CN102371336B - A kind of Water-based coating for lost foam casting - Google Patents

A kind of Water-based coating for lost foam casting Download PDF

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Publication number
CN102371336B
CN102371336B CN201110307594.7A CN201110307594A CN102371336B CN 102371336 B CN102371336 B CN 102371336B CN 201110307594 A CN201110307594 A CN 201110307594A CN 102371336 B CN102371336 B CN 102371336B
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coating
water
mesh
sodium
lost foam
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CN102371336A (en
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刘善江
梅少峰
肖铭
董立志
刘艳菲
薛小倩
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Hebei Chenyang water paint Co. Ltd.
Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Water Paint Co Ltd
Hebei Chenyang Industry and Trade Group Co Ltd
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Abstract

The invention discloses a kind of Water-based coating for lost foam casting, the coating is made up of following components by weight percentage:150 200 mesh mullite powders 15 18%, 80 150 mesh silica flours 5 8%, 200 320 mesh bauxites 12 18%, Ludox 1.2 1.5%, poly vinyl acetate emulsion 1.5 3.0%, carboxymethyl cellulose acid sodium 0.1 0.4%, sodium alkyl benzene sulfonate 0.15 0.35%, sodium sulphate 0.15 0.35%, n-octyl alcohol 0.1 0.3%, AEO 0.10 0.18%, surplus is water.

Description

A kind of Water-based coating for lost foam casting
Technical field
The present invention relates to casting field, more particularly to a kind of lost foam casting coating field.
Background technology
Lost foam casting is described as " green casting technology " and " foundry engieering of 21 century " with its unique advantage.From The sixties in last century has started using since in China, and through the continuous development of decades, the application of lost foam casting is continuous Expand, obtain good economic benefit and social benefit.
Lost foam casting coating is one of two big key technologies of lost foam casting process.The performance of coating directly affects casting The quality of part, has dramatically different with traditional sand mold cast paint.The main purpose of traditional sand casting coating is to prevent foundry goods Penetration and chemical scab are produced, and coating for dispellable mould casting is also cast with formation and holding in addition to above-mentioned two effect The important function of part cavity, therefore it must have higher normal temperature strength, elevated temperature strength and suitable hot permeability.
Although lost foam casting process since the advent of the world is comparatively fast developed, coating technology annoyings casting finished products always Rate is difficult to larger raising, and its quality for being primarily due to coating can not meet the requirement of lost foam casting process.One is Normal temperature strength does not reach requirement, causes apperance deformation and coating breakage to scrap foundry goods during moulding;Two is that elevated temperature strength is relatively low, is poured Occur during note foundry goods die cavity subside, destroy, coating peel off etc. scrap foundry goods;Three is that coating does not have suitable hot permeability, Too high gas permeability causes die cavity to subside, and too low gas permeability makes foundry goods produce the casting flaws such as pore, elephant skin, slag inclusion.
The content of the invention
For the deficiencies in the prior art, an object of the present invention is to provide a kind of Water-based coating for lost foam casting, The coating elevated temperature strength and low temperature intensity and other performance all meet lost foam casting use requirement, and process is simple, cost It is cheap.
For achieving the above object, the technical solution used in the present invention is:
A kind of Water-based coating for lost foam casting, the coating are made up of following components by weight percentage:150-200 Mesh mullite powder 15-18%, 80-150 mesh silica flour 5-8%, 200-320 mesh bauxite 12-18%, Ludox 1.2-1.5%, Poly vinyl acetate emulsion 1.5-3.0%, carboxymethyl cellulose acid sodium 0.1-0.4%, the stupid sodium sulfonate 0.15-0.35% of alkyl, sodium sulphate 0.15-0.35%, n-octyl alcohol 0.1-0.3%, AEO 0.10-0.18%, surplus is water.
Wherein, the coating preferably constitute for:150-200 mesh mullite powder 16-17%, 80-150 mesh silica flour 6-7%, 200-320 mesh bauxite 14-16%, Ludox 1.3-1.4%, poly vinyl acetate emulsion 2.4-2.6%, carboxymethyl cellulose acid sodium 0.2-0.4%, sodium alkyl benzene sulfonate 0.20-0.30%, sodium sulphate 0.20-0.30%, n-octyl alcohol 0.1-0.3%, poly alkyl alcohol Oxygen vinethene 0.14-0.16%, surplus is water.
Wherein, the coating optimum is consisted of:150-200 mesh mullite powder 16%, 80-150 mesh silica flour 6%, 200- 320 mesh bauxites 15%, Ludox 1.5%, poly vinyl acetate emulsion 2.5%, carboxymethyl cellulose acid sodium 0.3%, alkyl benzene sulphonate Sodium 0.25%, sodium sulphate 0.25%, n-octyl alcohol 0.2%, AEO 0.15%, surplus is water.
The preparation method of above-mentioned coating is:
A. mullite powder, silica flour and bauxite base-material are stirred in coating grinding equipment, is subsequently adding total water Base-material in base-material is moistened and is stirred out by the water of the 35% of amount;
B. by Ludox, poly vinyl acetate emulsion, carboxymethyl cellulose acid sodium, sodium alkyl benzene sulfonate, sodium sulphate, n-octyl alcohol, fat Fat alcohol APEO is sequentially added in the above-mentioned base-material for having moistened and having stirred out, and add total Water 5% water in painting 30-60min is stirred in material grinding equipment.
C. and then by the water of surplus in coating grinding equipment, and grind 120-180min.
From up to 1800 DEG C of fusing point for being because mullite powder in base-material based on mullite powder, heat resistance is good, Mullite powder low thermal expansion, makees base-material using mullite powder, and coating low temperature and elevated temperature strength are good, thermal conductivity, and does not come Stone flour heat storage coefficient is high, is conducive to accelerating the cooling of foundry goods, refines foundry goods work layer tissue and increases the spoken parts in traditional operas of foundry goods working lining Layer depth, is conducive to improving foundry goods service life.Be additionally added silica flour and bauxite in addition, silica flour fusing point up to 1713 DEG C, and Quartzy powder density 2700kg/m3, bauxite fusing point be more than 1770 DEG C, add appropriate silica flour and bauxite improve painting in base-material The suspendability of material.Water-based coating for lost foam casting adopts 150-200 mesh mullite powder 15-18%, 80-150 mesh silica flours 5-8%, 200-320 mesh bauxite 12-18%, is conducive to obtaining with good low temperature and elevated temperature strength performance as aggregate High-quality cast product.Graphite powder, talcum powder and diatomite are not added with base-material, are conducive to environmental protection without graphite, and talcum Contain the crystallization water in powder and diatomite, easily decompose under the effect of high-temperature metal liquation and discharge the crystallization water and form vapor immersion Molten metal, easily forms the casting flaws such as pore in foundry goods after solidification.
Coating of the present invention with Ludox, poly vinyl acetate emulsion carboxylic and Methyl cellulose acid sodium as main binding agent, both with height Warm bonding agent, has low temperature adhesive again.The substitution value of the carboxymethyl cellulose acid sodium selected by the present invention is 0.65-0.85, is gathered Right n > 200.Carboxymethyl cellulose acid Main Function of the sodium in coating has:One is to form netted stereochemical structure by macromolecular chain; Two is that Polymer adsorption hydrone forms solvated layer;Three are acted on shear thinning.Carboxymethyl cellulose is added in coating After sour sodium, thickening phenomenon is formed, makes paint adhesion effect improve.
In order to improve the suspendability of coating, the present invention adds sodium alkyl benzene sulfonate and sodium sulphate.
Easily occurs foam in coating, if removing not in time, it will affect dope layer surface quality, and then affect foundry goods matter Amount, adds n-octyl alcohol in coating, not only acts on good froth breaking, also with the effect for improving coating wetability.
In order to improve the wettability of coating, prevent dope layer from cracking and flaking off, fatty alcohol polyoxy second is added in coating Alkene ether makees surfactant, can significantly improve the combination property of dope layer, is highly beneficial to improving casting quality.
The present invention using water as carrier, with low cost, preserve, transport and it is easy to use the features such as.
The inventive method has the beneficial effect that:
The Water-based coating for lost foam casting of the present invention has excellent performance, with good suspension and thixotropy; Coating also has good gas permeability and higher surface strength, meets the requirement of coating for dispellable mould casting well.Should Coating method is simple, nonhazardous, and the surface finish of casting of production is high.This coating is mainly used in lost foam casting production casting Iron, cast steel and non-ferrous alloy casting.Compared with same kind of products at abroad, in the case where quality is suitable, required cost reduces by 50%. Instant invention overcomes refractory powder is expensive in existing routine casting coating preparation technology, coating material production is relatively costly to be lacked Fall into;Cast paint of the present invention is smooth and viscosity is suitable simultaneously.
With reference to embodiment, the invention will be further described:
Specific embodiment
Embodiment one
A kind of Water-based coating for lost foam casting, the coating are made up of following components by weight percentage:150-200 Mesh mullite powder 15%, 80-150 mesh silica flour 8%, 200-320 mesh bauxite 12%, Ludox 1.5%, poly vinyl acetate emulsion 1.5%, carboxymethyl cellulose acid sodium 0.4%, sodium alkyl benzene sulfonate 0.15%, sodium sulphate 0.35%, n-octyl alcohol 0.1%, fatty alcohol APEO 0.18%, surplus are water.
Embodiment two
A kind of Water-based coating for lost foam casting, the coating are made up of following components by weight percentage:150-200 Mesh mullite powder 18%, 80-150 mesh silica flour 5%, 200-320 mesh bauxite 18%, Ludox 1.2%, poly vinyl acetate emulsion 3.0%, carboxymethyl cellulose acid sodium 0.1%, sodium alkyl benzene sulfonate 0.35%, sodium sulphate 0.15%, n-octyl alcohol 0.3%, fatty alcohol APEO 0.10%, surplus are water.
Embodiment three
A kind of Water-based coating for lost foam casting, the coating are made up of following components by weight percentage:150-200 Mesh mullite powder 16%, 80-150 mesh silica flour 6%, 200-320 mesh bauxite 15%, Ludox 1.5%, poly vinyl acetate emulsion 2.5%, carboxymethyl cellulose acid sodium 0.3%, sodium alkyl benzene sulfonate 0.25%, sodium sulphate 0.25%, n-octyl alcohol 0.2%, fatty alcohol APEO 0.15%, surplus are water.
The preparation method of the coating of above-described embodiment one to three is:
A. mullite powder, silica flour and bauxite base-material are stirred in coating grinding equipment, is subsequently adding total water Base-material in base-material is moistened and is stirred out by the water of the 35% of amount;
B. by Ludox, poly vinyl acetate emulsion, carboxymethyl cellulose acid sodium, sodium alkyl benzene sulfonate, sodium sulphate, n-octyl alcohol, fat Fat alcohol APEO is sequentially added in the above-mentioned base-material for having moistened and having stirred out, and add total Water 5% water in painting 45min is stirred in material grinding equipment.
C. and then by the water of surplus in coating grinding equipment, and grind 150min.
Jing is tested, and the density of the Water-based coating for lost foam casting of embodiment one to three is 1.4-1.6g/cm3, place 72 Suspensibility after hour is more than 98%;The shear stress of coating is 16-19Pa.With the apparent viscosity for applying 4 viscosimeters measure coating It is worth for 40-42s.Thixotroping rate is 15%-17%.The brushing index of coating, drip amount and drip time respectively may be about 6.0,0.4g And 10s.The low temperature intensity of coating is higher than 800g/mm.After 1200 DEG C of roastings, the intensity of paint coatings is higher than 600g/mm.Apply The low temperature gas permeability of layer is higher than 13cm2·(kPa·min)-1, hot permeability is more than 30cm2·(kPa·min)-1
Applicant states that the present invention illustrates the detailed process equipment of the present invention and technological process by above-described embodiment, But above-mentioned detailed process equipment and technological process are the invention is not limited in, that is, does not mean that the present invention has to rely on above-mentioned detailed Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, Addition, the selection of concrete mode to the equivalence replacement and auxiliary element of each raw material of product of the present invention etc., all fall within the present invention's Within the scope of protection domain and disclosure.

Claims (3)

1. a kind of Water-based coating for lost foam casting, it is characterised in that the coating is by following component groups by weight percentage Into:It is 150-200 mesh mullite powder 15%, 80-150 mesh silica flour 8%, 200-320 mesh bauxite 12%, Ludox 1.5%, poly- Vinyl acetate breast 1.5%, carboxymethyl cellulose acid sodium 0.4%, sodium alkyl benzene sulfonate 0.15%, sodium sulphate 0.35%, n-octyl alcohol 0.1%th, AEO 0.18%, surplus are water.
2. a kind of Water-based coating for lost foam casting, it is characterised in that the coating is by following component groups by weight percentage Into:It is 150-200 mesh mullite powder 18%, 80-150 mesh silica flour 5%, 200-320 mesh bauxite 18%, Ludox 1.2%, poly- Vinyl acetate breast 3.0%, carboxymethyl cellulose acid sodium 0.1%, sodium alkyl benzene sulfonate 0.35%, sodium sulphate 0.15%, n-octyl alcohol 0.3%th, AEO 0.10%, surplus are water.
3. a kind of Water-based coating for lost foam casting, it is characterised in that the coating is by following component groups by weight percentage Into:It is 150-200 mesh mullite powder 16%, 80-150 mesh silica flour 6%, 200-320 mesh bauxite 15%, Ludox 1.5%, poly- Vinyl acetate breast 2.5%, carboxymethyl cellulose acid sodium 0.3%, sodium alkyl benzene sulfonate 0.25%, sodium sulphate 0.25%, n-octyl alcohol 0.2%th, AEO 0.15%, surplus are water.
CN201110307594.7A 2011-10-11 2011-10-11 A kind of Water-based coating for lost foam casting Active CN102371336B (en)

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Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
CN102836952A (en) * 2012-08-31 2012-12-26 太仓科博尔精密铸业有限公司 Resin sand type casting coating and preparation method thereof
CN102873262B (en) * 2012-08-31 2014-08-27 太仓科博尔精密铸业有限公司 Lost foam coating and preparation method thereof
CN102836953A (en) * 2012-08-31 2012-12-26 太仓科博尔精密铸业有限公司 Cast iron lost foam coating and preparation method thereof
CN103357813A (en) * 2013-07-24 2013-10-23 翼城县福旺铸造实业有限公司 Lost foam steel-casting paint formula and technology method thereof
CN105562592A (en) * 2016-01-11 2016-05-11 明光市留香泵业有限公司 Low-carbon-residue high-temperature-creep-resisting lost foam casting water-based paint with nanophase ceramic powder solution enhancement function and preparation method of water-based paint
CN107350424A (en) * 2017-09-11 2017-11-17 芜湖市云峰铸造有限责任公司 A kind of sand casting water-based coating
CN109261891B (en) * 2018-09-04 2020-07-31 安徽惠明机械制造有限公司 Coating for die-casting mold and preparation method thereof

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JP4309712B2 (en) * 2003-07-30 2009-08-05 株式会社木村鋳造所 Full mold casting method
CN101502868B (en) * 2009-03-06 2010-08-11 靖江市黎明铸造材料厂 Centrifugal casting radiant tube paint and preparation method thereof
CN101491823B (en) * 2009-03-06 2010-06-02 靖江市黎明铸造材料厂 Centrifugal casting roller coatings and preparation method thereof
CN101497105B (en) * 2009-03-12 2011-08-10 深圳市景鼎现代科技有限公司 Cast form water borne coating and technique for preparing the same
CN101642795B (en) * 2009-08-18 2011-08-03 泰州市永昌冶金设备有限公司 Coating for polystyrene lost foam mould
CN101767184B (en) * 2010-02-04 2011-09-28 西安理工大学 Lost foam casting cast iron coating for preventing carbon defects and preparation method thereof

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