CN102352440B - Method for recovering palladium sponge and bismuth from multi-metal catalyst utilized in sodium gluconate production - Google Patents
Method for recovering palladium sponge and bismuth from multi-metal catalyst utilized in sodium gluconate production Download PDFInfo
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- CN102352440B CN102352440B CN2011102241738A CN201110224173A CN102352440B CN 102352440 B CN102352440 B CN 102352440B CN 2011102241738 A CN2011102241738 A CN 2011102241738A CN 201110224173 A CN201110224173 A CN 201110224173A CN 102352440 B CN102352440 B CN 102352440B
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- palladium
- bismuth
- palladium sponge
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910052797 bismuth Inorganic materials 0.000 title claims abstract description 26
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000003054 catalyst Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 title abstract description 4
- 239000002184 metal Substances 0.000 title abstract description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000176 sodium gluconate Substances 0.000 title abstract 2
- 229940005574 sodium gluconate Drugs 0.000 title abstract 2
- 235000012207 sodium gluconate Nutrition 0.000 title abstract 2
- 239000000706 filtrate Substances 0.000 claims abstract description 46
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 21
- 238000011084 recovery Methods 0.000 claims abstract description 18
- 238000001354 calcination Methods 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000000746 purification Methods 0.000 claims abstract description 9
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 6
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 4
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims abstract description 4
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000007935 neutral effect Effects 0.000 claims abstract description 4
- 238000001556 precipitation Methods 0.000 claims abstract description 4
- 239000003863 metallic catalyst Substances 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 125000003963 dichloro group Chemical group Cl* 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 abstract description 7
- 239000007787 solid Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000047 product Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical compound C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- AAJRIJBGDLLRAE-UHFFFAOYSA-M sodium;butoxymethanedithioate Chemical compound [Na+].CCCCOC([S-])=S AAJRIJBGDLLRAE-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2011102241738A CN102352440B (en) | 2011-08-06 | 2011-08-06 | Method for recovering palladium sponge and bismuth from multi-metal catalyst utilized in sodium gluconate production |
Applications Claiming Priority (1)
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CN2011102241738A CN102352440B (en) | 2011-08-06 | 2011-08-06 | Method for recovering palladium sponge and bismuth from multi-metal catalyst utilized in sodium gluconate production |
Publications (2)
Publication Number | Publication Date |
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CN102352440A CN102352440A (en) | 2012-02-15 |
CN102352440B true CN102352440B (en) | 2013-01-09 |
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CN2011102241738A Expired - Fee Related CN102352440B (en) | 2011-08-06 | 2011-08-06 | Method for recovering palladium sponge and bismuth from multi-metal catalyst utilized in sodium gluconate production |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104342558A (en) * | 2014-05-12 | 2015-02-11 | 上海派特贵金属环保科技有限公司 | A method for recycling palladium from a spent precious metal catalyst |
CN104745837B (en) * | 2015-04-21 | 2017-01-18 | 昆山鸿福泰环保科技有限公司 | Recovery process of palladium in copper-nickel alloy |
CN107794376B (en) * | 2017-10-12 | 2019-05-31 | 安徽拜善晟制药有限公司 | The recovery method of Metal Palladium in a kind of thin powdered carbon carrier palladium-carbon catalyst |
CN113151681B (en) * | 2021-02-19 | 2022-07-12 | 石家庄绿色再生资源有限公司 | Process for recovering noble metal palladium from waste palladium catalyst |
WO2024023055A1 (en) * | 2022-07-26 | 2024-02-01 | Solvay Sa | Hydrometallurgical process for recovering palladium from a spent catalyst |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0767243A1 (en) * | 1995-10-07 | 1997-04-09 | BASF Aktiengesellschaft | Recovery of active components from carrier or monolythic catalysts |
CN101078054A (en) * | 2007-06-22 | 2007-11-28 | 厦门金达威维生素股份有限公司 | Method for reclaiming metal palladium and palladium chloride from waste loading palladium hydrogenation catalyst |
-
2011
- 2011-08-06 CN CN2011102241738A patent/CN102352440B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0767243A1 (en) * | 1995-10-07 | 1997-04-09 | BASF Aktiengesellschaft | Recovery of active components from carrier or monolythic catalysts |
CN101078054A (en) * | 2007-06-22 | 2007-11-28 | 厦门金达威维生素股份有限公司 | Method for reclaiming metal palladium and palladium chloride from waste loading palladium hydrogenation catalyst |
Non-Patent Citations (6)
Title |
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从废催化剂中回收有色和稀有金属;陈耐生;《黑龙江大学自然科学学报》;19861231(第2期);20-22 * |
从废钯碳催化剂中回收钯的研究;张永平;《山西化工》;20100228;第30卷(第1期);61-67 * |
催化氧化葡糖糖中失活钯铋炭催化剂再生方法探讨;彭方英等;《化工生产与技术》;20101231;第17卷(第3期);17-19 * |
张永平.从废钯碳催化剂中回收钯的研究.《山西化工》.2010,第30卷(第1期),20-22. |
彭方英等.催化氧化葡糖糖中失活钯铋炭催化剂再生方法探讨.《化工生产与技术》.2010,第17卷(第3期),17-19. |
陈耐生.从废催化剂中回收有色和稀有金属.《黑龙江大学自然科学学报》.1986,(第2期),61-67. |
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CN102352440A (en) | 2012-02-15 |
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Owner name: HENAN XINGFA BIOTECHNOLOGY CO., LTD. Free format text: FORMER NAME: HE'NAN XINGFA PRECISION CHEMICAL CO., LTD. |
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CB03 | Change of inventor or designer information |
Inventor after: An Qingtang Inventor after: Zi Yuncong Inventor after: Feng Binbin Inventor after: Wang Jianzhong Inventor after: Zhang Tingjing Inventor before: An Qingtang Inventor before: Zi Congyun Inventor before: Feng Binbin Inventor before: Wang Jianzhong Inventor before: Zhang Tingjing |
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Free format text: CORRECT: INVENTOR; FROM: AN QINGTANG ZI CONGYUN FENG BINBIN WANG JIANZHONG ZHANG TINGJING TO: AN QINGTANG ZI YUNCONG FENG BINBIN WANG JIANZHONG ZHANG TINGJING |
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CP01 | Change in the name or title of a patent holder |
Address after: 450008, No. 11, building 12, dragon spirit, the Yellow River East Road, Zheng Dong New District, Henan, Zhengzhou Patentee after: Henan Xingfa Biological Technology Co.,Ltd. Address before: 450008, No. 11, building 12, dragon spirit, the Yellow River East Road, Zheng Dong New District, Henan, Zhengzhou Patentee before: HENAN XINGFA FINE CHEMICAL Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130109 Termination date: 20210806 |
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CF01 | Termination of patent right due to non-payment of annual fee |