CN102240604B - Method for using collecting agent prepared from drainage oil for flotation and defluorination of iron ores - Google Patents
Method for using collecting agent prepared from drainage oil for flotation and defluorination of iron ores Download PDFInfo
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- CN102240604B CN102240604B CN 201010169973 CN201010169973A CN102240604B CN 102240604 B CN102240604 B CN 102240604B CN 201010169973 CN201010169973 CN 201010169973 CN 201010169973 A CN201010169973 A CN 201010169973A CN 102240604 B CN102240604 B CN 102240604B
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- collecting agent
- flotation
- waste oil
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- iron ore
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 138
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 84
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 69
- 238000005188 flotation Methods 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000006115 defluorination reaction Methods 0.000 title abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims description 43
- 239000012141 concentrate Substances 0.000 claims description 39
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 29
- 239000000194 fatty acid Substances 0.000 claims description 29
- 229930195729 fatty acid Natural products 0.000 claims description 29
- 150000004665 fatty acids Chemical class 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 22
- 239000003112 inhibitor Substances 0.000 claims description 18
- 235000019353 potassium silicate Nutrition 0.000 claims description 17
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 17
- 230000007062 hydrolysis Effects 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 229920002472 Starch Polymers 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 10
- 230000035484 reaction time Effects 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 239000012190 activator Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000000605 extraction Methods 0.000 claims description 9
- 239000000413 hydrolysate Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 8
- 239000001110 calcium chloride Substances 0.000 claims description 8
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 8
- 238000000746 purification Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 235000021393 food security Nutrition 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000007667 floating Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 42
- 235000019198 oils Nutrition 0.000 description 42
- 230000000694 effects Effects 0.000 description 25
- 238000003756 stirring Methods 0.000 description 23
- 229910052500 inorganic mineral Inorganic materials 0.000 description 16
- 239000011707 mineral Substances 0.000 description 16
- 230000009471 action Effects 0.000 description 14
- 239000004088 foaming agent Substances 0.000 description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 9
- 238000006477 desulfuration reaction Methods 0.000 description 9
- 230000023556 desulfurization Effects 0.000 description 9
- 239000011737 fluorine Substances 0.000 description 9
- 229910052731 fluorine Inorganic materials 0.000 description 9
- 238000007885 magnetic separation Methods 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- 238000011084 recovery Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- -1 Fatty acid compound Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000003784 tall oil Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000007790 scraping Methods 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- 241001251949 Xanthium sibiricum Species 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 229910052836 andradite Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052614 beryl Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- ZXOKVTWPEIAYAB-UHFFFAOYSA-N dioxido(oxo)tungsten Chemical compound [O-][W]([O-])=O ZXOKVTWPEIAYAB-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention relates to a method for using a collecting agent prepared from drainage oil for the flotation and the defluorination of iron ores, wherein a preparation process of the collecting agent comprises the following steps of: (a) purifying the drainage oil; and (b) carrying out hydrolysis reaction on the purified drainage oil obtained from the step (a) to obtain the collecting agent used for floating ores. When the collecting agent used by the invention and prepared from the drainage oil is used for the defluorination of floated iron ores, the selectivity of the collecting agent can be enhanced, and the technical indicator and the economic indicator of the flotation are enhanced favorably; and in addition, because a raw material used for the preparation of the collecting agent is the drainage oil, the technical scheme provided by the invention has important significance on the aspects of preventing environmental pollution, simplifying production process, reducing food security threat, and the like.
Description
Technical field
The invention belongs to the collecting agent field of flotation of ores, particularly relate to the method that a kind of collecting agent with the waste oil preparation is used for the iron ore flotation defluorinate.
Background technology
Fatty acid compound has important application as collecting agent in the flotation of mineral, fatty-acid collector commonly used comprises higher fatty acids and sodium salt thereof, for example: oleic acid, enuatrol, and the product that contains multiple fatty acid composition that from animals and plants and PETROLEUM PROCESSING byproduct, papermaking wastewater, extract, such as animal, plant fatty acid (soap), aphthenic acids (soap), oxidized paraffin wax (soap), tall oil (soap) and purified product thereof.
Because aliphatic acid has very active carboxyl functional group, so can carry out flotation to a lot of mineral.Fatty acid compound is widely used in the flotation of mineral for a long time as the anion collecting agent.But the mineral of its flotation mainly contain: 1. alkaline-earth metal salt mineral, such as scheelite, fluorite, iron ore, barite etc.; 2. metal oxide-type mineral are such as bloodstone, pyrolusite, cassiterite, wolframite, ilmenite etc.; 3. transition metal oxyacid salt mineral are such as malachite, chessy copper, smithsonite etc.; 4. silicate mineral is such as beryl, spodumene, zircon, andradite, tourmaline etc.
Fatty acid collecting agent is mainly synthetic by chemical method, China just is used for oxide ore flotation with soybean oil, camphor seed oil, achene of Siberian cocklebur wet goods vegetable oil raw materials through processing the synthetic fatty acid collecting agent in research as far back as five sixties of twentieth century, because there is lack of raw materials for it, research uses the tal fibre wet goods as the collecting agent of oxide ore flotation then.Tall oil is the byproduct that obtains in the alkali paper-making process take timber as raw material, only has pine alkali paper-making factory that production is just arranged.Owing to be subject to the impact that country limits disafforestation and closes little paper mill policy, the raw material sources of tall oil are relatively more nervous.And the paper mill is for number one, turns to gradually to produce refining tall oil and wait the industrial chemicals sale as making lacquer, and this has all limited the tal fibre oil supplying.The seventies and eighties, many to microorganism petro-jelly fermentation synthetic fatty acid research and comparison.After the nineties, advance by leaps and bounds about the research and development of fatty-acid collector, various aliphatic acid arise at the historic moment under the condition of different compound, modifications.Some scholar has carried out the research with raw material synthetic fatty acid collecting agents such as oil foot or petroleum by-products.
But present fatty acid collecting agent shortcoming also clearly, mainly is the poor selectivity to mineral, and reagent consumption is large; The solubility of medicament is low, in water, disperse bad, the collecting poor performance, the actual use needs emulsification often; Not anti-hard water; Flotation effect was bad when temperature was low, so that the flotation of need to heating; Need simultaneously to select gangue mineral inhibitor etc. during application.
Because the present employed normal fat acids of ore dressing collecting agent is poor selectivity at normal temperatures, wanting to obtain preferably effect has to ore pulp is heated to and carries out flotation more than 30 ℃, need to set up the device to warming up pulp, so just produce the very high expense of heating, increase the flotation cost.
Patent CN1031490A discloses a kind of collecting agent that utilizes the flotation oxide ore that waste material that refined plant when oil abandon makes for raw material, the employed raw material of the preparation of this collecting agent is the waste material of refined plant oil, the composition structure of aliphatic acid is not ideal enough in the raw material, and the flotation temperature of flotation mineral is higher.
Patent CN1097152A discloses a kind of flotation effect that synergist promotes fatty-acid collector of using, and still uses the cost that synergist can increase collecting agent.
Patent CN1343531A discloses a kind of preparation method of floatation catcher of iron ore, this patent disclosure be that croude fatty acids or fatty acid mixed are the collecting agent of base stock preparation, because the restriction of raw material, the kind of aliphatic acid formation is unreasonable in its product, and is not ideal enough on performance.
We know that the harm of waste oil is very large, are present class municipal refuses in the urgent need to address, and utilization of the present invention oil and fat preparation has wherein become collecting agent.The key technical problem that the present invention solves is to utilize the collecting agent of waste oil preparation for the flotation defluorination process of iron ore, play and reduce the double effects that pollutes and fully utilize, and promoting bargh to reduce beneficiation cost, the collecting agent of the present invention's preparation can obtain good index during to iron ore flotation at normal temperatures.
Through consulting amount of literature data, the fatty acid mixed of preparation is not also studied report at present as collecting agent take waste oil as raw material.The collecting agent that the present invention prepares take waste oil as raw material is functional, the existing a lot of defectives of fatty acid mixed collecting agent of the prior art have been overcome, can substitute existing fatty acid collecting agent, and application of the present invention can take full advantage of the waste oil of threatening environment and food security, realized the comprehensive regulation to environment.
Summary of the invention
The collecting agent that the invention provides a kind of preparation take waste oil as raw material is used for the method for iron ore flotation defluorinate, the method comprises that the collecting agent of the preparation take waste oil as raw material is used for the step of iron ore flotation defluorinate, and wherein collecting agent prepares by the hydrolysis of waste oil.
Preferably, the preparation of collecting agent comprises the steps:
(a) waste oil is carried out purification;
The reaction that is hydrolyzed of the waste oil of the purification that (b) a step is obtained namely obtains the collecting agent for the flotation mineral.
In the said method, selective hydrolysis is macromolecule alkali for hydrolysis, and preferable reaction temperature is 50-90 ℃, and the reaction time is preferably 30-90 minute.
In the said method, basic hydrolysis is preferably NaOH or potassium hydroxide hydrolysis.The consumption of alkali is preferably the 1-5% of waste oil quality.
Preferably, the preparation of collecting agent comprises the steps:
The waste oil of purification is carried out basic hydrolysis, and reaction temperature is 50-90 ℃, and the reaction time is 30-90 minute, after hydrolysis finishes, with resulting hydrolysate cooling, uses the organic extract liquid extraction, and it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1: 0.1-10.
That abandon when waste oil generally refers to the processed food such as hotel, restaurant, factory, family and discarded edible oil and fat discharging, be commonly called as hogwash fat, swill oil, also comprise the oil slick that enters in sewer, the cesspool, or repeatedly fry in shallow oil, exploded the grease (old oil) etc. of food.
In the said method, preferred purifying step comprises centrifugal removal suspension, adds certain water and removes the colloidality material, drying and dehydrating, carclazyte decolouring;
In the said method, basic hydrolysis is preferably NaOH or potassium hydroxide hydrolysis.
In the said method, organic extract liquid preferably can be from mixture the organic solvent of the saponified and unsaponifiable matter of extracting and demixing, be preferably benzinum;
In the said method, acid solution is any solution that can generate with saponified reaction aliphatic acid, and this acid solution is preferably hydrochloric acid solution or sulfuric acid solution.
Preferably, the preparation of collecting agent comprises the steps:
With the waste oil purification, then add alkali and be hydrolyzed, reaction temperature is that 50-90 ℃, reaction time are that 50-70 minute, alkali consumption are the 1-5% of waste oil quality, after resulting hydrolysate cooling, the extraction of use organic extract liquid, it is unsaponifiable matter at the middle and upper levels, lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1 in the product: 0.1-10 namely obtains collecting agent.
Preferably, the collecting agent of the application preparation take waste oil as raw material of the present invention comprises the steps: for the method for iron ore flotation defluorinate
To iron ore roughly select, selected and scan in step or a multistep, each step can be carried out 1 time or be repeated 1-6 time, wherein roughly select, selected and scan in each step adopt direct flotation or each to go on foot the employing reverse flotation,
Direct flotation comprises the steps:
Ore pulp to iron ore adds the pH values of pulp adjusting agent, adds any step or two steps in the inhibitor, adds afterwards collecting agent, then inflates, scrapes bubble, obtains froth pulp concentrate and bottom land product mine tailing.
Reverse flotation comprises the steps:
Add inhibitor, add any step or two steps in the activator to the iron ore ore pulp, add afterwards collecting agent, then inflate, scrape bubble, obtain froth pulp mine tailing and bottom land product concentrate;
Wherein inhibitor is preferably one or more in pyrophosphoric acid, waterglass, starch, sodium lignosulfonate, the CMS; Activator is preferably calcium chloride; The pH values of pulp adjusting agent is preferably sodium carbonate.
More preferably, the pH values of pulp adjusting agent is sodium carbonate in the direct flotation step, and inhibitor is pyrophosphoric acid;
More preferably, inhibitor is waterglass, sodium lignosulfonate, CMS in the reverse flotation step;
More preferably, inhibitor is pyrophosphoric acid, waterglass, starch in the selected step; Activator is calcium chloride;
More preferably, scan that the pH values of pulp adjusting agent is sodium carbonate in the step, inhibitor is sodium lignosulfonate;
Preferably, selected comprising the steps:
Add successively inhibitor in the concentrate that obtains to flotation, add any step or two steps in the collecting agent, then inflate, scrape bubble, bubble is directly inflated, scraped to the concentrate that perhaps flotation is obtained;
Preferably, scan and comprise the steps:
Add successively the pH values of pulp adjusting agent in the mine tailing that obtains to flotation, add inhibitor, add any step or the multistep in the collecting agent, then inflate, scrape bubble;
Wherein the preparation of collecting agent comprises the steps:
The waste oil of purification is hydrolyzed, and reaction temperature is 50-90 ℃, and the reaction time is 30-90 minute, after hydrolysis finishes, with resulting hydrolysate cooling, uses the organic extract liquid extraction, and it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1 in the product: 0.1-10.
Preferred purifying step comprises centrifugal removal suspension, adds certain water and removes the colloidality material, drying and dehydrating, carclazyte decolouring;
Hydrolysis is preferably NaOH or potassium hydroxide hydrolysis.
Organic extract liquid preferably can be from mixture the organic solvent of the saponified and unsaponifiable matter of extracting and demixing, be preferably benzinum;
Acid solution is any solution that can generate with saponified reaction aliphatic acid, and this acid solution is preferably hydrochloric acid solution or sulfuric acid solution.
Preferably, the preparation of collecting agent comprises the steps:
With the waste oil purification, then add alkali and be hydrolyzed, reaction temperature is that 50-90 ℃, reaction time are that 50-70 minute, alkali consumption are the 1-5% of waste oil quality, after resulting hydrolysate cooling, the extraction of use organic extract liquid, it is unsaponifiable matter at the middle and upper levels, lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1 in the product: 0.1-10 namely obtains collecting agent.
The collecting agent of using the preparation take waste oil as raw material of the present invention is used for can carrying out magnetic separation to mineral before the iron ore flotation defluorinate, the operations such as desulfurization, and then carry out flotation defluorinate step.
Beneficial effect
Collecting agent take waste oil as raw material production among the present invention is used for the iron ore flotation defluorinate at normal temperatures can reach preferably technical indicator, and can greatly reduce the loss of concentrate, improves the rate of recovery.This is conducive to save energy and reduce the cost, reduce the production cost of Mineral Processing Enterprises, improve the competitiveness of mineral processing in China enterprise, broken away from the past domestic ore such as iron ore and caused complex treatment process because grade is low, thereby cause cost higher, with the competition of Ore Imported in the disadvantage that is in a disadvantageous position.
Collecting agent production of the present invention with use in directly do not contact with human body, reduced the possibility that health is impacted, promote product and dominate the market on resistance also less.Fatty acid mixed collecting agent remaining in the ore dressing process finally is discharged into Tailings Dam, focuses on easily, perhaps with concentrate, can produce secondary pollution hardly.
From the pollution control angle, the present invention has proposed the fatty acid mixed collectors application of the preparation take waste oil as raw material innovatively in the iron ore flotation defluorinate.Use this series products, can farthest utilize the useful component in the waste oil, the collecting agent of producing is used for iron ore flotation can reach good technical indicator, does not particularly have new pollution sources to produce in the whole technique, has realized the double effects of pollution control and comprehensive utilization.The present invention can promote to realize pollution control and the comprehensive utilization of waste oil, benefits the whole society.
The collecting agent for preparing take waste oil as raw material among the present invention has further improved the technical indicator to the iron ore flotation defluorinate, is conducive to realize the more application of popularity.Therefore, the present invention is for avoiding environmental pollution, and it is all significant to improve the aspects such as mineral floating index, simplification production technology and the threat of minimizing food security.
The specific embodiment
In order to understand the present invention, the below further specifies the present invention with embodiment, but is not intended to limit protection scope of the present invention.
Embodiment 1 preparation collecting agent I
With the centrifugal removal suspension of waste oil, add a certain amount of water and remove the colloidality material, drying and dehydrating, then carclazyte decolouring adds NaOH and is hydrolyzed, and reaction temperature is that 60-80 ℃, reaction time are that 60 minutes, sodium hydroxide concentration are 2% of waste oil quality, after resulting hydrolysate cooling, use petroleum ether extraction, it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; A certain amount of mass concentration of saponified adding of taking off layer is 10% hydrochloric acid solution, so that the part by weight of fatty acid mixed and mixing-in fat acid sodium-salt is 1: 1 in the product, namely obtains collecting agent I.
Embodiment 2 preparation collecting agent II
With the centrifugal removal suspension of waste oil, add a certain amount of water and remove the colloidality material, drying and dehydrating, then carclazyte decolouring adds NaOH and is hydrolyzed, and reaction temperature is that 50-70 ℃, reaction time are that 70 minutes, sodium hydroxide concentration are 4% of waste oil quality, after resulting hydrolysate cooling, use petroleum ether extraction, it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; A certain amount of mass concentration of saponified adding of taking off layer is 8% hydrochloric acid solution, so that the part by weight of fatty acid mixed and mixing-in fat acid sodium-salt is 1: 10 in the product, namely obtains collecting agent II of the present invention.
Embodiment 3 preparation collecting agent III
With the centrifugal removal suspension of waste oil, add a certain amount of water and remove the colloidality material, drying and dehydrating, then carclazyte decolouring adds NaOH and is hydrolyzed, and reaction temperature is that 70-90 ℃, reaction time are that 30 minutes, sodium hydroxide concentration are 5% of waste oil quality, after resulting hydrolysate cooling, use petroleum ether extraction, it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; A certain amount of mass concentration of saponified adding of taking off layer is 12% hydrochloric acid solution, so that the part by weight of fatty acid mixed and mixing-in fat acid sodium-salt is 10: 1 in the product, namely obtains collecting agent III.
Embodiment 4: use the magnetic separation of iron ore concentrate reverse flotation defluorinate of collecting agent I after to desulfurization
Magnetic separation of iron ore concentrate is after desulfurization, the mass content 63% of iron, the mass content 1.3% of fluorine, carry out on this basis the defluorinate of iron ore concentrate reverse flotation, condition is: pulp density 40%, slurry temperature 20-25 ℃, pH values of pulp is about 8, sample ore stirs in the 0.75L flotation device after the 2min, adds waterglass 2000g/t, pharmacy effect time 3min, then add activator calcium chloride 200g/t, add collecting agent I 300g/t through after the 3min, after pharmacy effect 5min, add No. 2 oily 60g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 3min.Froth pulp is mine tailing, and bottom land is iron ore concentrate.
Carry out selectedly with iron ore concentrate, when selected, experimental condition is: pulp density 40%, slurry temperature 20-25 ℃, sample ore stirs in the 0.75L flotation device after the 3min, adds waterglass 1000g/t, pharmacy effect time 3min, then add collecting agent I 150g/t, after pharmacy effect 4min, add No. 2 oily 30g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 2min.
Obtain best floatation indicators: fluorine grade 0.15% in the iron ore concentrate, iron grade 68.80%, iron recovery reaches 91.12%.
Embodiment 5: use the magnetic separation of iron ore concentrate reverse flotation defluorinate of collecting agent II after to desulfurization
Magnetic separation of iron ore concentrate is after desulfurization, the mass content 63% of iron, the mass content 1.3% of fluorine, carry out on this basis the iron ore concentrate reverse flotation, condition is: pulp density 40%, slurry temperature 20-25 ℃, pH values of pulp is about 8, sample ore stirs in the 0.75L flotation device after the 2min, adds waterglass 2000g/t, pharmacy effect time 3min, then add activator calcium chloride 200g/t, add collecting agent II 300g/t through after the 3min, after pharmacy effect 5min, add No. 2 oily 60g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 3min.Froth pulp is mine tailing, and bottom land is iron ore concentrate.
Carry out selectedly with iron ore concentrate, when selected, experimental condition is: pulp density 40%, slurry temperature 20-25 ℃, sample ore stirs in the 0.75L flotation device after the 3min, adds waterglass 1000g/t, pharmacy effect time 3min, then add collecting agent II 150g/t, after pharmacy effect 4min, add No. 2 oily 30g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 2min.
Obtain best floatation indicators: fluorine grade 0.15% in the iron ore concentrate, iron grade 68.80%, iron recovery reaches 91.12%.
Embodiment 6: use the magnetic separation of iron ore concentrate reverse flotation defluorinate (use starch make inhibitor) of collecting agent I after to desulfurization
Take by weighing in the sodium chloride solution of 20g soluble starch adding 40ml 10%, stir, heat about 40min again in 80-90 ℃ of water-bath, color is milky, finally is diluted to 10% concentration by the starch consumption, is called starch No. 1.
Magnetic separation of iron ore concentrate is after desulfurization, the mass content 63% of iron, the mass content 1.3% of fluorine is carried out the iron ore concentrate reverse flotation on this basis, condition is: pulp density 40%, slurry temperature 20-25 ℃, pH values of pulp is about 8, and sample ore stirs after the 2min in the 0.75L flotation device, add waterglass 2000g/t, then pharmacy effect time 3min adds starch 2000g/t No. 1, stirring action 3min, add again activator calcium chloride 200g/t, add collecting agent I 300g/t through after the 3min, after pharmacy effect 5min, add No. 2 oily 60g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 3min.Froth pulp is mine tailing, and bottom land is iron ore concentrate.
Carry out selectedly with iron ore concentrate, when selected, experimental condition is: pulp density 40%, slurry temperature 20-25 ℃, sample ore stirs in the 0.75L flotation device after the 3min, adds waterglass 1000g/t, pharmacy effect time 3min, then add collecting agent I 150g/t, after pharmacy effect 4min, add No. 2 oily 30g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 2min.
Obtain best floatation indicators: fluorine grade 0.17% in the iron ore concentrate, iron grade 68.50%, iron recovery reaches 95.60%.
Embodiment 7: use collecting agent II to the defluorinate of magnetic separation of iron ore concentrate reverse flotation
Get iron ore concentrate 500g, in the flotation device of 0.75L, stir 2min, add waterglass 2000g/t, after the effect 3min, this moment, slurry pH was 8.21, added collecting agent II 300g/t, abundant effect through 5min medicament and mineral surfaces, add No. 2 oily 60g/t of foaming agent, inflation begins to scrape bubble after the stirring action 1min again, and scraping the bubble time is 3min.Next carry out selected to the bottom land concentrate, flowsheet of slurry agitation adds waterglass 1000g/t after the several seconds, add collecting agent II 150g/t after the stirring action 3min, adds No. 2 oily 40g/t of foaming agent after the stirring action 4min, begin to scrape bubble through inflating the several seconds after the 1min, scraping the bubble time is 2min.Then bottom land is carried out recleaning, flowsheet of slurry agitation adds waterglass 500g/t after the several seconds, add collecting agent II80g/t after the stirring action 3min, adds No. 2 oily 40g/t of foaming agent after the stirring action 4min, begin to scrape bubble through inflating the several seconds after the 1min, scraping the bubble time is 2min.
The final index that obtains is: the fluorine grade drops to 0.25% by 1.36% in the iron ore concentrate, and the iron grade is 68% in the iron ore concentrate, the rate of recovery 82.0% (oxygen is smart result forever); The fluorine grade drops to 0.44% by 1.80% in the iron ore concentrate, and the iron grade is 65.50% in the iron ore concentrate, the rate of recovery 81.72% (magnetic is smart result forever)
Embodiment 8: use collecting agent III to the magnetic separation of iron ore concentrate desulfurization after again reverse flotation defluorinate
Iron ore concentrate carries out the defluorinate of iron ore concentrate reverse flotation on this basis after desulfurization, add waterglass 2000g/t, then pharmacy effect time 3min adds starch 2000g/t No. 1, effect 3min, add again activator calcium chloride 200g/t, add collecting agent III 300g/t through after the 3min, after pharmacy effect 5min, add No. 2 oily 60g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 3min.Froth pulp is mine tailing, and bottom land is iron ore concentrate.Next iron ore concentrate carries out selected, ore pulp adds waterglass 1000g/t after the several seconds stirs, pharmacy effect time 3min, then add collecting agent III 150g/t, after pharmacy effect 4min, add No. 2 oily 30g/t of foaming agent, stirring action 1min, then inflate 20s, begin to scrape bubble, scrape bubble time 2min.
Obtain best floatation indicators: fluorine grade 0.15% in the iron ore concentrate, iron grade 68.95%, iron recovery reaches 95.80%.
Above embodiment shows that the collecting agent of waste oil preparation of the present invention has solved originally the technical problem of invention when Iron Ore Flotation stone, realized technique effect of the present invention.
Purposes of the present invention and method are described by specific embodiment.Those skilled in the art can use for reference the links such as content appropriate change raw material of the present invention, process conditions and realize corresponding other purpose, its relevant change does not all break away from content of the present invention, all similar replacements and change will become apparent to those skilled in the art that and all be deemed to be included within the scope of the present invention.
Claims (10)
1. the collecting agent of the preparation take waste oil as raw material is used for the method for iron ore flotation defluorinate, the method comprises that the collecting agent of the preparation take waste oil as raw material is used for the step of iron ore flotation defluorinate, wherein collecting agent prepares by the hydrolysis of waste oil, it is characterized in that the preparation of collecting agent comprises the steps:
The waste oil of purification is hydrolyzed, and reaction temperature is 50-90 ℃, and the reaction time is 30-90 minute, after hydrolysis finishes, with resulting hydrolysate cooling, uses the organic extract liquid extraction, and it is unsaponifiable matter at the middle and upper levels, and lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1: 0.1-10.
2. method according to claim 1, wherein purifying step comprises centrifugal removal suspension, adds certain water and removes the colloidality material, drying and dehydrating, carclazyte decolouring.
3. method according to claim 1 and 2 wherein is hydrolyzed to the hydrolysis of NaOH or potassium hydroxide.
4. method according to claim 1 and 2, wherein organic extract liquid is benzinum;
5. method according to claim 1 and 2, wherein acid solution is hydrochloric acid solution or sulfuric acid solution.
6. each described method according to claim 1 and 2 is characterized in that the preparation of collecting agent comprises the steps:
With the waste oil purification, then add alkali and be hydrolyzed, reaction temperature is that 50-90 ℃, reaction time are that 50-70 minute, alkali consumption are the 1-5% of waste oil quality, after resulting hydrolysate cooling, the extraction of use organic extract liquid, it is unsaponifiable matter at the middle and upper levels, lower floor is saponified; Take off a certain amount of acid solution of saponified adding of layer, so that the mass ratio of fatty acid mixed and mixing-in fat hydrochlorate is 1 in the product: 0.1-10 namely obtains collecting agent.
7. each described method according to claim 1-2, the method that the collecting agent that it is characterized in that the preparation take waste oil as raw material is used for the iron ore flotation defluorinate comprises the steps:
To iron ore roughly select, selected and scan in step or a multistep, each step can be carried out 1 time or be repeated 1-6 time, wherein roughly select, selected and scan in each step adopt direct flotation or each to go on foot the employing reverse flotation.
8. method according to claim 7, wherein inhibitor is one or more in pyrophosphoric acid, waterglass, starch, the sodium lignosulfonate; Activator is calcium chloride; The pH values of pulp adjusting agent is sodium carbonate.
9. method according to claim 8, wherein the pH values of pulp adjusting agent is sodium carbonate in the direct flotation step, inhibitor is pyrophosphoric acid; Inhibitor is waterglass, sodium lignosulfonate, CMS in the reverse flotation step; Inhibitor is pyrophosphoric acid, waterglass, starch in the selected step; Activator is calcium chloride; Scan that the pH values of pulp adjusting agent is sodium carbonate in the step, inhibitor is sodium lignosulfonate.
10. method according to claim 7, wherein
Selected comprising the steps:
Add successively inhibitor in the concentrate that obtains to flotation, add any step or multistep in the collecting agent, then inflate, scrape bubble, bubble is directly inflated, scraped to the concentrate that perhaps flotation is obtained;
Scan and comprise the steps:
Add successively the pH values of pulp adjusting agent in the mine tailing that obtains to flotation, add inhibitor, add any step or the multistep in the collecting agent, then inflate, scrape bubble.
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| CN104190549A (en) * | 2014-09-03 | 2014-12-10 | 鞍钢集团矿业公司 | Composite inhibitor for reverse flotation of hematite |
| CN105537003B (en) * | 2015-12-11 | 2018-02-13 | 中国地质科学院矿产综合利用研究所 | Drainage oil type collophanite reverse flotation collecting agent and preparation method thereof |
| CN107185720B (en) * | 2017-06-21 | 2020-02-07 | 湖北宜化江家墩矿业有限公司 | Collophanite collecting agent produced by modified illegal cooking oil |
| CN114632628A (en) * | 2020-12-16 | 2022-06-17 | 中国科学院过程工程研究所 | Gasification slag decarburization flotation synergist and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4203837A (en) * | 1976-01-16 | 1980-05-20 | Hoge John H | Process for removal of discrete particulates and solutes from liquids by foam flotation |
| CN1031490A (en) * | 1987-08-22 | 1989-03-08 | 化学工业部化学矿产地质研究院 | A kind of collecting agent and manufacture method thereof and purposes |
| CN1182641A (en) * | 1996-11-19 | 1998-05-27 | 包钢矿山研究所 | Anion type collector and preparing method and usage thereof |
| CN1775371A (en) * | 2005-12-07 | 2006-05-24 | 冯国臣 | Sulfogen ore impurity-removing, purifying and flotation process |
| CN101130181A (en) * | 2006-08-25 | 2008-02-27 | 博兴华润油脂化学有限公司 | Trapping agent for floatation of iron ore and method of producing the same |
| CN101462938A (en) * | 2008-12-12 | 2009-06-24 | 中南大学 | Method for preparing mixed fatty acid from hogwash oil and use method of mixed fatty acid |
-
2010
- 2010-05-12 CN CN 201010169973 patent/CN102240604B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4203837A (en) * | 1976-01-16 | 1980-05-20 | Hoge John H | Process for removal of discrete particulates and solutes from liquids by foam flotation |
| CN1031490A (en) * | 1987-08-22 | 1989-03-08 | 化学工业部化学矿产地质研究院 | A kind of collecting agent and manufacture method thereof and purposes |
| CN1182641A (en) * | 1996-11-19 | 1998-05-27 | 包钢矿山研究所 | Anion type collector and preparing method and usage thereof |
| CN1775371A (en) * | 2005-12-07 | 2006-05-24 | 冯国臣 | Sulfogen ore impurity-removing, purifying and flotation process |
| CN101130181A (en) * | 2006-08-25 | 2008-02-27 | 博兴华润油脂化学有限公司 | Trapping agent for floatation of iron ore and method of producing the same |
| CN101462938A (en) * | 2008-12-12 | 2009-06-24 | 中南大学 | Method for preparing mixed fatty acid from hogwash oil and use method of mixed fatty acid |
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