CN102257014B - 用于烯烃聚合的催化剂体系、它的生产和用途 - Google Patents

用于烯烃聚合的催化剂体系、它的生产和用途 Download PDF

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Publication number
CN102257014B
CN102257014B CN200980151043.7A CN200980151043A CN102257014B CN 102257014 B CN102257014 B CN 102257014B CN 200980151043 A CN200980151043 A CN 200980151043A CN 102257014 B CN102257014 B CN 102257014B
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alkyl
catalyst
groups
aryl
substituted
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Chinese (zh)
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CN102257014A (zh
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H.施米茨
F.方蒂内尔
J.希尔茨
S.米汉
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
CN200980151043.7A 2008-12-17 2009-12-12 用于烯烃聚合的催化剂体系、它的生产和用途 Active CN102257014B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08021878 2008-12-17
EP08021878.7 2008-12-17
PCT/EP2009/008911 WO2010069527A1 (en) 2008-12-17 2009-12-12 Catalyst system for olefin polymerization, its production and use

Publications (2)

Publication Number Publication Date
CN102257014A CN102257014A (zh) 2011-11-23
CN102257014B true CN102257014B (zh) 2014-06-04

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CN200980151043.7A Active CN102257014B (zh) 2008-12-17 2009-12-12 用于烯烃聚合的催化剂体系、它的生产和用途

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Country Link
US (1) US8664140B2 (enExample)
EP (1) EP2367854B1 (enExample)
JP (1) JP5752043B2 (enExample)
CN (1) CN102257014B (enExample)
WO (1) WO2010069527A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
JP5694827B2 (ja) * 2011-03-29 2015-04-01 日本ポリエチレン株式会社 オレフィン重合用触媒成分の製造方法、オレフィン重合用触媒及びオレフィンの重合方法
US9308087B2 (en) 2011-04-28 2016-04-12 Neovasc Tiara Inc. Sequentially deployed transcatheter mitral valve prosthesis
ES2918979T3 (es) 2014-02-11 2022-07-21 Univation Tech Llc Métodos para preparar copolímeros de etileno
CN106794455B (zh) 2014-08-19 2020-09-04 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
BR112017003170B1 (pt) 2014-08-19 2022-02-15 Univation Technologies, Llc Método para fazer um suporte de catalisador de alumina-sílica fluorado e sistema de catalisador de alumina-sílica fluorado
WO2016028276A1 (en) 2014-08-19 2016-02-25 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
CN115850552B (zh) 2017-12-01 2024-08-06 埃克森美孚化学专利公司 催化剂体系和使用其的聚合方法
US10926250B2 (en) 2017-12-01 2021-02-23 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
WO2022076216A1 (en) 2020-10-08 2022-04-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1041089A1 (en) * 1999-03-29 2000-10-04 Fina Research S.A. Production of polyethylene
EP1300423A1 (en) * 2001-09-27 2003-04-09 Atofina Research S.A. Catalyst system comprising a mixture of catalyst components for producing a polyolefin blend
US20050159300A1 (en) * 2004-01-21 2005-07-21 Jensen Michael D. Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength

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Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
ES2143636T3 (es) 1994-06-24 2000-05-16 Exxon Chemical Patents Inc Sistemas de catalizadores de polimerizacion, su produccion y uso.
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
WO1997036937A1 (en) 1996-03-29 1997-10-09 The Dow Chemical Company Metallocene cocatalyst
ID22443A (id) 1996-11-15 1999-10-14 Montelll Technology Co Bv Metallosena heterosiklik dan polimerisasi katalis
WO1998040419A1 (de) 1997-03-07 1998-09-17 Targor Gmbh Verfahren zur herstellung von olefinpolymerisaten mit erhöhtem schmelzpunkt
DE19733017A1 (de) 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
ID26574A (id) 1998-03-12 2001-01-18 Bp Chem Int Ltd Katalis-katalis polimerisasi
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
CN100340568C (zh) 1998-11-25 2007-10-03 塔戈尔股份有限公司 茂金属一卤化物
GB9906296D0 (en) * 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
DE102004020524A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
CA2605077C (en) * 2007-10-01 2014-07-08 Nova Chemicals Corporation A co-supported catalyst system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1041089A1 (en) * 1999-03-29 2000-10-04 Fina Research S.A. Production of polyethylene
EP1300423A1 (en) * 2001-09-27 2003-04-09 Atofina Research S.A. Catalyst system comprising a mixture of catalyst components for producing a polyolefin blend
US20050159300A1 (en) * 2004-01-21 2005-07-21 Jensen Michael D. Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength

Also Published As

Publication number Publication date
CN102257014A (zh) 2011-11-23
US8664140B2 (en) 2014-03-04
EP2367854A1 (en) 2011-09-28
WO2010069527A1 (en) 2010-06-24
JP2012512289A (ja) 2012-05-31
US20110294969A1 (en) 2011-12-01
EP2367854B1 (en) 2012-11-28
JP5752043B2 (ja) 2015-07-22

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