CN102242523B - Antifoaming agent for low-temperature paper making system - Google Patents
Antifoaming agent for low-temperature paper making system Download PDFInfo
- Publication number
- CN102242523B CN102242523B CN 201110178514 CN201110178514A CN102242523B CN 102242523 B CN102242523 B CN 102242523B CN 201110178514 CN201110178514 CN 201110178514 CN 201110178514 A CN201110178514 A CN 201110178514A CN 102242523 B CN102242523 B CN 102242523B
- Authority
- CN
- China
- Prior art keywords
- higher alcohols
- parts
- consumption
- wax
- paper making
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002518 antifoaming agent Substances 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000002148 esters Chemical class 0.000 claims abstract description 22
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 18
- 229920000570 polyether Polymers 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 4
- 150000001298 alcohols Chemical class 0.000 claims description 53
- 239000003995 emulsifying agent Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 14
- -1 Tissuemat E Substances 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000001993 wax Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004203 carnauba wax Substances 0.000 claims description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 3
- 229960002666 1-octacosanol Drugs 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 239000008931 Tadenan Substances 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 239000012170 montan wax Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- 229940014903 tadenan Drugs 0.000 claims description 2
- POOSGDOYLQNASK-UHFFFAOYSA-N tetracosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC POOSGDOYLQNASK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- 235000013869 carnauba wax Nutrition 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 33
- 230000003254 anti-foaming effect Effects 0.000 abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 description 30
- 238000010008 shearing Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000006260 foam Substances 0.000 description 5
- 230000005587 bubbling Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- MORMPWNLQJTSOT-UHFFFAOYSA-L disodium;4-dodecyl-2-(4-sulfonatophenoxy)benzenesulfonate Chemical compound [Na+].[Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C(OC=2C=CC(=CC=2)S([O-])(=O)=O)=C1 MORMPWNLQJTSOT-UHFFFAOYSA-L 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- GCCVBRCGRJWMDX-UHFFFAOYSA-N phenoxybenzene;sodium Chemical compound [Na].C=1C=CC=CC=1OC1=CC=CC=C1 GCCVBRCGRJWMDX-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000197194 Bulla Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 208000002352 blister Diseases 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Abstract
The invention provides a high-alcohol emulsion type antifoaming agent for a low-temperature paper making system. The antifoaming agent comprises the components of high alcohol, a nonionic surfactant, an anionic surfactant, high alcohol polyether ester, a wax-shaped substance, a thickening agent and water. In the invention, after the high alcohol polyether ester is introduced, the problem that the antifoaming effect of the high alcohol emulsion is poor under a low temperature condition is solved, thus the high alcohol emulsion can keep outstanding antifoaming performance under the low temperature paper making system, and the storage stability of the high alcohol emulsion can also be enhanced.
Description
Technical field
The present invention relates to a kind of paper industry and copy paper system defoamer, be under the jurisdiction of technical field of fine chemical preparations.
Technical background
Paper industry comprises slurrying, copies the operations such as paper and coating.Because various impacts with surface-active auxiliary agent in the wet end chemistry, be easy in water, produce the foam of a large amount of difficult eliminations, simultaneously, contained various string hydroxyls in the pulping raw material, be easy to make fiber surface and inner absorption to be difficult to remove the tiny bubble foam with common defoamer in a large number, have a strong impact on the quality of subsequent handling and product, therefore, the selection of defoamer and use, particularly important for machine hand's order.
The Main Function of defoamer for papermaking is that the bubble that will be adsorbed on the fiber fines is first peeled away, and then so that minute bubbles gather into bulla floats on the liquid level, the bubble vacuolar membrane attenuation on the last water surface is finally broken.The paper of copying of existing better performances is generally the higher alcohols emulsion defoamer with defoamer, take higher alcohols as main active, forms emulsion oil-in-water by emulsifying process.For example, US4976888 discloses a kind of higher alcohols emulsion defoamer that is comprised of higher alcohols, high-carbon alcohol ester, high boiling aliphatic hydrocarbon, Tissuemat E and emulsifying agent; US5679286 discloses a kind of higher alcohols emulsion defoamer that is comprised of higher alcohols, letones and emulsifying agent; US430359 discloses a kind of higher alcohols emulsion defoamer that is comprised of higher alcohols, aliphatic acid and saponified emulsifier; EP0149812 discloses a kind of higher alcohols emulsion defoamer that is comprised of higher alcohols, high-carbon alcohol ester, higher boiling aliphatic hydrocarbon, water-soluble acrylic (acrylamide) polymer and emulsifying agent; CA02493055 discloses a kind of higher alcohols emulsion defoamer that is comprised of higher alcohols, polyglycereol stearate, mineral oil, the two stearic amides of ethylenediamine, fatty acid ester and emulsifying agent.
Although present papermaking technology constantly promotes, the water temperature of plain boiled water is also on the rise, but because China is vast in territory, north-south climate differs greatly, cause in the winter time under the environment, the water temperature when Some Enterprises is copied paper is on the low side, existing higher alcohols emulsion defoamer, therefore can not adapt to the bubbling system under the low temperature, disappear and press down the bubble ability and become relatively poor.Simultaneously, because emulsion is non-stability system at thermodynamics, the higher alcohols emulsion defoamer is through long term storage or more likely occur easily being separated after the long term storage under the low temperature, thereby affects the use of defoamer.
The inventor by to wherein adding the higher alcohols polyether ester, can effectively solve the problem of the froth breaking variation of higher alcohols emulsion under cryogenic conditions through a large amount of experimental study and the field, has also strengthened the storage stability of higher alcohols emulsions simultaneously.
Summary of the invention
The objective of the invention is: provide a kind of under cryogenic conditions the good higher alcohols emulsion-type defoamer for papermaking of antifoam performance, its bin stability is good, preparation condition is gentle.
Antifoaming agent for low-temperature paper making system of the present invention is grouped into by following several one-tenth:
(1) higher alcohols.The higher alcohols that are suitable for defoamer of the present invention comprise carbon number be 12～28 monobasic to trihydroxylic alcohol, the higher alcohols of patent of the present invention are selected from dodecanol, tetradecanol, hexadecanol, octadecanol, eicosanol, tadenan, the pure and mild n-octacosanol of lignocerane.These alcohol use separately or multiple alcohol mixing is used.
(2) non-ionic surface active agent.General structure is as follows:
R
1O(EO)
mH
R wherein
1For carbon number is 8～28 alkyl, m is 10～60 integer.Take the consumption of higher alcohols as 100 parts by mass, then the consumption of non-ionic surface active agent is 0.01～10 part.
(3) anion surfactant.The froth breaking active component is dispersed in water, forms O/W type emulsion.Because it has stronger electric charge, therefore, be adsorbed on the mixed fatty alcohol microparticle surfaces after, can be so that the fatty alcohol particulate has stronger electric charge, thus stop the gathering of particle.Its structural formula is as follows:
R in the formula
2Saturated alkyl for carbon number 8～20.Take the consumption of higher alcohols as 100 parts by mass, then the consumption of emulsifying agent is 0.01～5 part.
(4) higher alcohols polyether ester.Described higher alcohols polyether ester represents with following structural formula:
R
3O(EO)
x(PO)
yCOR
4
R wherein
3For carbon number is 12～24 alkyl, x is 0～10 integer, and y is 1～30 integer; R
4For carbon number is 8～20 alkyl, take the consumption of higher alcohols as 100 parts by mass, the consumption of shellfish higher alcohols polyether ester is 10～50 parts.
(5) wax.Wax among the present invention is selected from paraffin, montan wax, microwax, Brazil wax, oxidized polyethlene wax, husky rope Fischer-Tropsch wax, Tissuemat E and beeswax.Take the consumption of higher alcohols as 100 parts by mass, then the consumption of wax is 16～40 parts.
(6) thickener.The effect of thickener is the stability that improves emulsion.Thickener of the present invention comprises xanthan gum, guar gum, polyvinyl alcohol, sodium carboxymethylcellulose, hydroxyethylcellulose and esters of acrylic acid, is preferably esters of acrylic acid, and its consumption is adjusted according to the required viscosity of reality.
(7) water.The consumption of water determines the solid content of final products, and final solid content is controlled at 0.1～35% for good, preferred 30%.
Said components is prepared the higher alcohols emulsion defoamer as follows: higher alcohols, non-ionic surface active agent, anion surfactant, higher alcohols polyether ester, wax are mixed, be warming up to 70～95 ℃; 70～95 ℃ water are slowly added said mixture, then by the further emulsification of high speed shear, replenish again suitable quantity of water to desired concn; At last, add thickener, be adjusted to required viscosity and get final product.
The specific embodiment
Embodiment 1
With 16 parts of octadecanols, 6 parts of Brazil waxs, 6 parts of higher alcohols polyether ester (C
12H
26O (EO)
1(PO)
30COC
9H
19), 1 part of non-ionic surface active agent (C
12H
26O (EO)
40H), 1 part of anion emulsifier (disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate) adds reactor, mix being warming up to 70 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Embodiment 2
With 20 parts of eicosanols, 4 parts of microwaxes, 4 parts of higher alcohols polyether ester (C
16H
34O (EO)
5(PO)
20COC
13H
27), 1 part of non-ionic surface active agent (C
16H
34O (EO)
20H), 1 part of anion emulsifier (octyl group diphenyl ether sodium disulfonate) adds reactor, mix being warming up to 85 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Embodiment 3
With 18 parts of tetracosanols, 6 parts of Tissuemat Es, 4 parts of higher alcohols polyether ester (C
22H
46O (EO)
9(PO)
8COC
15H
31), 1 part of non-ionic surface active agent (C
20H
42O (EO)
60H), 1 part of anion emulsifier (cetyl diphenyl ether sodium disulfonate) adds reactor, mix being warming up to 90 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Embodiment 4
With 10 parts of octadecanols, 6 parts of tadenans, 6 parts of paraffin, 6 parts of higher alcohols polyether ester (C
14H
30O (EO)
9(PO)
2COC
19H
37), 1 part of non-ionic surface active agent (C
14H
30O (EO)
40H), 1 part of anion emulsifier (disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate) adds reactor, mix being warming up to 95 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Embodiment 5
With 10 parts of hexadecanols, 10 parts of eicosanols, 4 parts of Brazil waxs, 2 parts of higher alcohols polyether ester (C
20H
42O (EO)
7(PO)
10COC
11H
23), 1 part of non-ionic surface active agent (C
18H
38O (EO)
20H), 1 part of anion emulsifier (myristyl diphenyl ether sodium disulfonate) adds reactor, mix being warming up to 80 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Embodiment 6
With 8 parts of eicosanols, 10 parts of n-octacosanols, 4 parts of paraffin, 6 parts of higher alcohols polyether ester (C
18H
38O (EO)
3(PO)
16COC
17H
35), 1 part of non-ionic surface active agent (C
22H
46O (EO)
60H), 1 part of anion emulsifier (octadecyl diphenyl ether sodium disulfonate) adds reactor, mix being warming up to 90 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Comparative Examples 1
With 10 parts of eicosanols, 12 parts of tadenans, 6 parts of microwaxes, 1 part of non-ionic surface active agent (C
8H
18O (EO)
60H), 1 part of anion emulsifier (disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate) adds reactor, mix being warming up to 87 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Comparative Examples 2
With 20 parts of octadecanols, 8 parts of Tissuemat Es, 1 part of non-ionic surface active agent (C
12H
26O (EO)
40H), 1 part of anion emulsifier (octyl group diphenyl ether sodium disulfonate) adds reactor, mix being warming up to 90 ℃, after stirring, add 70 parts 75 ℃ water, obtain emulsion by high-speed shearing equipment, add the acrylic ester thickener adjusting viscosity, obtain defoamer.
Performance test:
Defoamer in embodiment and the Comparative Examples is tested as follows:
1, viscosity test
Adopt NDJ-8 type viscosity apparatus to carry out viscosity test.Measure in the emulsion certain hour 20 ℃ and 40 ℃ of lower viscosity situations of change of storing.Specifically see Table 1:
The viscosity of table 1 higher alcohols emulsion defoamer
As shown in Table 1, the viscosity that has added the emulsion of part higher alcohols polyether esters changed not obvious in 60 day time, and did not add the emulsion of higher alcohols polyether ester, and it is large that viscosity becomes.
2, the mensuration of antifoaming performance
Key instrument device: Portable circulation bubbling instrument
Test condition: 20 ℃ of temperature, flow 9L/min, defoamer addition: 5ul
Tested media: corrugated paper plain boiled water
Concrete method of testing: the Portable circulation bubbling instrument is cleaned up, the foaming medium that adds ormal weight, be heated to design temperature, the turn-on flow rate pump, setting under the flow, circulation bubbling to foam volume is 300ml, then adds the defoamer sample of ormal weight, and record foam volume V is along with the Changing Pattern of time.Same time inner foam height is lower, and antifoaming performance is better.
Test result is as follows:
The antifoaming performance of table 2 higher alcohols emulsion
By as seen from Table 2, the paper of copying of the present invention's preparation has good antifoaming performance at low temperatures with the higher alcohols emulsion defoamer.
Claims (3)
1. antifoaming agent for low-temperature paper making system is characterized in that consisting of the following composition:
(1), higher alcohols, for carbon number be 12～28 monobasic to trihydroxylic alcohol, described higher alcohols use separately or multiple alcohol mixes and uses;
(2), non-ionic surface active agent, general structure is: R
1O (EO)
m H, wherein R
1For carbon number is 8～28 alkyl,
mIt is 10～60 integer; Take the consumption of higher alcohols as 100 parts by mass, then the consumption of non-ionic surface active agent is 0.01～10 part;
(3), anion emulsifier, its general structure is as follows:
R wherein
2Be the saturated alkyl of carbon number 8～20, take the consumption of higher alcohols as 100 parts by mass, then the consumption of anion emulsifier is 0.01～5 part;
(4) higher alcohols polyether ester, general structure is: R
3O (EO)
x (PO)
y COR
4, R wherein
3It is 12～24 alkyl for carbon number;
xBe 0～10 integer,
yIt is 1～30 integer; R
4It is 8～20 alkyl for carbon number; Take the consumption of higher alcohols as 100 parts by mass, then the consumption of higher alcohols polyether ester is 10～50 parts;
(5) wax is selected from paraffin, montan wax, microwax, Brazil wax, oxidized polyethlene wax, husky rope Fischer-Tropsch wax, Tissuemat E, Carnauba wax and beeswax, and take the consumption of higher alcohols as 100 parts by mass, then the consumption of wax is 16～40 parts;
(6) thickener is selected from xanthan gum, guar gum, polyvinyl alcohol, sodium carboxymethylcellulose, hydroxyethylcellulose and esters of acrylic acid, and its consumption is adjusted according to the required viscosity of reality;
(7) water;
Described antifoaming agent for low-temperature paper making system is prepared by following methods: higher alcohols, non-ionic surface active agent, anion surfactant, higher alcohols polyether ester, wax are mixed, be warming up to 70～95 ℃; 70 ~ 95 ℃ water are slowly added said mixture, then by the further emulsification of high speed shear; Replenish suitable quantity of water to desired concn; At last, add thickener, be adjusted to required viscosity and get final product.
2. a kind of antifoaming agent for low-temperature paper making system as claimed in claim 1, wherein (1) described higher alcohols are selected from dodecanol, tetradecanol, hexadecanol, octadecanol, eicosanol, tadenan, the pure and mild n-octacosanol of lignocerane.
3. a kind of antifoaming agent for low-temperature paper making system as claimed in claim 1, wherein (6) described thickener is esters of acrylic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110178514 CN102242523B (en) | 2011-06-29 | 2011-06-29 | Antifoaming agent for low-temperature paper making system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110178514 CN102242523B (en) | 2011-06-29 | 2011-06-29 | Antifoaming agent for low-temperature paper making system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102242523A CN102242523A (en) | 2011-11-16 |
| CN102242523B true CN102242523B (en) | 2013-05-01 |
Family
ID=44960750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110178514 Active CN102242523B (en) | 2011-06-29 | 2011-06-29 | Antifoaming agent for low-temperature paper making system |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102242523B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102600647B (en) * | 2012-03-29 | 2014-05-07 | 南京四新科技应用研究所有限公司 | Method for preparing stable aliphatic emulsion |
| CN103866610B (en) * | 2014-02-25 | 2016-08-17 | 苏州恒康新材料有限公司 | A kind of paper pulp defoamer and preparation method thereof |
| CN105220488A (en) * | 2015-10-20 | 2016-01-06 | 湖州国信物资有限公司 | A kind of novel polyethylene defoamer and preparation method thereof |
| CN106351064A (en) * | 2016-08-28 | 2017-01-25 | 山东成泰化工有限公司 | Antifoaming agent containing cyclohexane phthalate high alcohol ester |
| CN112023450A (en) * | 2019-06-03 | 2020-12-04 | 武汉秦曹环保科技有限公司 | Special defoaming agent for nuclear power plant and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3744593A1 (en) * | 1987-12-31 | 1989-07-13 | Basf Ag | DECEIVER BASED ON OIL-IN-WATER EMULSIONS |
| CN100427671C (en) * | 2004-12-10 | 2008-10-22 | 曹治平 | Moderate temperature prnited and dyed organosilicon anti-bubbling and its preparing method |
| CN100358607C (en) * | 2005-10-09 | 2008-01-02 | 南京四新科技应用研究所有限公司 | Preparation of highly efficient water phase system non-organic silicon defoaming agent |
| CN101530759B (en) * | 2009-03-11 | 2011-02-09 | 南京四新科技应用研究所有限公司 | Method for dispersing higher fatty alcohol mixture |
| CN101690857B (en) * | 2009-10-10 | 2011-12-28 | 南京四新科技应用研究所有限公司 | Natural high class fatty alcohol emulsion and preparation method thereof |
-
2011
- 2011-06-29 CN CN 201110178514 patent/CN102242523B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102242523A (en) | 2011-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102600647B (en) | Method for preparing stable aliphatic emulsion | |
| CN105148571B (en) | For the preparation method of the defoamer of water-based system | |
| CN102242523B (en) | Antifoaming agent for low-temperature paper making system | |
| CN103641195B (en) | A kind of silicone antifoam agent and preparation method thereof | |
| CN100358607C (en) | Preparation of highly efficient water phase system non-organic silicon defoaming agent | |
| CN101445760A (en) | Method for improving stability of mineral oil defoaming agent | |
| CN101690857B (en) | Natural high class fatty alcohol emulsion and preparation method thereof | |
| CN108744612B (en) | Mineral oil defoaming agent and preparation method thereof | |
| RU2659059C2 (en) | Foam control formulations | |
| EP2991746A1 (en) | Biodiesel-based emulsion defoamer and method for making the same | |
| CN102558937A (en) | Economical coating antifoaming agent | |
| CN104436766B (en) | A kind of silicon composition | |
| JPH06104165B2 (en) | Defoamer based on oil-in-water emulsion | |
| CN100427671C (en) | Moderate temperature prnited and dyed organosilicon anti-bubbling and its preparing method | |
| JPH01210005A (en) | Anti-foaming agent based on o/w emulsion | |
| CN101927139A (en) | Self-emulsifier and use thereof in tertiary oil recovery | |
| CN103669108A (en) | Organic silicon defoamer for paper making industry and preparation method thereof | |
| CN103830937A (en) | Preparation method of stable natural fatty alcohol emulsion | |
| CN111514619A (en) | Water-based foam control agent and preparation method thereof | |
| WO1991000763A1 (en) | Low viscosity defoaming/antifoaming formulations | |
| CN107137959B (en) | A kind of preparation method of non-silicon emulsion defoaming agent | |
| CN105273710B (en) | Acidproof defoamer and preparation method thereof | |
| CN101003008A (en) | Method for enhancing stability of emulsion | |
| JP3656174B2 (en) | Antifoam composition | |
| CN103628353B (en) | A kind of method improving fatty alcohol emulsion stability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 210027, Nanjing, Jiangsu Province, Xiaguan Road, Shimonoseki District No. 199 Zijin venture special community building D11 Applicant after: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City Address before: 306 room 01, 168 Sheng garden, No. 210037 North Central Road, Jiangsu, Nanjing Applicant before: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20111116 Assignee: Chuzhou Sixin Science and Technology Co., Ltd. Assignor: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City Contract record no.: 2013320000267 Denomination of invention: Antifoaming agent for low-temperature paper making system License type: Exclusive License Record date: 20130327 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| C56 | Change in the name or address of the patentee |
Owner name: JIANGSU INSTITUTE OF FOUR NEW TECHNOLOGYAPPLICATIO Free format text: FORMER NAME: SIXIN SCIENCE + TECHNOLOGY APPLIED INST. CO., LTD., NANJING CITY |
|
| CP03 | Change of name, title or address |
Address after: 210027 Gulou District, Nanjing Province, east of the East Wing Road, No. 199 Zijin (Shimonoseki) science and technology venture special community D11 block Patentee after: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Address before: 210027, Nanjing, Jiangsu Province, Xiaguan Road, Shimonoseki District No. 199 Zijin venture special community building D11 Patentee before: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Antifoaming agent for low-temperature paper making system Effective date of registration: 20151103 Granted publication date: 20130501 Pledgee: Bank of Nanjing, Zhujiang branch, Limited by Share Ltd Pledgor: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Registration number: 2015990000946 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 210027 A22, 199 shogundong Road, Gulou District, Nanjing, Jiangsu. Patentee after: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Address before: 210027 Nanjing, Jiangsu, Gulou District, No. 199 shogundong Road, purple gold (Xiaguan) technology entrepreneurship special community D11 Patentee before: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. |