CN102294862A - Flexible screen protection film and preparation method thereof - Google Patents

Flexible screen protection film and preparation method thereof Download PDF

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Publication number
CN102294862A
CN102294862A CN2011101961125A CN201110196112A CN102294862A CN 102294862 A CN102294862 A CN 102294862A CN 2011101961125 A CN2011101961125 A CN 2011101961125A CN 201110196112 A CN201110196112 A CN 201110196112A CN 102294862 A CN102294862 A CN 102294862A
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base material
film
adhesive layer
vacuum
aforesaid
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CN2011101961125A
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CN102294862B (en
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魏亮
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NINGBO SOKEN CHEMICAL CO Ltd
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NINGBO SOKEN CHEMICAL CO Ltd
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Abstract

The invention discloses a flexible screen protection film, which is characterized by comprising a base material, a sterilizing and hardening layer, a gluing layer and a release film, wherein the sterilizing and hardening layer is arranged on the first surface of the base material; the gluing layer is arranged on the second surface of the base material; the release film is stuck on the gluing layer; and in addition, the base material is a PU (Poly Urethane) film, a TPU (thermoplastic urethanes) film, a PO (Propylene Oxide) film or a PVC (Poly Vinyl Chloride) film; the sterilizing and hardening layer is plated on the base material by vacuum evaporation, vacuum ion plating or vacuum sputtering; and the sterilizing and hardening layer is pure copper, copper alloy or copper oxide. The invention also discloses a preparation method of the flexible screen protection film. Compared with the prior art, the flexible screen protection film has the advantages that the surface of the protection film has the functions of preventing from starching and sterilizing. The flexibility of the whole protection film is greatly increased, and no creases are generated in the folding or bending process.

Description

A kind of flexible screen diaphragm and preparation method thereof
Technical field
The present invention relates to a kind of screen protection film of digital product, relate in particular to the folding crooked flexible screen diaphragm of a kind of energy, the invention still further relates to the preparation method of this flexible screen diaphragm.
Background technology
The screen of the digital product of prior art (mobile phone, MP4, PSP, portable computer) is plane, can not fold bending, carries very inconvenience.As a kind of development trend; and existing digital product (particularly mobile phone) screen all enclose one deck screen protection film; general PC diaphragm, the PET diaphragm of adopting; AR diaphragm, the document of this class can referenced patent number is the Chinese utility model patent " screen protection film " (Granted publication CN201514774U) of ZL200920169661.1.This type of diaphragm is pretty good for folding effect screen, and for collapsible flexure type screen, can appear to produce phenomenon such as arch upward in the middle of the folding line in the folding or crooked process, thereby have a strong impact on the outward appearance and the use of mobile phone.
In addition, the screen protection film is for scratch resistance, and the surface can compound layer of metal add hard formation, and this kind scheme has well solved the shortcoming that the mobile phone screen surface is easy to scratch.But mobile phone was repeatedly touched in one day, and its surface can stay a lot of bacteriums, though existing technology also has the technology that makes the safeguard film for cellular phone surface possess sterilizing ability, yet there are no existing sterilizing function also has the diaphragm of scratch resistance function to occur.
Summary of the invention
Technical problem to be solved by this invention is that a kind of flexible screen diaphragm that can fold bending that is applicable to digital product is provided at the above-mentioned state of the art.
Technical problem to be solved by this invention is to provide a kind of flexible screen diaphragm with the anti-zoned function of sterilization that is applicable to digital product at the above-mentioned state of the art.
Technical problem to be solved by this invention is the preparation method that the flexible screen diaphragm of the folding bending of a kind of energy is provided at the above-mentioned state of the art.
Technical problem to be solved by this invention is to provide a kind of preparation method with flexible screen diaphragm of the anti-zoned function of sterilization at the above-mentioned state of the art.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: a kind of flexible screen diaphragm; it is characterized in that comprising base material; sterilization adds hard formation; adhesive layer and mould release membrance; aforesaid sterilization adds the first surface that hard formation is arranged in base material; aforesaid adhesive layer is arranged in the second surface of base material; and aforesaid mould release membrance is adhered on the adhesive layer; and; aforesaid base material is PU (polyurethane) film; TPU (TPUE) film; PO (polyolefin) film or PVC (Corvic) film; aforesaid sterilization adds hard formation by vacuum evaporation; vacuum ion plating or vacuum sputtering are plated on the base material, and it is fine copper that aforesaid sterilization adds hard formation; the oxide of copper alloy or copper.
As preferably, described base material thickness is 25 μ m~250 μ m, full light transmission rate 〉=70%, mist degree≤1.5.
As preferably, described sterilization stiffened layer thickness is 10nm~3000nm, pencil hardness 〉=1H.
As preferably, described mould release membrance thickness is 25 μ m~100 μ m, and described adhesive layer thickness is 2 μ m~60 μ m.
A kind of method for preparing the flexible screen diaphragm is characterized in that comprising the steps: with the base material to be deposited film, adopts vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation at the first surface of base material; With the second surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.
A kind of method for preparing the flexible screen diaphragm, it is characterized in that comprising the steps: with the base material to be deposited film, first surface at base material adopts vacuum evaporation, vacuum ion plating or vacuum sputtering plated deposition one deck ITO (Indium Tin Oxides) layer, adopts vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation again at the ITO laminar surface; With the second surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.The ITO layer is the nano indium tin metal oxide, has the good electric conductivity and the transparency.
Compared with prior art, the invention has the advantages that: the present invention adopts the oxide of fine copper, copper alloy or copper as the base material deposited layer, makes the diaphragm surface possess the function of anti-scratch and sterilization simultaneously; In addition, base material adopts fexible films such as PU film, TPU film, PO film, PVC film, makes whole protecting film degree of flexibility heighten, even also do not produce folding line in folding or BENDING PROCESS.
Description of drawings
Fig. 1 is embodiment 1 a sectional structure schematic diagram.
Fig. 2 is embodiment 7 sectional structure schematic diagrames.
The specific embodiment
Embodiment describes in further detail the present invention below in conjunction with accompanying drawing.
Embodiment 1; as shown in Figure 1, the flexible screen diaphragm comprises that base material 2, sterilization add hard formation 1, adhesive layer 3 and mould release membrance 4,1 layer of first surface that is arranged in base material 2 of sterilization stiffened; adhesive layer 3 is arranged in the second surface of base material 2; mould release membrance 4 is adhered on the adhesive layer 3, and sterilization adds hard formation and is plated on the base material by vacuum evaporation, vacuum ion plating or vacuum sputtering, in the present embodiment; base material is the PU film; thickness is 25 μ m, and full light transmission rate is 80%, mist degree 0.9%.Adhesive layer thickness is 10 μ m, and mould release membrance thickness is 25 μ m, and it is red copper that sterilization adds hard formation, and thickness is 20nm, pencil hardness 1H.
The preparation method of flexible screen diaphragm comprises the steps: with the base material to be deposited film, adopts vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation on its surface; With the non-deposition surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.
Embodiment 2, and base material is the TPU film in the flexible screen diaphragm in the present embodiment, and thickness is 38 μ m, and full light transmission rate is 85%, mist degree 1.0%.Adhesive layer thickness is 15 μ m, and mould release membrance thickness is 38 μ m, and sterilization adds hard formation and is bronze, and thickness is 100nm, pencil hardness 2H.Preparation method's reference example 1.
Embodiment 3, and base material is the PVC film in the flexible screen diaphragm in the present embodiment, and thickness is 100 μ m, and full light transmission rate is 90%, mist degree 0.9%.Adhesive layer thickness is 50 μ m, and mould release membrance thickness is 50 μ m, and it is brass that sterilization adds hard formation, and thickness is 1000nm, pencil hardness 3H.Preparation method's reference example 1.
Embodiment 4, and base material is the PVC film in the flexible screen diaphragm in the present embodiment, and thickness is 50 μ m, and full light transmission rate is 90%, mist degree 0.9%.Adhesive layer thickness is 60 μ m, and mould release membrance thickness is 100 μ m, and it is chromium-copper that sterilization adds hard formation, and thickness is 2000nm, pencil hardness 3H.Preparation method's reference example 1.
Embodiment 5, and base material is the PU film in the flexible screen diaphragm in the present embodiment, and thickness is 100 μ m, and full light transmission rate is 91%, mist degree 0.9%.Adhesive layer thickness is 25 μ m, and mould release membrance thickness is 50 μ m, and it is red copper that sterilization adds hard formation, and thickness is 3000nm, pencil hardness 3H.Preparation method's reference example 1.
Embodiment 6, and base material is the PU film in the flexible screen diaphragm in the present embodiment, and thickness is 250 μ m, and full light transmission rate is 92%, mist degree 0.8%.Adhesive layer thickness is 50 μ m, and mould release membrance thickness is 100 μ m, and it is red copper that sterilization adds hard formation, and protective layer thickness is 500nm, pencil hardness 3H.Preparation method's reference example 1.
Embodiment 7, and as shown in Figure 2, base material 2 is the PO film in the flexible screen diaphragm of present embodiment, and thickness is 125 μ m, and full light transmission rate is 90%, mist degree 0.8%.Adhesive layer 3 thickness are 50 μ m, and mould release membrance 4 thickness are 100 μ m, and sterilization adds hard formation 1 and is red copper, sterilization adds hard formation 1 and is deposited on the ITO layer 2 (ITO itself has the stiffened effect), and sterilization stiffened layer thickness is 100nm, hardness 3H, ITO layer 2 is deposited on the base material 2, and ITO layer 2 is 100nm.
The preparation method: with the base material is deposited film, first surface at base material adopts vacuum evaporation, vacuum ion plating or vacuum sputtering plated deposition one deck ITO layer, adopts vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation again at the ITO laminar surface; With the second surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.Wherein, the thickness of ITO layer can be with reference to sterilization stiffened layer thickness.
The flexible screen diaphragm of the various embodiments described above gained all has the function of anti-scratch and sterilization, can satisfy folding crooked requirement simultaneously again.

Claims (7)

1. flexible screen diaphragm; it is characterized in that comprising that base material, sterilization add hard formation, adhesive layer and mould release membrance; aforesaid sterilization adds the first surface that hard formation is arranged in base material; aforesaid adhesive layer is arranged in the second surface of base material; and aforesaid mould release membrance is adhered on the adhesive layer; and; aforesaid base material is PU film, TPU film, PO film or PVC film; aforesaid sterilization adds hard formation and is plated on the base material by vacuum evaporation, vacuum ion plating or vacuum sputtering, and aforesaid sterilization adds the oxide that hard formation is fine copper, copper alloy or copper.
2. flexible screen diaphragm; it is characterized in that comprising base material; the ITO layer; sterilization adds hard formation; adhesive layer and mould release membrance; aforesaid ITO layer is by vacuum evaporation; vacuum ion plating or vacuum sputtering are plated on the first surface of base material; aforesaid adhesive layer is arranged in the second surface of base material; and aforesaid mould release membrance is adhered on the adhesive layer; and; aforesaid base material is the PU film; the TPU film; PO film or PVC film; aforesaid sterilization adds hard formation by vacuum evaporation; vacuum ion plating or vacuum sputtering are plated on the ITO layer, and it is fine copper that aforesaid sterilization adds hard formation; the oxide of copper alloy or copper.
3. flexible screen diaphragm according to claim 1 and 2 is characterized in that described base material thickness is 25 μ m~250 μ m, full light transmission rate 〉=70%, mist degree≤1.5.
4. flexible screen diaphragm according to claim 1 and 2 is characterized in that described sterilization stiffened layer thickness is 10nm~3000nm, pencil hardness 〉=1H.
5. flexible screen diaphragm according to claim 1 and 2 is characterized in that described mould release membrance thickness is 25 μ m~100 μ m, and described adhesive layer thickness is 2 μ m~60 μ m.
6. method for preparing any flexible screen diaphragm in the claim 1,3,4,5, it is characterized in that comprising the steps: with the base material to be deposited film, adopt vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation at the first surface of base material; With the second surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.
7. method for preparing the described flexible screen diaphragm of claim 2, it is characterized in that comprising the steps: with the base material to be deposited film, first surface at base material adopts vacuum evaporation, vacuum ion plating or vacuum sputtering plated deposition one deck ITO layer, adopts vacuum evaporation, vacuum ion plating or the sterilization of vacuum sputtering plated deposition one deck to add hard formation again at the ITO laminar surface; With the second surface pressure-sensitive adhesive coating of this film that deposits, form adhesive layer then, behind the oven drying, mould release membrance is pasted pay on adhesive layer again.
CN201110196112.5A 2011-07-11 2011-07-11 Flexible screen protection film and preparation method thereof Active CN102294862B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102774564A (en) * 2012-07-31 2012-11-14 苏州萃智新技术开发有限公司 Protective film for pop can
CN106708171A (en) * 2015-07-21 2017-05-24 联想(北京)有限公司 Connecting apparatus and electronic device
CN107603506A (en) * 2017-10-10 2018-01-19 东莞市纳利光学材料有限公司 A kind of full bag mantle of Curved screen and preparation method thereof
CN108004505A (en) * 2017-12-26 2018-05-08 江苏蔚联机械股份有限公司 A kind of screen color ornamental strip with metallic luster and preparation method thereof
CN108365001A (en) * 2018-04-16 2018-08-03 江苏集萃有机光电技术研究所有限公司 A kind of ITO substrates and preparation method thereof
CN111147634A (en) * 2019-12-26 2020-05-12 深圳宏瑞新材料股份有限公司 OLED folding or winding screen and manufacturing process thereof
CN111925737A (en) * 2020-06-29 2020-11-13 浙江欣麟新材料技术有限公司 Sterilizing type fingerprint hardening prevention foldable screen protection film capable of being bent by heating
CN112029433A (en) * 2020-09-07 2020-12-04 浙江佳阳塑胶新材料有限公司 Flexible mobile phone screen protective film and preparation method thereof
CN112622291A (en) * 2019-09-24 2021-04-09 北京小米移动软件有限公司 Flexible screen cover plate attaching method and device and terminal equipment
CN115243545A (en) * 2020-03-27 2022-10-25 三菱综合材料株式会社 Antibacterial member
CN115522165A (en) * 2022-09-02 2022-12-27 深圳市志凌伟业光电有限公司 Manufacturing process of vehicle window heating film

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CN2684310Y (en) * 2004-02-24 2005-03-09 吴克礼 Screen protective paste film having nanometer photocatalyst
CN1594645A (en) * 2004-07-16 2005-03-16 姜培齐 Product with antibacterial and wearresistant surface
CN1659453A (en) * 2002-04-29 2005-08-24 3M创新有限公司 Removable antireflection film
CN1995442A (en) * 2006-02-28 2007-07-11 姜培齐 Method for producing surface antibiotic product using physical gas phase deposition technology
US20070275200A1 (en) * 2004-07-14 2007-11-29 Panac Co., Ltd. Self-Adhesive Film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1659453A (en) * 2002-04-29 2005-08-24 3M创新有限公司 Removable antireflection film
CN2684310Y (en) * 2004-02-24 2005-03-09 吴克礼 Screen protective paste film having nanometer photocatalyst
US20070275200A1 (en) * 2004-07-14 2007-11-29 Panac Co., Ltd. Self-Adhesive Film
CN1594645A (en) * 2004-07-16 2005-03-16 姜培齐 Product with antibacterial and wearresistant surface
CN1995442A (en) * 2006-02-28 2007-07-11 姜培齐 Method for producing surface antibiotic product using physical gas phase deposition technology

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102774564A (en) * 2012-07-31 2012-11-14 苏州萃智新技术开发有限公司 Protective film for pop can
CN106708171A (en) * 2015-07-21 2017-05-24 联想(北京)有限公司 Connecting apparatus and electronic device
CN107603506B (en) * 2017-10-10 2021-05-07 东莞市纳利光学材料有限公司 Curved-surface screen full-wrapping soft film and preparation method thereof
CN107603506A (en) * 2017-10-10 2018-01-19 东莞市纳利光学材料有限公司 A kind of full bag mantle of Curved screen and preparation method thereof
CN108004505A (en) * 2017-12-26 2018-05-08 江苏蔚联机械股份有限公司 A kind of screen color ornamental strip with metallic luster and preparation method thereof
CN108365001A (en) * 2018-04-16 2018-08-03 江苏集萃有机光电技术研究所有限公司 A kind of ITO substrates and preparation method thereof
CN112622291A (en) * 2019-09-24 2021-04-09 北京小米移动软件有限公司 Flexible screen cover plate attaching method and device and terminal equipment
CN111147634A (en) * 2019-12-26 2020-05-12 深圳宏瑞新材料股份有限公司 OLED folding or winding screen and manufacturing process thereof
CN115243545A (en) * 2020-03-27 2022-10-25 三菱综合材料株式会社 Antibacterial member
CN111925737A (en) * 2020-06-29 2020-11-13 浙江欣麟新材料技术有限公司 Sterilizing type fingerprint hardening prevention foldable screen protection film capable of being bent by heating
CN112029433A (en) * 2020-09-07 2020-12-04 浙江佳阳塑胶新材料有限公司 Flexible mobile phone screen protective film and preparation method thereof
CN115522165A (en) * 2022-09-02 2022-12-27 深圳市志凌伟业光电有限公司 Manufacturing process of vehicle window heating film
CN115522165B (en) * 2022-09-02 2024-02-02 深圳市志凌伟业光电有限公司 Manufacturing process of car window heating film

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