CN102351551A - Energy-saving swing-groove for continuous casting tundish and preparation method thereof - Google Patents

Energy-saving swing-groove for continuous casting tundish and preparation method thereof Download PDF

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Publication number
CN102351551A
CN102351551A CN2011102006051A CN201110200605A CN102351551A CN 102351551 A CN102351551 A CN 102351551A CN 2011102006051 A CN2011102006051 A CN 2011102006051A CN 201110200605 A CN201110200605 A CN 201110200605A CN 102351551 A CN102351551 A CN 102351551A
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continuous casting
hours
aggregate
preparation
groove
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CN2011102006051A
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CN102351551B (en
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张发明
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WUXI CITY YIHONG REFRACTORY MATERIALS Co Ltd
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WUXI CITY YIHONG REFRACTORY MATERIALS Co Ltd
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Abstract

The invention discloses an energy-saving swing-groove for a continuous casting tundish and a preparation method thereof. Raw materials for the swing-groove comprise aggregate prepared from used refractory materials discarded in steel mills and fine powder of recovered materials, with the rest being additives. The preparation method for the swing-groove comprises the following steps: weighing the raw materials by weight, adding the raw materials and water into a sand mixer for stirring, gradually adding stirred mud into a mold, and carrying out vibration at the same time; maintaining a green body with the mold obtained after molding in natural environment; roasting a product obtained after natural maintenance in a drying room, cooling the product to a room temperature after roasting is finished, and carrying out packaging to obtain a finished product. According to the invention, resources are saved, sources of pollution to environment are reduced, and reutilization of used refractory materials is realized; product cost for the finished product in the invention decreases by more than 50% compared to product cost for conventional swing-grooves for continuous casting tundishs.

Description

A kind of energy-saving continuous casting tundish is with pendulum groove and preparation method thereof
 
Technical field
The invention belongs to the metallurgical casting field, relate to a kind of continuous casting tundish that is applied in the steelmaking equipment and use pendulum groove and preparation method thereof.
Background technology
Continuous small-billet casting generally adopts the metering nozzle pouring technology, compares with stopper control cast, and the metering nozzle pouring technology lacks the beam control device.Open and water when starting, the mode that the groove drainage is repeatedly put in general employing reduces molten steel flow, guarantees fully solidifying of strand in the mold, and with the ingot-guiding head mortise.
Tundish has stopper, slide gate nozzle and three kinds of forms of metering nozzle to mold steel flow control device, adopts the metering nozzle mode to pour into a mould the strand of 120mm * 120mm section, and traditional mode of watering of opening is: when the tundish liquid level reach a certain height, the centre was unwrapped and watered.Connect away earlier and open the molten steel that waters first with the pendulum groove, treat steel rheology circle after, remove the pendulum groove and inject molten steel to mold, when the molten steel in mold level reaches the 200mm left and right sides, swing in the pendulum groove, stop in mold the injection molten steel and open cold water.At interval 5~15s arranges the pendulum groove, injects molten steel to mold again, and 2~4 times so repeatedly, when mold liquid level during apart from 80~100mm suitable for reading, the pendulum groove swings in, and opens and waters, and when mold liquid level descended, the pendulum groove was arranged, and molten steel gets into mold, normal cast.
All directly discarding mostly after present domestic steel mill uses with refractory, recovery utilization rate has only 20%, and our company has manufactured continuous casting tundish pendulum groove through to the research with refractory with refractory.Through the high temperature sintering homogenization process, its result of use is superior to the ecosystem material with refractory.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of refractory materials that utilizes after steel mill uses, effectively reduces production costs, and the material that economizes on resources, the continuous casting tundish that reduces source of pollution is with pendulum groove and preparation method thereof.
A kind of energy-saving continuous casting tundish is characterized in that with the pendulum groove its component and content are:
Component particle diameter content (weight ratio)
Recovery aggregate 5mm≤≤8mm 15 ~ 18%
3mm≤ <5mm 15~20%
1mm≤ <3mm 14~19%
0.5?mm< <1mm 8~12%
Reclaimed materials fine powder order number≤320 22 ~ 26%
Additive: comprise
Luminite cement 5 ~ 10%
Fine silica powder 3 ~ 8%
Kyanite 2 ~ 5%
Heat-resistance stainless steel steel fiber 0.8 ~ 1.5%
Tripoly phosphate sodium STPP 0.2-1.2%.
Above-mentioned recovery aggregate reaches Al with the physical and chemical index that reclaims fine powder 2O 3>=70%, Fe 2O 3≤2%; Reclaimed materials fine powder order number≤320 orders.
The present invention also provides the preparation method of above-mentioned continuous casting tundish with the pendulum groove, may further comprise the steps:
1) formwork erection at first: machine oil is cleaned out and evenly coated to mold inner surfaces.
2) will reclaim aggregate and reclaimed materials powder, additive by above-mentioned content weighing, and drop in the sand mill again and stirred 3-5 minute, and add entry then, the add-on of water is the 6-7% of solid component weight, and the back discharging stirs.
3) pug that mixes is added in the model gradually, vibration until expecting the position, does not have obvious exhaust simultaneously, and surperficial bleeding is for well.
4) maintenance and the demoulding: the curing in the mold in physical environment of the base substrate after the moulding, wait to expect abundant sclerosis, carry out the demoulding again, seasoning is 72 hours again.
5) drying room of packing into of the product after the seasoning is toasted.80 ℃ were toasted 12 hours, and 110 ℃ were toasted 22 hours, and 200 ℃ were toasted 10 hours, and 250 ℃ were toasted 10 hours, and 350 ℃ were toasted 12 hours.Baking finishes postcooling to room temperature, is finished product after the packing.
The preparation process of above-mentioned recovery aggregate and recovery fine powder is:
1) useless alumina brick, corundum brick, waste material after recovery steel mill uses, the physical and chemical index of waste material should reach Al 2O 3>=70%, Fe 2O 3≤2%.
2) will reclaim waste materials such as alumina brick, corundum brick and pulverize through jaw crusher and twin rollers successively, pulverize material, remove the Fe that pulverizes in the material again through being with the washing of running roller sand machine, drying 2O 3And impurity, final sizing, be divided into particle diameter be respectively 5mm≤≤8mm, 3mm≤<5mm, 1mm≤<3mm, 0 mm<<aggregate of 1mm, and order number≤320 purposes reclaim the waste residue powder.
The relative prior art of the present invention has following some advantage:
1, the present invention has utilized steel mill to use waste materials such as back depleted refractory materials alumina brick, corundum brick as aggregate; Having reduced production cost significantly reaches more than 50%; Adopt rejected material to prepare starting material, practiced thrift the resource and the energy, significantly reduced environomental pollution source.
2, reclaimed materials makes the continuous casting tundish also good than high energy consumption ecosystem material with pendulum groove result of use, and has increased work-ing life because of through reburning the knot homogenization process.
3, utilize the recovery depleted can produce a variety of refractory materialss with refractory, because reclaimed materials passes through the high temperature sintering homogenizing, its performance is superior to the ecosystem energy and material, and result of use is better than high energy consumption ecosystem material, receives very much users' welcome.
Embodiment
Below in conjunction with specific embodiment the present invention is done further elaboration.
Embodiment 1:
Component particle diameter content (weight ratio)
Recovery aggregate 5mm≤≤8mm 15%
3mm≤ <5mm 20%
1mm≤ <3mm 15%
0.5?mm< <1mm ?10%
Reclaimed materials fine powder order number≤320 orders 24%
Additive: comprise
Luminite cement 8%
Fine silica powder 5%
Kyanite 2%
Heat-resistance stainless steel steel fiber 0.8%
Tripoly phosphate sodium STPP 0.2%.
The preparation process of present embodiment:
1) formwork erection at first: machine oil is cleaned out and coated to mold inner surfaces, must evenly and be difficult for too thick.
2) will reclaim aggregate and reclaimed materials powder, additive by above-mentioned content weighing, and drop in the sand mill again and stirred 3-5 minute, and add entry then and add entry then, the add-on of water is the 6-7% of solid component weight, and the back discharging stirs.
3) pug that mixes is added in the model gradually, vibration until expecting the position, does not have obvious exhaust simultaneously, and surperficial bleeding is for well.
4) maintenance and the demoulding: the curing in the mold in physical environment of the base substrate after the moulding, wait to expect abundant sclerosis, carry out the demoulding again, seasoning is 72 hours again.
5) drying room of packing into of the product after the seasoning is toasted.80 ℃ were toasted 12 hours, and 110 ℃ were toasted 22 hours, and 200 ℃ were toasted 10 hours, and 250 ℃ were toasted 10 hours, and 350 ℃ were toasted 12 hours.Baking finishes postcooling to room temperature, is finished product after the packing.
 
Embodiment 2:
Component particle diameter content (weight ratio)
Recovery aggregate 5mm≤≤8mm 18%
3mm≤ <5mm ?15%
1mm≤ <3mm ?17%
0.5?mm< <1mm ?12%
Reclaimed materials fine powder order number≤320 orders 22%
Additive: comprise
Luminite cement 6%
Fine silica powder 5%
Kyanite 3%
Heat-resistance stainless steel steel fiber 1%
Tripoly phosphate sodium STPP 1%.
The preparation process of present embodiment is with embodiment 1.
 
Embodiment 3:
Component particle diameter content (weight ratio)
Recovery aggregate 5mm≤≤8mm 16%
3mm≤ <5mm ?17%
1mm≤ <3mm 17%
0.5?mm< <1mm 10%
Reclaimed materials fine powder order number≤320 orders 26%
Additive: comprise
Luminite cement 6%
Fine silica powder 4%
Kyanite 2.5%
Heat-resistance stainless steel steel fiber 1%
Tripoly phosphate sodium STPP 0.5%.
The preparation process of present embodiment is with embodiment 1.
The working method of above-mentioned aggregate is:
Waste materials such as the useless alumina brick after 1) recovery steel mill uses, corundum brick, the physical and chemical index of waste material should reach Al 2O 3>=70%, Fe 2O 3≤2%.What will meet physical and chemical index carries out following process with refractory.
2) refractory materials that reclaims is pulverized through jaw crusher and twin rollers successively, pulverized the washing of material warp band running roller sand machine, dry, remove the Fe that pulverizes in the material again 2O 3And impurity, final sizing, be divided into particle diameter be respectively 5mm≤≤8mm, 3mm≤<5mm, 1mm≤<3mm, 0.5 mm<<aggregate of four kinds of specifications of 1mm and the reclaimed materials fine powder of order number≤320.
The continuous casting tundish of the present invention's preparation is with pendulum groove physical and chemical index
Figure 594189DEST_PATH_IMAGE002

Claims (4)

1. an energy-saving continuous casting tundish is characterized in that with the pendulum groove component and content are:
Component particle diameter content (weight ratio)
Recovery aggregate 5mm≤≤8mm 15 ~ 18%
3mm≤ <5mm ?15~20%
1mm≤ <3mm ?14~19%
0.5?mm< <1mm 8~12%
Reclaimed materials fine powder order number≤320 orders 22 ~ 26%
Additive: comprise
Luminite cement 5 ~ 10%
Fine silica powder 3 ~ 8%
Kyanite 2 ~ 5%
Heat-resistance stainless steel steel fiber 0.8 ~ 1.5%
Tripoly phosphate sodium STPP 0.2-1.2%.
2. energy-saving continuous casting tundish according to claim 1 is characterized in that with the pendulum groove said recovery aggregate and reclaimed materials fine powder all are to obtain through refining with refractory with steel mill to form, and the physical and chemical index that reclaims aggregate and reclaimed materials fine powder is Al 2O 3>=70%, Fe 2O 3≤2.0 %, reclaimed materials fine powder order number≤320 orders.
3. the said energy-saving continuous casting tundish of claim 1 is characterized in that may further comprise the steps with the preparation method who puts groove:
1) machine oil is cleaned out and evenly coated to formwork erection at first with mold inner surfaces;
2) will reclaim aggregate and reclaimed materials powder, additive by above-mentioned content weighing, and drop in the sand mill again and stirred 3-5 minute, and add entry then, the add-on of water is the 6-7% of solid component weight, and the back discharging stirs;
3) pug that mixes is added in the model gradually, vibration until expecting the position, does not have obvious exhaust simultaneously, and surperficial bleeding is for well;
4) maintenance and the demoulding: the curing in the mold in physical environment of the base substrate after the moulding, wait to expect abundant sclerosis, carry out the demoulding again, seasoning is 72 hours again;
5) drying room of packing into of the product after the seasoning is toasted 80 ℃ of bakings 12 hours, 110 ℃ of bakings 22 hours, 200 ℃ of bakings 10 hours, 250 ℃ of bakings 10 hours, 350 ℃ of bakings 12 hours; Baking finishes postcooling to room temperature, is finished product after the packing.
4. energy-saving continuous casting tundish according to claim 3 is characterized in that step 2 with the preparation method of pendulum groove) in reclaim aggregate and reclaimed materials fine powder preparation process be:
1) refractory materials after recovery steel mill uses, the physical and chemical index of these refractory materialss should reach Al 2O 3>=70%, Fe 2O 3≤2%;
2) refractory materials that reclaims is pulverized through jaw crusher and twin rollers successively, pulverized the washing of material warp band running roller sand machine, dry, remove the Fe that pulverizes in the material again 2O 3And impurity, final sizing, be divided into particle diameter be respectively 5mm≤≤8mm, 3mm≤<5mm, 1mm≤<3mm, 0.5 mm<<aggregate of four kinds of specifications of 1mm, and order number≤320 purposes reclaim the waste residue powder.
CN 201110200605 2011-07-18 2011-07-18 Energy-saving swing-groove for continuous casting tundish and preparation method thereof Expired - Fee Related CN102351551B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103833394A (en) * 2014-01-08 2014-06-04 长兴明晟冶金炉料有限公司 Tundish coating
CN114573356A (en) * 2020-12-01 2022-06-03 云南濮耐昆钢高温材料有限公司 Regenerated corundum air-permeable brick cup and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381237A (en) * 2008-10-23 2009-03-11 陆建荣 Environment-friendly type continuous casting dry material for tundish and preparation method thereof
CN101580398A (en) * 2009-06-29 2009-11-18 河南省耕生耐火材料有限公司 Ladle kerb casting material and ladle kerb preparation method thereof
CN101786891A (en) * 2010-02-03 2010-07-28 山东轻工业学院 Air-set mold bulk material for continuous casting tundish and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381237A (en) * 2008-10-23 2009-03-11 陆建荣 Environment-friendly type continuous casting dry material for tundish and preparation method thereof
CN101580398A (en) * 2009-06-29 2009-11-18 河南省耕生耐火材料有限公司 Ladle kerb casting material and ladle kerb preparation method thereof
CN101786891A (en) * 2010-02-03 2010-07-28 山东轻工业学院 Air-set mold bulk material for continuous casting tundish and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103833394A (en) * 2014-01-08 2014-06-04 长兴明晟冶金炉料有限公司 Tundish coating
CN103833394B (en) * 2014-01-08 2015-09-09 长兴明晟冶金炉料有限公司 Tundish paint
CN114573356A (en) * 2020-12-01 2022-06-03 云南濮耐昆钢高温材料有限公司 Regenerated corundum air-permeable brick cup and preparation method thereof

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