CN102350825A - Process for preparing fluorine-containing high polymer high frequency circuit board material by hydrothermal method - Google Patents
Process for preparing fluorine-containing high polymer high frequency circuit board material by hydrothermal method Download PDFInfo
- Publication number
- CN102350825A CN102350825A CN2011101422331A CN201110142233A CN102350825A CN 102350825 A CN102350825 A CN 102350825A CN 2011101422331 A CN2011101422331 A CN 2011101422331A CN 201110142233 A CN201110142233 A CN 201110142233A CN 102350825 A CN102350825 A CN 102350825A
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- Prior art keywords
- emulsion
- sheet material
- containing polymer
- circuit board
- frequency line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims abstract description 46
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 27
- 239000011737 fluorine Substances 0.000 title claims abstract description 27
- 229920000642 polymer Polymers 0.000 title claims abstract description 27
- 238000001027 hydrothermal synthesis Methods 0.000 title claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 239000000839 emulsion Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 20
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 19
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 18
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 18
- 239000002105 nanoparticle Substances 0.000 claims abstract description 16
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 16
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- 238000005096 rolling process Methods 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims abstract description 3
- 230000008569 process Effects 0.000 claims description 19
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical group CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 229920002521 macromolecule Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 239000011889 copper foil Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229940043279 diisopropylamine Drugs 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 229910004247 CaCu Inorganic materials 0.000 claims description 5
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 239000000758 substrate Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 2
- 238000005253 cladding Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
- 238000004891 communication Methods 0.000 description 6
- 239000003989 dielectric material Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- 230000010365 information processing Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000008054 signal transmission Effects 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- 208000035126 Facies Diseases 0.000 description 1
- AMVVEDHCBDQBJL-UHFFFAOYSA-N [Ca][Zr] Chemical compound [Ca][Zr] AMVVEDHCBDQBJL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201110142233.1A CN102350825B (en) | 2011-05-30 | 2011-05-30 | Process for preparing fluorine-containing high polymer high frequency circuit board material by hydrothermal method |
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CN201110142233.1A CN102350825B (en) | 2011-05-30 | 2011-05-30 | Process for preparing fluorine-containing high polymer high frequency circuit board material by hydrothermal method |
Publications (2)
Publication Number | Publication Date |
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CN102350825A true CN102350825A (en) | 2012-02-15 |
CN102350825B CN102350825B (en) | 2014-03-26 |
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CN201110142233.1A Expired - Fee Related CN102350825B (en) | 2011-05-30 | 2011-05-30 | Process for preparing fluorine-containing high polymer high frequency circuit board material by hydrothermal method |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107278037A (en) * | 2017-06-29 | 2017-10-20 | 安徽升鸿电子有限公司 | The copper-clad plate of 6.5≤Dk≤10 is made using turning hot pressing mode |
CN107311517A (en) * | 2017-06-29 | 2017-11-03 | 安徽升鸿电子有限公司 | The method that Dk > 10 copper-clad plate base material is made using turning mode |
CN107382291A (en) * | 2017-06-22 | 2017-11-24 | 庐江县典扬电子材料有限公司 | The preparation method of the copper-clad plate base materials of 2.2≤Dk < 6.5 |
CN107509311A (en) * | 2017-06-29 | 2017-12-22 | 安徽升鸿电子有限公司 | The method that the copper-clad plate base material of 6.5≤Dk≤10 is made using turning mode |
CN114644846A (en) * | 2020-12-17 | 2022-06-21 | 常熟三爱富中昊化工新材料有限公司 | Fluorine-containing polymer emulsion copper-clad plate and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000024050A1 (en) * | 1998-10-22 | 2000-04-27 | Applied Materials, Inc. | Cvd nanoporous silica low dielectric constant films |
EP1225194A2 (en) * | 2001-01-17 | 2002-07-24 | Air Products And Chemicals, Inc. | Method of forming a dielectric interlayer film with organosilicon precursors |
CN101942180A (en) * | 2010-09-08 | 2011-01-12 | 广东生益科技股份有限公司 | Epoxy resin composition and copper clad laminate manufactured by using same |
-
2011
- 2011-05-30 CN CN201110142233.1A patent/CN102350825B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000024050A1 (en) * | 1998-10-22 | 2000-04-27 | Applied Materials, Inc. | Cvd nanoporous silica low dielectric constant films |
EP1225194A2 (en) * | 2001-01-17 | 2002-07-24 | Air Products And Chemicals, Inc. | Method of forming a dielectric interlayer film with organosilicon precursors |
CN101942180A (en) * | 2010-09-08 | 2011-01-12 | 广东生益科技股份有限公司 | Epoxy resin composition and copper clad laminate manufactured by using same |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107382291A (en) * | 2017-06-22 | 2017-11-24 | 庐江县典扬电子材料有限公司 | The preparation method of the copper-clad plate base materials of 2.2≤Dk < 6.5 |
CN107278037A (en) * | 2017-06-29 | 2017-10-20 | 安徽升鸿电子有限公司 | The copper-clad plate of 6.5≤Dk≤10 is made using turning hot pressing mode |
CN107311517A (en) * | 2017-06-29 | 2017-11-03 | 安徽升鸿电子有限公司 | The method that Dk > 10 copper-clad plate base material is made using turning mode |
CN107509311A (en) * | 2017-06-29 | 2017-12-22 | 安徽升鸿电子有限公司 | The method that the copper-clad plate base material of 6.5≤Dk≤10 is made using turning mode |
CN114644846A (en) * | 2020-12-17 | 2022-06-21 | 常熟三爱富中昊化工新材料有限公司 | Fluorine-containing polymer emulsion copper-clad plate and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN102350825B (en) | 2014-03-26 |
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Owner name: NEW MATERIALS CO., LTD. YUNNAN SILVER PEAK Free format text: FORMER OWNER: ZHOU TAO Effective date: 20140811 Free format text: FORMER OWNER: NEW MATERIALS CO., LTD. YUNNAN SILVER PEAK Effective date: 20140811 |
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Effective date of registration: 20140811 Address after: 650200, Yunnan City, Kunming province Kai Kai District Pioneer Park 4 Patentee after: YUNNAN INFINE NEO-MATERIAL Co.,Ltd. Address before: 650200, Yunnan City, Kunming province Kai Kai District Pioneer Park 4 Patentee before: Zhou Tao Patentee before: YUNNAN INFINE NEO-MATERIAL Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140326 |
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CF01 | Termination of patent right due to non-payment of annual fee |