CN102350755B - Brightening grating mold and manufacturing method thereof - Google Patents

Brightening grating mold and manufacturing method thereof Download PDF

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Publication number
CN102350755B
CN102350755B CN201110261727.1A CN201110261727A CN102350755B CN 102350755 B CN102350755 B CN 102350755B CN 201110261727 A CN201110261727 A CN 201110261727A CN 102350755 B CN102350755 B CN 102350755B
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nickel
phosphorus
mold
brightening
roller
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CN102350755A (en
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张益民
吴庆富
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CHENGDU FSCREEN SCI-TECH Co Ltd
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CHENGDU FSCREEN SCI-TECH Co Ltd
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Abstract

The invention provides a brightening grating mold which is convenient to process and long in service life. The brightening grating mold comprises a full-blank roller, wherein a copper layer, a high phosphorus nickel-phosphorus alloy coating and a grating are arranged on the full-blank roller in turn. Due to adoption of a pulse power source, an electroforming process and a high-phosphorus electroplating solution, nickel-phosphorus alloy can be completely electroformed and deposited on a plurality types of metals, the phosphorus content can be up to 10 to 13 percent, the formed nickel-phosphorus alloy is non-crystal nickel-phosphorus alloy, and the thickness of the alloy is more than 0.5 mm, so the micro machining mechanical properties of a diamond molding cutter for the nickel-phosphorus alloy is improved, high finishment can be obtained, a large-size precision mold can be conveniently processed, and the service life of the mold is greatly prolonged. The nickel-phosphorus alloy obtained by the electroforming and depositing method is uniform in coating and strong in adhesive power, a non-crystal with high phosphorus content is obtained, and zero abrasion of a mold roller can be realized theoretically. Moreover, a nickel-phosphorus alloy roller is a grating mold roller so that the service life of the grating mold roller can be prolonged by 3 to 10 times.

Description

Brightening optical grating mold and preparation method thereof
Technical field
The present invention relates to grating mold in a kind of photoelectric display device and preparation method thereof.
Background technology
Brightening optical grating material is the light pipe element in display device, conventionally the grizzly bar by circular arc, cylinder, triangle equal section shape forms, and is widely used in MD projection TV set, LCD backlight module, naked-eye 3 D television and volumetric packaging material etc. in modern display technology.
Brightening optical grating mold is carved grating fringe by diamond cutter conventionally on running roller, but diamond cutter can only process on non-ferrous metal, and the machining property of non-ferrous metal is poor, and service life is short, can not meet the demand of current large scale industrialization in enormous quantities.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of brightening optical grating mold of being convenient to processing, long service life.
The present invention also will provide a kind of preparation method of above-mentioned brightening optical grating mold.
The technical scheme that technical solution problem of the present invention adopts is: brightening optical grating mold, comprise full base roller, and on described full base roller, be disposed with copper layer, nickel-phosphor alloy coating and grating.
Further, the diameter of described full base roller is more than 300mm, and length is more than 1800mm.
Further, the thickness of described nickel-phosphor alloy coating is more than 0.5mm.
Further, the pitch of described grating is less than 0.05mm.
The preparation method of brightening optical grating mold, the method comprises the following steps: 1) on full base roller, plate fine copper; 2) electroplate liquid of electroforming high content of phosphorus, the nickel-phosphor alloy coating of the high thickness of deposition high phosphorus, the composition content of this electroplate liquid is: nickelous sulfate 120-300g/L, nickel chloride 30-45g/L, inferior sodium phosphate 45-90g/L, boric acid 20-35g/L and sodium fluoride 30-50g/L; 3) on nickel-phosphor alloy coating, process grating, thereby make brightening optical grating mold of the present invention.
Further, step 2) described electroforming adopts the pulse power.
Further, step 2) phosphorus content >=12% (percentage by weight, as follows) of described electroplate liquid.
Further, step 2) thickness of described nickel-phosphor alloy coating is more than 0.5mm.
The invention has the beneficial effects as follows: the present invention adopts the electroplate liquid of the pulse power, electroforming process and high content of phosphorus, electroforming nickel deposited-phosphorus alloy on various metals intactly, phosphorus content can be up to 10-13%, what form is noncrystal nickel-phosphor alloy, more than thickness can reach 0.5mm, improve the microfabrication mechanical performance of diamond forming cutter to nickel-phosphor alloy, can obtain high fineness, precision die that can be machining large-sized easily, and the service life of greatly improving mould.The nickel-phosphor alloy that electroforming deposition process obtains, coating is even, and strong adhesion obtains the noncrystal of high content of phosphorus, can realize in theory zero wearing and tearing of mould roller.Particularly on grating mould roller, adopt nickel-phosphor alloy roller, can make its life-span increase 3-10 doubly, by Ultra-precision diamond grating mold Special Purpose Machine for Processing, processing fine structure grating lens.
The specific embodiment
First the present invention extrudes and scribes the full base roller of electroforming on figure roller at photoelectric display device, more than diameter is preferably in 300mm, more than length is preferably in 1800mm; Then adopt pulse power electroforming deposited amorphous state nickel-phosphor alloy, then adopt natural diamond machine tooling to go out high-accuracy grating mould roller, raster pitch is less than 0.05mm.Adopt that this ultraprecise grating mould roller can production precision reaches that 1 inch of 500 line is above, the grating lens of 90 ℃ of pitch 24-150 μ m, angle 88-100 °, heat resistance >, can process various lenticular optical textures simultaneously.
Method of the present invention comprises the following steps:
1) on full base roller, plate fine copper;
2) electroplate liquid of electroforming high content of phosphorus, the nickel-phosphor alloy coating of the high thickness of deposition high phosphorus, the composition content of this electroplate liquid is: nickelous sulfate 120-300g/L, nickel chloride 30-45g/L, inferior sodium phosphate 45-90g/L, boric acid 20-35g/L and sodium fluoride 30-50g/L;
3) on nickel-phosphor alloy coating, process grating, thereby make brightening optical grating mold of the present invention.
Above-mentioned steps 1) object is: because the electric conductivity of copper is high, can accelerate the speed of nickel-phosphor alloy electroforming deposition.Above-mentioned steps 2) electroforming deposition adopts the pulse power, the electroplate liquid of electroforming high content of phosphorus (phosphorus content >=12%), complete the accumulation of amorphous nickel-phosphor alloy coating, the thickness of amorphous nickel-phosphor alloy coating that deposition forms can reach 1mm, the thickness of coating forming can meet the depth of groove requirement of grating lens structure processing, and the thickness of general electrochemical process nickel-phosphor alloy can only reach 0.20-0.30mm, can not meet the needs of ultraprecise processing.Because the phosphorus content in coating is up to more than 7.5%, more than can making like this surface roughness arrival Ra0.008mm of diamond cutter processing, then by extruding or UV Stereolithography technique, can make high permeability, large-sized grating lens, also improve significantly the service life of ultraprecise mould simultaneously.
Following table is the contrast of the parameter of 3 electroplate liquid components of the present invention and 2 resulting nickel-phosphor alloy coating of comparative example.
The apparent mass of the nickel-phosphor alloy coating that in upper table, embodiment 1-3 arrives is fine, there is no air-flow vestige, and coating is half light, non-variegation phenomenon; The high Current Zone of coating is not easy to burn, and technological operation is good; The crystallization of coating is careful, is beneficial to machining; The thickness evenness of coating is when more than 0.5 millimeter (coating) better; Binding force of cladding material is good; The positive internal stress of coating is less, and centre, edge coating are all without be full of cracks.
The apparent mass of the nickel-phosphor alloy coating that in upper table, comparative example 1 arrives is poor, has less air-flow vestige, and coating shows silver gray, has variegated phenomenon; Coating is thicker in the crystallization of edge, and coating is careful in middle crystallization, is beneficial to machining; The thickness evenness of coating very poor when more than 0.5 millimeter (coating), when current density is larger, edge effect is more serious; Binding force of cladding material is good; The positive internal stress of coating is less, and intermediate deposit is without be full of cracks, and there is a small amount of be full of cracks in the edge of coating.
The apparent mass of the nickel-phosphor alloy coating that in upper table, comparative example 2 arrives is very poor, has more air-flow vestige, and coating shows grey; Coating crystallization is thick, is unfavorable for machining; The thickness evenness of coating very poor when more than 0.5 millimeter (coating), when current density is larger, edge effect is more serious; Binding force of cladding material is good, and Dan edge engaging force is very poor; The internal stress of coating is very large, and coating has be full of cracks, coating cannot be thickeied.
In sum, the performance of nickel-phosphor alloy coating of the present invention meets the specification requirement of brightening optical grating mold, and the performance of the nickel-phosphor alloy coating of all the other two comparative examples can not meet the technical conditions of brightening optical grating mold.

Claims (7)

1. brightening optical grating mold, comprises full base roller, it is characterized in that: on described full base roller, be disposed with copper layer, nickel-phosphor alloy coating and grating.
2. brightening optical grating mold as claimed in claim 1, is characterized in that: the diameter of described full base roller is more than 300mm, and length is more than 1800mm.
3. brightening optical grating mold as claimed in claim 1, is characterized in that: the thickness of described nickel-phosphor alloy coating is more than 0.5mm.
4. brightening optical grating mold as claimed in claim 1, is characterized in that: the pitch of described grating is less than 0.05mm.
5. the preparation method of brightening optical grating mold as claimed in claim 1, is characterized in that: the method comprises the following steps: 1) on full base roller, plate fine copper; 2) electroplate liquid of electroforming high content of phosphorus, the nickel-phosphor alloy coating of deposition high phosphorus thickness more than 0.5mm, the composition content of this electroplate liquid is: nickelous sulfate 120-300g/L, nickel chloride 30-45g/L, inferior sodium phosphate 45-90g/L, boric acid 20-35g/L and sodium fluoride 30-50g/L; 3) on nickel-phosphor alloy coating, process grating, thereby make brightening optical grating mold of the present invention.
6. the preparation method of brightening optical grating mold as claimed in claim 5, is characterized in that: step 2) the described electroforming employing pulse power.
7. the preparation method of brightening optical grating mold as claimed in claim 5, is characterized in that: step 2) phosphorus content >=12% percentage by weight of described electroplate liquid.
CN201110261727.1A 2011-09-06 2011-09-06 Brightening grating mold and manufacturing method thereof Active CN102350755B (en)

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Application Number Priority Date Filing Date Title
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CN102350755B true CN102350755B (en) 2014-11-26

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Publication number Priority date Publication date Assignee Title
CN103144225B (en) * 2013-02-27 2015-07-29 成都菲斯特科技有限公司 The cylindric grating mould roller of 3D display

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CN200950166Y (en) * 2006-04-29 2007-09-19 杭州照相机械研究所 Aspheric surface diffraction optics lens
CN101571606B (en) * 2009-06-01 2011-05-04 浙江工业大学 Large-size micro-prism type reflecting material die and preparation method thereof
AU2011200827A1 (en) * 2010-03-02 2011-09-22 X6D Limited 3D glasses with RF synchronization
CN202200442U (en) * 2011-09-06 2012-04-25 成都菲斯特科技有限公司 Brightening optical grating mold

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Inventor after: Zhang Yimin

Inventor after: Wu Qingfu

Inventor before: Zhang Yimin

Inventor before: Wu Qingfu

Inventor before: Zeng Jiliang

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Free format text: CORRECT: INVENTOR; FROM: ZHANG YIMIN WU QINGFU CENG JILIANG TO: ZHANG YIMIN WU QINGFU

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