Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of have mildew-resistant, deoxidation and fresh-keeping multi-functional powdery biscuit mildew-resistant deoxidizing antistaling agent are provided.
Powdery biscuit mildew-resistant deoxidizing antistaling agent is made up of red bentonite, dolomite Concave-convex clay rod, bauxite, sulfuric acid, reduced iron powder, Tea Polyphenols and calcium propionate.
The production method of powdery biscuit mildew-resistant deoxidizing antistaling agent: red bentonite, dolomite Concave-convex clay rod, bauxite mixing are carried out pulverizing jointly with reduced iron powder, Tea Polyphenols and calcium propionate after acidifying, compressing tablet and the heat treatment, be packaged as powdery biscuit mildew-resistant deoxidizing antistaling agent.
Iron oxide content >=14% in the red bentonite, alundum (Al content >=10%; The content of calcium oxide >=24% in the dolomite Concave-convex clay rod, magnesian content >=12%; Alundum (Al content >=55% in the bauxite; Red bentonite, dolomite Concave-convex clay rod and bauxite are mixed into mineral intermixture; The acidified processing of mineral intermixture back generates sulfate mixtures such as part of sulfuric acid calcium, magnesium sulfate, ferrous sulfate and aluminum sulfate; Calcium sulfate, magnesium sulfate, ferrous sulfate and aluminum sulfate all have higher wettability power; Mineral intermixture with acidification carries out activation heat treatment again, has improved the moisture sorption effect of the mineral intermixture of acidification greatly.
Red bentonite originates in horse race mining area, mountain, Gui Wu town, Xuyi County, Jiangsu Province; Main component has quartz, montmorillonite, kaolinite, bloodstone and feldspar, iron oxide content >=14%, alundum (Al content >=10%; The mining area reserves have more than 1,000,000 tons; Be an opencut,, still fail the large tracts of land exploitation at present because purposes is not extensive.
Reduced iron powder can absorb airborne oxygen, and 1 gram reduced iron powder deoxygenation ability is 300mL, amounts to air 1500mL, and deaerating effect is good, reduced iron powder grain fineness≤0.074 that the present invention selects for use millimeter.
Tea Polyphenols has very strong antioxidation, and is soluble in water, and stability is extremely strong, and pigment in the biscuit and vitamins are had protective effect, makes biscuit keep original color and luster and trophic level in a long time, can effectively prevent the corruption of biscuit, and can eliminate peculiar smell.
Calcium propionate is water-soluble, is the acid type food preservative, under acid condition, produces free propionic acid, has antibacterial action, and its bacteriostasis receives the influence of environment pH value, and the inhibitory action of mould is best when pH value 5.0.
Dolomite Concave-convex clay rod, bauxite and reduced iron powder are common commodity.
The present invention is achieved through following technical proposals:
1, the batching of powdery biscuit mildew-resistant deoxidizing antistaling agent is made up of following component by weight percentage: mould inhibitor 40~85%, reduced iron powder 14~58%, Tea Polyphenols 0.01~2% and calcium propionate 0.01~2%;
The production method of powdery biscuit mildew-resistant deoxidizing antistaling agent: input pulverizer after the batch mixes of powdery biscuit mildew-resistant deoxidizing antistaling agent is pulverized, and the grain fineness after the pulverizing≤0.074 millimeter packs and is powdery biscuit mildew-resistant deoxidizing antistaling agent;
The production method of said mould inhibitor: 1. the batching of mineral intermixture is made up of following component by weight percentage: red bentonite 25~55%, dolomite Concave-convex clay rod 20~50% and bauxite 15~40%; 2. pulverize the grain fineness after the pulverizing≤0.50 millimeter after the batch mixes with mineral intermixture; 3. the preparation of dilute sulfuric acid is made up of following component by weight percentage: sulfuric acid 2~20% and the water 80~98% of concentration 98 ﹪; 4. the batching of acidification is made up of following component by weight percentage: mineral intermixture 55~75% and dilute sulfuric acid 25~45% after the pulverizing; 5. dilute sulfuric acid is slowly added in the mineral intermixture after the pulverizing and carry out acidification, the mineral intermixture of acidified processing was stacked after 24~72 hours, and extruding is tablet in the input twin rollers, and the THICKNESS CONTROL of tablet is at 1~3 millimeter; 6. tablet is imported and heat-treated the back mould inhibitor that is in the rotary dryer, the temperature during heat treatment is controlled at 250~320 ℃, and the time was controlled at 60~180 minutes, the water content of mould inhibitor≤1.0%.
Acidification technology of the present invention does not have discharge of wastewater, and method is simple, and is environment friendly and pollution-free.
After mould inhibitor added measuring cup, placing in the drier that fills saturated aqueous sodium chloride, is under 35 ℃ the condition in temperature, 24 hours Static Water absorption >=20%.
Reduced iron powder can absorb airborne oxygen; 1 gram reduced iron powder deoxygenation ability is 300mL, amounts to air 1500mL, and deaerating effect is good; This is those skilled in the art's a common practise, but uses reduced iron powder can not reach the fresh-keeping effect of mildew-resistant deoxidation simultaneously separately; After adopting in the present invention that reduced iron powder, mould inhibitor, Tea Polyphenols and calcium propionate are common and pulverizing, be packaged as have mildew-resistant, deoxidation and fresh-keeping multi-functional powdery biscuit mildew-resistant deoxidizing antistaling agent.
Powdery biscuit mildew-resistant deoxidizing antistaling agent is placed in the packing container of biscuit, and mildew-resistant, deoxidation and fresh-keeping carried out synchronously, can remove free oxygen and part free water in the Biscuit package.
Water content according to different biscuits; Select the different ingredients by weight percentage of powdery biscuit mildew-resistant deoxidizing antistaling agent; When keeping a certain amount of moisture, carry out mildew-resistant, deoxidation and fresh-keeping, powdery biscuit mildew-resistant deoxidizing antistaling agent can effectively prevent the oxidation of biscuit composition and suppress microbial growth and breeding.
The not blending of powdery biscuit mildew-resistant deoxidizing antistaling agent can be guaranteed the inherent quality of biscuit in the biscuit raw material, can keep the original fresh flavor of biscuit, in the shelf-life, can not occur dry and crackedly, also can not produce tart flavour, putrid and deteriorated flavor, musty or other smells.
After powdery biscuit mildew-resistant deoxidizing antistaling agent used, when general garbage disposal, degradable did not have environmental pollution.
Powdery biscuit mildew-resistant deoxidizing antistaling agent is applicable in the inner wrapping that is placed on biscuit.
The specific embodiment
Below in conjunction with embodiment the present invention is done further description:
1, the batching of powdery biscuit mildew-resistant deoxidizing antistaling agent is made up of following component by weight percentage: mould inhibitor 66%, reduced iron powder 33.5%, Tea Polyphenols 0.3% and calcium propionate 0.2%;
The production method of powdery biscuit mildew-resistant deoxidizing antistaling agent: input pulverizer after the batch mixes of powdery biscuit mildew-resistant deoxidizing antistaling agent is pulverized, and the grain fineness after the pulverizing≤0.074 millimeter packs and is powdery biscuit mildew-resistant deoxidizing antistaling agent;
The production method of said mould inhibitor: 1. the batching of mineral intermixture is made up of following component by weight percentage: red bentonite 40%, dolomite Concave-convex clay rod 34% and bauxite 26%; 2. pulverize the grain fineness after the pulverizing≤0.50 millimeter after the batch mixes with mineral intermixture; 3. the preparation of dilute sulfuric acid is made up of following component by weight percentage: sulfuric acid 8% and the water 92% of concentration 98 ﹪; 4. the batching of acidification is made up of following component by weight percentage: mineral intermixture 65% and dilute sulfuric acid 35% after the pulverizing; 5. dilute sulfuric acid is slowly added in the mineral intermixture after the pulverizing and carry out acidification, the mineral intermixture of acidified processing was stacked after 48 hours, and extruding is tablet in the input twin rollers, and the THICKNESS CONTROL of tablet is at 1.5 millimeters; 6. tablet is imported and heat-treated the back mould inhibitor that is in the rotary dryer, the temperature during heat treatment is controlled at 280~300 ℃, and the time was controlled at 120 minutes, the water content of mould inhibitor≤1.0%.
Through on-the-spot test, mould inhibitor added measuring cup after, place in the drier that fills saturated aqueous sodium chloride, be under 35 ℃ the condition in temperature, 24 hours Static Water absorption >=24%.