CN102265885A - Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof - Google Patents
Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof Download PDFInfo
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- CN102265885A CN102265885A CN2010101932166A CN201010193216A CN102265885A CN 102265885 A CN102265885 A CN 102265885A CN 2010101932166 A CN2010101932166 A CN 2010101932166A CN 201010193216 A CN201010193216 A CN 201010193216A CN 102265885 A CN102265885 A CN 102265885A
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- rimsulfuron
- atrazine
- bentazone
- herbicide
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Abstract
The invention belongs to the field of herbicide, and relates to a mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof. The herbicide comprises main effective components of bentazone, rimsulfuron and atrazine in a mass ratio of 0.1-80:0.1-80:0.1-80, and the three accounts for 1-85wt% in the herbicide. The mixed herbicide has substantial effects on application to weeding after seedling in soybean field, and especially application to control of gramineae weeds and broad leaf weeds in soybean field. Compared with a single dose, the herbicide of the invention, on the premise of enhancing drug effect, delays weed resistance, has a wide weeding spectrum and a long persistent period, and is safe to soybean and later crops.
Description
Technical field
The invention belongs to the weed killer herbicide field, relate to a kind of mixed herbicide and application thereof that contains bentazone, rimsulfuron 25 and atrazine.
Technical background
Bentazone has another name called Lysimachia sikokiana pellet, Bentazon, chemical name: the 3-isopropyl-(1H)-and benzo-2,1,3-thiadiazine-4-ketone-2, the 2-dioxide, structural formula is:
This weed killer herbicide is an optionally herbicide after seedling of contact killing type tool, is used for cauline leaf processing in seedling stage, works by the blade contact.Dry land is used, and is transmitted to by the blade face infiltration earlier and suppresses photosynthesis in the chloroplast.The paddy field is used and can be absorbed by root again by the blade face infiltration, is transmitted to cauline leaf, hinders weeds photosynthesis and water metabolism strongly, causes nutrition hunger, makes physiological function lack of proper care and cause death.Active ingredient is detoxified to active weak glycoconjugates metabolism in the tolerable crop body, and to crop safety, 6-18 week bentazone can be by microbial decomposition in soil after the dispenser.But bentazone is invalid to grassy weed, and herbicidal spectrum is single.
Atrazine (Atrazine) has another name called atrazine, a kind of triazine herbicide, and formal name used at school 2-chloro-4-ethylamino-6-isopropylamino-1,3,5-triazines, its structural formula is as follows:
Atrazine is before the selectivity inner sucting conduction type seedling, herbicide after seedling, is absorbed as the master with root, and cauline leaf absorbs seldom, is transmitted to plant meristematic tissue and leaf portion rapidly, disturbs photosynthesis that weeds are caused death.In resistance crop bodies such as corn, decomposed the generation innocuous substance by the corn ketolase, thereby to safety such as corns.Its spectrum of grass extremely is wider, can prevent and kill off multiple annual gramineae and broad leaved weed.Because atrazine is absorbed as the master with root, so that density takes place is higher when weeds, or plant is when big, and it is difficult to thoroughly cut weeds extremely, and, there have been many weeds that it has been produced serious resistance.
Rimsulfuron 25 (rimsulfuron); claim rimsulfuron again, commodity are by name precious to become (Titus), is E.I.Du Pont Company in 20th century sulfonylurea herbicide successfully researched and developed of the mid-80; chemical name: 1-(4,6 dimethoxypyridins-2-yl)-3-(3-ethylsulfonyl-2-pyridine sulphonyl) urea.Its structural formula is as follows:
Rimsulfuron 25 has advantages such as high selectivity, efficient, low toxicity, is a kind of important corn field herbicide.The bud post processing is taked in dispenser, absorbs rapidly in plant conduction and suppresses the synthetic of weeds valine and isoleucine by weeds cauline leaf and root, stops cell division, kills weeds.Flavescence in 3 days behind the susceptible weeds suction medicine, withered death in 1～3 week.Can effectively prevent and kill off most of broad-leaveds and grassy weed, as creeping thistle, lady's-grass, Commelina communis, barnyard grass grass, Annual Ryegrass, Amaranthus retroflexus, clearvers, numerous beach wormwood, corn poppy, the scope of application is wide, can be used for crops such as corn, potato and tomato.Rimsulfuron 25 is one of kind outstanding in the sulfonylurea herbicide kind of developing in recent years, has good market prospects.But, rimsulfuron 25 price comparison height, unit are use cost height makes it be subjected to greatly restriction in sale and use.
Corn field herbicide is limit by crop safety at present, it is also limited to kill the grass spectrum, be used alone the agent of weed killer herbicide list and can not control the generation of corn field weed completely effectively, moreover some weed killer herbicide is because water-soluble big or the field lasting period is oversize, consumption is excessive or the inhomogeneous residual hazard that all causes easily this season crop or succession crop of dispenser.
Summary of the invention:
The purpose of this invention is to provide a kind of mixed herbicide that contains bentazone, rimsulfuron 25 and atrazine.
Another object of the present invention provides this herbicide applications.
A kind of mixed herbicide that contains bentazone, rimsulfuron 25 and atrazine, it is characterized in that this weed killer herbicide is main active ingredient with bentazone, rimsulfuron 25 and atrazine, the mass ratio of bentazone, rimsulfuron 25 and atrazine is 0.1～80: 0.1～80: 0.1～80, and the mass ratio of preferred bentazone, rimsulfuron 25 and atrazine is 1～60: 1～40: 1～60.
In mixed herbicide, bentazone, rimsulfuron 25 and the atrazine three gross mass percentage composition in weed killer herbicide is 1～85%, and preferred gross mass percentage composition is 20～75%.
In the ternary built preparation of bentazone of the present invention, rimsulfuron 25 and atrazine, except active ingredient bentazone, rimsulfuron 25 and atrazine, can also add the auxiliary agents such as conventional surfactants, thickener, solvent or solid packing that allow on the pesticidal preparations and be mixed with any one formulation that allows on the agricultural chemicals.Preferably be processed into suspending agent, missible oil, water dispersion granule or wetting powder etc.
Mixed herbicide of the present invention can be used in the weed killer herbicide of preparation corn field postemergence weed control, particularly uses in various grass family and the broad leaved weed in preventing and kill off corn field.
Herbicidal composition of the present invention has the following advantages:
1, activity of weeding height.Herbicidal composition of the present invention can kill weeds by three kinds of different mechanism, makes weeds resistance generation speed reduce, and three kinds of composition Synergistics, has greatly improved the removing activity of weed killer herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.Three kinds of weed killer herbicides to kill the grass spectrum different, the three is combined the herbicidal spectrum and the activity of these three kinds of medicaments with the be mixed medicament that makes of special ratios, make that the herbicidal spectrum of mix preparation is wideer, the lasting period is longer.
3, delay the weeds resistance.The present invention can significantly improve the preventive effect to various resistant weeds, delays the drug-fast generation of weeds, prolongs the service life of medicament.
4, safe.Herbicidal composition of the present invention is applied to the corn field postemergence weed control, and it can prevent and kill off various grass family or broad leaved weed in the corn field, under the prerequisite that has improved drug effect, corn and succession crop is all had safety.
Specific embodiments
Embodiment 1
Bentazone 10%, atrazine 28%, rimsulfuron 25 2%, alkylphenol polyoxyethylene 4%, polyoxyethylene polyoxy third rare block compound 5%, xanthans 2%, vegetable oil supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 40% oil-suspending agent.
Embodiment 2
Bentazone 10%, atrazine 14%, rimsulfuron 25 1%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 9%, alkylphenol polyoxyethylene 5%, sodium lignin sulfonate to 100%, being mixed with active ingredient quality percentage composition according to the formulation method of routine is 25% the outstanding agent of doing.
Embodiment 3
Bentazone 40%, atrazine 33%, rimsulfuron 25 2%, sodium lignin sulfonate 7%, neopelex 5%, ammonium sulfate 5%, diatomite supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 75% water dispersion granule.
Embodiment 4
Bentazone 30%, atrazine 34%, rimsulfuron 25 1%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 9%, sodium lignin sulfonate 7%, white carbon 9%, kaolin supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 65% wetting powder.
Embodiment 5
Bentazone 29%, atrazine 1%, rimsulfuron 25 10%, alkylphenol polyoxyethylene 4%, polyoxyethylene polyoxy third rare block compound 5%, xanthans 2%, vegetable oil supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 40% oil-suspending agent.
Embodiment 6
Bentazone 1%, atrazine 20%, rimsulfuron 25 4%, alkylphenol polyoxyethylene 4%, polyoxyethylene polyoxy third rare block compound 5%, xanthans 2%, vegetable oil supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 25% oil-suspending agent.
Embodiment 7
Bentazone 60%, atrazine 14%, rimsulfuron 25 1%, sodium lignin sulfonate 7%, neopelex 5%, ammonium sulfate 5%, diatomite supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 75% water dispersion granule.
Embodiment 8
Bentazone 10%, atrazine 60%, rimsulfuron 25 5%, sodium lignin sulfonate 7%, neopelex 5%, ammonium sulfate 5%, diatomite supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 75% water dispersion granule.
Embodiment 9
Bentazone 20%, atrazine 15%, rimsulfuron 25 40%, sodium lignin sulfonate 7%, neopelex 5%, ammonium sulfate 5%, diatomite supplies 100%, and being mixed with active ingredient quality percentage composition according to the formulation method of routine is 75% water dispersion granule.
Embodiment 10
1), indoor active determination test
Utilize the preparation of embodiment 1～4, measure its co-toxicity coefficient corn field common weed dayflower.
Test method: the seed of quantitative dayflower is seeded in respectively in the Disposable paper cup of 9cm, sows 10～15 seeds in every glass, in illumination box, cultivate, treat that dayflower 3～6 leaves during the phase, do the processing of spraying on the composition spray in crawler type.Handle in the greenhouse, back and continue to cultivate, each handles preventive effect to weeds routine observation, and each weeds fresh weight after handling of weighing behind the 30d is pressed the method for nineteen sixty propositions such as Sun Yunpei, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient shows that greater than 100 two kinds of active principles have synergistic effect, and co-toxicity coefficient shows that less than 100 two kinds of active principles have antagonism.Measurement result is as shown in table 1.
The indoor determination of activity result of table 1
The above results proves absolutely, bentazone, rimsulfuron 25 and atrazine three complex preparation all have significant synergy preventing and kill off on the dayflower.
2), field control effectiveness test:
Reagent agent:
4 kinds of ternary built weed killer herbicides among the embodiment 1～4.
The contrast medicament:
25% bentazone aqua (commercially available), 38% atrazine suspending agent (commercially available), 25% rimsulfuron 25 dry suspending agent (commercially available).
For studying thing: corn
Maize seedling was 3～6 leaf phases, grew fine, and robust plant does not have other damage by disease and insect.
Prevent and kill off object:
Corn field advantage weeds are as grassy weed: barnyard grass grass, green foxtail, and broad leaved weed: dayflower, piemarker anti-Zhi Amaranth etc.
Test method:
According to the area of experimental plot, the accurate good various medicaments of weighing, and after converting the water dilution, utilize knapsack sprayer, and carrying out even spraying, shower nozzle is selected the Fan spray head of weed killer herbicide special use for use.During spraying, note soup is evenly sprayed application in the experimental plot, accomplish not leak the phenomenon of spray, many sprays.
After the test respectively behind medicine 20d, 40d observe the weeds death condition, and the activity of weeding of more various medicaments.In addition, also to behind medicine, observe the condition of production of crop in 1～15d, whether crop be had poisoning to investigate medicament.
Embodiments of the invention preparation weeding test effect see the following form 2 (20d behind the medicine) and table 3 (40d behind the medicine).
20 days drug effect results after table 2 dispenser
| Handle medicament | Consumption (ga.i./mu) | Grass family preventive effect (%) | Broad leaved weed preventive effect (%) | Total preventive effect (%) |
| Embodiment 1 | 50 | 94 | 93 | 93 |
| Embodiment 2 | 50 | 92 | 90 | 91 |
| Embodiment 3 | 50 | 94 | 95 | 94 |
| Embodiment 4 | 50 | 92 | 93 | 93 |
| 38% atrazine suspending agent | 150 | 85 | 77 | 80 |
| 25% bentazone aqua | 100 | - | 88 | 49 |
| 25% rimsulfuron 25 dry suspending agent | 4 | 90 | 83 | 85 |
40 days drug effect results after table 3 dispenser
| Handle medicament | Consumption (ga.i./mu) | Grass family preventive effect (%) | Broad leaved weed preventive effect (%) | Total preventive effect (%) |
| Embodiment 1 | 50 | 91 | 88 | 89 |
| Embodiment 2 | 50 | 89 | 90 | 89 |
| Embodiment 3 | 50 | 90 | 90 | 90 |
| Embodiment 4 | 50 | 89 | 90 | 90 |
| 38% atrazine suspending agent | 150 | 75 | 68 | 70 |
| 25% bentazone aqua | 100 | - | 72 | 35 |
| 25% rimsulfuron 25 dry suspending agent | 4 | 75 | 69 | 72 |
Consumption in table 2 and the table 3 all refers to the consumption of active ingredient in each preparation.As can be seen, the present invention has significant preventive effect to grassy weed and broad leaved weed from table 2 and table 3, and synergy is remarkable, and the lasting period is long.
Table 4 medicament is to the security survey result of crop
Each corn of handling in the sub-district grows fine, and each is handled the sub-district and does not see any medicine spot, illustrates that compound drug of the present invention is to the equal safety of corn.
Claims (8)
1. mixed herbicide that contains bentazone, rimsulfuron 25 and atrazine, it is characterized in that this weed killer herbicide is main active ingredient with bentazone, rimsulfuron 25 and atrazine, the mass ratio of bentazone, rimsulfuron 25 and atrazine is 0.1～80: 0.1～80: 0.1～80.
2. the mixed herbicide that contains bentazone according to claim 1, the mass ratio that it is characterized in that bentazone, rimsulfuron 25 and atrazine in the described mixed herbicide is 1～60: 1～40: 1～60.
3. mixed herbicide according to claim 1 and 2 is characterized in that described bentazone, rimsulfuron 25 and the atrazine three quality percentage composition in weed killer herbicide is 1～85%.
4. mixed herbicide according to claim 3 is characterized in that described bentazone, rimsulfuron 25 and the atrazine three quality percentage composition in weed killer herbicide is 20～75%.
5. mixed herbicide according to claim 1 is characterized in that it is that the auxiliary agent that allows on main active ingredient and the agricultural chemicals is mixed with any one formulation with bentazone, rimsulfuron 25 and atrazine.
6. mixed herbicide according to claim 5 is characterized in that described formulation is suspending agent, missible oil, water dispersion granule or wetting powder.
7. the application of the described mixed herbicide of claim 1 in the corn field postemergence weed control.
8. the described mixed herbicide of claim 1 application in various grass family or the broad leaved weed in preventing and kill off corn field.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010193216 CN102265885B (en) | 2010-06-03 | 2010-06-03 | Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010193216 CN102265885B (en) | 2010-06-03 | 2010-06-03 | Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102265885A true CN102265885A (en) | 2011-12-07 |
| CN102265885B CN102265885B (en) | 2013-08-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010193216 Active CN102265885B (en) | 2010-06-03 | 2010-06-03 | Mixed herbicide containing bentazone, rimsulfuron and atrazine, and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103250725A (en) * | 2013-05-22 | 2013-08-21 | 吴江市德佐日用化学品有限公司 | Ternary weed-killing composition for corn field |
| CN110506751A (en) * | 2019-08-28 | 2019-11-29 | 广东省生物工程研究所（广州甘蔗糖业研究所） | The Weed removal medicinal fertilizer and the preparation method and application thereof removed containing rimsulfuron, diuron and green bristlegrass |
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|---|---|---|---|---|
| CN1514686A (en) * | 2001-02-14 | 2004-07-21 | ������ɽ���� | Coformulation of oil-soluble herbicide and water-soluble heribcide as stable oil-in-water emulsion or microemulsion |
| CN101564040A (en) * | 2009-05-21 | 2009-10-28 | 孙永吉 | Herbicide composition and preparation thereof |
| CN101595885A (en) * | 2009-07-10 | 2009-12-09 | 赵邦斌 | The Herbicidal combinations that is used for corn field |
| CN101617675A (en) * | 2008-07-02 | 2010-01-06 | 山东滨农科技有限公司 | Herbicide composition |
-
2010
- 2010-06-03 CN CN 201010193216 patent/CN102265885B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1514686A (en) * | 2001-02-14 | 2004-07-21 | ������ɽ���� | Coformulation of oil-soluble herbicide and water-soluble heribcide as stable oil-in-water emulsion or microemulsion |
| CN101617675A (en) * | 2008-07-02 | 2010-01-06 | 山东滨农科技有限公司 | Herbicide composition |
| CN101564040A (en) * | 2009-05-21 | 2009-10-28 | 孙永吉 | Herbicide composition and preparation thereof |
| CN101595885A (en) * | 2009-07-10 | 2009-12-09 | 赵邦斌 | The Herbicidal combinations that is used for corn field |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103250725A (en) * | 2013-05-22 | 2013-08-21 | 吴江市德佐日用化学品有限公司 | Ternary weed-killing composition for corn field |
| CN110506751A (en) * | 2019-08-28 | 2019-11-29 | 广东省生物工程研究所（广州甘蔗糖业研究所） | The Weed removal medicinal fertilizer and the preparation method and application thereof removed containing rimsulfuron, diuron and green bristlegrass |
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| CN102265885B (en) | 2013-08-07 |
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