CN102317427B - Improvements relating to fabric treatment compositions - Google Patents
Improvements relating to fabric treatment compositions Download PDFInfo
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- CN102317427B CN102317427B CN200980156838.7A CN200980156838A CN102317427B CN 102317427 B CN102317427 B CN 102317427B CN 200980156838 A CN200980156838 A CN 200980156838A CN 102317427 B CN102317427 B CN 102317427B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Abstract
A fabric conditioning composition, which comprises: a) at least one cationic or nonionic softening agent, b) a powder of botanical origin, and c) an optional polymeric deposition aid, wherein the powder of botanical origin has a particle size of from 0. 1 to 100 [mu]m, preferably from 0. 5 to 50 and most preferably from 1 to 45 [mu]m.
Description
Technical field
The present invention relates to comprise the fabric-conditioning compositions of plant origin micro mist.
Background technology
The fabric softness of using clay particle to give from washing or cleaning is known in the art.Similarly, the nano particle of silicon-dioxide or titanium dioxide and the purposes of micro-encapsulated fragrance particle are now by the fully open perfume compound effect for strengthening.
The open water of US2003/0087788 (Rhodia Inc) dispersibles particle, the hydrophobicity spices that comprises drop form, described hydrophobicity spices be finely dispersed in can for the polypeptide in plant or synthetic source (for example soybean or wheat) water-soluble/dispersible solid organic substrate in and by it, sealed.
EP0908171 (Gem Energy Industry Ltd) discloses a kind of dry powder draft cleaning compositions, comprises (a) as the herbaceous plant of soap or washing composition; (b) be used as the herbaceous plant of foaming promotor; (c) be used as the herbaceous plant of pore forming material; (d) be used as the herbaceous plant of painted or color restoration or maintaniing agent; (e) be used as the herbaceous plant of amendment.
WO00/77153 (Unilever plc) discloses a kind of detergent tablet, comprises the particle that (a) contains organic surface active agent and detergent builder compound; But (b) the water-insoluble water-swellable particle of vegetable material, it comprises Mierocrystalline cellulose and xylogen, and Root-bark of Coconut for example can obtain in vegetable material fragmentation being entered to liquid dispersion on the basis of separated its fiber not.
We have now found that the micronised powder of plant origin can be deposited on fabric by washing cleaning products, gives fabric beneficial agent or new fragrant enhancement.The example of this powder comprises the ginger for spices; For pure and fresh bitter orange, lemon or orange; Petal for perfume compound; Leafing agent, for example oat benevolence powder, rice or bran powder; The pigment of various natural origins, for example curcuma powder of anti-inflammatory benefit; For example, for the seed derivative of perfume compound, Elettaria cardamomum (L.) Maton and coriandrum; For example, for the various dry herbaceous plant of perfume compound and antimicrobial benefit, peppermint, wild marjoram, green tea, Folium Lauri nobilis and tea tree.
summary of the invention
Aspect first, the invention provides a kind of fabric-conditioning compositions, it comprises:
A) at least one positively charged ion or non-ionic softener,
C) powder of plant origin, and
D) optional polymer deposition auxiliary agent,
Wherein the powder of plant origin has 0.1 to 100 μ m, preferably 0.5 to 50 μ m and the most preferably granularity of 1 to 45 μ m.
Aspect second of the present invention, a kind of method of processing fabric is provided, comprise the step with the compositions-treated textile article defining in front claim as any one.
In another aspect of the present invention, a kind of method of preparing composition is provided, comprise the powder efflorescence to 0.1 of plant origin to 100 microns, preferably 0.2 to 90 micron, more preferably 0.5 to 60 micron, more preferably 1 to 45 micron and the granularity of 2 to 30 microns most preferably.
detailed Description Of The Invention
The powder of plant origin
The present invention requires the purposes of ultrafine powder.The powder that is suitable for the present composition is the sl. sol. of plant origin, preferred insoluble grainy texture thing.They are fragrance preferably, and preferably includes one or more fragrant essential oils.
Powder of the present invention can have any shape, and may not be spherical, can have the long-width ratio (ratio of length over diameter) that is greater than 1.In the context of the present invention, micronization, ultra-fine or finely divided expression granularity have 0.1 to 100 micron, and preferably 0.2 to 90 micron, more preferably 0.5 to 60 micron, more preferably 1 to 45 micron and the greatest axis of 2 to 30 microns most preferably.
The particle of suitable dimension can be by any suitable method, such as efflorescence, the acquisition such as mill.Classification, for example, by screening, can be used to separated required size range.
Powder is the material of plant origin, and can be derived from any part of plant, such as stem tuber, fruit, flower, flower part (calyx, stamen etc.), seed, bean or pea, beanpod, pith, timber, bark, bar, stem, blade, root, rhizome, shell, crust, pericarp and composition thereof.
The example of aromatics powder comprises vanilla bean powder, ginger powder, Cortex Cinnamomi powder, cocoa powder, Ground Cloves, Elettaria cardamomum (L.) Maton powder, coriandrum powder, cumin powder, Caraway powder, dill powder, red chilly powder, cyanine powder, curcuma powder, coffee bean powder, tea leaf powder, tea tree powder, strawberry leaves powder, Monarda citriodora leaf powder, herbal medicine powder (Rosmarinus officinalis for example, Thymus vulgaris, Laurus nobilis, Sage, tarragon, peppermint, sweet basil, Herba Melissae officinalis, verbena, red Citrus bergamia, marjoram, lavender and wild marjoram), Phytoconcentrol Chamomile powder, fennel powder, limette fruit peel powder, lemon fruit peel powder, natsudaidai fruit peel powder, red tangerine fruit peel powder, tangerine fruit peel powder, lemon grass meal, apple ground-slag, lemon endeavor river pear powder, red clover grass meal, licorice powder and composition thereof.
Preferred non-aromatic powder comprises ginseng powder, powdered rice hulls, wheat shell powder, Buckwheat shell powder and composition thereof.
Powdered material can be natural form, or can be produced by the method for for example aging, fermentation and roasting, and described method can increase or change and forms aromachemicals.
By cleaning product, this powder is transported to fabric kimonos and loads onto a large amount of benefits of each composition that can give from native state, described composition is difficult to be carried by washing application.These comprise lasting fragrance and pure and fresh, antibacterial activity, deodorant activities, skin anti-aging and comfortable (well-being) active, change fabric thoughts and feelings (feel), nice and cool benefit and warm benefit.
Plant powder of the present invention can be to introduce in cleaning composition with mode like other powdered constituent class.
The powder of plant origin is with 0.1 to 10 wt% of whole compositions, preferred 0.3 to 6 wt%, more preferably 0.4 to 4 wt% and most preferably the amount of 0.5 to 3 wt% exist.
The powder that is suitable for the plant origin in the present invention is not to extract or separated material, polymkeric substance for example, and for example xylogen, starch or protein, but the plant of powdered in loose condition (of surface) is local.This powder does not wish to comprise Mierocrystalline cellulose or derivatived cellulose, for example polymer derivant, for example ether of cellulose.Plant part (being pre-powdered) and powder do not experience for example chemical purification, to remove for example xylogen or pigment component (but certainly, can being washed or cleaning).
Polymer deposition auxiliary agent
Micropowder is deposited on base material and can be realized by any suitable approach by washing formula of the present invention.
For example, by filtering, wherein the granularity of powder is intercepted between fabric fibre particle.Filtration mechanism requires particle or the group of primary granule to have the size that can compare with aperture between yarn.
The granularity that is suitable for filtering is generally 1 to 30 micron.It is visible that larger particle starts naked eyes, the removal and less particle tends to be in the suds.The particle of approximately 5 to 15 microns is preferred, invisible and show by filtering and deposit on fabric well because they tend to naked eyes.
Micropowder by washing of the present invention formula deposition can also by polymkeric substance assistant depositing realize and surpass based on filtration method carry.When existing, polymer deposition auxiliary agent is with 0.01 to 5% of composition total weight, preferably 0.02 to 3%, more preferably 0.2 to 2% and most preferably 0.5 to 1.6% level suitably exist.
Be suitable for polymer deposition agent of the present invention and comprise natural polymer and the synthetic polymer of modification.
The polymkeric substance that is suitable for depositing micropowder is open in WO9709406, high MW polyethylene oxide (PEO) particularly, and it is at main washing sedimentary clay particle; EP0299575B1 and WO9527037 disclose high MW PEO, polyacrylic ester, polyacrylamide, polyvinyl alcohol and polymine, and it is for mainly washing sedimentary clay particle; Use similar polymkeric substance list and guar gum with EP0387426B1.
The open suitable wash phase polymer deposition auxiliary agent for emulsion drop of WO 01/07546 A1, comprises cation guar gum polymkeric substance, cationic polyacrylamide, cationic potato starch and cationic cellulose derivative.
The natural polymer that is suitable for preferred modification of the present invention can be selected from cationic starch, cation guar gum, cationic cellulose and nonionic locust bean gum (LBG).Preferred cationic starch is cation-modified yam starch.
The suitable example of cationic polymers comprises cation guar gum polymkeric substance, Jaguar (purchased from Rhone Poulenc) for example, cationic cellulose derivative, Celquats (purchased from National Starch) for example, Flocaid (purchased from National Starch), cationic potato starch, for example Softgel (purchased from Aralose) and cationic polyacrylamide, for example PCG (purchased from Allied Colloids).
Suitable nonionic deposition aid comprises high molecular weight polyethylene glycol, for example PEO WSRN 750 (purchased from Union Carbide).
Preferred synthetic polymer as deposition aid can be selected from polyethylene oxide (PEO), polymine (PEI), poly-(acrylate), poly-(acrylamide), polyethylene terephthalate-polyoxyethylene terephthalate (PET/POET) polymkeric substance and composition thereof.
Fabric softener
Fabric-conditioning compositions
Fabric-conditioning compositions of the present invention is suitable for using in washing methods.Example comprises clean (for example amendment or ornamenting agent), or aftertreatment ' wet tissue (wet tissue) ' type product.Composition of the present invention is preferably and cleans the softening compositio adding.
Composition of the present invention can be any physical form, for example tablet, bar, slurry, gel or liquid, spraying, rod, dipping base material, foam or mousse.Especially, said composition can be liquid state or unitary dose, for example bag.
Liquid product of the present invention can have 2.5 to 7 pH.It is stable that this pH scope preferably keeps in the preservation period of product.
Activeconstituents in composition is fabric conditioner.Can comprise more than a kind of activeconstituents.
Tenderizer
The fabric conditioner of any routine can be for composition of the present invention.Amendment can be positively charged ion or non-ionic.They can be for example with 0.5 wt% to 35 wt% of composition, preferred 1 wt% to 30 wt%, more preferably the amount of 3 wt% to 25 wt% is used.
Preferred softening actives for cleaning conditioner composition of the present invention is quaternary ammonium compound.For the quaternary ammonium fabric softener material of composition of the present invention, can be trolamine (TEA) quaternary ammonium compound of ester-bonding, comprise single-, the mixture of two-and three-ester bonding component.
Typically, TEA based fabric soften compound comprise the list of this compound-, the mixture of two-and three-ester form, wherein the component of diester bonding is constituted to many 70 wt%, preferred 60 wt% at the most, 55 wt% at the most for example, or the fabric softening compound of 45 wt% even at the most, and the component of monoesters bonding forms the fabric softening compound of at least 10 wt%.
Being suitable for first group of quaternary ammonium compound of the present invention (QAC) is represented by formula (I):
Wherein each R is independently selected from C
5-35alkyl or alkenyl; R
1represent C
1-4alkyl, C
2-4thiazolinyl or C
1-4hydroxyalkyl; T is generally O-CO (ester group being connected with R via its carbon atom), but may further be CO-O (ester group being connected with R via its Sauerstoffatom); N is 1 to 4 numerical value; M is 1,2 or 3 numerical value; And X
-for anionic counter ion, for example halogenide or alkyl-sulphate, for example muriate or Methylsulfate.The dibasic acid esters modification of formula I (being m=2) is preferred, conventionally has the list relevant with them-and three-ester homologues.This material is particularly suitable for the present invention.
Particularly preferred reagent is the dibasic acid esters of methylsulfuric acid trolamine, is called in addition " TEA ester quaternary ammonium ".Commercial embodiments comprises Prapagen TQL, purchased from Clariant, with Tetranyl AHT-1, purchased from Kao, (being both two of methylsulfuric acid trolamine-[hardened tallow ester]), AT-1 (two of methylsulfuric acid trolamine-[butter ester]), and L5/90 (two of methylsulfuric acid trolamine-[palm ester]), both purchased from Kao, and Rewoquat WE15 (diester of methylsulfuric acid trolamine, has derived from C
10-C
20and C
16-C
18the fatty acyl residue of unsaturated fatty acids), purchased from Witco Corporation.
The second group of QAC being suitable in the present invention represented by formula (II):
Each R wherein
1group is independently selected from C
1-4alkyl, hydroxyalkyl or C
2-4thiazolinyl; Each R wherein
2group is independently selected from C
8-28alkyl or alkenyl; Wherein n, T and X
-as defined above.
The preferred material of second group comprises 1, two [butter the acyloxy]-3-Trimethylamine 99 propane chloride, 1 of 2-, two [hardened tallow the acyloxy]-3-Trimethylamine 99 propane chloride, 1 of 2-, two [oily the acyloxy]-3-Trimethylamine 99 propane chloride of 2-and two [the stearoyl-oxy]-3-Trimethylamine 99 propane chloride of 1,2-.This material, at US 4,137, is described in 180 (Lever Brothers).Preferably, these materials also comprise a certain amount of corresponding monoesters.
The 3rd group of QAC being suitable in the present invention represented by formula (III):
(R
1)
2-N
+-[(CH
2)n-T-R
2]
2 X
- (III)
Each R wherein
1group is independently selected from C
1-4alkyl or C
2-4thiazolinyl; Each R wherein
2group is independently selected from C
8-28alkyl or alkenyl; And n, T and X
-as defined above.The preferred material of the 3rd group comprises two (2-butter acyloxy ethyl) alkyl dimethyl ammonium chlorides and sclerosis modification thereof.
The iodine number of quaternary ammonium fabric softener material is 0 to 60, is preferably 0 to 45, more preferably 0 to 30, and most preferably be 0 to 20.
Iodine number is defined as the grams of the iodine of every 100 g test materials absorptions.NMR spectroscopy, for measuring the Appropriate technology of the iodine number of tenderizer of the present invention, is used Johnson and Shoolery at Anal.Chem., in 34,1136 (1962) and the method for describing in EP 593,542 (Unilever, 1993).
Non-ester soften compound preferably has the alkyl or alkenyl chain length of mentioning for above non-ester soften compound.
The preferred type of non-ester soften compound is the quaternary material being represented by formula (IV) :-
Each R wherein
1group is independently selected from C
1-4alkyl, hydroxyalkyl or C
2-4thiazolinyl; And R
2group is independently selected from C
8-28alkyl or alkenyl; And X
-as defined above.
Composition can comprise total amount 0.5 wt% to 40 wt%, preferred 1.5 wt% to 30 wt%, and more preferably 4 wt% to 25 wt%, the fabric softening compound of 10 wt% to 30 wt% most preferably, based on composition total weight.
Said composition can be used as that replacement scheme comprises or additionally comprise non-ionic fabric softener, for example lanolin and derivative thereof.The other non-ionic fabric softener that is suitable for the present composition is Viscotrol C, for example, purchased from Now Chemicals.
Yelkin TTS and other phosphatide are also suitable soften compounds.
The preferred type of another kind of tenderizer is sugared polyester.When existing, sugared polyester is preferably selected from sucrose polyester, glucose polyester and cellobiose polyester, most preferably sucrose polyester.
Sugar polyester can be liquid, soft solid or solid.
For preferably sucrose polyester of the present invention, each sugar ring has 2 to 4 hydrocarbon chains, and wherein hydrocarbon chain has the length of 12 to 22 carbon atoms.Particularly preferred sucrose polyester is sucrose four eruciate.
The Ryoto Sugar Ester ER290 of the example of preferred sucrose polyester for being provided by Mitsubishi Kagaku Foods Corporation, it is sucrose four eruciate, with according to the specification sheets of producer, be mainly four eruciate, five eruciate and six eruciate and there is 2 HLB value.
Sugar polyester can be pure, maybe can comprise impurity.When existing, impurity is preferably selected from free fatty acids, fatty acid methyl ester, soap, inorganic salt and composition thereof.
Most preferred SPE is commercially available available, Emanon SCR-PK (purchased from KAO) for example, and it is the derivative SPE of palm-kernel, mainly comprises C
12-C
14, there is approximately 20% C
18cholesterol degree, and SPE-THSBO (purchased from Clariant), it mainly has C derived from contact hardening soybean oil
16-C
18chain, has approximately 80% single and two degrees of unsaturation.The average esterification degree of above-mentioned preferred SPE is 4.2 to 4.7.
SCR-PK comprises 20% impurity at the most, and SPE-THSBO is pure.The K soap that SCR-PK comprises 4 to 6 wt%, the free fatty acids of 2.5 wt%, the fatty acid methyl ester of 10 to 15 wt% and lower than 1% KCl.
Sugar polyester is non-ionic oil, needs emulsifying agent, and sugared polyester is necessary for emulsification form.Emulsifying agent is preferably selected from cats product, anion surfactant, nonionogenic tenside and composition thereof.
Ultra-fine grain of the present invention itself can be used as non-ionic softener, for example stablizer and the emulsifying agent of sugared polyester (SPE).Again paid close attention to recently solid particulate as the research (Binks, the up-to-date idea of B. P. Current Opinions in Colloid Interface Science(colloidal interface science) of emulsifying agent, 2002,7,21).
Latest activity about surfactivity colloidal solid has concentrated on extremely low long-width ratio (spherical) particle.Only nearest, the people such as Alargova, Langmuir, 2006,22,765-774, has proved that high-aspect-ratio particle can be for emulsion-stabilizing.
In fabric softening compositions, can there is nonionic stabiliser.Suitable nonionic stabiliser can be for for example using the oxyalkylated linear C of 10 to 20 mol of alkylene oxide
8to C
22alcohol, C
10to C
20alcohol or its mixture.Other stablizer comprises the deflocculate polymkeric substance as described in EP 0415698A2 and EP 0458599B1.
Advantageously, nonionic stabiliser is with the oxyalkylated linear C of 10 to 20 mol of alkylene oxide
8to C
22alcohol.Preferably, the level of nonionic stabiliser is 0.1 to 10 wt%, and more preferably 0.5 to 5 wt%, most preferably is 1 to 4 wt%.Quaternary ammonium compound and/or other cationic softening agent are suitably extremely about 1:1 of 40:1 to the mol ratio of nonionic stabiliser, are preferably 18:1 to about 3:1.
Said composition also can comprise lipid acid, for example C
8to C
24alkyl or alkenyl monocarboxylic acid or its polymkeric substance.Preferred fatty acid is non-saponification, and more preferably lipid acid is free for example oleic acid, lauric acid or tallow fatty acid.The level of fatty acid material preferably surpasses 0.1 wt%, more preferably surpasses 0.2 wt%.Concentrated composition can comprise 0.5 wt% to 20 wt%, the more preferably lipid acid of 1 wt% to 10 wt%.Quaternary material or other cationic softening agent are preferably 10:1 to 1:10 to the weight ratio of fatty acid material.
Also may comprise that some can be used for the monoalkyl cationic surfactant of the main cleaning composition of fabric.Operable cats product comprises general formula R 1R2R3R4N
+x
-quaternary ammonium salt, wherein R group, for long or short hydrocarbon chain, typically is alkyl, hydroxyalkyl or ethoxylated alkyl, X is that (for example wherein R1 is C to gegenion
8-C
22alkyl, preferably C
8-C
10or C
12-C
14alkyl, R2 is methyl, R3 and R4 can be identical or different and be the compound of methyl or hydroxyethyl); And cationic ester (for example cholinesterase).
For the water-based of adding amendment, clean the level of positively charged ion or non-ionic softener from 3 to 30%, more preferably 5 to 25% variations.In super concentrated solution, plant powder can be incorporated in the substantially anhydrous system that comprises 60% fabric-softening actives at the most.
Fabric-conditioning compositions of the present invention also can comprise the auxiliary agent of makeup, medicine and/or dermatological field Plays, for example wetting ability or lipophilicity gelifying agent, wetting ability or lipophilicity promoting agent, sanitas, oxidation inhibitor, solvent, spices, filler, screening agent, sterilant, odour absorbents, light stripping agent (singlet oxygen or free radical type) and dyestuff.The amount of these various auxiliary agents be in field under consideration normally used those, and be for example 0.01 to 20% of composition total weight.According to its characteristic, these auxiliary agents can be introduced in fat phase and/or water.The example that is used for suitable sterilant of the present invention comprises Proxel, and (1,2-phenyl isothiazoline-3-ketone (1,2-benzisothiazolin-3-one)), purchased from for example Univar, Avecia and Uniqema; With Kathon CG (methylchloroisothiazandnone and methylisothiazolinone), purchased from Rhom and Haas.
Base material
When washing, base material can be any base material, wishes for example processing of washing or cleaning process of deposition vegetable particle and experience on it.
Especially, base material can be fabric.
Process
With compositions-treated base material of the present invention, can be completed by any method, described method is for example washing, soaks or clean base material, also can, by directly applying, such as spraying, friction, drop, smear etc., complete.
Processing can comprise makes base material contact with the aqueous medium that comprises material of the present invention.
Can, in the processing separated with conventional home washings step, with for example spray composition form for family expenses (or industry) application, to fabric, provide processing.Suitable spraying distribution device discloses and is hereby incorporated by WO 96/15310 (Procter & Gamble).
Composition of the present invention can be used to for fabric provides fragrance and/or smell benefit, for example, reduce stench.
Embodiment
Embodiment
Now according to following non-limiting example explanation embodiment of the present invention.Except as otherwise noted, all proportions provides with the wt% of whole compositions.
embodiment 1: for the preparation of the present invention's powder
(a) centrifugal milling
The plant powder of the Retsch ZM1000 ultra centrifugal mill prepared sizes that use is turned round with 10,000 rpm speed in the scope of asking for protection.This runner milling is equipped with 24 tooth rotors and 0.12 mm screen cloth.
For avoiding potential loss or the sex change of during milling heating material and volatile oil, they before being admitted to runner milling with dry ice blend.
(b) size classification
Then use Endecotts Ltd (Britain) test screen cloth to be divided into different granularity fractions from centrifugal fine powder of milling.
The screen cloth of different orifice size is laminated to each other, and 10 g powder are placed in top mesh, and screen cloth lamination is placed on Retsch AS200 sieve shaker, makes powder be divided into different granularity fractions.Retsch controls and is set to the amplitude with 1.5 mm, shakes 5 minutes, has 10 seconds vibration interval.Between interval, take off screen cloth lamination, manually beat several times.
During the technique of milling, some scented plants powder become seriously coalescent.This point makes that to carry out size classification unrealistic by shaking.But powder can easily be brushed past screen cloth, to allow to be divided into different size ranges.
Table 1 provides two examples that are retained in the granularity fraction on each screen cloth from 10 g initial powders.
Table 1: shake (ginger) and brush and smear after (Elettaria cardamomum (L.) Maton) 30 minutes the weight fraction on screen cloth that is retained in from 10 g initial powders.
In all following particle deposition experiments, use the granularity fraction of < 45 μ m.
embodiment 2: according to the softener composition 1 to 4 that comprises herbal medicine and spices of the present invention
According to the present invention, the fabric conditioner composition 1 to 4 in table 2 comprises herbal medicine and spices.
Table 2: fabric softening compositions 1 to 4
*the ginger of efflorescence and size classification, Elettaria cardamomum (L.) Maton and lavender powder as mentioned above.Lavender 70%, Phytoconcentrol Chamomile 30%.
*ayurveda blend comprises Radix Glycyrrhizae 15%, Chinese cassia tree 5%, ginger 15%, orange peel 20%, Elettaria cardamomum (L.) Maton 40%, cloves 5%.
*tEA quat is the cationic softener based on trolamine, has the IPA of butter or hard butter chain and 15% as solvent.
* * Emanon SCR-PK is the sucrose polyester softening oil derived from palm-kernel oil.
embodiment 3: the evaluation that powder deposits on fabric
For during evaluate cleaning from the deposition of the ultra-fine vegetable particle of positively charged ion tenderising soln, use Linitester, it is by the rolling of 100 ml scales simulation automatic washing devices.
Can be by measuring solution and clothing in contact front and back, the turbidity of scavenging solution or light transmission, quantize the deposition level from the particle of scavenging solution.In the situation that existing, cationic softener can not carry out light transmission or turbidity measurement for this purpose, because their intrinsic haziness.For the positively charged ion condition that environment is cleaned in simulation, therefore we rely on the transparent micellar solution of cats product (CTAC), and according to the step of following summary :-
1. in each Linitester still, add 100 g to comprise following solution :-
Cetyltrimethylammonium chloride (CTAC) cats product (0.025 g),
Deposited polymer (from the polymers soln of previous preparation) (0.002 g), and
Plant powder (0.015 g).
2. Linitester temperature setting is set to 40 ℃.
3. (before deposition) after 5 minutes, sampling 5 ml samples are measured for light transmission.
4. by 20 * 20 cm
2fabric detects thing and joins in still.
5. then make Linitester operation 20 minutes.
6. during end of run, take out fabric, rotate and dry.
7. discharging second 5 ml sample (after deposition) measures for light transmission.
On spectrophotometer analytical sample at the percent transmittancy of 560 nm.
Following table 3 is summarised under 3 kinds of different deposited polymers existence, the mint particles deposition of the < 45 μ m of scavenging solution.Deposition recently represents with the percentage of the particle total amount of adding in solution.
For transmission % being converted to deposition %, the function acquisition calibration curve according to transmission % as micro mist concentration.
Table 3: under Softgel BDA, Viscogum BE and polymkeric substance JR exist, the deposition of the mint particles of the scavenging solution of next self-contained 0.002 % polymer deposition auxiliary agent on cotton, poly-cotton and polyester.
Use the transmission % under Hewlett Packard 8453 UV/Vis spectrophotometer measurement λ=560 nm.
Softgel BDA (Avebe) is low for having, the cationic potato starch of 0.05% substitution value (electric charge (charg)).
Ucare polymkeric substance JR-30M (Amerchol) has the cationic hydroxyethyl cellulose of 1.5-2.2% substitution value in the past.
LBG (Sigma) is nonionic Viscogum BE polysaccharide.
Come the transportation horizontal of independent cationic solution of the scavenging solution of self simulation washing plant condition to be unexpectedly better than water.Except polyester, polymkeric substance has improved deposition, and wherein high charge density JR polymkeric substance has the deposition of the improvement that is better than contrasting CTAC.
Astoundingly, LBG, probably due to the recognition (recognition) of its affinity and Mierocrystalline cellulose unit, has the deposition (the positively charged base material in CTAC) of improvement on cotton and poly-cotton.
The wet thing that detects has strong deposited particles smell, and described particle has faint vestige when dry.For synthetics, polyester for example, this point is enough to the ambiguous smell of vinegar of polyester textile to be covered as pleasant smell.
Claims (18)
1. a fabric-conditioning compositions, it comprises:
A) at least one positively charged ion or non-ionic softener, wherein cationic softening agent is quaternary ammonium compound,
B) powder of plant origin, its amount with 0.1 to 10 wt% of whole compositions exists, and be selected from vanilla bean powder, cocoa powder, coriandrum powder, cumin powder, Caraway powder, dill powder, coffee bean powder, tea leaf powder, tea tree powder, blackberry leaf powder, Monarda citriodora leaf powder, herbal medicine powder, Phytoconcentrol Chamomile powder, sour orange peel powder, lemon fruit peel powder, natsudaidai fruit peel powder, tangerine fruit peel powder, lemon grass meal, apple ground-slag, lemon endeavor river pear powder, red clover grass meal, red chilly powder, cyanine powder and composition thereof, and
C) polymer deposition auxiliary agent,
Wherein the powder of plant origin has the granularity of 1 to 45 μ m.
2. according to the composition of claim 1, wherein said herbal medicine powder is ginger powder, Cortex Cinnamomi powder, Ground Cloves, Elettaria cardamomum (L.) Maton powder, curcuma powder or fennel powder.
3. according to the composition of claim 1, wherein the powder of plant origin exists with the amount of 0.3 to 5 wt% of whole compositions.
4. according to the composition of claim 1, wherein the powder of plant origin exists with the amount of 0.5 to 3 wt% of whole compositions.
5. according to the composition of claim 1, wherein said herbal medicine powder is licorice powder.
6. according to the composition of claim 1, wherein said tangerine fruit peel powder is red tangerine fruit peel powder.
7. according to the composition of claim 1, its herbal medicine be selected from Rosmarinus officinalis, Thymus vulgaris, Laurus nobilis, Sage, tarragon, peppermint, sweet basil, Herba Melissae officinalis, verbena, red Citrus bergamia, marjoram, lavender and wild marjoram.
8. according to the composition of claim 1-4 any one, wherein plant powder is native state, aging, slaking, fermentation or roasting.
9. according to the composition of claim 1-4 any one, wherein polymer deposition auxiliary agent exists with 0.01 to 5% level of composition total weight.
10. according to the composition of claim 1-4 any one, natural polymer or synthetic polymer that wherein polymer deposition auxiliary agent is modification.
11. according to the composition of claim 10, and wherein the natural polymer of modification is selected from cationic starch, cation guar gum, cationic cellulose and nonionic Viscogum BE.
12. according to the composition of claim 11, and wherein cationic starch is cation-modified yam starch.
13. according to the composition of claim 10, and wherein synthetic polymer is selected from polyethylene oxide, polymine, poly-(acrylate), poly-(acrylamide), polyethylene terephthalate-polyoxyethylene terephthalate polymkeric substance and composition thereof.
14. according to the composition of claim 1, the trolamine quaternary ammonium compound that wherein quaternary ammonium compound is ester-bonding, comprise single-, the mixture of the component of two-and three-ester bonding.
15. process the method for fabric, and it comprises the step with the compositions-treated textile article defining in front claim as any one.
16. preparations are as the method for the composition of claim 1 to 14 any one definition, and it comprises that by the powder efflorescence of plant origin be the step of the granularity of 1 to 45 μ m.
17. provide the purposes of smell benefit for fabric as the composition of claim 1 to 14 any one definition.
18. purposes according to claim 17, wherein said smell benefit is fragrance.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08171732.4 | 2008-12-16 | ||
| EP08171732 | 2008-12-16 | ||
| PCT/EP2009/065893 WO2010069733A1 (en) | 2008-12-16 | 2009-11-26 | Improvements relating to fabric treatment compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102317427A CN102317427A (en) | 2012-01-11 |
| CN102317427B true CN102317427B (en) | 2014-08-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980156838.7A Expired - Fee Related CN102317427B (en) | 2008-12-16 | 2009-11-26 | Improvements relating to fabric treatment compositions |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP2366011B1 (en) |
| CN (1) | CN102317427B (en) |
| AR (1) | AR074747A1 (en) |
| BR (1) | BRPI0922529A2 (en) |
| ES (1) | ES2406058T3 (en) |
| PL (1) | PL2366011T3 (en) |
| WO (1) | WO2010069733A1 (en) |
| ZA (1) | ZA201103931B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5961915B2 (en) * | 2011-03-11 | 2016-08-03 | 高砂香料工業株式会社 | Coffee extract |
| CN104804890A (en) * | 2014-01-25 | 2015-07-29 | 无锡市拓普科技开发中心 | Decontaminating and deoiling agent for fabric dyeing |
| KR101637473B1 (en) * | 2014-02-25 | 2016-07-08 | 주식회사 엘지생활건강 | Fabric softener composition |
| CN104762811B (en) * | 2015-03-26 | 2017-01-25 | 海门市金麒麟红木投资发展有限公司 | Special natural softener for textiles and preparation method for special natural softener |
| WO2017107819A1 (en) * | 2015-12-22 | 2017-06-29 | Rhodia Operations | Compositions comprising quat and polysaccharides |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047336A (en) * | 1989-05-11 | 1990-11-28 | 普罗格特-甘布尔公司 | Used perfume particles in washing and the care composition |
| US5840669A (en) * | 1997-06-20 | 1998-11-24 | Gem Energy Industry Limited | Herbal dry cleaning powder composition |
| CN1643124A (en) * | 2002-01-29 | 2005-07-20 | 荷兰联合利华有限公司 | Detergent compositions |
| CN1667110A (en) * | 2004-03-09 | 2005-09-14 | 王旭 | Plant type environmental protection washing powder |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5898026A (en) * | 1989-09-22 | 1999-04-27 | Colgate Palmolive Company | Liquid crystal compositions |
| DE60137258D1 (en) * | 2000-12-21 | 2009-02-12 | Unilever Nv | CLEANING COMPOSITIONS |
| GB0228354D0 (en) * | 2002-12-05 | 2003-01-08 | Unilever Plc | Detergent compositions |
| GB0514716D0 (en) * | 2005-07-19 | 2005-08-24 | Unilever Plc | Process to form fabric softening particle,particle obtained and its use |
| AU2007263190B2 (en) * | 2006-06-19 | 2010-04-08 | Unilever Plc | Laundry composition |
-
2009
- 2009-11-26 BR BRPI0922529A patent/BRPI0922529A2/en active Search and Examination
- 2009-11-26 WO PCT/EP2009/065893 patent/WO2010069733A1/en active Application Filing
- 2009-11-26 ES ES09756758T patent/ES2406058T3/en active Active
- 2009-11-26 CN CN200980156838.7A patent/CN102317427B/en not_active Expired - Fee Related
- 2009-11-26 PL PL09756758T patent/PL2366011T3/en unknown
- 2009-11-26 EP EP09756758A patent/EP2366011B1/en active Active
- 2009-12-15 AR ARP090104865A patent/AR074747A1/en not_active Application Discontinuation
-
2011
- 2011-05-27 ZA ZA2011/03931A patent/ZA201103931B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047336A (en) * | 1989-05-11 | 1990-11-28 | 普罗格特-甘布尔公司 | Used perfume particles in washing and the care composition |
| US5840669A (en) * | 1997-06-20 | 1998-11-24 | Gem Energy Industry Limited | Herbal dry cleaning powder composition |
| CN1643124A (en) * | 2002-01-29 | 2005-07-20 | 荷兰联合利华有限公司 | Detergent compositions |
| CN1667110A (en) * | 2004-03-09 | 2005-09-14 | 王旭 | Plant type environmental protection washing powder |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102317427A (en) | 2012-01-11 |
| WO2010069733A1 (en) | 2010-06-24 |
| PL2366011T3 (en) | 2013-08-30 |
| BRPI0922529A2 (en) | 2016-08-09 |
| ZA201103931B (en) | 2012-08-29 |
| EP2366011A1 (en) | 2011-09-21 |
| ES2406058T3 (en) | 2013-06-05 |
| AR074747A1 (en) | 2011-02-09 |
| EP2366011B1 (en) | 2013-02-20 |
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