CN102240601B - Method for using collector prepared from illegal cooking oil in fluorite flotation - Google Patents
Method for using collector prepared from illegal cooking oil in fluorite flotation Download PDFInfo
- Publication number
- CN102240601B CN102240601B CN2010101699617A CN201010169961A CN102240601B CN 102240601 B CN102240601 B CN 102240601B CN 2010101699617 A CN2010101699617 A CN 2010101699617A CN 201010169961 A CN201010169961 A CN 201010169961A CN 102240601 B CN102240601 B CN 102240601B
- Authority
- CN
- China
- Prior art keywords
- collecting agent
- add
- flotation
- waste oil
- steps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005188 flotation Methods 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 33
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 title claims abstract description 25
- 239000010436 fluorite Substances 0.000 title claims abstract description 25
- 239000008162 cooking oil Substances 0.000 title abstract 6
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 73
- 239000002699 waste material Substances 0.000 claims description 43
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 29
- 239000000194 fatty acid Substances 0.000 claims description 29
- 229930195729 fatty acid Natural products 0.000 claims description 29
- 150000004665 fatty acids Chemical class 0.000 claims description 27
- 238000002360 preparation method Methods 0.000 claims description 26
- 239000000047 product Substances 0.000 claims description 26
- 230000000694 effects Effects 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 22
- 230000007062 hydrolysis Effects 0.000 claims description 17
- 239000003112 inhibitor Substances 0.000 claims description 16
- 239000004115 Sodium Silicate Substances 0.000 claims description 15
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 15
- 239000012141 concentrate Substances 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 12
- 230000035484 reaction time Effects 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 238000000605 extraction Methods 0.000 claims description 9
- 239000000413 hydrolysate Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000000746 purification Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 2
- 229920002521 macromolecule Polymers 0.000 claims description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 235000013305 food Nutrition 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 40
- 235000019198 oils Nutrition 0.000 description 40
- 229910052500 inorganic mineral Inorganic materials 0.000 description 12
- 239000011707 mineral Substances 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 238000007790 scraping Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- -1 Fatty acid compound Chemical class 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000003784 tall oil Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000021393 food security Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- 241001251949 Xanthium sibiricum Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 229910052836 andradite Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052614 beryl Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- ZXOKVTWPEIAYAB-UHFFFAOYSA-N dioxido(oxo)tungsten Chemical compound [O-][W]([O-])=O ZXOKVTWPEIAYAB-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
- 229940070527 tourmaline Drugs 0.000 description 1
- 239000011032 tourmaline Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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- Fats And Perfumes (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010101699617A CN102240601B (en) | 2010-05-12 | 2010-05-12 | Method for using collector prepared from illegal cooking oil in fluorite flotation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010101699617A CN102240601B (en) | 2010-05-12 | 2010-05-12 | Method for using collector prepared from illegal cooking oil in fluorite flotation |
Publications (2)
Publication Number | Publication Date |
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CN102240601A CN102240601A (en) | 2011-11-16 |
CN102240601B true CN102240601B (en) | 2013-11-13 |
Family
ID=44958957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010101699617A Expired - Fee Related CN102240601B (en) | 2010-05-12 | 2010-05-12 | Method for using collector prepared from illegal cooking oil in fluorite flotation |
Country Status (1)
Country | Link |
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CN (1) | CN102240601B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102941159B (en) * | 2012-11-27 | 2014-09-10 | 化工部长沙设计研究院 | Method for extracting borax from mixed salt through reverse flotation |
CN103553905B (en) * | 2013-11-01 | 2015-06-17 | 中南大学 | Unsaturated alicyclic carboxylic acid and preparation method and application thereof |
CN104226487A (en) * | 2014-08-08 | 2014-12-24 | 西北矿冶研究院 | Silicate gangue mineral combination inhibitor |
CN105834009B (en) * | 2016-06-15 | 2018-11-06 | 武汉工程大学 | Fluorite flotation collecting agent based on gutter oil and its preparation method and application |
CN108672097B (en) * | 2018-05-14 | 2020-08-07 | 广东省资源综合利用研究所 | Scheelite collecting agent and preparation method and application thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4203837A (en) * | 1976-01-16 | 1980-05-20 | Hoge John H | Process for removal of discrete particulates and solutes from liquids by foam flotation |
CN1031490A (en) * | 1987-08-22 | 1989-03-08 | 化学工业部化学矿产地质研究院 | A kind of collecting agent and manufacture method thereof and purposes |
CN1150065A (en) * | 1996-04-30 | 1997-05-21 | 冶金工业部马鞍山矿山研究院 | Process for preparing fluorite collector agent |
CN1182641A (en) * | 1996-11-19 | 1998-05-27 | 包钢矿山研究所 | Anion type collector and preparing method and usage thereof |
CN1775371A (en) * | 2005-12-07 | 2006-05-24 | 冯国臣 | Sulfogen ore impurity-removing, purifying and flotation process |
CN101462938A (en) * | 2008-12-12 | 2009-06-24 | 中南大学 | Method for preparing mixed fatty acid from hogwash oil and use method of mixed fatty acid |
-
2010
- 2010-05-12 CN CN2010101699617A patent/CN102240601B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4203837A (en) * | 1976-01-16 | 1980-05-20 | Hoge John H | Process for removal of discrete particulates and solutes from liquids by foam flotation |
CN1031490A (en) * | 1987-08-22 | 1989-03-08 | 化学工业部化学矿产地质研究院 | A kind of collecting agent and manufacture method thereof and purposes |
CN1150065A (en) * | 1996-04-30 | 1997-05-21 | 冶金工业部马鞍山矿山研究院 | Process for preparing fluorite collector agent |
CN1182641A (en) * | 1996-11-19 | 1998-05-27 | 包钢矿山研究所 | Anion type collector and preparing method and usage thereof |
CN1775371A (en) * | 2005-12-07 | 2006-05-24 | 冯国臣 | Sulfogen ore impurity-removing, purifying and flotation process |
CN101462938A (en) * | 2008-12-12 | 2009-06-24 | 中南大学 | Method for preparing mixed fatty acid from hogwash oil and use method of mixed fatty acid |
Also Published As
Publication number | Publication date |
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CN102240601A (en) | 2011-11-16 |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160127 Address after: The south of Guantao County in Hebei province 056000 Handan City, 106 State Road and Handan Jinan railway interchange Patentee after: Hebei harvest Petrochemical Co.,Ltd. Address before: 100083, Beijing, Haidian District Jing Shu Road, No. 2 Business Plaza 603A Patentee before: BEIJING JUNZHIQING SCIENCE AND TECHNOLOGY Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180731 Address after: 100083 room 603A, room 2, Jing Shu Yuan Road, Haidian District, Beijing Patentee after: BEIJING JUNZHIQING SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: 056000 the intersection of Chengnan 106 National Road and Hanji railway in Guantao County, Handan, Hebei. Patentee before: Hebei harvest Petrochemical Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131113 |