CN102352498A - Method for preparing Al/Pb lamellar composite materials - Google Patents

Method for preparing Al/Pb lamellar composite materials Download PDF

Info

Publication number
CN102352498A
CN102352498A CN2011103063009A CN201110306300A CN102352498A CN 102352498 A CN102352498 A CN 102352498A CN 2011103063009 A CN2011103063009 A CN 2011103063009A CN 201110306300 A CN201110306300 A CN 201110306300A CN 102352498 A CN102352498 A CN 102352498A
Authority
CN
China
Prior art keywords
matrix material
salt
alloy
preparation
metal bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2011103063009A
Other languages
Chinese (zh)
Other versions
CN102352498B (en
Inventor
赖延清
蒋良兴
吕晓军
郝科涛
李劼
刘业翔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUNMING HENDERA SCIENCE AND TECHNOLOGY Co.,Ltd.
Original Assignee
Central South University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central South University filed Critical Central South University
Priority to CN2011103063009A priority Critical patent/CN102352498B/en
Publication of CN102352498A publication Critical patent/CN102352498A/en
Application granted granted Critical
Publication of CN102352498B publication Critical patent/CN102352498B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/14—Electrodes for lead-acid accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/045—Electrochemical coating; Electrochemical impregnation
    • H01M4/0452—Electrochemical coating; Electrochemical impregnation from solutions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/045—Electrochemical coating; Electrochemical impregnation
    • H01M4/0454—Electrochemical coating; Electrochemical impregnation from melts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0483—Processes of manufacture in general by methods including the handling of a melt
    • H01M4/0485—Casting
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/14—Electrodes for lead-acid accumulators
    • H01M4/16—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/82—Multi-step processes for manufacturing carriers for lead-acid accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

The invention relates to a method for preparing Al/Pb composite materials, which comprises three steps of base body surface pretreatment, surface chemical plating and metal bathing. An Al base body adopts a molten salt method for surface pretreatment for removing oil and oxides on the base body surface, and the fresh surface is protected form being oxidized again; the molten salt chemical plating is carried out in chloride molten salt containing lead elements, in addition, a certain amount of auxiliary salt is added into the molten salt for optimizing the alloy composition of a plating layer, and a transition layer is formed at the interface of the Al/Pb composite material; the metal bathing treatment is carried out in a Pb alloy melt body for many times after the chemical plating, and the ingredient and the thickness of the plating layer are controlled; and then, the heat treatment is carried out, the mutual diffusion of bonding interface elements is promoted, the stress of the plating layer is eliminated, the completeness of the plating layer is ensured, and the ingredient uniformity of the plating layer is improved. The method has the advantages that the operation of each work procedure is simple, the firm metallurgical bonding is formed between the Al/Pb composite materials, the Pb plating layer is compact and flat, and the thickness and the ingredients are controllable.

Description

A kind of preparation method of Al/Pb stratified composite
Technical field
The present invention relates to a kind of preparation method of Al/Pb matrix material, particularly a kind of preparation method of Al/Pb stratified composite belongs to metallic substance and fused salt chemistry field.
Background technology
Metal Pb and alloy thereof be because its excellent corrosion resistance and electrocatalysis ability, electrochemical field such as synthesizes and be widely used in hydrometallurgy, lead-acid cell, organism.But because lead density is big, poor electric conductivity, physical strength are low, it can increase labour intensity in actual application, improve electrode resistance volts lost and easy place creep, buckling deformation, and electrochemical process is had a negative impact.Therefore, improve the specific conductivity and the physical strength of Pb alloy electrode, the weight that reduces entire electrode seems particularly important.
With respect to metal Pb, metal A l has following advantage: (1) Al conducts electricity very well, and electric conductivity is 7 times of Pb; (2) physical strength of Al is high, and tensile strength is more than 5 times of Pb; (3) Al is the metal of extensive industrialization, and material is easy to get and low price; 4) Al's is in light weight, and density is merely 24% of Pb.Therefore, if can prepare well-set Pb layer in metal A l both sides, form the Al/Pb matrix material, advantage that can comprehensive two kinds of metals improves the performance of Pb electrode comprehensively.Yet metal A l and Pb are divided into difficult miscible system in thermodynamic system, and metal A l very easily forms the fine and close sull of one deck in air, are difficult at the Al matrix surface and form one deck densification, atresia, and the good Pb coating of basal body binding force.
Traditional aluminium surface lead plating technology; Generally need to be coated with transition layer on the aluminum substrate surface earlier; Announced a kind of preparation method of lead-aluminum composite anode plate like patent 200710065927.3, utilized the method for dipping to plate other metal of one deck in advance, then casting one deck Pb alloy on the surface in surface of aluminum plate.Patent 01135605.7 has been announced a kind of working method of lead-coated light high conducting slab lattice, need surface of aluminum plate in advance immersion plating zinc or copper as transition layer.Patent 200910094290.X has announced the method for a kind of aluminium and aluminum alloy surface Direct Electroplating lead, and aluminum substrate will pass through mechanical grinding, oil removing, alkali erosion, pickling process before lead plating, and between alkali erosion and pickling process, also has electric clean, activation procedure.Though this method has been saved the step of preplating transition layer, required pre-treatment step is many and complicated, and can only obtain pure lead-coat, and non-metallurgical binding between coating and the matrix is unfavorable for its practical application.Muscovite L.A.Yolshina immerses metal A l in the molten chloride that contains the Pb constituent element and carries out electroless plating Pb, has obtained the good Pb coating of bonding force.This method operation is simple, and matrix is the process of a consumption in the process of electroless plating, can guarantee that matrix is a unsalted surface forever, does not have zone of oxidation, and this can improve the bonding force of Al and Pb greatly.But, contain LiCl and KCl in the used fused salt, and the LiCl price is more expensive, the KCl suction is serious, and this has increased preparation cost and difficulty.Add this molten salt system and can only be coated with pure Pb coating, and be difficult to realize the complete covering of Pb coating to the Al matrix, there is hole in coating, does not form metallurgical binding between the Al/Pb, has had a strong impact on the application of Al/Pb matrix material.Contriver early stage is to improving molten salt system, and after the fused salt chemistry plating, increased the metal bath step, though can make coating complete, and bonding force increases, and also has following problem: 1) assist salt SnCl 2Though adding can promote the mutual diffusion of element, do not find in the metallograph significantly to cross coating, and the fused salt surface blistering is serious, very unfavorable to being coated with process; 2) though metal bath step may command Coating composition, the thinner thickness of coating, circulation time under lead-acid cell positive and negative electrode WV will soon peeling, comes off; 3) substrate pretreated is a mechanical grinding, matrix that can not deal with complex shapes.Though and aqueous solution pre-treatment is to the base shape no requirement (NR), the drying process of handling matrix well can make the oxidation again of fresh matrix, to coating and matrix combine totally unfavorable; 4) because whole process time is shorter, and the mutual diffusion of element is insufficient, the bonding force of coating and matrix is not enough.
Therefore, need also need further to improve to this method.
Summary of the invention
The present invention is directed to the deficiency of traditional fused salt chemistry electroplating method, molten salt system and technology have been carried out major tuneup, and its concrete processing parameter is described, make that gained Al/Pb matrix material combines firmly, thickness and controllable component.
The preparation method of a kind of Al/Pb matrix material of the present invention comprises the steps:
The first step: matrix surface pre-treatment
Al or Al alloy substrate are soaked in the fused salt mixt that comprises a kind of muriate and a kind of fluorochemical at least; The metallic element of said muriate and fluorochemical is at least a among Al, Na, K, Ca, Mg, the Li; Said fused salt mixt temperature is 250-600 ℃, and soak time is 30s～10min;
Second step: surface chemical plating
Al or Al alloy substrate that the first step is obtained place PbCl 2-NaCl-CaCl 2Fused salt in, said temperature of molten salt is 350 ℃～550 ℃, the electroless plating time is 30s～5min; At Al or Al alloy substrate coating surface one deck ternary alloy transition layer;
The 3rd step: metal bath
The test specimen that second step was obtained places Pb or Pb alloy (Pb-Me) melt, carries out the one-time surface metal bath at least, and the temperature of said Pb or Pb alloy (Pb-Me) melt is 320～550 ℃, and the time of a said metal bath is 3～60s; Promptly obtain the Al/Pb matrix material.
Among the preparation method of a kind of Al/Pb matrix material of the present invention, in the fused salt of said surface chemical plating, the quality percentage composition of each component is PbCl 250%～90%, NaCl 5%～30%, CaCl 21%～20%;
Among the preparation method of a kind of Al/Pb matrix material of the present invention, also include in the fused salt of said surface chemical plating and account for said PbCl 2-NaCl-CaCl 2Mass percent be the auxilliary salt of 0～10% halogenide, the auxilliary salt of said halogenide is the muriate or the fluorochemical of at least a element among Sn, Cu, Na, K, Ag, Al, the RE.
Among the preparation method of a kind of Al/Pb matrix material of the present invention, the alloying element Me in said Pb or Pb alloy (Pb-Me) melt is selected from least a among Ag, Ca, RE, Bi, Cu, Sn, Sb, the Al.
Among the preparation method of a kind of Al/Pb matrix material of the present invention, said metal bath number of times is 1～5 time, selects according to the requirement to thickness of coating.
The preparation method of a kind of Al/Pb matrix material of the present invention, the Al/Pb matrix material that said metal bath obtains is incubated 30min～5h, furnace cooling in 100～300 ℃.
The preparation method of a kind of Al/Pb matrix material of the present invention comprises the steps:
The first step: substrate pretreated and surface chemical plating
Al or Al alloy substrate are placed PbCl 2-NaCl-CaCl 2In the auxilliary salt of main salt and halogenide, the auxilliary salt of said halogenide is for comprise the fused salt mixt of a kind of muriate and a kind of fluorochemical at least; Said muriatic metallic element is at least a among Sn, Al, Ag, Cu, the RE, and the metallic element of fluorochemical is at least a among Na, K, Mg, the Li; The quality percentage composition of the auxilliary salt of said halogenide is 0～10%; The temperature of said fused salt is 350 ℃～550 ℃, and the fused salt treatment time is 30s～20min; At Al or Al alloy substrate coating surface one deck ternary alloy transition layer;
Second step: metal bath
The test specimen that the first step is obtained places Pb or Pb alloy (Pb-Me) melt, carries out the one-time surface metal bath at least, and the temperature of said Pb or Pb alloy (Pb-Me) melt is 320～550 ℃, and the time of a said metal bath is 3～60s; Promptly obtain the Al/Pb matrix material.
The present invention has carried out major tuneup to traditional molten electroless plating Pb method, and technological process and gained Al/Pb matrix material have following advantage:
(1) the surface preparation step of matrix, utilize partially halogenated thing fused salt can with Al 2O 3The characteristics of reaction, the greasy dirt and the sull of removing aluminum alloy surface.Realize oil removing and remove one step of oxide compound and accomplish, and avoided the mechanical grinding method can not the dealing with complicated matrix and the aqueous solution handle the defective of the reoxidation of back drying course.Simultaneously, the fused salt pre-treatment can be carried out effective preheating and activation with matrix, helps improving Al surface chemical plating reaction uniformity and the difform Al/Pb matrix material of preparation;
(2) adopt PbCl 2-NaCl-CaCl 2Fused salt carries out surface chemical plating, can guarantee fresh Al surface not by oxidation again, and Al combines firmly with Pb.Particularly at PbCl 2-NaCl-CaCl 2Fused salt in add the auxilliary salt (CuCl of small amount of halide 2, NaF, AgCl and RECl 2), not only can effectively promote the Al/Pb interface to form the ternary alloy transition layer, and the appearance that can stop fused salt surfactant foam layer, make easy and simple to handle;
(3) the employing metal bath after the fused salt chemistry plating is handled; And under the temperature lower, carry out repeatedly metal bath than fused salt, can effectively regulate and control the composition and the thickness of coating, and repair the hole in the coating in the electroless plating process; Make coating smooth, smooth, complete, satisfy application requiring;
(4) the Al/Pb matrix material to preparation carries out 100～300 ℃ insulation annealing, can promote the mutual diffusion of bonding interface element, forms tangible transition layer, thereby further improves the bonding force of coating and matrix.
In sum, process method of the present invention is simple, and is easy to operate, to the shape no requirement (NR) of matrix, helps on the Al of complicacy matrix, forming the complete and uniform Pb alloy layer of thickness.Simultaneously, formed firm metallurgical binding between gained Al/Pb composite layer and the matrix, Pb coating is fine and close, smooth, thickness and controllable component.Be suitable for industrial applications.
Embodiment
In conjunction with following examples content of the present invention is elaborated.
Embodiment 1:
With metal A l is matrix, at 250 ℃ AlCl 3Surface preparation 20min in the-KF melt takes out matrix, and immerses PbCl 2(50wt.%)-NaCl (30wt.%)-CaCl 2(20wt.%) carry out surface chemical plating in the melting salt, temperature of molten salt is 550 ℃; Behind the 30s matrix is taken out from fused salt; Immerse temperature immediately and be and carry out surface metal in 550 ℃ Pb-Sb (15wt.%) alloy melt and bathe; Take out behind the 20s, at 100 ℃ of following thermal treatment 5h, obtaining thickness of coating is the Al/Pb-Sb stratified composite of 40um with sample.
Embodiment 2:
With porous metal Al-Sn (5wt.%) alloy is matrix, at 600 ℃ NaF-CaCl 2Surface preparation 30s in the-NaCl melt takes out matrix, and immerses PbCl 2(80wt.%)-NaCl (10wt.%)-CaCl 2(8wt.%)-CuCl 2(2wt.%) carry out surface chemical plating in the melting salt, temperature of molten salt is 450 ℃.Behind the 4min matrix is taken out from fused salt; Immerse temperature immediately and be and carry out surface metal in Pb-Sn (3wt.%)-Ca (0.4wt.%) alloy melt of 320 ℃ and bathe; Take out behind the 3s; Repeat metal bath 5 times, at 200 ℃ of following thermal treatment 2.5h, obtaining thickness of coating is the Al-Sn/Pb-Sn-Ca composite porous material of 250um with sample.
Embodiment 3:
With metal A l-Cu (0.3wt.%)-Si (5wt.%) alloy is matrix, and surface preparation 10min in 400 ℃ KF-KCl melt takes out matrix, and immerses PbCl 2(92wt.%)-NaCl (5wt.%)-CaCl 2(1.5wt.%)-and carrying out surface chemical plating in NaF (0.5wt.%)-AgCl (1wt.%) melting salt, temperature of molten salt is 360 ℃; Behind the 5min matrix is taken out from fused salt; Immerse temperature immediately and be and carry out surface metal in Pb-Ag (1wt.%)-Nd (0.05wt.%) alloy melt of 350 ℃ and bathe; Take out behind the 60s; Repeat metal bath 3 times, at 300 ℃ of following thermal treatment 30min, obtaining thickness of coating is the Al-Cu-Si/Pb-Ag-Nd matrix material of 170um with sample.
Embodiment 4:
With metal A l rod is matrix, and it is immersed PbCl 2(82wt.%)-NaCl (10wt.%)-CaCl 2(5.5wt.%)-NaF (0.5wt.%)-CeCl 2(2wt.%) carry out surface preparation and electroless plating in the melting salt, temperature of molten salt is 430 ℃.Behind the 3min matrix is taken out from fused salt; Immerse temperature immediately and be and carry out surface metal in Pb-Sb (2wt.%)-Ce (0.05wt.%) alloy melt of 350 ℃ and bathe; Take out behind the 30s; Repeat metal bath 3 times, at 300 ℃ of following thermal treatment 20min, obtaining thickness of coating is the Al/Pb-Sb-Ce matrix material of 170um with sample.

Claims (10)

1. the preparation method of an Al/Pb matrix material comprises the steps:
The first step: matrix surface pre-treatment
Al or Al alloy substrate are soaked in the fused salt mixt that comprises a kind of muriate and a kind of fluorochemical at least; The metallic element of said muriate and fluorochemical is at least a among Al, Na, K, Ca, Mg, the Li; Said fused salt mixt temperature is 250-600 ℃, and soak time is 30s～10min;
Second step: surface chemical plating
Al or Al alloy substrate that the first step is obtained place PbCl 2-NaCl-CaCl 2Fused salt in, said temperature of molten salt is 350 ℃～550 ℃, the electroless plating time is 30s～5min; At Al or Al alloy substrate coating surface one deck ternary alloy transition layer;
The 3rd step: metal bath
The test specimen that second step was obtained places Pb or Pb alloy (Pb-Me) melt, carries out the one-time surface metal bath at least, and the temperature of said Pb or Pb alloy (Pb-Me) melt is 320～550 ℃, and the time of a said metal bath is 3～60s; Promptly obtain the Al/Pb matrix material.
2. the preparation method of a kind of Al/Pb matrix material according to claim 1 is characterized in that: in the fused salt of said surface chemical plating, the quality percentage composition of each component is PbCl 250%～90%, NaCl5%～30%, CaCl 21%～20%;
3. the preparation method of a kind of Al/Pb matrix material according to claim 2 is characterized in that: also include in the fused salt of said surface chemical plating and account for said PbCl 2-NaCl-CaCl 2Mass percent be the auxilliary salt of 0～10% halogenide, the auxilliary salt of said halogenide is the muriate or the fluorochemical of at least a element among Sn, Cu, Na, K, Ag, Al, the RE.
4. the preparation method of a kind of Al/Pb matrix material according to claim 3 is characterized in that: the alloying element Me in said Pb or Pb alloy (Pb-Me) melt is selected from least a among Ag, Ca, RE, Bi, Cu, Sn, Sb, the Al.
5. the preparation method of a kind of Al/Pb matrix material according to claim 4 is characterized in that: said metal bath number of times is 1～5 time.
6. according to the preparation method of any described a kind of Al/Pb matrix material of claim 1-5, it is characterized in that: the Al/Pb matrix material that said metal bath obtains is incubated 30min～5h, furnace cooling in 100～300 ℃.
7. the preparation method of an Al/Pb matrix material comprises the steps:
The first step: substrate pretreated and surface chemical plating
Al or Al alloy substrate are placed PbCl 2-NaCl-CaCl 2In the auxilliary salt of main salt and halogenide, the auxilliary salt of said halogenide is for comprise the fused salt mixt of a kind of muriate and a kind of fluorochemical at least; Said muriatic metallic element is at least a among Sn, Al, Ag, Cu, the RE, and the metallic element of fluorochemical is at least a among Na, K, Mg, the Li; The quality percentage composition of the auxilliary salt of said halogenide is 0～10%; The temperature of said fused salt is 350 ℃～550 ℃, and the fused salt treatment time is 30s～20min; At Al or Al alloy substrate coating surface one deck ternary alloy transition layer;
Second step: metal bath
The test specimen that the first step is obtained places Pb or Pb alloy (Pb-Me) melt, carries out the one-time surface metal bath at least, and the temperature of said Pb or Pb alloy (Pb-Me) melt is 320～550 ℃, and the time of a said metal bath is 3～60s; Promptly obtain the Al/Pb matrix material.
8. the preparation method of a kind of Al/Pb matrix material according to claim 7 is characterized in that: in the fused salt of said surface chemical plating, the quality percentage composition of each component is PbCl 250%～90%, NaCl5%～30%, CaCl 21%～20%;
9. the preparation method of a kind of Al/Pb matrix material according to claim 8 is characterized in that: said metal bath number of times is 1～5 time.
10. according to the preparation method of any described a kind of Al/Pb matrix material of claim 1-9, it is characterized in that: the Al/Pb matrix material that said metal bath obtains is incubated 30min～5h, furnace cooling in 100～300 ℃.
CN2011103063009A 2010-10-18 2011-10-11 Method for preparing Al/Pb lamellar composite materials Active CN102352498B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011103063009A CN102352498B (en) 2010-10-18 2011-10-11 Method for preparing Al/Pb lamellar composite materials

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201010510065.2 2010-10-18
CN2010105100652A CN101949031A (en) 2010-10-18 2010-10-18 Composite porous electrode for sulfuric acid system and preparation method thereof
CN2011103063009A CN102352498B (en) 2010-10-18 2011-10-11 Method for preparing Al/Pb lamellar composite materials

Publications (2)

Publication Number Publication Date
CN102352498A true CN102352498A (en) 2012-02-15
CN102352498B CN102352498B (en) 2013-01-02

Family

ID=43452653

Family Applications (4)

Application Number Title Priority Date Filing Date
CN2010105100652A Pending CN101949031A (en) 2010-10-18 2010-10-18 Composite porous electrode for sulfuric acid system and preparation method thereof
CN2011103063009A Active CN102352498B (en) 2010-10-18 2011-10-11 Method for preparing Al/Pb lamellar composite materials
CN2011103061569A Active CN102383145B (en) 2010-10-18 2011-10-11 Composite porous electrode for sulfuric acid system and preparation method thereof
CN2011103101091A Expired - Fee Related CN102315455B (en) 2010-10-18 2011-10-13 Aluminium-based light-type grid for plumbic acid cells and preparation method thereof

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN2010105100652A Pending CN101949031A (en) 2010-10-18 2010-10-18 Composite porous electrode for sulfuric acid system and preparation method thereof

Family Applications After (2)

Application Number Title Priority Date Filing Date
CN2011103061569A Active CN102383145B (en) 2010-10-18 2011-10-11 Composite porous electrode for sulfuric acid system and preparation method thereof
CN2011103101091A Expired - Fee Related CN102315455B (en) 2010-10-18 2011-10-13 Aluminium-based light-type grid for plumbic acid cells and preparation method thereof

Country Status (3)

Country Link
CN (4) CN101949031A (en)
WO (1) WO2012051797A1 (en)
ZA (1) ZA201302807B (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101949031A (en) * 2010-10-18 2011-01-19 中南大学 Composite porous electrode for sulfuric acid system and preparation method thereof
CN102206838B (en) * 2011-04-22 2013-03-13 昆明理工恒达科技有限公司 Method for preparing novel anode material for non-ferrous metal electrodeposition
CN102593529B (en) * 2012-02-24 2014-08-27 中南大学 Variable-polarity lead-acid battery and using method thereof
CN102610829B (en) * 2012-03-23 2015-01-21 江苏华富储能新技术股份有限公司 Cadmium-free copper, aluminum and rare earth alloy grid of power type lead-acid battery and preparation method of cadmium-free copper, aluminum and rare earth alloy grid
CN102747408A (en) * 2012-07-12 2012-10-24 内蒙古第一机械集团有限公司 Lead-based multivariant alloy electroplating anode
CN103794754B (en) * 2012-11-02 2017-04-12 华为技术有限公司 Composite negative electrode and preparation method thereof as well as electrochemical power source and application thereof
CN103710731A (en) * 2013-12-10 2014-04-09 中南大学 Composite anode used for wet metallurgy
CN104347848A (en) * 2014-10-10 2015-02-11 吴骏 Method for preparing electrode plate of storage battery
CN104466192B (en) * 2014-11-14 2018-02-02 超威电源有限公司 Lead acid accumulator plate grid structure
CN104882616B (en) * 2015-05-19 2018-10-02 李毛丁 Lead-acid battery 3D collectors and preparation method thereof
CN104868176B (en) * 2015-05-19 2018-10-09 李毛丁 A kind of 3D lead-acid batteries and preparation method thereof
CN105552314B (en) * 2015-12-08 2017-09-26 哈尔滨工业大学 A kind of preparation method of high reliability bipolar plates for bipolarity lead accumulator
CN105537312B (en) * 2015-12-21 2018-02-02 洛阳铜一金属材料发展有限公司 A kind of copper-lead complex plate strip and preparation method thereof
CN105945084B (en) * 2016-05-17 2018-04-06 湖南汇博金属材料有限责任公司 Surface cupric stainless steel fibre and its preparation technology
CN107665995A (en) * 2017-09-05 2018-02-06 超威电源有限公司 A kind of lead-acid battery aluminium base grid and preparation method thereof, preparation facilities
CN110129593B (en) * 2019-04-18 2020-08-04 肇庆理士电源技术有限公司 Method for preparing alloy
CN112439784B (en) * 2019-08-29 2023-09-22 青岛九环新越新能源科技股份有限公司 Composite metal belt production method based on liquid metal
CN110838571B (en) * 2019-11-25 2021-04-02 北京居安瑞韩电子有限公司 Lead-coated aluminum electrode manufacturing method and storage battery
CN111063894A (en) * 2019-11-30 2020-04-24 河南超威电源有限公司 Rare earth grid alloy for lead-acid storage battery
CN112225295B (en) * 2020-10-19 2021-10-15 南京理工大学 Tubular microporous titanium-based ruthenium oxide film anode applied to wastewater treatment and preparation method thereof
CN112736366B (en) * 2020-12-29 2023-06-27 上海应用技术大学 Method for cast-welding light metal negative grid lead storage battery busbar
CN113046787A (en) * 2021-03-12 2021-06-29 赵坤 Electrolyte, system and method for wet lead recovery of waste lead storage battery lead plaster ternary system
CN113097573B (en) * 2021-03-25 2022-08-12 北京阳光鸿志电气工程技术有限公司 Quick-charging full-sealed maintenance-free lead-acid storage battery
CN113394408A (en) * 2021-06-17 2021-09-14 昆明高聚科技有限公司 Long-life light composite positive grid and preparation method thereof, and positive electrode plate and preparation method thereof
CN113381263B (en) * 2021-08-11 2021-10-15 南通斯高蕊机械设备有限公司 Intelligent production device of high-uniformity carbon brush
CN114039041B (en) * 2021-11-04 2022-09-09 昆明理工恒达科技股份有限公司 High-capacity lead-carbon energy storage battery and preparation method thereof
CN114804301B (en) * 2022-04-11 2023-06-27 贵州大学 Electroosmosis composite doped manganese oxide coated electrode and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5794567A (en) * 1980-12-02 1982-06-12 Aichi Steel Works Ltd Method for coating dissimilar metal on metal
US20010004477A1 (en) * 1999-12-09 2001-06-21 Akira Fukunaga Solution containing metal component, method of and apparatus for forming thin metal film
CN101608326A (en) * 2009-04-03 2009-12-23 昆明理工大学 The method of aluminium and aluminum alloy surface Direct Electroplating lead

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA865535B (en) * 1985-07-30 1987-03-25 Polycristal Technologies Corp Porous electrodes and method of making same
US5013414A (en) * 1989-04-19 1991-05-07 The Dow Chemical Company Electrode structure for an electrolytic cell and electrolytic process used therein
JPH03173065A (en) * 1989-11-30 1991-07-26 Yuasa Battery Co Ltd Sealed lead-acid battery
DE19619333C1 (en) * 1996-05-14 1997-05-15 Dirk Schulze Electrode covered by graded fine-coarse-fine sintered layers of titanium particles
CN100562606C (en) * 2004-08-31 2009-11-25 三洋电机株式会社 The manufacture method of electrode for electrolysis and electrode for electrolysis
JP2007046129A (en) * 2005-08-11 2007-02-22 Sanyo Electric Co Ltd Electrode for electrolysis, and method for producing electrode for electrolysis
CN101235521B (en) * 2007-01-29 2010-07-14 中南大学 Energy-saving anode for non-ferrous metal electrodeposition
CN101092707A (en) * 2007-04-06 2007-12-26 昆明理工大学 Method for preparing aluminium and lead composite electrode material
CN101333668A (en) * 2008-07-18 2008-12-31 中南大学 Method for preparing Pb-based porous energy-conserving anode for non-ferrous metal deposition
CN101922024B (en) * 2010-09-08 2011-10-12 中南大学 Light composite electro-catalysis energy-saving anode for non-ferrous metal electro-deposition and preparation method thereof
CN101949031A (en) * 2010-10-18 2011-01-19 中南大学 Composite porous electrode for sulfuric acid system and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5794567A (en) * 1980-12-02 1982-06-12 Aichi Steel Works Ltd Method for coating dissimilar metal on metal
US20010004477A1 (en) * 1999-12-09 2001-06-21 Akira Fukunaga Solution containing metal component, method of and apparatus for forming thin metal film
CN101608326A (en) * 2009-04-03 2009-12-23 昆明理工大学 The method of aluminium and aluminum alloy surface Direct Electroplating lead

Also Published As

Publication number Publication date
CN101949031A (en) 2011-01-19
ZA201302807B (en) 2014-05-26
WO2012051797A1 (en) 2012-04-26
CN102383145B (en) 2013-11-06
CN102383145A (en) 2012-03-21
CN102352498B (en) 2013-01-02
CN102315455A (en) 2012-01-11
CN102315455B (en) 2013-08-14

Similar Documents

Publication Publication Date Title
CN102352498B (en) Method for preparing Al/Pb lamellar composite materials
CN106825999B (en) A kind of preparation method of foam metal Combined Welding tablet
CN102703846B (en) Hot dip coating Zn-Al-Zr alloy coating and hot dip coating method of hot dip coating Zn-Al-Zr alloy coating
WO2014156638A1 (en) All-solid-state secondary battery
CN106670235B (en) Production method of copper-aluminum composite plate strip and copper-aluminum composite plate strip
CN109848611B (en) Preparation method of Sn-based composite solder sheet based on porous Ni/Cu alloy
CN101426961B (en) Heat-resistant Sn-plated Cu-Zn alloy strip suppressed in whiskering
CN105908226A (en) Steel sheet for hot pressing
CN113564507B (en) Hot galvanizing low-temperature plating solution and preparation method and application thereof
CN109750288B (en) Preparation method of high oxidation-resistant corrosion-resistant composite coating on surface of low-carbon steel
CN104762639B (en) Hydrometallurgy electro-deposition operation porous aluminum based composite anode and preparation method
CN100554518C (en) A kind of Ru-Ni-Al compound coating and preparation method thereof
CN104762638B (en) A kind of hydrometallurgy electro-deposition operation aluminum-base composite lead anode and preparation method thereof
CN1152974C (en) Hot-dip technology for producing steel-in-copper wires by flux activating method and its apparatus
CN110846662B (en) Copper/graphene-plated magnesium alloy composite material and preparation method thereof
CN114150348B (en) WC particle reinforced low-silver lead alloy composite anode plate for nonferrous metal electrodeposition and preparation method
CN110724976B (en) Aluminum/lead anode plate and preparation method thereof
CN114369786A (en) Aluminum-steel composite material and preparation method thereof
CN204570063U (en) Hydrometallurgy galvanic deposit operation porous aluminum based composite anode
CN108330324A (en) New zinc magnesium-based galvanizing by dipping spends Mg-In-Ni kirsites with no zinc
CN113136536B (en) Method for modifying surface of low alloy steel based on hot dipping technology
CN113174503A (en) Preparation method of high-strength magnesium-based three-dimensional graphene composite material
CN114293038B (en) Preparation method of corrosion-resistant cerium-containing Zn-Cu-Ti coating
CN115608961A (en) Light high-strength high-conductivity copper-aluminum composite material and preparation method thereof
CN102021610B (en) Light composite anode plate for electrodeposition and manufacturing method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20210419

Address after: No. 1299, Changyuan North Road, high tech Zone, Kunming, Yunnan 650000

Patentee after: KUNMING HENDERA SCIENCE AND TECHNOLOGY Co.,Ltd.

Address before: Yuelu District City, Hunan province 410083 Changsha Lushan Road No. 932

Patentee before: CENTRAL SOUTH University