CN102352211A - Epoxy resin metal adhesive and preparation method thereof - Google Patents
Epoxy resin metal adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN102352211A CN102352211A CN2011102622119A CN201110262211A CN102352211A CN 102352211 A CN102352211 A CN 102352211A CN 2011102622119 A CN2011102622119 A CN 2011102622119A CN 201110262211 A CN201110262211 A CN 201110262211A CN 102352211 A CN102352211 A CN 102352211A
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- preparation
- metal adhesive
- tackiness agent
- constitutive material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Epoxy Resins (AREA)
Abstract
The invention discloses an epoxy resin metal adhesive and a preparation method thereof. According to the invention, raw materials of E-44 epoxy resin, organic tertiary amine, triethylamine, sodium sulfate, methyltriacetoxysilane, maleic anhydride, aluminum oxide powder, and straw ashes are mixed and stirred according to a formulated weight ratio, such that the epoxy resin metal adhesive is obtained. The method provided by the invention is characterized in simple preparation, convenient operation, and low cost. The prepared epoxy resin metal adhesive has advantages of high adhesive strength, good thermal endurance, and good applicability.
Description
Technical field
The present invention relates to a kind of sizing agent, be specifically related to a kind of epoxide alloy tackiness agent and preparation method thereof.
Background technology
Develop rapidly along with rubber industry; Rubber composite is widely used; And the quality of rubber and epoxide alloy tackiness agent is the successful key of matrix material, and increasing and the expansion of Application Areas of composite product kind is more and more harsher to the requirement of adhering technique.Technology such as traditional chlorinated rubber method, isocyanic ester method can not satisfy new requirement.
Summary of the invention
To the deficiency of prior art, the object of the present invention is to provide a kind of bond strength height, good heat resistance, epoxide alloy tackiness agent that price is low and preparation method thereof.
The present invention adopts following technical scheme to achieve these goals:
The epoxide alloy tackiness agent is characterized in that the weight part of its constitutive material is: E-44 Resins, epoxy 50-60 part, trimethylamine 1-3 part, triethylamine 1-3 part, sodium sulfate 1-3 part, methyl triacetoxysilane 20-25 part, MALEIC ANHYDRIDE 5-10 part, aluminum oxide powder 1-2 part, stalk ashes 1-2 part.
The preparation method of epoxide alloy tackiness agent is characterized in that may further comprise the steps:
(1) presses weight part mixing E-44 Resins, epoxy, methyl triacetoxysilane and the MALEIC ANHYDRIDE of constitutive material, stir, obtain mixed liquor A;
(2) in the mixed liquor A that step (1) obtains, add trimethylamine, triethylamine, sodium sulfate, aluminum oxide powder and stalk ashes, reacted 3-4 hour by the constitutive material weight part, controlled temperature 80-85 ℃, discharging after the reaction cooled.
Beneficial effect of the present invention:
Preparing method of the present invention is simple, and is easy to operate, and cost is low, high, the good heat resistance of the epoxide alloy tackiness agent bond strength that makes, and suitability is strong.
Embodiment
Embodiment 1:The epoxide alloy tackiness agent, the weight part of its constitutive material is: 50 parts of E-44 Resins, epoxy, 1 part of trimethylamine, 1 part of triethylamine, 1 part in sodium sulfate, 20 parts of methyl triacetoxysilanes, 5 parts of MALEIC ANHYDRIDE, 1 part of aluminum oxide powder, 1 part in stalk ashes.
The preparation method of epoxide alloy tackiness agent may further comprise the steps:
(1) presses weight part mixing E-44 Resins, epoxy, methyl triacetoxysilane and the MALEIC ANHYDRIDE of constitutive material, stir, obtain mixed liquor A;
(2) in the mixed liquor A that step (1) obtains, add trimethylamine, triethylamine, sodium sulfate, aluminum oxide powder and stalk ashes, reacted 3-4 hour by the constitutive material weight part, controlled temperature 80-85 ℃, discharging after the reaction cooled.
Embodiment 2:The epoxide alloy tackiness agent, the weight part of its constitutive material is: 55 parts of E-44 Resins, epoxy, 2 parts of trimethylamines, 2 parts of triethylamines, 2 parts in sodium sulfate, 22 parts of methyl triacetoxysilanes, 8 parts of MALEIC ANHYDRIDE, 1.5 parts of aluminum oxide powders, 1.5 parts in stalk ashes.
The preparation method of epoxide alloy tackiness agent may further comprise the steps:
(1) presses weight part mixing E-44 Resins, epoxy, methyl triacetoxysilane and the MALEIC ANHYDRIDE of constitutive material, stir, obtain mixed liquor A;
(2) in the mixed liquor A that step (1) obtains, add trimethylamine, triethylamine, sodium sulfate, aluminum oxide powder and stalk ashes, reacted 3-4 hour by the constitutive material weight part, controlled temperature 80-85 ℃, discharging after the reaction cooled.
Embodiment 3:The epoxide alloy tackiness agent, the weight part of its constitutive material is: 60 parts of E-44 Resins, epoxy, 3 parts of trimethylamines, 3 parts of triethylamines, 3 parts in sodium sulfate, 25 parts of methyl triacetoxysilanes, 10 parts of MALEIC ANHYDRIDE, 2 parts of aluminum oxide powders, 2 parts in stalk ashes.
The preparation method of epoxide alloy tackiness agent may further comprise the steps:
(1) presses weight part mixing E-44 Resins, epoxy, methyl triacetoxysilane and the MALEIC ANHYDRIDE of constitutive material, stir, obtain mixed liquor A;
(2) in the mixed liquor A that step (1) obtains, add trimethylamine, triethylamine, sodium sulfate, aluminum oxide powder and stalk ashes, reacted 3-4 hour by the constitutive material weight part, controlled temperature 80-85 ℃, discharging after the reaction cooled.
Embodiment 4:The metal adhesive and the plain metal tackiness agent performance comparison of the present invention's preparation:
| Performance | Metal adhesive of the present invention | The plain metal tackiness agent |
| Setting time (min) | 3.0 | 2.4 |
| Stability in storage (h) | 140 | 30 |
| Tensile shear strength (Mpa) | 29.0 | 28.6 |
| Tensile shear strength (Mpa) after aging | 30.8 | 29.7 |
Claims (2)
1. an epoxide alloy tackiness agent is characterized in that the weight part of its constitutive material is: E-44 Resins, epoxy 50-60 part, trimethylamine 1-3 part, triethylamine 1-3 part, sodium sulfate 1-3 part, methyl triacetoxysilane 20-25 part, MALEIC ANHYDRIDE 5-10 part, aluminum oxide powder 1-2 part, stalk ashes 1-2 part.
2. the preparation method of an epoxide alloy as claimed in claim 1 tackiness agent is characterized in that may further comprise the steps:
(1) presses weight part mixing E-44 Resins, epoxy, methyl triacetoxysilane and the MALEIC ANHYDRIDE of constitutive material, stir, obtain mixed liquor A;
(2) in the mixed liquor A that step (1) obtains, add trimethylamine, triethylamine, sodium sulfate, aluminum oxide powder and stalk ashes, reacted 3-4 hour by the constitutive material weight part, controlled temperature 80-85 ℃, discharging after the reaction cooled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110262211 CN102352211B (en) | 2011-09-06 | 2011-09-06 | Epoxy resin metal adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110262211 CN102352211B (en) | 2011-09-06 | 2011-09-06 | Epoxy resin metal adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102352211A true CN102352211A (en) | 2012-02-15 |
| CN102352211B CN102352211B (en) | 2013-06-05 |
Family
ID=45575854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110262211 Expired - Fee Related CN102352211B (en) | 2011-09-06 | 2011-09-06 | Epoxy resin metal adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102352211B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060219757A1 (en) * | 2005-04-05 | 2006-10-05 | General Electric Company | Method for producing cure system, adhesive system, and electronic device |
| CN1938356A (en) * | 2004-03-30 | 2007-03-28 | 株式会社钟化 | Hardenable composition |
| CN101440268A (en) * | 2008-12-30 | 2009-05-27 | 黑龙江省科学院石油化学研究院 | Low temperature curing high temperature resistant inorganic / organic hybridization epoxy adhesive and preparation thereof |
| CN101734747A (en) * | 2009-12-31 | 2010-06-16 | 中国科学院等离子体物理研究所 | Adsorption and decoloration method of printing and dyeing wastewater by using power plant straw ash |
-
2011
- 2011-09-06 CN CN 201110262211 patent/CN102352211B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1938356A (en) * | 2004-03-30 | 2007-03-28 | 株式会社钟化 | Hardenable composition |
| US20060219757A1 (en) * | 2005-04-05 | 2006-10-05 | General Electric Company | Method for producing cure system, adhesive system, and electronic device |
| CN101440268A (en) * | 2008-12-30 | 2009-05-27 | 黑龙江省科学院石油化学研究院 | Low temperature curing high temperature resistant inorganic / organic hybridization epoxy adhesive and preparation thereof |
| CN101734747A (en) * | 2009-12-31 | 2010-06-16 | 中国科学院等离子体物理研究所 | Adsorption and decoloration method of printing and dyeing wastewater by using power plant straw ash |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102352211B (en) | 2013-06-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101698787A (en) | Epoxy resin binder used for repairing blade and preparation method thereof | |
| CN102002309A (en) | Epoxy polyester type powder coating for evaporator and preparation method thereof | |
| CN101717490B (en) | Rosin-modified epoxy ester resin and preparation method thereof | |
| CN103483993A (en) | Low-temperature curing powder paint | |
| CN102352212B (en) | High-strength metal adhesive and preparation method thereof | |
| CN101831104B (en) | Plastic welding rod | |
| CN103497654A (en) | Low-temperature curing powder coating | |
| CN103980669A (en) | Preparation method for epoxy resin board | |
| CN107201092A (en) | A kind of preparation method of epoxidation crosslinked polypropylene powdery paints | |
| CN102352211B (en) | Epoxy resin metal adhesive and preparation method thereof | |
| CN103044859A (en) | Waterproof insulation epoxy resin composition, adhesive tape and preparation method thereof | |
| CN109265801A (en) | A kind of guitar panel, side plate or backboard and preparation method thereof | |
| CN103131303B (en) | A kind of powder coating containing Vanay | |
| CN102329589B (en) | Anti-molten metal adhesive and preparation method thereof | |
| CN103773290A (en) | Preparation method for thermoplastic acrylic resin adhesive | |
| CN102329592B (en) | Metal adhesive with multiple components and preparation method thereof | |
| CN102329588B (en) | High-abrasion-resistant metal adhesive and preparation method thereof | |
| CN102329591A (en) | Metal binder and preparation method thereof | |
| CN102329590B (en) | Adhesive for metal bonding and preparation method thereof | |
| CN102352192B (en) | Metal adhesive composition and preparation method thereof | |
| CN102352191B (en) | Metal adhesive and preparation method thereof | |
| CN102101996A (en) | Pressure-sensitive adhesive used for cotton paper or non-woven fabrics and preparation method thereof | |
| CN103773289A (en) | Thermoplastic acrylic resin adhesive | |
| CN112694851A (en) | High-adhesion-strength conductive adhesive capable of repairing microelectronic assembly and preparation method thereof | |
| CN101134883A (en) | White glue and method for preparing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130605 Termination date: 20150906 |
|
| EXPY | Termination of patent right or utility model |