CN102368567B - Formation method for dynamic lead-acid cell jar formation - Google Patents

Formation method for dynamic lead-acid cell jar formation Download PDF

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Publication number
CN102368567B
CN102368567B CN2011103092497A CN201110309249A CN102368567B CN 102368567 B CN102368567 B CN 102368567B CN 2011103092497 A CN2011103092497 A CN 2011103092497A CN 201110309249 A CN201110309249 A CN 201110309249A CN 102368567 B CN102368567 B CN 102368567B
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charging
hours
acid
battery
formation
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CN102368567A (en
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张森
赵文超
余江
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Chaowei Power Supply Co Ltd
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Chaowei Power Supply Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The invention provides a formation method for dynamic lead-acid cell jar formation, comprising the following steps: adding sulfuric acid in a lead-acid cell, then standing for 2 h, and then starting charging; charging 0.112 (A) for 2 h; charging 0.212 (A) for 2 h; charging 0.312 (A) for 30 h; charging 0.412 (A) for 10 h; 0.212 (A) for 10 h; discharging -0.512 (A) to 12 V/per cell; charging 0.412 (A) for 10 h; charging 0.312 (A) for 5 h; charging 0.212 (A) for 5 h; discharging -1.012 (A) to 11.00 V/per cell; charging 0.412 (A) for 4 h; charging 0.312 (A) for 5 h; charging 0.1512 (A) for 2 h; standing for 1 h; extracting acid and washing; discharging -1.012 (A) to 10.50 V/per cell; charging 0.312 (A) for 6.5 h; charging 0.212 (A) for 2 h; charging 0.112 (A) for 2.0 h, and checking acid leakage. According to the invention, the positive plate formation of the cell can be guaranteed, and the active substance of the cell can transformed fully.

Description

A kind of chemical synthesizing method of power-type lead-acid container formation
Technical field
The present invention relates to the storage battery field, be specifically related to a kind of chemical synthesizing method of power-type lead-acid container formation.
Background technology
At present exist a lot of problems in the process that is internalized into of lead-acid battery: 1, be difficult to guarantee that the positive plate of battery changes into evenly, positive plate is prone to spends phenomenon in vain; 2, the active material of battery is difficult to abundant conversion; 3, be difficult to guarantee before the discharge of battery combo to be filled with electric weight inexcessive, reduced the authenticity of discharge data; 4, the difference of temperature causes the battery discharge data distortion behind the battery overcharge; 5, there is the phenomenon of leakage often to occur after battery dispatches from the factory.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of chemical synthesizing method of power-type lead-acid container formation, the positive plate that can guarantee battery changes into evenly, the active material of battery is fully changed, before the battery combo discharge to be filled with electric weight inexcessive, the battery discharge data are undistorted, the phenomenon of leakage can not occur after battery dispatches from the factory.
For solving above-mentioned existing technical problem, the present invention adopts following scheme: a kind of chemical synthesizing method of power-type lead-acid container formation is characterized in that: comprise the steps:
Step 1: left standstill 2 hours after sulfuric acid added lead-acid battery, restart charging;
Step 2: 0.1l 2(A) charging is 2 hours;
Step 3: 0.2l 2(A) charging is 2 hours;
Step 4: 0.3l 2(A) charging is 30 hours;
Step 5: 0.4l 2(A) charging is 10 hours;
Step 6: 0.2l 2(A) charging is 10 hours;
Step 7 :-0.5l 2(A) only be discharged to 12V/;
Step 8: 0.4l 2(A) charging is 10 hours;
Step 9: 0.3l 2(A) charging is 5 hours;
Step 10: 0.2l 2(A) charging is 5 hours;
Step 11 :-1.0l 2(A) only be discharged to 11.00V/;
Step 12: 0.4l 2(A) charging is 4 hours;
Step 13: 0.3l 2(A) charging is 5 hours;
Step 14: 0.15l 2(A) charging is 2 hours;
Step 15: leave standstill and took out acid, cleaning in 1 hour;
Step 10 six :-1.0l 2(A) only be discharged to 10.50V/;
Step 10 seven: 0.3l 2(A) charging is 6.5 hours;
Step 10 eight: 0.2l 2(A) charging is 2 hours;
Step 10 nine: 0.1l 2(A) charging is 2.0 hours, checks to have or not to leak acid.
As preferably, the density of sulfuric acid is 1.260g/cm in the described step 1 3, temperature is 25 ℃.
Beneficial effect:
The present invention adopts technique scheme that a kind of chemical synthesizing method of power-type lead-acid container formation is provided, the positive plate that has guaranteed battery changes into evenly, the active material of battery is fully changed, before the battery combo discharge to be filled with electric weight inexcessive, the battery discharge data are undistorted, the phenomenon of leakage can not occur after battery dispatches from the factory.
Embodiment
A kind of chemical synthesizing method of power-type lead-acid container formation comprises the steps:
Step 1: left standstill 2 hours after sulfuric acid added lead-acid battery, restart charging;
Step 2: 0.1l 2(A) charging is 2 hours;
Step 3: 0.2l 2(A) charging is 2 hours;
Step 4: 0.3l 2(A) charging is 30 hours;
Step 5: 0.4l 2(A) charging is 10 hours;
Step 6: 0.2l 2(A) charging is 10 hours;
Step 7 :-0.5l 2(A) only be discharged to 12V/;
Step 8: 0.4l 2(A) charging is 10 hours;
Step 9: 0.3l 2(A) charging is 5 hours;
Step 10: 0.2l 2(A) charging is 5 hours;
Step 11 :-1.0l 2(A) only be discharged to 11.00V/;
Step 12: 0.4l 2(A) charging is 4 hours;
Step 13: 0.3l 2(A) charging is 5 hours;
Step 14: 0.15l 2(A) charging is 2 hours;
Step 15: leave standstill and took out acid, cleaning in 1 hour;
Step 10 six :-1.0l 2(A) only be discharged to 10.50V/;
Step 10 seven: 0.3l 2(A) charging is 6.5 hours;
Step 10 eight: 0.2l 2(A) charging is 2 hours;
Step 10 nine: 0.1l 2(A) charging is 2.0 hours, checks to have or not to leak acid.
The density of sulfuric acid is 1.260g/cm in the described step 1 3, temperature is 25 ℃.
Step 2 to step 11 is that battery changes into the stage: step 2 to the electric weight that is filled with first of step 6 is 7.5 to 8 times of rated capacity, has guaranteed that battery positive plate changes into even, well-done, has solved the phenomenon of spending in vain of positive plate; The shallow discharge of step 7 is beneficial to the again conversion of active material; Step 8 to step 11 is the stage that changes into again, has guaranteed the abundant conversion of cell active materials.
Step 12 to step 14 is that battery is mended the electricity stage, is filled with electric weight and is 1.7 times of rated capacity, mainly be guarantee before the discharge of battery combo to be filled with electric weight inexcessive, guarantee the authenticity of discharge data.
Step 15 be battery take out acid, wash phase, battery temperature after the cleaning will be close to ambient temperature, avoided causing the battery discharge data distortion because of the difference of temperature behind the battery overcharge, in the very first time safety valve of battery is added simultaneously and build the oxidation that has reduced the self discharge of battery and stopped negative plate.
Step 10 six is battery combo discharge regime, and load voltage measures and record the parameter as the battery combo when average 10.50V, guarantees the authenticity of discharge data.
Step 10 seven to step 10 nine is that the last of battery replenishes the electricity stage, the charge parameter of onboard charger on the simulation market, be filled with electric weight and be the 1.25-1.28 of rated capacity doubly, guaranteed the stability of battery, the charging later stage checks and has or not the phenomenon of leaking acid, can stop to have after battery dispatches from the factory the phenomenon of leakage to occur fully.
l 2Refer to 2 hour rate current values.

Claims (2)

1. the chemical synthesizing method of a power-type lead-acid container formation is characterized in that: comprise the steps:
Step 1: left standstill 2 hours after sulfuric acid added lead-acid battery, restart charging;
Step 2: 0.1l 2(A) charging is 2 hours;
Step 3: 0.2l 2(A) charging is 2 hours;
Step 4: 0.3l 2(A) charging is 30 hours;
Step 5: 0.4l 2(A) charging is 10 hours;
Step 6: 0.2l 2(A) charging is 10 hours;
Step 7 :-0.5l 2(A) only be discharged to 12V/;
Step 8: 0.4l 2(A) charging is 10 hours;
Step 9: 0.3l 2(A) charging is 5 hours;
Step 10: 0.2l 2(A) charging is 5 hours;
Step 11 :-1.0l 2(A) only be discharged to 11.00V/;
Step 12: 0.4l 2(A) charging is 4 hours;
Step 13: 0.3l 2(A) charging is 5 hours;
Step 14: 0.15l 2(A) charging is 2 hours;
Step 15: leave standstill and took out acid, cleaning in 1 hour;
Step 10 six :-1.0l 2(A) only be discharged to 10.50V/;
Step 10 seven: 0.3l 2(A) charging is 6.5 hours;
Step 10 eight: 0.2l 2(A) charging is 2 hours;
Step 10 nine: 0.1l 2(A) charging is 2.0 hours, checks to have or not to leak acid;
Described l 2Refer to 2 hour rate current values.
2. the chemical synthesizing method of a kind of power-type lead-acid container formation according to claim 1, it is characterized in that: the density of sulfuric acid is 1.260g/cm in the described step 1 3, temperature is 25 ℃.
CN2011103092497A 2011-10-13 2011-10-13 Formation method for dynamic lead-acid cell jar formation Active CN102368567B (en)

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CN102593533B (en) * 2012-03-15 2013-11-20 超威电源有限公司 Method for internalizing valve-regulated lead acid storage battery
CN102723532A (en) * 2012-05-27 2012-10-10 山东圣阳电源科技有限公司 Rapid forming process used for internal formation of lead-acid storage batteries
CN103035958B (en) * 2012-12-18 2014-12-17 超威电源有限公司 Storage battery charging formation acid extraction and acid control process
CN103199214B (en) * 2013-03-08 2015-05-13 超威电源有限公司 Acid pumping control technology of container formation lead-acid storage battery
CN103311508A (en) * 2013-04-10 2013-09-18 陕西凌云蓄电池有限责任公司 Manufacturing method of tubular colloid storage battery for storing energy
CN103326081B (en) * 2013-06-27 2015-04-15 浙江天能电池(江苏)有限公司 First charging method for electrified polar plate battery of power-driven road vehicle
CN103384021B (en) * 2013-08-01 2016-07-06 超威电源有限公司 Accumulator is internalized into charge technology
CN103633388B (en) * 2013-11-08 2016-02-10 超威电源有限公司 A kind of be internalized into lead acid accumulator change into standard
CN103956523B (en) * 2014-04-15 2016-04-13 株洲冶炼集团股份有限公司 A kind of power car super accumulator formation method
CN104134826B (en) * 2014-07-09 2016-07-06 天能电池(芜湖)有限公司 A kind of accumulator eight is filled seven and is put and be internalized into charge technology
CN104218263B (en) * 2014-08-14 2016-08-24 超威电源有限公司 A kind of power type colloid battery internal formation process
CN105226332B (en) * 2015-09-30 2017-12-01 风帆有限责任公司 A kind of method for controlling valve-control sealed lead acid battery oxygen blast cyanidation
CN106058347B (en) * 2016-06-30 2018-12-14 济源市万洋绿色能源有限公司 A kind of lead-acid accumulator is internalized into pulse charge method
CN107528099B (en) * 2017-07-29 2020-01-17 界首市南都华宇电源有限公司 Formation method of quick-charging lead storage battery
CN109659638B (en) * 2018-12-18 2021-08-17 超威电源集团有限公司 Heavy-current formation process for power type lead storage battery
CN110148797B (en) * 2019-04-30 2021-11-19 超威电源集团有限公司 Formation method of lead-acid storage battery
CN111029671B (en) * 2019-12-10 2022-06-21 天能电池(芜湖)有限公司 Acid-adding charging process capable of reducing charging energy consumption
CN111477982B (en) * 2020-04-15 2021-12-28 天能电池(芜湖)有限公司 Formation process of low-charging-rate CNF battery for energy storage

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