CN102350186B - Application of moistureproof pressure-maintaining drying agent in instrument with good seal in humid or underwater environment - Google Patents

Application of moistureproof pressure-maintaining drying agent in instrument with good seal in humid or underwater environment Download PDF

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Publication number
CN102350186B
CN102350186B CN201110200260.XA CN201110200260A CN102350186B CN 102350186 B CN102350186 B CN 102350186B CN 201110200260 A CN201110200260 A CN 201110200260A CN 102350186 B CN102350186 B CN 102350186B
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Prior art keywords
instrument
drying agent
peroxide
substance
pressure
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CN201110200260.XA
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Chinese (zh)
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CN102350186A (en
Inventor
王�锋
高云虎
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TANGSHAN YUANTENG AUTOMATION EQUIPMENT CO., LTD.
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TANGSHAN YUANTENG AUTOMATION EQUIPMENT Co Ltd
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Abstract

The invention relates to an application of a drying agent in a moistureproof pressure-maintaining drying agent for a tightly sealed instrument which can work in a wet or underwater environment. The drying agent provided by the invention is composed of a substance A and a substance B, wherein the mass ratio of the substance A to the substance B is 1: 1-1.5; the substance A is a mixture of a peroxide or a peroxide with an uperoxide; and the substance B is an organic acid. The drying agent has strong water absorption and can rapidly release nontoxic and tasteless oxygen with the maximum water absorption amount being 24% of its weight and the maximum oxygen release amount being 44% of its weight. The drying agent becomes a white powder after absorbing water, is suitable for an instrument which operates in an underwater or wet environment, and can be used to guarantee a drying environment inside the instrument, increase the pressure inside the instrument shell and alleviate and prevent continuous immersion of water molecules.

Description

Application in the instrument and meter of moistureproof pressure-maintaining drying agent good seal in humidity or underwater environment
Technical field:
The present invention relates to drier, specifically the application in the instrument and meter of a kind of moistureproof pressure-maintaining drying agent good seal in humidity or underwater environment.
Background technology:
In feedwater water supply industry, the working environment of most of instrument and meter, all in the deep-well that wetness is larger relatively, is even immersed in water.Steam can be seeped in product shell in product long-play process, affects life-span and the runnability of electronic device.
The measure the most widely of present moistureproof way is to add conventional dry drying prescription, DeGrain.Existing desiccant product (1) silica-gel desiccant: main component is silica, processes granular or pearl by natural minerals through purifying.Be used for the storage of instrument, instrument, apparatus, leather, case and bag, footwear, textile, food, medicine etc. and the relative humidity that transportation controls environment, prevent that article from making moist, go mouldy and corrosion; (2) mineral agent drier: adopt pure natural raw mineral materials and active hygroscopic agent refining to form, for the preserved in dry atmosphere of optical instrument, electronic product, medical health care, packaging for foodstuff and war products and the product for civilian use; (3) quick lime drier: be white or linen block; (4) fiber desiccant: formed through special process exquisiteness by pure natural plant fiber, processing technology is complicated, and processing cost is high.
Because the humidity of working environment is relatively large, hydrone content is quite high.And in the housing of instrument and meter, have hardly steam, so can there is water diffusion.In airtight instrument housing, only absorb water vapour, can increase the inside and outside pressure reduction of housing when product is fully immersed in water, the pressure of water is greater than the pressure that in housing, air produces, thereby make hydrone constantly penetrate in housing, conventional dry drying prescription is consumed completely very soon, and increase housing inside and outside differential pressure and form vicious circle, affect the normal work of electronic device.
Summary of the invention:
The present invention is intended to solve that existing drier exists because absorbing the steam penetrating in electronic product casing, increases the problem of the inside and outside pressure reduction of housing, and provide a kind of steam that can either effectively absorb to reach the moistureproof effect dehumidifying, can keep the air pressure in airtight instrument again, effectively stop steam to continue the application in the instrument and meter of moistureproof pressure-maintaining drying agent good seal in humidity or underwater environment of permeating in instrument.
The technical scheme that the present invention solves described problem employing is:
Application in the instrument and meter of a kind of moistureproof pressure-maintaining drying agent good seal in humidity or underwater environment, described moistureproof pressure-maintaining drying agent is comprised of A material and B material, the mass ratio of A material and B material is 1:1-1.5, and A material is the mixture of peroxide or peroxide and superoxides; B material is organic acid.
Described peroxide is potassium peroxide and sodium peroxide a kind of or its mixture wherein.
Described superoxides is potassium superoxide or sodium superoxide or super rubidium oxide or super cesium oxide.
Described organic acid is oxalic acid and citric acid a kind of or its mixture wherein.
The particle diameter of described Peroxides and Superoxides is 0-6mm.
The particle diameter of described oxalic acid and citric acid is 0-8mm.
In technical scheme of the present invention, if use merely sodium peroxide or potassium peroxide still, for the requirement of better adaptation field working conditions, to have added in right amount superoxides to meet moisture effect, make it to emit rapidly oxygen and increase the pressure in instrument and meter.A material belongs to alkalescence, and it is acid that B material belongs to, and if there is water inlet in a large number in unexpected instrument and meter, acid-base neutralization reaction can occur A B material, reduces alkaline harm.
Compared with prior art, advantage of the present invention is: have very strong water absorbing properties, and can discharge nonpoisonous and tasteless oxygen very soon.Maximum can absorb 24% of own wt, discharge 44% oxygen of own wt.After water suction, be white powder, be applicable to be operated under water or moist instrument and meter in, not only guaranteed the environment that instrument internal is dry but also increased the pressure in Instrument shell, alleviate and stop hydrone to continue immersion.
The specific embodiment:
Below by embodiment, further set forth the present invention, object is only to understand better content of the present invention.Therefore, the cited case does not limit the scope of the invention.
Tested thing: 13 micro-power consumption measuring and control terminal enclosure, material, for strengthening nylon, classification of waterproof IP66, is of a size of 320mm * 244mm * 80mm.Between upper cover and housing, there is an O-ring seal, with 14, step up screw and step up.During experiment, weigh in the balance and get 26 grams of anhydrous cupric sulfates, be divided into impartial 13 parts and put into respectively 13 housings.Can not make copper sulphate directly contact with A material.
Embodiment 1:
Raw material: 1 part of A material; 1.5 parts of B materials.A material is sodium peroxide; B material is: oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 2:
Raw material: 1 part of A material; 1.5 parts of B materials.A material is potassium peroxide; B material is citric acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 3:
Raw material: 1 part of A material; 1.5 parts of B materials.A material is comprised of 70% sodium peroxide and 30% potassium peroxide; B material is comprised of 70% oxalic acid and 30% citric acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 4:
Raw material: 1 part of A material; 1 part of B material.A material is comprised of 75% sodium peroxide and 25% sodium superoxide; B material is oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 5:
Raw material: 1 part of A material; 1 part of B material.A material is comprised of 75% sodium peroxide and 25% potassium superoxide; B material is oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 6:
Raw material: 1 part of A material; 1.2 parts of B materials.A material is comprised of 75% potassium peroxide and 25% sodium superoxide; B material is oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 7:
Raw material: 1 part of A material; 1.2 parts of B materials.A material is comprised of 75% potassium peroxide and 25% potassium superoxide; B material is oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 8:
Raw material: 1 part of A material; 1.3 parts of B materials.A material is comprised of 85% sodium peroxide and 15% super rubidium oxide; B material is oxalic acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 9:
Raw material: 1 part of A material; 1.3 parts of B materials.A material is comprised of 85% potassium peroxide and 15% super rubidium oxide; B material is citric acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 10:
Raw material: 1 part of A material; 1.4 parts of B materials.A material is comprised of 90% sodium peroxide and 10% super cesium oxide; B material is citric acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Embodiment 11:
Raw material: 1 part of A material; 1.4 parts of B materials.A material is by 90% potassium peroxide 90% and 10% super cesium oxide; B material is citric acid.
All raw materials are evenly mixed, adopt as required the fire prevention tribute silk fabric of good water permeability to pack.
Actual moistureproof pressure-maintaining contrast test:
Drier prepared by above-described embodiment 1-11 and commercially available common drier compare to be tested, and each prepares 15 grams, and test condition is: the housing that strengthens nylon is immersed in the water of 35 ℃.
Test result is as following table:
Figure DEST_PATH_IMAGE002A
From test result, see that drier of the present invention has good moistureproof pressure-maintaining effect to the instrument and meter being operated in humidity or water.
Points for attention:
The fabric of, good water permeability ventilative with fire protection flame retarding tribute silk, glass fibre etc. is as encapsulating material.Fabric outside layer of plastic film excellent sealing.Packing case material is preferably selected iron sheet packing case, is convenient to transportation and management.With fire protection flame retarding fabric encapsulation, can avoid staff careless in the situation that, water to be sprinkled upon on drier and meet accident, with layer of plastic film excellent sealing, can stop the active ingredient of moistureproof pressure-maintaining drying agent when transportation or the storage to react with the steam in the middle of air the content of avoiding reducing its active ingredient.
After A material consumption, need focus on.Processing method, prepares one barrel of water, in first A material being aborted, and then B material is thrown in into.After spending a few minutes, water can be outwelled.

Claims (4)

1. the application in the instrument and meter of moistureproof pressure-maintaining drying agent good seal in humidity or underwater environment, described moistureproof pressure-maintaining drying agent is comprised of A material and B material, it is characterized in that, the mass ratio of A material and B material is 1:1-1.5, and A material is the mixture of peroxide or peroxide and superoxides; B material is organic acid.
2. the application in the instrument and meter of moistureproof pressure-maintaining drying agent as claimed in claim 1 good seal in humidity or underwater environment, is characterized in that, described peroxide is potassium peroxide and sodium peroxide a kind of or its mixture wherein.
3. the application in the instrument and meter of moistureproof pressure-maintaining drying agent as claimed in claim 1 good seal in humidity or underwater environment, is characterized in that, described superoxides is potassium superoxide or sodium superoxide or super rubidium oxide or super cesium oxide.
4. the application in the instrument and meter of moistureproof pressure-maintaining drying agent as claimed in claim 1 good seal in humidity or underwater environment, is characterized in that, described organic acid is oxalic acid and citric acid a kind of or its mixture wherein.
CN201110200260.XA 2011-07-18 2011-07-18 Application of moistureproof pressure-maintaining drying agent in instrument with good seal in humid or underwater environment Expired - Fee Related CN102350186B (en)

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CN102350186B true CN102350186B (en) 2014-04-09

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1287869A (en) * 1999-09-09 2001-03-21 吉海平 Oxygen generator used in room
JP2003260328A (en) * 2002-03-13 2003-09-16 Shin Etsu Polymer Co Ltd Drying agent having cushioning function
EP2093162A1 (en) * 2008-02-20 2009-08-26 Airsec S.A.S. Moisture absorbing polymeric formulations with enhanced absorption properties
CN102144664A (en) * 2010-12-27 2011-08-10 山东营养源食品科技有限公司 Solid hydrogen peroxide sustained release preparation and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2071070U (en) * 1989-12-27 1991-02-13 广东煤矿安全仪器厂 Mine filting type oxygen-producing life self-saving device
JP5141063B2 (en) * 2007-03-26 2013-02-13 トヨタ自動車株式会社 Exhaust gas purification device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1287869A (en) * 1999-09-09 2001-03-21 吉海平 Oxygen generator used in room
JP2003260328A (en) * 2002-03-13 2003-09-16 Shin Etsu Polymer Co Ltd Drying agent having cushioning function
EP2093162A1 (en) * 2008-02-20 2009-08-26 Airsec S.A.S. Moisture absorbing polymeric formulations with enhanced absorption properties
CN102144664A (en) * 2010-12-27 2011-08-10 山东营养源食品科技有限公司 Solid hydrogen peroxide sustained release preparation and preparation method thereof

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