle fiber bundles enter in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 55 ℃ by temperature again collects again, speed is 170m/ minute, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 170m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 103 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 170m/ minute, enter crimping machine curling after, spray processing with the speed of 170m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is that the sodium alginate mass percentage content is 0.1%~1%, the sodium alginate that the Tea Polyphenols mass percentage content is 0.08%~0.7% and Tea Polyphenols mixed aqueous solution, tow after processing is dried by drying plant, 60 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.8dtex, total silk density 4.256ktex, single wire fracture intensity 2.0 ± 0.3CN/dtex, elongation at break 5.7 ± 1.5%, the rate 5.5 ± 1% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.8mg, nicotine content is 1.21mg, and alkoxy free group and alkyl diradical content are 11.5mg, and carbon monoxide content is 11.6mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment five: the JH-90 single-screw bar extruder that the present embodiment is used Jinhu County, Zhejiang molding machine limited company to produce carries out melt spinning, every JH-90 Double-screw extruder has 6 spinneretss (5 of actual uses), each spinnerets 492 hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts two step spin processes spinning.
Take 96 parts of polylactic acid poly ester polymers, the Biomax Tnerma1300 heatproof additive of 4 parts of du pont company productions mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.6 part of polyethylene glycol, 0.6 the mixture of part polyhydroxyalkanoate and 2.75 parts of heat stabilizers and anti-oxidant auxiliary agent is put into the mixer of drive agitating device, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, and stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is by 0.05 part of Tea Polyphenols, 2.178 part polypropylene, 0.022 the mixture containing oxygen plastic additive and 0.5 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.3 part of sepiolite powder and 0.6 part of titanium dioxide being mixed, by 95 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that JH-90 Double-screw extruder is set is 220 ℃~230 ℃, 235 ℃~245 ℃ of metering section temperature, the receiver section temperature is 240 ℃~255 ℃, the Melting pump temperature is 240 ℃~245 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of JH-90 single-screw bar extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 100m/ minute, re-using ring blowing mode carries out cooling to as-spun fibre, cooled as-spun fibre is by the antistatic groove that is placed with antistatic additive with roller, every 2460 as-spun fibres are synthetic a branch of, obtain altogether 1 bundle fiber bundle, by fall bucket storage of fibre bundle, be no more than 12 hours memory time, the fibre bundle of 2460 of 6 bundles is merged into after a large bundle and enters in first seven rollers drawing machine after drawing-off, then enter again drawing-off in second seven roller drawing machine after the water-soaked that is 76 ℃ by temperature and collect, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 120m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 100 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 120m/ minute, enter crimping machine curling after, again with the speed of 120m/ minute by being arranged at the spray equipment spray that is placed with anti-cigarette poison solution after doctor blade, spray processing, anti-cigarette poison solution is that the low chitosan mass degree that molecular weight is 5000~20,000 is 0.1%~1%, the sodium alginate mass percentage content is 0.1%~1%, the sodium alginate that the Tea Polyphenols mass percentage content is 0.08%~0.7%, low shitosan and Tea Polyphenols mixed aqueous solution, tow after spray is processed is dried by drying plant, 58 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.1dtex, total silk density 45700dtex, single wire fracture intensity 1.9CN/dtex, elongation at break 6.2 ± 1.5%, the rate 5.3 ± 1.5% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.3mg, nicotine content is 1.2mg, and alkoxy free group and alkyl diradical content are 11.4mg, and carbon monoxide content is 11.2mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment six: the JH-90 single-screw bar extruder that the present embodiment is used Jinhu County, 2 Zhejiang molding machine limited company to produce carries out melt spinning simultaneously, every JH-90 single-screw bar extruder has 6 spinneretss, each spinnerets 1.08 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 99.6 parts of polylactic acid poly ester polymers, 0.4 a part nucleating agent in polylactic acid production mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.6 part of polyethylene glycol, 0.6 the mixture of part polyhydroxyalkanoate and 2.53 parts of heat stabilizers and anti-oxidant auxiliary agent is put into mixer, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, and stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is the anti-oxidant auxiliary agent of SONOX215/225 of being produced by Shandong Province Linyi City Sanfeng Chemical Industry Co., Ltd. of 0.03 part, 2.079 part polypropylene, 0.021 the mixture containing oxygen plastic additive and 0.4 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.6 part of sepiolite powder and 0.6 part of titanium dioxide being mixed, by 100 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the blending and modifying poly-lactic acid material is removed to water treatment, make its moisture be no more than 0.005%(weight), the extruded segment temperature that JH-90 single-screw bar extruder is set is 220 ℃~230 ℃, 235 ℃~245 ℃ of metering section temperature, the receiver section temperature is 240 ℃~255 ℃, the Melting pump temperature is 240 ℃~245 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of JH-90 Double-screw extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 80m/ minute, re-using ring blowing mode carries out cooling to as-spun fibre, cooled as-spun fibre is by the antistatic groove that is placed with antistatic additive with roller, every 1.08 ten thousand as-spun fibres are synthetic a branch of, obtain altogether 12 bundle fiber bundles, fibre bundle enters respectively in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 76 ℃ by temperature again collects again, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 160m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 100 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 160m/ minute, enter crimping machine curling after, again with the speed of 160m/ minute by being arranged at the spray equipment spray that is placed with anti-cigarette poison solution after doctor blade, spray processing, anti-cigarette poison solution is that the Tea Polyphenols mass percentage content is 0.08%~0.7% Tea Polyphenols aqueous solution, tow after spray is processed is dried by drying plant, 50 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 4.0dtex, total silk density 4.32kdtex, single wire fracture intensity 1.79CN/dtex, elongation at break 6.35 ± 1.5%, the rate 5.2 ± 1.5% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.6mg, nicotine content is 1.14mg, and alkoxy free group and alkyl diradical content are 11.8mg, and carbon monoxide content is 11.7mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment seven: the SHJ-92HT Double-screw extruder that the present embodiment is used Jinhu County, Zhejiang molding machine limited company to produce carries out melt spinning, every SHJ-92HT Double-screw extruder has 6 spinneretss (practical 5), each spinnerets 520 hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts two step spin processes spinning.
Take 99.6 parts of polylactic acid poly ester polymers, 0.4 a part nucleating agent in polylactic acid production mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.6 part of polyethylene glycol, 0.6 the mixture of part polyhydroxyalkanoate and 2.53 parts of heat stabilizers and anti-oxidant auxiliary agent is put into mixer, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, and stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is the anti-oxidant auxiliary agent of SONOX215/225 of being produced by Shandong Province Linyi City Sanfeng Chemical Industry Co., Ltd. of 0.03 part, 2.079 part polypropylene, 0.021 the mixture containing oxygen plastic additive and 0.4 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.6 part of sepiolite powder and 0.6 part of titanium dioxide being mixed, by 100 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the blending and modifying poly-lactic acid material is removed to water treatment, make its moisture be no more than 0.005%(weight), the extruded segment temperature that SHJ-92HT Double-screw extruder is set is 220 ℃~230 ℃, 235 ℃~245 ℃ of metering section temperature, the receiver section temperature is 240 ℃~255 ℃, the Melting pump temperature is 240 ℃~245 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of SHJ-92HT Double-screw extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 80m/ minute, re-using ring blowing mode carries out cooling to as-spun fibre, cooled as-spun fibre is by the antistatic groove that is placed with antistatic additive with roller, every 2600 as-spun fibres are synthetic a branch of, obtain altogether 1 bundle fiber bundle, by fall bucket storage of fibre bundle, be no more than 12 hours memory time, the fibre bundle of 2600 of 6 bundles is merged into after the large bundle of 15600 and enters in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 76 ℃ by temperature again collects again, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 120m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 100 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 120m/ minute, enter crimping machine curling after, spray processing with the speed of 120m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is that the Tea Polyphenols mass percentage content is 0.08%~0.7% Tea Polyphenols aqueous solution, tow after spray is processed is dried by drying plant, 55 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 2.8dtex, total silk density 43600dtex, single wire fracture intensity 1.86CN/dtex, elongation at break 7.34% ± 1%, the rate 5.2% ± 1.5% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.3mg, nicotine content is 1.08mg, and alkoxy free group and alkyl diradical content are 12.1mg, and carbon monoxide content is 11.9mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment eight: the SHJ-92HT Double-screw extruder that the present embodiment is used Jinhu County, Zhejiang molding machine limited company to produce carries out melt spinning, every SHJ-92HT Double-screw extruder has 6 spinneretss (practical 5), each spinnerets 492 hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts two step spin processes spinning.
Take 97 parts of polylactic acid poly ester polymers, the Biomax Tnerma1300 heatproof additive of 3 parts of du pont company productions mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 0.6 part of polyethylene glycol, 0.6 the mixture of part polyhydroxyalkanoate and 2.53 parts of heat stabilizers and anti-oxidant auxiliary agent is put into mixer, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, and stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is the anti-oxidant auxiliary agent of SONOX215/225 of being produced by Shandong Province Linyi City Sanfeng Chemical Industry Co., Ltd. of 0.03 part, 2.079 part polypropylene, 0.021 the mixture containing oxygen plastic additive and 0.4 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.8 part of sepiolite powder and 0.6 part of titanium dioxide being mixed, by 100 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the blending and modifying poly-lactic acid material is removed to water treatment, make its moisture be no more than 0.005%(weight), the extruded segment temperature that SHJ-92HT Double-screw extruder is set is 220 ℃~230 ℃, 235 ℃~245 ℃ of metering section temperature, the receiver section temperature is 240 ℃~255 ℃, the Melting pump temperature is 240 ℃~245 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of SHJ-92HT Double-screw extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 60m/ minute, re-using ring blowing mode carries out cooling to as-spun fibre, cooled as-spun fibre is by the antistatic groove that is placed with antistatic additive with roller, every 2460 as-spun fibres are synthetic a branch of, obtain altogether 1 bundle fiber bundle, by fall bucket storage of fibre bundle, be no more than 12 hours memory time, the fibre bundle of 2460 of 6 bundles is merged into after the large bundle of 14760 and enters in first seven rollers drawing machine after drawing-off, then enter again drawing-off in second seven roller drawing machine after the water-soaked that is 76 ℃ by temperature and collect, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 150m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 98 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 150m/ minute, enter crimping machine curling after, spray processing with the speed of 150m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is that the Tea Polyphenols mass percentage content is 0.08%~0.7% Tea Polyphenols aqueous solution, tow after spray is processed is dried by drying plant, 55 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.15dtex, total silk density 4.65kdtex, single wire fracture intensity 1.92CN/dtex, elongation at break 6.38 ± 1.5%, the rate 5.87% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 12.1mg, nicotine content is 1.27mg, and alkoxy free group and alkyl diradical content are 12mg, and carbon monoxide content is 12.2mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".
Embodiment nine: the GH-100Y triple helical bar extruder that the present embodiment is used two center, capital, Taibei innovation plastics machinery Co., Ltds to produce carries out melt spinning, every GH-100Y triple helical bar extruder has 6 spinneretss, each spinnerets 1.2 ten thousand hole, spinneret hole is trilobal, bore dia 0.16mm, aperture 0.56mm, the present embodiment adopts a step spin processes spinning.
Take 98 parts of polylactic acid poly ester polymers, the Biomax Tnerma1300 heatproof additive of 2 parts of du pont company productions mixes and obtains 100 parts of temperature-resistant polylactic acid polyester mixtures, by 100 parts of temperature-resistant polylactic acid polyester mixtures and 1 part of polyethylene glycol, the mixture of 1 part of polyhydroxyalkanoate and 2.53 parts of heat stabilizers and anti-oxidant auxiliary agent is put into mixer, heating 30 ℃~40 ℃ dissolves to polyethylene glycol, and stir, wherein the mixture of heat stabilizer and anti-oxidant auxiliary agent is the anti-oxidant auxiliary agent of SONOX215/225 of being produced by 0.03 part of Shandong Province Linyi City Sanfeng Chemical Industry Co., Ltd., 2.079 part polypropylene, 0.021 the mixture containing oxygen plastic additive and 0.4 part of poly butylene succinate composition that part Qingdao Kang Wen biological plastics Co., Ltd produces, after again 0.5 part of zeolite powder and 0.5 part of titanium dioxide being mixed, by 90 purpose vibrating screens, evenly be sieved in mixer, stir, obtain the blending and modifying poly-lactic acid material, the extruded segment temperature that GH-100Y triple helical bar extruder is set is 220 ℃~230 ℃, 230 ℃~240 ℃ of metering section temperature, the receiver section temperature is 240 ℃~250 ℃, the Melting pump temperature is 240 ℃~250 ℃, the blending and modifying poly-lactic acid material is poured in the feeder hopper device of GH-100Y triple helical bar extruder and carried out melt spinning, wherein as-spun fibre extruding wire vent speed is 80m/ minute, as-spun fibre is by starting from the filament plate that of GH-100Y triple helical bar extruder, terminate in drawing machine air-conditioned room before, air-conditioned room keeps 23 ℃~26 ℃ of constant temperature, in the air-conditioned room porch, use ring blowing mode to carry out cooling to as-spun fibre simultaneously, cooled as-spun fibre is by that arrange and the antistatic groove that is placed with antistatic additive with the roller spinnerets quantity Matching, every 1.2 ten thousand as-spun fibres are synthetic a branch of, 12 bundle fiber bundles enter in first seven rollers drawing machine after drawing-off, entering drawing-off in second seven roller drawing machine after the water-soaked that is 80 ℃ by temperature again collects again, speed is 160m/ minute, fibre bundle after drawing-off is carried out to the HEAT SETTING processing with the speed of 160m/ minute by the steam chest be arranged on before crimping machine, it in steam chest, is wherein wet-hot steam, setting temperature is 97 ℃, fibre bundle after typing after spraying by cold water spray device with the speed of 160m/ minute, enter crimping machine curling after, spray processing with the speed of 160m/ minute by the spray equipment that is placed with anti-cigarette poison solution be arranged at after doctor blade again, anti-cigarette poison solution is the n-propyl gallate aqueous solution that n-propyl gallate content is 0.06%, tow after spray is processed is dried by drying plant, 50 ℃ of bake out temperatures, drying time is 8~16 minutes, obtain the cigarette-filter tow product, tow width 32mm, filament density 3.33dtex, total silk density 4.0ktex, single wire fracture intensity 1.78CN/dtex, elongation at break 6.22 ± 1.5%, the rate 5.26 ± 1% of getting damp, after being made into filter tip and being arranged on cigarette, tar content is 11.8mg, nicotine content is 1.18mg, and alkoxy free group and alkyl diradical content are 11.8mg, and carbon monoxide content is 12.1mg, and also reduction greatly of content of beary metal, the New Set of satisfied " Framework Convention on Tobacco Control ".