CN102306826B - Impact resistant and vibration resistant lithium/thionyl chloride battery - Google Patents
Impact resistant and vibration resistant lithium/thionyl chloride battery Download PDFInfo
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- CN102306826B CN102306826B CN2011102357397A CN201110235739A CN102306826B CN 102306826 B CN102306826 B CN 102306826B CN 2011102357397 A CN2011102357397 A CN 2011102357397A CN 201110235739 A CN201110235739 A CN 201110235739A CN 102306826 B CN102306826 B CN 102306826B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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Abstract
The invention relates to an impact resistant and vibration resistant lithium/thionyl chloride battery. The battery comprises a housing. The following components are orderly arranged in the housing, from bottom to top: a bottom insulating sheet, a battery core, an upper insulating sheet, a top insulating sheet, and a metal-glass top cap. Electrolyte is filled in the battery core. The battery core is in a structure of rolled layers. The battery core comprises orderly arranged components of: a separating membrane, a cathode sheet, another separating membrane, and an anode sheet. The metal-glass top cap is provided with a central column in the center. A cathode lead is connected with the central column. An arc transition is arranged on the edge of the lower surface of the metal-glass top cap. Anode leads are clamped and welded between the metal-glass top cap and the housing. There are at least two anode leads. The anode leads are annularly and uniformly distributed along the inner wall of the battery housing. The battery is suitable to be applied in oil exploitation and geological exploration engineering. The battery resists environmental probations of high temperatures, and impacts and vibrations of drilling bits and drill pipes. With the battery, the battery core is prevented from loosening.
Description
Technical field
The present invention relates to field of batteries, be meant a kind of lithium/thinly chloride (Li/SOCl especially
2) battery.
Background technology
Lithium/thinly chloride (Li/SOCl
2) battery be a kind of be anode with the lithium, carbon is made cathode carrier, the thionyl chloride (SOCl of anhydrous tetrachloro-lithium aluminate
2) solution makes the lithium battery of electrolyte.Lithium/thinly chloride battery has characteristics such as specific energy height, specific power are big, discharging voltage balance, temperature applicable range is wide, storage life is long, in military and civilian industry such as Aero-Space, underawater ordnance, navigator, geological prospecting, instrument and meter, all is widely used.Lithium/thinly chloride battery is specific energy and the highest a kind of battery of specific power in the current battery field.
Above excellent specific property is arranged just, and in recent years, lithium/thinly chloride battery is used widely in oil exploitation, geological prospecting.In oil exploitation, geological prospecting engineering; Need be to intending exploitation or the enforcement boring of prospecting zone; On the one hand the track in this length of creeping into is measured, on the other hand the environmental aspect in this length of creeping into is measured, to gather and to write down various floor datas.And serve as the power of gathering and writing down various floor datas, be lithium/thinly chloride battery.
Lithium/thinly chloride battery is underground along with the underground survey appearance progressively gets under drill bit, drilling rod drive, and not only will bear increasingly high temperature test, impact and the vibrations that also will bear drill bit, drilling rod simultaneously.According to the relevant criterion requirement, want to bear the environmental test of-40 ℃ ~ 175 ℃ of temperature with the battery tube that brill is gone into the well, can also bear vibration acceleration 196m/s simultaneously
2(swept frequency range 20Hz ~ 200Hz, sweep speed is 1oct/min), impact acceleration 455m/s
2, the harsh operating mode test of semisinusoidal waveform 11ms.
At present, domesticly be used for the battery tube that the While-drilling down-hole measurement appearance is gone into the well, use the improved slightly lithium/thinly chloride battery of domestic production mostly.The structure of existing lithium/thinly chloride battery is: comprise a housing, the inside of housing is placed with bottom insulation sheet, battery core body, top insulating trip and metal-glass from bottom to up successively and seals up lid, is perfused with electrolyte in the battery core body; The battery core body is a multilayer web-like structure; Comprise barrier film, negative electrode pole piece, barrier film and anode pole piece successively, barrier film is non-woven glass fiber, and the negative electrode pole piece is that carbon and polytetrafluoroethylene binding agent and nickel draw in the net to close film; Anode pole piece is that lithium and nickel draw in the net to close film; The bottom that metal-glass is sealed up lid is placed with the top insulating trip, and the center that metal-glass is sealed up lid is provided with newel, and a cathode tab directly is welded on the newel; An anode lug is welded on the inwall of housing, or folder is welded in metal-glass and seals up in lid and the crack of housing.
The lithium/thinly chloride battery of existing structure, not only resistance to elevated temperatures is difficult to satisfy the environmental test of down-hole higher temperature, and its immanent structure also is difficult to satisfy the harsh operating mode test of underground vibrating, impact.This is because at first, the play that is difficult to satisfy the battery core body as the cathode tab of monopole ear is split vibrations, impact and might sealing-off or fracture; Split vibrations in the play of battery core body, impact and the ability sealing-off is also arranged down or fracture as the anode lug of monopole ear; Secondly; An anode lug is welded on the battery container inwall; Also possibly there is rosin joint in not only operation inconvenience, and anode lug folder is welded in metal-glass and seals up the production technology in the crack of lid and housing; Can cause metal-glass to seal up the decentraction of lid and housing again, the consistency of girth welding is reduced; The 3rd; Because metal-glass is sealed up lid and is generally cylindrical structure, the anode lug is being clipped in metal-glass when sealing up in the crack of lid and housing, it is tangent that metal-glass is sealed up the edge, lower surface and the battery container port of lid; Easily the anode lug is cut off, thereby cause rosin joint.
In addition; Some battery production enterprises are in order to overcome the influence of down-hole higher temperature to battery; Adopt the addition that reduces inside battery active material and barrier film; To increase the redundant space of inside battery, slow down electrolyte and under hot environment, decomposes, gasify and the swelling that causes battery, strengthened the possibility that the battery core body becomes flexible again.
The lithium/thinly chloride battery of existing structure; When the addition that reduces inside battery active material and barrier film; Certainly lead to the loosening of battery core body; And single cathode tab and single anode ear and welding manner thereof can't suppress the loosening of battery core body again, and the loosening security performance harm to the performance of battery, especially battery of this battery core body is bigger.Becoming flexible of battery core body can't be satisfied underground vibrating, impacted the requirement to battery, and the lighter causes inside battery to open circuit, and weight person causes internal short-circuit of battery, even causes the battery explosion.These all possibly cause drillng operation to interrupt and compelled the trip-out, and tight amount influences the economic benefit of oil exploitation, geological prospecting job scheduling and wellbore construction troop.
Summary of the invention
Technical problem to be solved by this invention is: a kind of temperature test that can not only bear-40 ℃ ~ 175 ℃ is provided, and impact and the vibrations that can also bear drill bit, drilling rod simultaneously suppress the lithium/thinly chloride battery that loosening shock-resistant, vibration appears in the battery core body.
For addressing the above problem, the technical scheme that the present invention adopts is: a kind of lithium/thinly chloride battery of shock-resistant, vibration comprises a housing; The inside of housing is disposed with bottom insulation sheet, battery core body, top insulating trip, top insulating trip and metal-glass from bottom to up and seals up lid, is perfused with electrolyte in the battery core body, and the battery core body is a layer web-like structure; Comprise barrier film, negative electrode pole piece, barrier film and anode pole piece successively; Barrier film is non-woven glass fiber, and the negative electrode pole piece is that carbon and polytetrafluoroethylene binding agent and nickel draw in the net to close film, and anode pole piece is that lithium and nickel draw in the net to close film; The center that metal-glass is sealed up lid is provided with newel; Cathode tab is connected with newel, and the lower surface edge that said metal-glass is sealed up lid is provided with arc transition, and anode lug folder is welded in metal-glass and seals up between lid and the housing; Described anode lug is provided with two at least, and the anode lug evenly distributes along wall circular in the battery container.
Described anode pole piece is provided with 2 ~ 6 anode lugs.
The invention has the beneficial effects as follows: the lithium/thinly chloride battery of above-mentioned a kind of shock-resistant, vibration; Adopt the multianode lug; Can not only strengthen metal-glass and seal up lid and housing concentricity, thereby the quality of girth welding is effectively improved, increase the input and output rate of battery; The more important thing is; Can battery core body and battery container closely be fused; Controlled the loosening of battery core body, protected inside battery cathode tab and anode lug to avoid damage effectively, stopped battery and taken place because of the phenomenon that the down-hole is impacted, vibration causes internal break, internal short-circuit; Effectively guarantee the progress of oil exploitation, geological prospecting operation, promoted the economic benefit of wellbore construction troop greatly.
Description of drawings
Fig. 1 is the structural representation of lithium/thinly chloride battery of a kind of shock-resistant, vibration of the present invention;
Fig. 2 is the sectional structure sketch map of A-A direction among Fig. 1;
Fig. 3 is the sectional structure sketch map of A-A direction among Fig. 1 of the another kind of embodiment of the present invention;
Fig. 4 is the sectional structure sketch map of A-A direction among Fig. 1 of the another kind of embodiment of the present invention;
Fig. 5 is the structure for amplifying sketch map of B portion among Fig. 1;
Fig. 6 is the structural representation of collector;
Among the figure: 1, housing, 2, the bottom insulation sheet, 3, the battery core body, 31, barrier film, 32, the negative electrode pole piece; 33, anode pole piece, 4, the top insulating trip, 5, metal-glass seals up lid, 51, arc transition; 6, electrolyte, 7, the top insulating trip, 8, vitreum, 9, newel; 10, cavity, 11, the anode lug, 12, collector, 121, the metal currect collecting net.
Embodiment
Through specific embodiment a kind of lithium/thinly chloride battery shock-resistant, vibration of the present invention is done further to describe in detail below.
As shown in Figure 1, a kind of shock-resistant, the vibration lithium/thinly chloride battery, comprise a housing 1; The inside of housing 1 is disposed with bottom insulation sheet 2, battery core body 3, top insulating trip 4 and metal-glass from bottom to up and seals up and cover 5, is provided with electrolyte 6 in the battery core body 3, and battery core body 3 is a multilayer web-like structure; Comprise barrier film 31, negative electrode pole piece 32 and anode pole piece 33; Described barrier film 31 is non-woven glass fiber, and negative electrode pole piece 32 draws in the net to close film for carbon and polytetrafluoroethylene binding agent and nickel, and anode pole piece 33 draws in the net to close film for lithium and nickel; Metal-glass is sealed up and is covered 5 bottom and be provided with top insulating trip 7; Metal-glass is sealed up and is covered 5 center and be provided with newel 9 through vitreum 8, and cathode tab is connected with newel 9, like Fig. 2, shown in Figure 5; 4 anode lugs 11 are set in the described anode pole piece 33; Anode lug 11 evenly distributes along wall circular in the battery container 1, and said metal-glass is sealed up and cover 5 lower surface edge and be provided with arc transition 51, and the upper end of anode lug 11 presss from both sides and is welded in metal-glass and seals up and cover between 5 sidewalls and the housing 1.
The anode layer 33 of the lithium/thinly chloride battery of above-mentioned shock-resistant, vibration is when making; At first make collector 12 with 4 anode lugs 11; As shown in Figure 6; Collector 12 comprises metal currect collecting net 121 and anode lug 11, and metal currect collecting net 121 can be that nickel draws in the net or stainless steel draws in the net, also can be nickel punching net or stainless steel punching net; Anode lug 11 can be the nickel lug, also can be the stainless steel lug.Then lithium paper tinsel and collector 12 are rolled into one, become anode pole piece 33, but single face roll extrusion lithium paper tinsel, also can two-sided roll extrusion lithium paper tinsel.When fixed anode lug 11; With anode lug 11 include in metal-glass seal up cover 5 and housing 1 between; Implement press seal and crack boxing; Make to be connected more closely firmly between anode lug 11 and the housing 1, wherein metal-glass is sealed up and is covered the arc transition 51 that 5 lower surface edge is provided with, thereby can prevent that metal-glass from sealing up cover 5 edge, lower surface with 11 cut-outs of anode lug.
As shown in Figure 1, a kind of shock-resistant, the vibration lithium/thinly chloride battery, comprise a housing 1; The inside of housing 1 is disposed with bottom insulation sheet 2, battery core body 3, top insulating trip 4 and metal-glass from bottom to up and seals up and cover 5, is provided with electrolyte 6 in the battery core body 3, and battery core body 3 is a multilayer web-like structure; Comprise barrier film 31, negative electrode pole piece 32 and anode pole piece 33; Described barrier film 31 is non-woven glass fiber, and negative electrode pole piece 32 draws in the net to close film for carbon and polytetrafluoroethylene binding agent and nickel, and anode pole piece 33 draws in the net to close film for lithium and nickel; Metal-glass is sealed up and is covered 5 bottom and be provided with top insulating trip 7; Metal-glass is sealed up and is covered 5 center and be provided with newel 9 through vitreum 8, and cathode tab is connected with newel 9, like Fig. 3, shown in Figure 5; 2 anode lugs 11 are set in the described anode layer 33; Anode lug 11 evenly distributes along wall circular in the battery container 1, and said metal-glass is sealed up and cover 5 lower surface edge and be provided with arc transition 51, and the upper end of anode lug 11 presss from both sides and is welded in metal-glass and seals up and cover between 5 sidewalls and the housing 1.
The anode layer 33 of the lithium/thinly chloride battery of above-mentioned shock-resistant, vibration is when making; At first make collector 12 with 2 anode lugs 11; As shown in Figure 6; Collector 12 comprises metal currect collecting net 121 and anode lug 11, and metal currect collecting net 121 can be that nickel draws in the net or stainless steel draws in the net, also can be nickel punching net or stainless steel punching net; Anode lug 11 can be the nickel lug, also can be the stainless steel lug.Then lithium paper tinsel and collector 12 are rolled into one, become anode layer 33, but single face roll extrusion lithium paper tinsel, also can two-sided roll extrusion lithium paper tinsel.When fixed anode lug 11; Anode lug 11 is included between loam cake 5 and the housing 1; Implement press seal and crack boxing; Make to be connected more closely firmly between anode lug 11 and the housing 1, wherein metal-glass is sealed up and is covered the arc transition 51 that 5 lower surface edge is provided with, thereby can prevent that metal-glass from sealing up cover 5 edge, lower surface with 11 cut-outs of anode lug.
As shown in Figure 1, a kind of shock-resistant, the vibration lithium/thinly chloride battery, comprise a housing 1; The inside of housing 1 is disposed with bottom insulation sheet 2, battery core body 3, top insulating trip 4 and metal-glass from bottom to up and seals up and cover 5, is provided with electrolyte 6 in the battery core body 3, and battery core body 3 is a multilayer web-like structure; Comprise barrier film 31, negative electrode pole piece 32 and anode pole piece 33; Described barrier film 31 is non-woven glass fiber, and negative electrode pole piece 32 draws in the net to close film for carbon and polytetrafluoroethylene binding agent and nickel, and anode pole piece 33 draws in the net to close film for lithium and nickel; Metal-glass is sealed up and is covered 5 bottom and be provided with top insulating trip 7; Metal-glass is sealed up and is covered 5 center and be provided with newel 9 through vitreum 8, and cathode tab is connected with newel 9, like Fig. 4, shown in Figure 5; 6 anode lugs 11 are set in the described anode pole piece 33; Anode lug 11 evenly distributes along wall circular in the battery container 1, and said metal-glass is sealed up and cover 5 lower surface edge and be provided with arc transition 51, and the upper end of anode lug 11 presss from both sides and is welded between loam cake 5 sidewalls and the housing 1.
The anode pole piece 33 of the lithium/thinly chloride battery of above-mentioned shock-resistant, vibration is when making; At first make collector 12 with 6 anode lugs 11; As shown in Figure 6; Collector 12 comprises metal currect collecting net 121 and anode lug 11, and metal currect collecting net 121 can be that nickel draws in the net or stainless steel draws in the net, also can be nickel punching net or stainless steel punching net; Anode lug 11 can be the nickel lug, also can be the stainless steel lug.Then lithium paper tinsel and collector 12 are rolled into one, become anode pole piece 33, but single face roll extrusion lithium paper tinsel, also can two-sided roll extrusion lithium paper tinsel.When fixed anode lug 11; With anode lug 11 include in metal-glass seal up cover 5 and housing 1 between; Implement press seal and crack boxing; Make to be connected more closely firmly between anode lug 11 and the housing 1, wherein metal-glass is sealed up and is covered the arc transition 51 that 5 lower surface edge is provided with, thereby can prevent that metal-glass from sealing up cover 5 edge, lower surface with 11 cut-outs of anode lug.
In conjunction with the foregoing description, the invention has the beneficial effects as follows: above-mentioned a kind of vibration resistance, the lithium/thinly chloride battery of impact, adopt the multianode lug; The quality of girth welding is effectively improved, increased the input and output rate of battery, the more important thing is; Can battery core body and battery container closely be fused; Controlled the loosening of battery core body, protected inside battery cathode tab and anode lug to avoid damage effectively, stopped battery and taken place because of underground vibrating, impact cause the phenomenon of internal break, internal short-circuit; Effectively guarantee the progress of oil exploitation, geological prospecting operation, promoted the economic benefit of wellbore construction troop greatly.
The above embodiments are the principle and the effect thereof of illustrative the invention only, and the embodiment of part utilization, but not is used to limit the present invention; Should be pointed out that for the person of ordinary skill of the art under the prerequisite that does not break away from the invention design, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Claims (2)
1. shock-resistant, as a to vibrate lithium/thinly chloride battery comprises a housing, and the inside of housing is disposed with bottom insulation sheet, battery core body, top insulating trip, top insulating trip and metal-glass from bottom to up and seals up lid; Be perfused with electrolyte in the battery core body; The battery core body is a layer web-like structure, comprises barrier film, negative electrode pole piece, barrier film and anode pole piece successively, and barrier film is non-woven glass fiber; The negative electrode pole piece is that carbon and polytetrafluoroethylene binding agent and nickel draw in the net to close film; Anode pole piece is that lithium and nickel draw in the net to close film, and the center that metal-glass is sealed up lid is provided with newel, and cathode tab is connected with newel; It is characterized in that: the lower surface edge that said metal-glass is sealed up lid is provided with arc transition; Anode lug folder is welded in metal-glass and seals up between lid and the housing, and described anode lug is provided with two at least, and the anode lug evenly distributes along wall circular in the battery container.
2. according to claim 1 a kind of shock-resistant, the vibration lithium/thinly chloride battery, it is characterized in that: described anode pole piece is provided with 2 ~ 6 anode lugs.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102357397A CN102306826B (en) | 2011-08-17 | 2011-08-17 | Impact resistant and vibration resistant lithium/thionyl chloride battery |
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| CN2011102357397A CN102306826B (en) | 2011-08-17 | 2011-08-17 | Impact resistant and vibration resistant lithium/thionyl chloride battery |
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| CN102306826B true CN102306826B (en) | 2012-11-21 |
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| CN103236516A (en) * | 2013-04-03 | 2013-08-07 | 河南迈奇能源技术有限公司 | Preparation method for high temperature battery positive electrode |
| CN110323461B (en) * | 2019-06-20 | 2024-08-27 | 武汉孚安特科技有限公司 | High-capacity lithium thionyl chloride energy type battery and preparation method thereof |
| CN218695333U (en) * | 2022-11-16 | 2023-03-24 | 宁德时代新能源科技股份有限公司 | Pressing plate structure and welding machine |
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| US4565753A (en) * | 1985-04-03 | 1986-01-21 | Gte Government Systems Corporation | Electrochemical cell having wound electrode structures |
| JPH1064551A (en) * | 1996-08-22 | 1998-03-06 | Toshiba Battery Co Ltd | Inorganic nonaqueous solvent battery |
| CN201146203Y (en) * | 2008-01-09 | 2008-11-05 | 比亚迪股份有限公司 | Battery cover plate and battery |
| CN201812885U (en) * | 2009-10-20 | 2011-04-27 | 梅岭化工厂 | Annular lithium thionyl chloride battery structure |
| CN202205851U (en) * | 2011-08-17 | 2012-04-25 | 苏州金科发锂电池有限公司 | Impact and vibration resistant lithium/thionyl chloride battery |
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Address after: Suzhou City, Jiangsu province 215618 city of Zhangjiagang Tang town yangshe road Suzhou Jinke Energy Technology Co Ltd Patentee after: Suzhou Jinke Energy Technology Co., Ltd. Address before: Suzhou City, Jiangsu province 215618 city of Zhangjiagang Tang town yangshe road Suzhou Jinke hair lithium battery Patentee before: Suzhou Jinkefa Lithium Battery Co., Ltd. |