CN102303216A - Method for producing copper-clad aluminum bar - Google Patents

Method for producing copper-clad aluminum bar Download PDF

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Publication number
CN102303216A
CN102303216A CN201110250139A CN201110250139A CN102303216A CN 102303216 A CN102303216 A CN 102303216A CN 201110250139 A CN201110250139 A CN 201110250139A CN 201110250139 A CN201110250139 A CN 201110250139A CN 102303216 A CN102303216 A CN 102303216A
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copper
clad aluminum
aluminum bar
rolling
welding
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CN201110250139A
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CN102303216B (en
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孙华侨
刘绍异
杨国栋
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Sun Huaqiao
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Priority to CN201410585316.1A priority Critical patent/CN104439923B/en
Priority to CN201410585375.9A priority patent/CN104384857B/en
Priority to CN201110250139.8A priority patent/CN102303216B/en
Priority to CN201410585374.4A priority patent/CN104353966B/en
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Abstract

The invention relates to a method for producing a copper-clad aluminum bar. The method comprises the following steps of: removing oxidation layers from the surfaces of a copper belt and an aluminum bar; feeding the copper belt and the aluminum bar into a cladding machine for molding and welding; rolling and tightening by using a cold-rolling mill; saw-cutting according to a required size, and continuously feeding copper-clad aluminum bar materials which are cut off into an intermediate-frequency heating furnace for pre-heating; feeding the copper-clad aluminum bar materials into a continuous heating furnace; operating the copper-clad aluminum bar materials through a roller bed and then feeding the copper-clad aluminum bar materials into a hot-rolling mill for finish rolling and cooling; drawing and setting the rolled copper-clad aluminum bar materials, and performing fixed-length saw-cutting according to a process; putting the copper-clad aluminum bar materials which are subjected to the fixed-length cutting into a vacuum annealing furnace, performing bright annealing, and thus obtaining a finished product; and putting the finished product on an automatic packaging line, packaging the finished product and then warehousing. By coating a copper layer outside an aluminum core, the method for producing the copper-clad aluminum bar has the advantages of low cost, continuous production, short process flow, high production efficiency, mechanical operation and high bonding strength of interfaces; and requirements of electric equipment can be met.

Description

The production method of copper clad aluminum wire
Technical field
The present invention relates to a kind of production method of copper clad aluminum wire.
Background technology
Copper clad aluminum wire be a kind of be matrix with aluminium, the outer copper that coats makes the bimetallic that forms metallurgical binding between permanent atom between them, surface-brightening, rounding, zero defect.It is the energy cheaply of the high-quality of copper being stablized electric conductivity and aluminium, with lower contact resistance, and the novel conductor material that is combined as a whole.Instead of pure copper bar comprehensively; The weight ratio of copper clad aluminum wire is: copper accounts for 40%; Aluminium accounts for 60%; It under the same size situation fine copper row's 2-2.5 double-length; Current-carrying capacity is fine copper row's 90.7%; Sectional area increase about 10% can reach identical current-carrying capacity with fine copper fully during selection, and its mechanical property and electrical property all can satisfy requirement of client.Copper clad aluminum wire advantage: 1, good electrical conductivity: copper aluminium volume ratio is 15% or 20% copper clad aluminum wire electrical property, and compare it to exchange current-carrying capacity be 90.7% of fine copper with copper bar.2, in light weight: the density of copper clad aluminum wire only is fine copper row's 37%-40%, and the length of equivalent weight (volume) is 2-2.5 times of fine copper row.3, good mechanical performance: have good tensile strength, flexible and percentage elongation.4, combine between firm copper aluminium: in various environment temperatures, reach nonvolatil atom intergranular between two kinds of different metal materials and combine, and copper layer (zinc-plated, zinc layer) is evenly distributed, do not have any physical imperfection.5, good ductility and reliability: through special Technology for Heating Processing, have certain plasticity, help punching, shearing, bending machining product and do not ftracture, do not separate.
What the external compound row's product of production of copper aluminium generally adopted is quiet liquid extrusion technique; It is that copper and aluminium are processed composite blank, utilizes high hydrostatic pressure and processes the solid phase combination between deformation rate effect realization copper, the aluminium greatly, and distortion evenly; But can not produce continuously, production efficiency is lower.The technology of domestic employing is airtight casting, and cost is high, and loss is big, and technological requirement is complicated, and manufacturing cost is high, unsuitable production in enormous quantities the in enormous quantities, can not really accomplish energy-conserving and environment-protective.
The weak point of above-mentioned copper clad aluminum wire of the prior art is: existing manufacturing technique, and metallurgical binding is relatively poor between aluminium, the copper, causes contact resistance to strengthen; Resistance of deformation and plasticity are relatively poor, and resistivity is higher, and the mechanical performance of workpiece often can not be satisfied the demand, and how to address these problems, and are the technical barriers of this area.
Summary of the invention
The technical problem that the present invention will solve provides that a kind of step is simple, metallurgical binding better, resistivity is lower and plasticity and the toughness production method of copper clad aluminum wire preferably.
For solving the problems of the technologies described above, the production method of copper clad aluminum wire provided by the invention comprises the steps:
A, copper strips, aluminium row is carried out surperficial deoxidation layer handle;
B, then goes into coating machine moulding welding with copper strips, aluminium dispatch, tightens up with cold-rolling mill is rolling then, then according to the required size sawing;
C, the good copper cover aluminum discharge that will break are sent into continuously and are preheated 60-150 second in the heating in medium frequency stove, make its temperature adjust to 300-600 ℃;
D, then the copper cover aluminum discharge is sent into continuous furnace, heating-up temperature is 300-620 ℃, and be 90 minutes-120 minutes heat time heating time;
E, then the copper cover aluminum discharge is sent into hot-rolling mill finish rolling, cooling through roller-way operation;
F, rolling good copper cover aluminum discharge carried out drawing typing after, according to the sawing of technology scale;
After G, the copper cover aluminum discharge that scale is good are put into vacuum annealing furnace and carried out bright annealing, obtain finished product, annealing temperature is 400-600 ℃, and annealing time is 6-12 hour;
H, finished product is put on the automatic packaging line packing warehouse-in.
Particularly, the mill speed of said hot-rolling mill is the 80-100 meter per second, and rolling temperature is 280-640 ℃.
Further, the welding manner that said coating machine moulding welding is adopted is: continuously from the fusion welding copper clad aluminum wire, speed of welding is greater than 15 meters/minute from fusing soldering welder for employing high frequency argon arc.
The technique effect that the present invention has: the production method of copper clad aluminum wire of the present invention is that the aluminium core coats the copper layer outward; Cost is low, can produce continuously, and technological process is short, production efficiency is high, all adopt mechanized operation; Interface bond strength is high, can satisfy the requirement of electrical equipment fully.
The specific embodiment
Below in conjunction with accompanying drawing and embodiment the present invention is elaborated:
The production method of the copper clad aluminum wire of present embodiment comprises the steps:
A, employing clad material processor carry out surperficial deoxidation layer with copper strips, aluminium row to be handled;
B, then goes into coating machine moulding welding with copper strips, aluminium dispatch, tightens up with cold-rolling mill is rolling then, then according to the required size sawing;
C, the good copper cover aluminum discharge that will break are sent into continuously and are preheated 60-150 second in the heating in medium frequency stove, make its temperature adjust to 300-600 ℃; Adopt intermediate frequency furnace to preheat, be suitable for making copper top layer and aluminum surface layer in transient heating, the top layer moment thawing of two kinds of alloying metals reaches metallurgical binding truly.
D, then the copper cover aluminum discharge is sent into continuous furnace, heating-up temperature is 300-620 ℃, and be 90 minutes-120 minutes heat time heating time; Adopt continuous furnace to make the purpose of copper cover aluminum discharge thermal change be: to reduce the distortion of materials drag, improve plasticity, be beneficial to the shaping in the operation of rolling, improve stability in the operation of rolling.
E, then the copper cover aluminum discharge is sent into hot-rolling mill finish rolling, cooling through roller-way operation; Rolling is the roll that metal material is placed two reverse rotations, makes it to obtain compression, also is to be higher than to make metal material produce plastic deformation and crystallization more simultaneously under the recrystallization temperature condition.The rolling product that can make improves its tissue when being shaped, thereby obtains our needed size and dimension, makes the product of shaping change crystalline state to improve the mechanical performance of workpiece.
F, rolling good copper cover aluminum discharge carried out drawing typing after, according to the sawing of technology scale; The mill speed of said hot-rolling mill is the 80-100 meter per second, and rolling temperature is 280-640 ℃.
After G, the copper cover aluminum discharge that scale is good are put into vacuum annealing furnace and carried out bright annealing, obtain finished product, annealing temperature is 400-600 ℃, and annealing time is 6-12 hour; Annealing is that the product workpiece is placed in certain material frame, is heated to preset temperature according to the Different products specification, and after in this temperature, keeping certain hour, naturally cools to normal temperature.This annealing steps is suitable for improving plasticity and toughness, makes the chemical composition homogenising, removes residual stress, the physical property that obtains expecting; Also be suitable for reducing resistivity, strengthen the conductance of copper clad aluminum wire.In addition, annealing also is suitable for eliminating the slight oxidation of copper clad aluminum wire in production process, improves the surface quality of copper clad aluminum wire.
H, finished product is put on the automatic packaging line packing warehouse-in.
The welding manner that said coating machine moulding welding is adopted is: continuously from the fusion welding copper clad aluminum wire, speed of welding is greater than 15 meters/minute from fusing soldering welder for employing high frequency argon arc.
Obviously, the foregoing description only be for clearly the present invention is described and is done for example, and be not to be qualification to embodiment of the present invention.For the those of ordinary skill in affiliated field, on the basis of above-mentioned explanation, can also make other multi-form variation or change.Here need not also can't give exhaustive to all embodiments.And these belong to conspicuous variation or the change that spirit of the present invention extended out and still are among protection scope of the present invention.

Claims (3)

1. the production method of a copper clad aluminum wire is characterized in that comprising the steps:
A, copper strips, aluminium row is carried out surperficial deoxidation layer handle;
B, then goes into coating machine moulding welding with copper strips, aluminium dispatch, tightens up with cold-rolling mill is rolling then, then according to the required size sawing;
C, the good copper cover aluminum discharge that will break are sent into continuously and are preheated 60-150 second in the heating in medium frequency stove, make its temperature adjust to 300-600 ℃;
D, then the copper cover aluminum discharge is sent into continuous furnace, heating-up temperature is 300-620 ℃, and be 90 minutes-120 minutes heat time heating time;
E, then the copper cover aluminum discharge is sent into hot-rolling mill finish rolling, cooling through roller-way operation;
F, rolling good copper cover aluminum discharge carried out drawing typing after, according to the sawing of technology scale;
After G, the copper cover aluminum discharge that scale is good are put into vacuum annealing furnace and carried out bright annealing, obtain finished product, annealing temperature is 400-600 ℃, and annealing time is 6-12 hour;
H, finished product is put on the automatic packaging line packing warehouse-in.
2. the production method of copper clad aluminum wire according to claim 1, it is characterized in that: the mill speed of said hot-rolling mill is the 80-100 meter per second, rolling temperature is 280-640 ℃.
3. the production method of copper clad aluminum wire according to claim 2 is characterized in that: the welding manner that said coating machine moulding welding is adopted is: adopt the high frequency argon arc from fusing soldering welder continuously from the fusion welding copper clad aluminum wire, speed of welding is greater than 15 meters/minute.
CN201110250139.8A 2011-08-26 2011-08-26 Method for producing copper-clad aluminum bar Active CN102303216B (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201410585316.1A CN104439923B (en) 2011-08-26 2011-08-26 A kind of resistivity is relatively low and the production method of plasticity and the preferable copper clad aluminum wire of toughness
CN201410585375.9A CN104384857B (en) 2011-08-26 2011-08-26 The production method of the copper clad aluminum wire that a kind of resistivity is relatively low
CN201110250139.8A CN102303216B (en) 2011-08-26 2011-08-26 Method for producing copper-clad aluminum bar
CN201410585374.4A CN104353966B (en) 2011-08-26 2011-08-26 A kind of plasticity and the production method of the preferable copper clad aluminum wire of toughness

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110250139.8A CN102303216B (en) 2011-08-26 2011-08-26 Method for producing copper-clad aluminum bar

Related Child Applications (3)

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CN201410585316.1A Division CN104439923B (en) 2011-08-26 2011-08-26 A kind of resistivity is relatively low and the production method of plasticity and the preferable copper clad aluminum wire of toughness
CN201410585375.9A Division CN104384857B (en) 2011-08-26 2011-08-26 The production method of the copper clad aluminum wire that a kind of resistivity is relatively low
CN201410585374.4A Division CN104353966B (en) 2011-08-26 2011-08-26 A kind of plasticity and the production method of the preferable copper clad aluminum wire of toughness

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CN102303216B CN102303216B (en) 2014-12-10

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102608427A (en) * 2012-03-15 2012-07-25 河南中孚实业股份有限公司 Method for measuring resistance of crimped section of copper and aluminum composite row
CN102682926A (en) * 2012-05-30 2012-09-19 青岛圆鑫双金属有限公司 Production technology of cooper clad aluminum row by using instant permanent bonding method
CN102760535A (en) * 2012-07-23 2012-10-31 苏州市南方欣达双金属材料有限公司 Production method for copper clad aluminum busbars
CN103022851A (en) * 2012-12-21 2013-04-03 东莞市金澜电工材料有限公司 Novel copper-aluminum transition plate production technology covering copper on double faces at one end of aluminum plate
CN103358099A (en) * 2013-07-19 2013-10-23 烟台孚信达双金属股份有限公司 Pass rolling technology for copper clad aluminum busbars
CN104409136A (en) * 2014-12-22 2015-03-11 孙华桥 Compound conducting bar
CN104439904A (en) * 2013-09-13 2015-03-25 王学平 Continuous extrusion production process and production equipment of copper-coated aluminum busbar
CN106098210A (en) * 2016-07-29 2016-11-09 汉舟四川铜铝复合科技有限公司 A kind of production method of the strong conduction copper of resistance to temperature rise aluminum interface alloy composite pipe bus
CN106205866A (en) * 2016-07-29 2016-12-07 汉舟四川铜铝复合科技有限公司 The processing method of wave duct in the alloy composite conductor of a kind of copper aluminum interface
CN106229076A (en) * 2016-07-29 2016-12-14 汉舟四川铜铝复合科技有限公司 A kind of production method of copper aluminum interface alloy composite bus in equipment for power transmission and distribution
CN108941238A (en) * 2017-05-18 2018-12-07 艾洛益(杭州)材料科技有限公司 The continuous preparation process of copper clad aluminium composite bus
CN109396755A (en) * 2018-09-12 2019-03-01 浙江海普厨具有限公司 Sand-blasting-free aluminum plate production line for cookware and production process thereof
CN113871095A (en) * 2021-09-27 2021-12-31 张纪云 Production process and production line of copper-clad aluminum flat wire

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JP3470795B2 (en) * 2000-03-24 2003-11-25 東京特殊電線株式会社 Copper coated aluminum wire
CN101236798A (en) * 2008-02-04 2008-08-06 北京科技大学 A copper adulterated aluminum complex flat line and its making method
CN101465171A (en) * 2007-12-21 2009-06-24 徐志超 Method for making copper dural alclad bus-bar row continuously through coating, welding and rolling
CN101645333A (en) * 2008-08-05 2010-02-10 北京有色金属研究总院 Rolling method for producing copper clad aluminum row
CN101645334A (en) * 2008-08-05 2010-02-10 北京有色金属研究总院 Extrusion rolling composite method for producing copper clad aluminum row

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
JP3470795B2 (en) * 2000-03-24 2003-11-25 東京特殊電線株式会社 Copper coated aluminum wire
CN101465171A (en) * 2007-12-21 2009-06-24 徐志超 Method for making copper dural alclad bus-bar row continuously through coating, welding and rolling
CN101236798A (en) * 2008-02-04 2008-08-06 北京科技大学 A copper adulterated aluminum complex flat line and its making method
CN101645333A (en) * 2008-08-05 2010-02-10 北京有色金属研究总院 Rolling method for producing copper clad aluminum row
CN101645334A (en) * 2008-08-05 2010-02-10 北京有色金属研究总院 Extrusion rolling composite method for producing copper clad aluminum row

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102608427B (en) * 2012-03-15 2015-09-02 河南中孚实业股份有限公司 A kind of measuring method of Copper-Aluminum compound row crimp segment resistance
CN102608427A (en) * 2012-03-15 2012-07-25 河南中孚实业股份有限公司 Method for measuring resistance of crimped section of copper and aluminum composite row
CN102682926A (en) * 2012-05-30 2012-09-19 青岛圆鑫双金属有限公司 Production technology of cooper clad aluminum row by using instant permanent bonding method
CN102760535A (en) * 2012-07-23 2012-10-31 苏州市南方欣达双金属材料有限公司 Production method for copper clad aluminum busbars
CN103022851A (en) * 2012-12-21 2013-04-03 东莞市金澜电工材料有限公司 Novel copper-aluminum transition plate production technology covering copper on double faces at one end of aluminum plate
CN103022851B (en) * 2012-12-21 2015-11-11 东莞市金澜电工材料有限公司 At the Novel copper-aluminium rebound production process of aluminium sheet one end double-sided copper-clad
CN103358099A (en) * 2013-07-19 2013-10-23 烟台孚信达双金属股份有限公司 Pass rolling technology for copper clad aluminum busbars
CN103358099B (en) * 2013-07-19 2015-05-27 烟台孚信达双金属股份有限公司 Pass rolling technology for copper clad aluminum busbars
CN104439904A (en) * 2013-09-13 2015-03-25 王学平 Continuous extrusion production process and production equipment of copper-coated aluminum busbar
CN104439904B (en) * 2013-09-13 2016-08-17 王学平 Copper clad aluminum wire continuous extrusion production technique and the equipment of production thereof
CN104409136A (en) * 2014-12-22 2015-03-11 孙华桥 Compound conducting bar
CN104409136B (en) * 2014-12-22 2016-09-07 孙华桥 A kind of preparation method of compound conductive bar
CN106098210A (en) * 2016-07-29 2016-11-09 汉舟四川铜铝复合科技有限公司 A kind of production method of the strong conduction copper of resistance to temperature rise aluminum interface alloy composite pipe bus
CN106205866A (en) * 2016-07-29 2016-12-07 汉舟四川铜铝复合科技有限公司 The processing method of wave duct in the alloy composite conductor of a kind of copper aluminum interface
CN106229076A (en) * 2016-07-29 2016-12-14 汉舟四川铜铝复合科技有限公司 A kind of production method of copper aluminum interface alloy composite bus in equipment for power transmission and distribution
CN108941238A (en) * 2017-05-18 2018-12-07 艾洛益(杭州)材料科技有限公司 The continuous preparation process of copper clad aluminium composite bus
CN109396755A (en) * 2018-09-12 2019-03-01 浙江海普厨具有限公司 Sand-blasting-free aluminum plate production line for cookware and production process thereof
CN109396755B (en) * 2018-09-12 2020-12-04 浙江海普厨具有限公司 Sand-blasting-free aluminum plate production line for cookware and production process thereof
CN113871095A (en) * 2021-09-27 2021-12-31 张纪云 Production process and production line of copper-clad aluminum flat wire

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