CN102311827A - Pulverized coal and semicoke hybrid coal and preparation method thereof - Google Patents

Pulverized coal and semicoke hybrid coal and preparation method thereof Download PDF

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Publication number
CN102311827A
CN102311827A CN201110192728A CN201110192728A CN102311827A CN 102311827 A CN102311827 A CN 102311827A CN 201110192728 A CN201110192728 A CN 201110192728A CN 201110192728 A CN201110192728 A CN 201110192728A CN 102311827 A CN102311827 A CN 102311827A
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coal
semicoke
mixed type
brown
preparation
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何德民
张秋民
关珺
李云山
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Dalian University of Technology
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Dalian University of Technology
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Abstract

The invention belongs to the technical field of coal chemical industry, and specifically relates to a preparation method of a pulverized coal and semicoke hybrid coal through moulding of coal pyrolysis semicoke. The pulverized coal and semicoke hybrid coal is prepared by mixing, stirring compacting and moulding semicoke and brown coal in a ratio of 0.5-1. According to the invention, the moulding preparation of the pulverized coal and semicoke hybrid coal solves a raise dust problem during individual transportation of semicoke, a problem of incapability of individual brown coal long distance transportation as well as a problem of low calorific value of common molded coal. The pulverized coal and semicoke hybrid coal prepared by mixing and moulding of brown coal and semicoke can be combusted, with a high combustion utilization efficiency and reduced energy waste and environmental pollution.

Description

A kind of coal tar mixed type coal and preparation method thereof
Technical field
The invention belongs to technical field of coal chemical industry, be specifically related to the method that the moulding of coal cracking semicoke prepares the coal tar mixed type coal.
Background technology
Brown coal are produced through the pyrolysis of low temperature brown coal solid heat carrier method in the process of semicoke, coal tar oil and gas, with producing a large amount of product semicokes.
The brown coal of China generally have characteristics such as lower calorific value, high-moisture, high ash content, high volatile, and brown coal easy-weathering spontaneous combustion simultaneously is not suitable for long-distance transport, and the application region scope is very limited.The semicoke calorific value that the brown coal pyrolysis produces improves a lot than former brown coal calorific value, and is broken but the brown coal pyrolytic process can collapse, and produces a large amount of coke breezes, because its granularity is less, ash content is higher, is prone to airborne dust in loading and unloading and the transportation, and long-distance transport utilizes very not convenient.。
Summary of the invention
The objective of the invention is to overcome above-mentioned not enough problem; A kind of coal tar mixed type coal is provided; Adopt the preparation of coal cracking semicoke and coal dust mixing moulding; Not only solve airborne dust problem in the independent transportation of semicoke, but also solved the problem that the independent transportation of brown coal can not be transported at a distance, also solved common moulded coal calorific value problem of lower simultaneously.Another object of the present invention provides a kind of preparation method of coal tar mixed type coal, and technology is simple, and the moulded coal of production has HS and high heating value concurrently.
The present invention realizes that the technical scheme that above-mentioned purpose adopts is: a kind of coal tar mixed type coal is 0.5~1 mixed stirring pressing and moulding by brown coal and semicoke according to the coking coal ratio.
Said semicoke adopts self low temperature brown coal solid heat carrier method pyrolysis char.
The preparation method of a kind of coal tar mixed type coal of the present invention: at first broken, damping to the raw material brown coal, with the brown coal after handling and semicoke according to coking coal than the mixed that is 0.5~1, stir after compression moulding had both obtained the coal tar mixed type coal.
Said fragmentation: the break process process of raw material brown coal, the raw material brown coal are handled particle diameter less than 6mm.
Said damping: the brown coal after the fragmentation are carried out drying treatment, handle to the brown coal moisture content be 10-30%.
Said compacting is meant carries out extrusion forming under the 60-180MPa forming pressure.
Coal tar mixed type coal of the present invention; Prepare the coal tar mixed type coal through moulding and not only solved airborne dust problem in the independent transportation of semicoke, but also solved the problem that the independent transportation of brown coal can not be transported at a distance, also solved common moulded coal calorific value problem of lower simultaneously.The two mixing moulding of brown coal and semicoke prepares reignition utilization behind the coal tar mixed type coal, the utilising efficiency of not only burning height, and reduced the waste of the energy relatively and to the pollution of environment.
Technology of the present invention is reasonable, and simple easy handling is reasonable like particle size after cracking, and wherein briquette molding moisture is the important factor that influences intensity behind the briquette molding, and the moisture of raw coal comprises inherent moisture and free moisture.Moisture is the sticker and the lubricant of moulding, help the sticker that reduces internal friction, serve as the coal intergranular thereby suitable moisture can make the coal intergranular be easy to move, but excess moisture can influence the approaching of coal grain, thereby influence the intensity of moulded coal.So need damping that its moisture is adjusted, Fig. 1 is seen in concrete influence.
The own cohesiveness of semicoke that the pyrolysis of brown coal solid heat carrier method produces is relatively poor, and no matter how molding technological condition changes, and all can't embark on journey separately.Brown coal self moulding separately descends with addition of the semicoke rear formability to some extent.Semicoke content is very crucial to the influence of coal and semicoke mixing moulding effect thereof, and moisture makes semicoke can carry out mixing moulding as sticker in brown coal wherein and the brown coal, and shaping strength is as shown in Figure 2 with the semicoke content in the mixing moulding.
Said compacting is meant the compaction curve analysis of basis to the coal tar mixed type coal of raw materials used coal, chooses and carries out extrusion forming under the better suited forming pressure.The present invention has realized energy-conservation, the consumption reduction and the target of cleaningization of production process indirectly.
Description of drawings:
Fig. 1 is that shaping strength of the present invention is with moisture content change figure.
Fig. 2 is that shaping strength of the present invention is with semicoke content figure.
Embodiment:
Further narrate coal tar mixed type coal provided by the invention and preparation method thereof below in conjunction with embodiment.
Embodiment 1-2
After brown coal process tramp iron separator deironing earlier; Send into four toothed roll crushers (also can be other type disintegrating apparatus or combination) that have counterpunch board it is carried out fragmentation; Be crushed to less than 6mm, ball milling (also can be equipment or the combination that other types are regulated granularity) is regulated granularity.Broken typical size-grade distribution such as table 1,
Size-grade distribution after certain brown coal of table 1 are pulverized
Figure DEST_PATH_655416DEST_PATH_IMAGE001
Brown coal particle after the fragmentation adopts about the dry adjusting of rotating drum dryer (also can be other type drying plant or combination) brown coal moisture to 20%.Adopt the solid heat carrier method pyrolysis installation to prepare the low temperature pyrogenation semicoke.Brown coal after the damping are mixed by certain mass ratio with semicoke; The pressure pressed that goes up at 60-180MPa at four-column type oil pressure pressing machine (also can be other type molding device) becomes the coal tar mixed type coal, and specification is the cylinder (also can be other specification mixed type coal) of the high 20-30mm of diameter 50mm.
Coal tar mixed type coal dropping strength that obtains and cold pressing strength and preparation condition parameter thereof are seen table 2.
Table 2 coal tar mixed type coal dropping strength and cold pressing strength and preparation condition parameter list thereof
Title Semicoke content/% Moisture content/% Forming pressure/MPa Dropping strength/% Cold pressing strength/MPa
Instance 1 coal tar mixed type coal 20 20 110 79.79 11.25
Instance 2 coal tar mixed type coals 20 25 140 42.88 10.06
Embodiment 3-8
Under embodiment 1 processing condition identical with 2, adopt different semicoke additions (10%-40%) preparations coal tar mixed type coal, its concrete semicoke addition and the dropping strength and the cold pressing strength that make the coal tar mixed type coal are seen table 3.
Table 3 coal tar mixed type coal dropping strength and cold pressing strength and semicoke thereof add scale
Title Semicoke content Dropping strength Cold pressing strength
Instance
3 coal tar mixed type coals 10 80.81 13.44
Instance 4 coal tar mixed type coals 20 73.89 12.11
Instance 5 coal tar mixed type coals 20 79.79 11.25
Instance 6 coal tar mixed type coals 30 46.25 8.1
Instance 7 coal tar mixed type coals 40 18.58 5.25
Instance 8 coal tar mixed type coals 50 0 3.0

Claims (6)

1. coal tar mixed type coal, it is characterized in that: it is 0.5~1 mixed stirring pressing and moulding by brown coal and semicoke according to the coking coal ratio.
2. a kind of coal tar mixed type coal according to claim 1 is characterized in that: said semicoke adopts self low temperature brown coal solid heat carrier method pyrolysis char.
3. the preparation method of a coal tar mixed type coal is characterized in that: at first broken, damping to the raw material brown coal, with the brown coal after handling and semicoke according to coking coal than the mixed that is 0.5~1, stir after compression moulding had both obtained the coal tar mixed type coal.
4. the preparation method of a kind of coal tar mixed type coal according to claim 3 is characterized in that: said fragmentation: the break process process of raw material brown coal, the raw material brown coal are handled particle diameter less than 6mm.
5. the preparation method of a kind of coal tar mixed type coal according to claim 3 is characterized in that: said damping: the brown coal after the fragmentation are carried out drying treatment, handle to the brown coal moisture content be 10-30%.
6. the preparation method of a kind of coal tar mixed type coal according to claim 3 is characterized in that: said compacting is meant carries out extrusion forming under the 60-180MPa forming pressure.
CN201110192728A 2011-07-11 2011-07-11 Pulverized coal and semicoke hybrid coal and preparation method thereof Pending CN102311827A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753650A (en) * 2016-12-21 2017-05-31 北京神雾环境能源科技集团股份有限公司 A kind of preparation method of formed coke
CN106947564A (en) * 2017-03-23 2017-07-14 宁夏中润工贸有限公司 A kind of clean type coal and its production method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1903717A (en) * 2006-08-01 2007-01-31 长春惠工净化工业有限公司 Production method of desulfur denitrate dust collecting active coke
CN101070498A (en) * 2006-05-09 2007-11-14 梁刚 Method for preparing shaped-coal using coal or charcoal as raw material and adding additives
RU2376342C1 (en) * 2008-07-09 2009-12-20 Сергей Романович Исламов Briquetting method of semi-coke
CN101709880A (en) * 2009-11-10 2010-05-19 中国五环工程有限公司 Combustion power generating process of lignite processing and upgrading long-distance transportation power plant boiler

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070498A (en) * 2006-05-09 2007-11-14 梁刚 Method for preparing shaped-coal using coal or charcoal as raw material and adding additives
CN1903717A (en) * 2006-08-01 2007-01-31 长春惠工净化工业有限公司 Production method of desulfur denitrate dust collecting active coke
RU2376342C1 (en) * 2008-07-09 2009-12-20 Сергей Романович Исламов Briquetting method of semi-coke
CN101709880A (en) * 2009-11-10 2010-05-19 中国五环工程有限公司 Combustion power generating process of lignite processing and upgrading long-distance transportation power plant boiler

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753650A (en) * 2016-12-21 2017-05-31 北京神雾环境能源科技集团股份有限公司 A kind of preparation method of formed coke
CN106947564A (en) * 2017-03-23 2017-07-14 宁夏中润工贸有限公司 A kind of clean type coal and its production method

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Application publication date: 20120111