CN102260547B

CN102260547B - Ethanol gasoline and preparation method thereof

Info

Publication number: CN102260547B
Application number: CN2010105455857A
Authority: CN
Inventors: 唐良荣
Original assignee: YONGZHOU JIN YING NEW ENERGY DEVELOPMENT Co Ltd
Current assignee: Yongzhou Jin Ying New Energy Development Co., Ltd.
Priority date: 2010-11-09
Filing date: 2010-11-09
Publication date: 2012-11-28
Anticipated expiration: 2030-11-09
Also published as: CN102260547A

Abstract

The invention discloses an ethanol gasoline and a preparation method thereof and relates to the field of new energy. The ethanol gasoline consists of 10 to 25 percent of ethanol, 67 to 85 percent of gasoline, 2 to 3 percent of additive and 3 to 5 percent of method. The preparation method of the ethanol gasoline comprises: pouring a solubilizer, an energy-increasing and consumption-reducing agent, an antioxygen, a metal corrosion inhibitor and a rubber swelling inhibitor into a reaction kettle according to a required ratio, stirring, uniformly mixing and obtaining an additive; mixing the additive, ethanol and methanol according to a required ratio and thus obtaining modified ethanol; and mixing the modified ethanol and the gasoline according to a required ratio to obtain the ethanol gasoline. The ethanol gasoline fuel oil is simple in preparation and high in performance and can be used by mixing with China-standard gasoline in any ratio; when the ethanol gasoline fuel oil is used, the oil consumption compares that of the China-standard gasoline, and the emission index meets an environment-protection requirement; and the ethanol gasoline fuel oil can be widely used in various gasoline-burning motor vehicles, such as cars, buses, forklifts, assisted vehicles, agricultural vehicles, motorcycles, loading vehicle and tractor shovels.

Description

Ethanol petrol and compound method

Technical field

The present invention relates to a kind of ethanol petrol and compound method.

Background technology

World petroleum resource is exhausted, and the consumption of China's oil still increases sharply with the speed in year 13%.China's hydrocarbon resources relative shortage just became net import of oil state from 1993, and petroleum demand increased progressively 7% every year in nearly 5 years, and actively seeking new automobile-used substitute energy becomes one of main path of alleviating contradiction between oil supply and demand.Ethanol is renewable resources as the sun power material that is transformed by grain.The grain-production district of China can provide abundant raw material sources for promoting ethanol petrol.Along with developing of automobile industry, the variation of following automobile fuel is a megatrend, and ethanol petrol will present its potential business opportunity.The ethanol petrol that carry out in our times various countries and domestic each province and city, what face mainly is that cost is too high, octane value is not high, calorific value is lower, oil consumption is higher, low temperature driveability and drive problems such as acceleration characteristics is relatively poor.

Summary of the invention

The present invention aims to provide a kind of E 33 modification ethanol petrol fuel and concocting methods, and purpose is to provide a kind of need not to reequip available engine and oiler structure, through improving additive and concocting method, produces a kind of ethanol petrol fuel of direct use.Adopt part methyl alcohol to replace ethanol simultaneously, and methanol prices far below ethanol, so also solved the problem of the ethanol selling at exorbitant prices that ethanol petrol faced.

Technical scheme of the present invention: ethanol petrol each component weight percent of the present invention is: ethanol: 10%-25%, gasoline: 67%-85%, additive: 2%-3%, methyl alcohol: 3%-5%.

Additive according to the invention is a kind of composite additive, and each weight percentages of components is solubilizing agent 0.5%-1.5%, energization consumption reduction agent 1%-2.5%, oxidation inhibitor 0.4%-0.5%, metal corrosion inhibitor 0.2%-1%, swell rubber suppressor factor 0.3%-1%.

Solubilizing agent according to the invention is made up of polynary primary isoamyl alcohol and unitary fatty alcohol, and the agent of energization consumption reduction is by C _9-12Alkane, pix carbonis praeparsta and anhydrous hydrazine are formed; Oxidation inhibitor is made up of tensio-active agent phosphoric acid, acid amides, dimethoxy and alkanoic acid; Metal corrosion inhibitor is made up of azimidobenzene, organic amine and passivator, and the swell rubber suppressor factor is made up of ferrocene, organic amine, sanitas, ETHYLE ACETATE.

Solubilizing agent according to the invention is made up of the polynary primary isoamyl alcohol of 0.25%-0.8% and the unitary fatty alcohol of 0.25%-0.7%, and the agent of energization consumption reduction is by the C of 0.3%-1.5% _9-12The pix carbonis praeparsta of alkane, 0.2%-1% and the anhydrous hydrazine of 0.1%-1% are formed; Oxidation inhibitor is made up of the tensio-active agent phosphoric acid of 0.05%-0.2%, the acid amides of 0.1%-0.16%, the dimethoxy of 0.05%-0.14% and the alkanoic acid of 0.1%-0.2%; Metal corrosion inhibitor is made up of the benzotriazole of 0.05%-0.5%, the organic amine of 0.1%-0.4% and the passivator of 0.05%-0.3%, and the swell rubber suppressor factor is made up of the ferrocene of 0.1%-0.4%, the organic amine of 0.1%-0.3%, the sanitas of 0.05%-0.25%, the ETHYLE ACETATE of 0.05%-0.35%.

The compound method of ethanol petrol according to the invention: earlier solubilizing agent, the agent of energization consumption reduction, oxidation inhibitor, metal corrosion inhibitor, swell rubber suppressor factor are poured in the reaction kettle in required ratio and are stirred, mix additive; With additive and methyl alcohol, ethanol according to required mixed, modification ethanol; Modification ethanol and gasoline are promptly got ethanol petrol according to required mixed.

Ethanol petrol fuel preparation of the present invention is simple, functional, can use with arbitrary proportion with GB gasoline, and oil consumption is suitable with GB gasoline, the discharge index compliance with environmental protection requirements.Adopt the check of SH/T0689 detection method through authoritative institution, sulphur (S) content is 0.0008% (m/m), adopts the check of IEC62321:2008 Ed.1 Sec.10 testing method, and plumbous (Pb) content is N.D. (not detecting).The result shows that sulphur content and lead content in the additive of the present invention are far below sulphur, lead content in national standard and domestic other similar methanol gasoline additives.In addition; The present invention also has following effect: low emission: E33 modification ethanol petrol fuel shows through road tests; Use E33 modification ethanol petrol, under the prerequisite of not carrying out the mover transformation, dynamic performance is constant basically; The CO of exhaust emissions and HC compound decreased average effectively reduce and have reduced deleterious exhaust emissions; Carbon distribution is few: because of the combustioncharacteristics of vehicle ethanol automobile, and effective arc control plug, the combustion chamber, valve, the formation of vapor pipe sourdine position carbon distribution has been avoided because of carbon distribution forms the fault that causes, and the mover that can not wear and tear prolongs mover work-ing life; Energy-conservation: produce the alcoholic acid main raw material and contain sugar, starch-containing crop and fiber-like fuel, these all belong to renewable resources and the source is abundant, thereby use alcohol fuel can reduce the dependence of vehicle to petroleum resources, help Chinese energy safety; Change with oil and make things convenient for: E33 modification alcohol fuel can with regular gasoline intersect use, use with arbitrarily; Application Areas is extensive: E33 modification alcohol fuel can be adaptable across the various Motor vehicles that use gasoline, like car, passenger vehicle, fork truck, vehicle using motor, agricultural vehicle, motorcycle, load wagon, forklift etc.

Embodiment

Embodiment 1: get 10 parts of ethanol, 3 parts of methyl alcohol and 85 parts of gasoline are subsequent use.At first, in reaction kettle, form by weight ratio and add following raw material: the polynary primary isoamyl alcohol of solubilizing agent 0.25% and 0.25% unitary fatty alcohol, the C of energization consumption reduction agent 0.3% _9-12Alkane, 0.2% pix carbonis praeparsta, 0.1% anhydrous hydrazine; The tensio-active agent phosphoric acid of oxidation inhibitor 0.05%, 0.1% acid amides, 0.05% dimethoxy, 0.1% alkanoic acid; The benzotriazole of metal corrosion inhibitor 0.05%, 0.1% organic amine, 0.05% passivator; The ferrocene of swell rubber suppressor factor 0.2%, 0.1% organic amine, 0.05% sanitas, 0.05% ETHYLE ACETATE generate additive through uniform mixing.In reaction kettle, add 10% ethanol then by weight ratio, 3% methyl alcohol mixes with additive, can generate modification ethanol.At last 85% gasoline is mixed with modification ethanol, can generate the finished product ethanol petrol.

Embodiment 2: get 15 parts of ethanol, 4 parts of methyl alcohol and 78.5 parts of gasoline are subsequent use.At first, in reaction kettle, form by weight ratio and add following raw material: the polynary primary isoamyl alcohol of solubilizing agent 0.3% and 0.3% unitary fatty alcohol, the C of energization consumption reduction agent 0.5% _9-12Alkane, 0.4% pix carbonis praeparsta, 0.1% anhydrous hydrazine; The tensio-active agent phosphoric acid of oxidation inhibitor 0.05%, 0.1% acid amides, 0.05% dimethoxy, 0.1% alkanoic acid; The benzotriazole of metal corrosion inhibitor 0.05%, 0.1% organic amine, 0.05% passivator; The ferrocene of swell rubber suppressor factor 0.1%, 0.1% organic amine, 0.1% sanitas, 0.1% ETHYLE ACETATE generate additive through uniform mixing.In reaction kettle, add 15% ethanol then by weight ratio, 4% methyl alcohol mixes with additive, can generate modification ethanol.At last 78.5% gasoline is mixed with modification ethanol, can generate the finished product ethanol petrol.

Embodiment 3: get 25 parts of ethanol, 5 parts of methyl alcohol and 67 parts of gasoline are subsequent use.At first, in reaction kettle, form by weight ratio and add following raw material: the polynary primary isoamyl alcohol of solubilizing agent 0.25% and 0.25% unitary fatty alcohol, the C of energization consumption reduction agent 0.3% _9-12Alkane, 0.3% pix carbonis praeparsta, 0.4% anhydrous hydrazine; The tensio-active agent phosphoric acid of oxidation inhibitor 0.1%, 0.1% acid amides, 0.1% dimethoxy, 0.1% alkanoic acid; The benzotriazole of metal corrosion inhibitor 0.1%, 0.35% organic amine, 0.1% passivator; The ferrocene of swell rubber suppressor factor 0.1%, 0.25% organic amine, 0.1% sanitas, 0.1% ETHYLE ACETATE generate additive through uniform mixing.In reaction kettle, add 25% ethanol then by weight ratio, 5% methyl alcohol mixes with additive, can generate EF33 modification ethanol.At last 67% gasoline is mixed with EF33 modification ethanol, can generate finished product E33 modification ethanol petrol.

Claims

1. ethanol petrol is characterized in that the each component weight percent is:

Ethanol: 10%-25%

Gasoline: 67%-85%

Additive: 2%-3%

Methyl alcohol: 3%-5%

Said additive is a kind of composite additive; The each component weight percent is solubilizing agent 0.5%-1.5%; Energization consumption reduction agent 1%-2.5%; Oxidation inhibitor 0.4%-0.5%; Metal corrosion inhibitor 0.2%-1%, swell rubber suppressor factor 0.3%-1%, wherein: solubilizing agent is made up of the polynary primary isoamyl alcohol of 0.25%-0.8% and the unitary fatty alcohol of 0.25%-0.7%; The agent of energization consumption reduction is made up of the C9-12 alkane of 0.3%-1.5%, the pix carbonis praeparsta of 0.2%-1% and the anhydrous hydrazine of 0.1%-1%; Oxidation inhibitor is made up of the tensio-active agent phosphoric acid of 0.05%-0.2%, the acid amides of 0.1%-0.16%, the dimethoxy of 0.05%-0.14% and the alkanoic acid of 0.1%-0.2%, and metal corrosion inhibitor is made up of the benzotriazole of 0.05%-0.5%, the organic amine of 0.1%-0.4% and the passivator of 0.05%-0.3%, and the swell rubber suppressor factor is made up of the ferrocene of 0.1%-0.4%, the organic amine of 0.1%-0.3%, the sanitas of 0.05%-0.25%, the ETHYLE ACETATE of 0.05%-0.35%.

2. the compound method of ethanol petrol as claimed in claim 1 is characterized in that: earlier solubilizing agent, the agent of energization consumption reduction, oxidation inhibitor, metal corrosion inhibitor, swell rubber suppressor factor are poured in the reaction kettle and are stirred, mix additive; With additive and ethanol, methyl alcohol according to required mixed, modification ethanol; Then with modification ethanol and gasoline according to required mixed, obtain ethanol petrol.