CN102230144A - Steels and application thereof - Google Patents

Steels and application thereof Download PDF

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CN102230144A
CN102230144A CN 201110191486 CN201110191486A CN102230144A CN 102230144 A CN102230144 A CN 102230144A CN 201110191486 CN201110191486 CN 201110191486 CN 201110191486 A CN201110191486 A CN 201110191486A CN 102230144 A CN102230144 A CN 102230144A
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steel
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oil
steels
corrosion
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CN102230144B (en
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高光亮
李永安
韩福生
张金中
林继兴
牛丽媛
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RUIZHI STEEL Co.,Ltd.
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Zhejiang Industry and Trade Vocational College
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Abstract

The invention discloses steels, which comprise the following raw material components in percentage by weight: 0.015 to 0.03 percent of carbon element, 8 to 12.0 percent of chromium element, 2.5 to 5.0 percent of manganese element, 0.8 to 2.0 percent of nickel element, 0.15 to 0.50 percent of molybdenum element, 0.20 to 0.80 percent of copper element and 80 to 87.5 percent of ferrum element. In the steels, the mechanical performance of the steels is enhanced, the high medium corrosivity resistance of the steels is improved substantially, and the service life of the steels is prolonged.

Description

A kind of steel and application thereof
Technical field
The present invention relates to the steel field, particularly relate to a kind of steel and application thereof.
Background technology
Oil pipe, oil well casing, sucker rod, oil well pump and the ground transport pipes etc. that use in the oil-gas field well of countries in the world exploitation all stand salt, chlorion, carbonic acid gas, hydrogen sulfide, sulfide, acid, alkali for a long time, contain the strong corrosion of the multiple corrosive mediums such as water of corrosive compound, reach the powerful wearing and tearing of tempering property particulate such as sand grains, therefore, annual consumptions such as oil pipe, oil well casing, sucker rod, oil well pump are all very huge, the cost of winning height, resource, energy consumption are big, are unfavorable for the development of low-carbon (LC) green economy.How to solve the heavy corrosion and the wear problem of oil pipe, oil well casing, sucker rod, oil well pump and the ground transport pipe etc. that use in the oil-gas field well, how to improve and prolong its work-ing life, it is the problem of countries in the world scientific research department research always, address this problem effectively and just seem very necessary, and be imminent.
In recent years, in the countries in the world with the production in oil field, relevant colleges and universities and R﹠D institution and some incorporated businesses of exploitation, carried out number of research projects for the heavy corrosion and the wear problem that how to solve employed oil pipe in the oil-gas field well, oil well casing, sucker rod, oil well pump and ground transport pipe etc., comprised how research improves the bulk properties of material and the reinforcement performance of material surface etc.
Reinforcement aspect of performance on the research material surface, result of study comprise chronizing oil pipe, pulse Vacuum nitrogenize anti-corrosion pumping bar, plate and ooze tungsten-bast alloy anti-corrosive abrasion-proof oil conduit sucker rod (DSW), spraying tungstenalloy anticorrosive abrasion-proof sucker rod, AOC anti-corrosion pumping bar, nano anti-corrosive sucker rod or the like.The common feature of existing these anti-corrosion pumping bars is that top coat is anticorrosion, and as diffusion coating, plating infiltration layer, and sprayed coating is a surface strengthening technology and these coatings all adopt.This anti-corrosion measure can bring good preservative effect and long work-ing life for part, member or the device that bears static load, and can only play preservative activity preferably for bearing the repeated load component in certain working hour.Because the mechanical property of surface anticorrosion coating always there are differences with the mechanical property of bulk material, cause the strain of the strain of adopting top coat rot-resistant component its top layer under the effect of repeated load and body inconsistent, therefore, when load to this type component alternation after effect for some time, coating will crack or peel off with body and come off, at this moment, the corrosion speed of body will significantly be accelerated and occur losing efficacy.Obviously, the bulk properties that improves material solves heavy corrosion and the wear problem that uses in the oil-gas field well, is a kind of both economical and reasonable method approach.
Aspect the bulk properties of research raising material, domestic superstrength, the bainite type, high-strength non-hardened and non-tempered developed once with steel etc., though the mechanical property of material satisfies the service requirements of oil-gas field well, corrosion resistance nature improves little, restricts their large-scale application.In addition, also develop common austenitic stainless steel, it is essential type impregnating material, is widely used in industries such as chemical industry, pharmacy.But, its use range is restricted because its strength property is generally all low than common steel alloy.Once development and production go out the steel alloy of several high-strength corrosion-resistings in earlier 1990s in the U.S., and its performance is very good, but its price is very expensive, are difficult to large-scale popularization application on oil-gas field well development engineering.Generally adopt in the world and add elements such as to improve thermodynamics of alloys Cr, Ni stable and directly retardance anodic process, Mo; as Mo18-Ni40 nickel-base alloy, Ni22-25Cr stainless steel etc.; make the very fast sealer corrosion structure that forms high stable alloy constituent element of material surface with one or several atomic layer level thickness; but; the price of Cr, Ni, Mo element is higher, and add-on surpasses the significantly production cost of increase material of 3%Mo, 5%Ni, 18%Cr.
Oil-gas field wells such as the Cr13 iron of the 10Cr3MoNi of domestic-developed and remodeling, its erosion resistance all is greatly improved with steel than conventional oil gas field wells such as 20CrMoA, but, in multiple corrosive mediums such as sulfide hydrogen, it is poor that its anticorrosion effect just seems, according to SY 5329-1994 " petroclastic rock reservoir water water quality proposed standard " People's Republic of China's oil and gas industry standard, the corrosion speed of 10Cr3MoNi material reaches 0.7634mm/a, and the corrosion speed of the Cr13 material of remodeling reaches 0.2564mm/a.
Summary of the invention
The purpose of this invention is to provide a kind of steel, solved and born under the tension and compression repeated load problem that Corrosion Of Steel is serious in the prior art.
The present invention is achieved through the following technical solutions: a kind of steel, contain following feed composition by weight percentage: 0.015~0.03% carbon, 8.0~12.0% chromium element, 2.5~5.0% manganese element, 0.8~2.0% nickel element, 0.15~0.50% molybdenum element, 0.20~0.80% copper, 80~87.5% ferro element.
Further, above-mentioned steel contain following feed composition by weight percentage: 0.015~0.03% carbon, 9.5~10.5% chromium element, 2.5~3.0% manganese element, 1.2~1.5% nickel element, 0.15~0.50% molybdenum element, 0.20~0.60% copper, 83.87~86% ferro element.
Further, also comprise 0.02~0.10% niobium element in the above-mentioned steel.
Further, also comprise 0.05~0.10% titanium elements in the above-mentioned steel.
Simultaneously, the present invention also provides the application of a kind of above-mentioned steel in the oil-gas field well.
The beneficial effect that the present invention produces is as follows: steel provided by the present invention have not only strengthened the mechanical property of steel, and have improved the high anti-corrosive medium of steel significantly, have prolonged the work-ing life of steel.
Embodiment
Be noted that following detailed description all is exemplary, is intended to the invention provides further instruction.Unless otherwise, all technology used herein and scientific terminology have the identical meanings with general technical staff of the technical field of the invention's common sense.
In a kind of typical embodiment of the present invention, a kind of steel are provided, contain following feed composition by weight percentage: 0.015~0.03% carbon, 8.0~12.0% chromium element, 2.0~5.0% manganese element, 0.8~2.0% nickel element, 0.15~0.50% molybdenum element, 0.20~0.80% copper, 80~87.5% ferro element.
In a kind of preferably embodiment of the present invention, above-mentioned steel contain following feed composition by weight percentage: 0.015~0.03% carbon, 9.5~10.5% chromium element, 2.5~3.0% manganese element, 1.2~1.5% nickel element, 0.15~0.50% molybdenum element, 0.20~0.60% copper, 83.87~86% ferro element.
In a kind of more preferably embodiment of the present invention, above-mentioned well is with also comprising 0.02~0.10% niobium element or 0.05~0.10% titanium elements in the steel.
Titanium or niobium are the strong carbide forming elements, and major function all is crystal grain thinning and forms titanium or the carbide and the nitride of niobium in steel, reduce or avoid deleterious Cr 23C 6The type carbide is separated out, thereby improves the intensity and the solidity to corrosion of steel.
In steel of the present invention, inevitably can there be a part of impurity element, as silicon, sulphur and phosphorus etc.In steel of the present invention siliceous amount mark be controlled at≤0.30%.Three parts silicon is equivalent to a carbon equivalent, needs the siliceous amount mark of strict control.The sulphur massfraction is controlled at≤and 0.004%.Iron sulphide helps galvanic corrosion in the steel, and special anti-H 2 S ability is hanged down an order of magnitude than prior art when smelting.
The phosphorus massfraction is controlled at≤and 0.03%.The massfraction of this part impurity can influence the result of use of steel too much.The strict control of in smelting technology, taking measures.In addition, residual element As, Sn in the steel, Sb, Pb, Bi have considerable influence to well with the performance of steel, corrosion resisting property particularly, in smelting technology, should not bring into or overall control in ppm level level.
Steel preparation method provided by the present invention is identical with method of the prior art, and wherein, the smelting temperature of steel is 1650~1550 ℃, wants strict controlled oxidation system inclusion to effect of material performance in the smelting process of steel.The rolling temperature of steel is 1200~850 ℃, cooling in heap.The thermal treatment temp of steel is 600~720 ℃.Smelt and adopt electric arc furnace refining just that molten steel is provided, with AOD or VOD stove first steel-making water is carried out the oxygen decarburization desulfurization, further alloying is watered ingot after adjusting composition and refinings such as temperature, the degassing.Embryo flaw detection left by milling train, and temperature control control cold rolling becomes section bar, and arrangement is cut scale and become a useful person after the thermal treatment.
Below in conjunction with specific embodiment 1-7 steel of the present invention are described further, and provide according to the prepared steel of embodiment 1-7 and carry out firm toughness and erosion resistance experimental data.
Embodiment 1
Material component: 0.025% carbon, 10.0% chromium element, 2.5% manganese element, 1.5% nickel element, 0.30% molybdenum element, 0.50% copper, all the other are iron.
The preparation method is same as the prior art, and the smelting temperature of steel is 1650~1550 ℃, wants strict controlled oxidation system inclusion to effect of material performance in the smelting process of steel.The rolling temperature of steel is 1200~850 ℃, cooling in heap.The thermal treatment temp of steel is 600~720 ℃.Smelt and adopt electric arc furnace refining just that molten steel is provided, with AOD or VOD stove first steel-making water is carried out the oxygen decarburization desulfurization, further alloying is watered ingot after adjusting composition and refinings such as temperature, the degassing.Embryo flaw detection left by milling train, and temperature control control cold rolling becomes section bar, and arrangement is cut scale and become a useful person after the thermal treatment.
Embodiment 2
Material component: 0.025% carbon, 10.0% chromium element, 2.5% manganese element, 1.5% nickel element, 0.30% molybdenum element, 0.50% copper, 0.05% niobium element, all the other are iron.
The preparation method is with embodiment 1.
Embodiment 3
Material component: 0.025% carbon, 10.0% chromium element, 2.5% manganese element, 1.5% nickel element, 0.30% molybdenum element, 0.50% copper, 0.05% titanium elements, all the other are iron.
The preparation method is with embodiment 1.
Embodiment 4
Material component: 0.015% carbon, 8.0% chromium element, 2.5% manganese element, 0.8% nickel element, 0.15% molybdenum element, 0.20% copper, all the other are iron.
The preparation method is with embodiment 1.
Embodiment 5
Material component: 0.015% carbon, 9.5% chromium element, 2.5% manganese element, 1.2% nickel element, 0.15% molybdenum element, 0.20% copper, all the other are iron.
The preparation method is with embodiment 1.
Embodiment 6
Material component: 0.03% carbon, 12% chromium element, 5.0% manganese element, 2.0% nickel element, 0.5% molybdenum element, 0.80% copper, all the other are iron.
The preparation method is with embodiment 1.
Embodiment 7
Material component: 0.03% carbon, 10.5% chromium element, 3.0% manganese element, 1.5% nickel element, 0.50% molybdenum element, 0.60% copper, all the other are iron.
The preparation method is with embodiment 1.
Test
To test according to the prepared steel of embodiment 1-7, and further steel provided by the present invention be analyzed according to test result.
The mechanical property of materials: according to SY/T 5029-2006 " sucker rod " People's Republic of China's oil and gas industry standard and GB/T 228-2002 " metallic substance tensile test at room temperature method " national standard.Test result sees Table 1.
Table 1. measuring mechanical property result
Figure BDA0000074703960000071
By data in the table 1 as can be known, can meet in SY/T 5029-2006 " sucker rod " People's Republic of China's oil and gas industry standard and GB/T 228-2002 " the metallic substance tensile test at room temperature method " national standard requirement according to the mechanical property of the prepared steel of embodiment of the invention 1-7 about the steel mechanical property.
The Corrosion Protection test: according to SY 5329-1994 " petroclastic rock reservoir water water quality proposed standard " People's Republic of China's oil and gas industry standard, test condition sees Table 2, and test result sees Table 3.
For the Corrosion Protection of the steel of identity basis embodiment of the invention 1-7 made better, two kinds of Comparative Examples are provided below, and under as table 2 test condition, have carried out the Corrosion Protection test respectively.
Table 2 simulation oil field test medium is formed (g/L)
Figure BDA0000074703960000082
Table 3 high-temperature high-pressure anti-corrosive performance test result
Figure BDA0000074703960000091
By data in the table 3 as can be known by the prepared steel of the present invention under the simulation oil field environmental applications, erosion rate is starkly lower than standard value, the weight loss in the use reduces, under equal conditions, steel provided by the present invention can be corrosion-resistant better, wear-resistant, increases its work-ing life.
In sum, steel provided by the present invention have not only strengthened the mechanical property of steel, and have improved the high anti-corrosive medium of steel significantly, have prolonged the work-ing life of steel.
The above is the preferred embodiments of the present invention only, is not limited to the present invention, and for a person skilled in the art, the present invention can have various changes and variation.Within the spirit and principles in the present invention all, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (5)

1. steel, it is characterized in that, contain following feed composition by weight percentage: 0.015~0.03% carbon, 8.0~12.0% chromium element, 2.5~5.0% manganese element, 0.8~2.0% nickel element, 0.15~0.50% molybdenum element, 0.20~0.80% copper, 80~87.5% ferro element.
2. steel according to claim 1, it is characterized in that, contain following feed composition by weight percentage: 0.015~0.03% carbon, 9.5~10.5% chromium element, 2.5~3.0% manganese element, 1.2~1.5% nickel element, 0.15~0.50% molybdenum element, 0.20~0.60% copper, 83.87~86% ferro element.
3. steel according to claim 1 and 2 is characterized in that, also comprise 0.02~0.10% niobium element.
4. steel according to claim 1 and 2 is characterized in that, also comprise 0.05~0.10% titanium elements.
5. one kind as each described steel application in the oil-gas field well of claim 1-4.
CN 201110191486 2010-11-25 2011-07-08 Steels and application thereof Active CN102230144B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102839333A (en) * 2012-09-28 2012-12-26 浙江睿智钢业有限公司 Steel, oil pumping rod containing same and application of steel
CN106011685A (en) * 2016-07-07 2016-10-12 浙江睿智钢业有限公司 High-strength anticorrosive steel and application
CN106734667A (en) * 2016-12-24 2017-05-31 无锡市通亦和精密机械有限公司 A kind of pipe expanding equipment
CN107043896A (en) * 2017-03-04 2017-08-15 蒋培丽 Anticorrosion steel and its forging technology
CN108998747A (en) * 2018-08-17 2018-12-14 南京力同重工机械有限公司 A kind of corrosion-resistant steel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0386728A1 (en) * 1989-03-08 1990-09-12 Nippon Steel Corporation Martensitic stainless steels excellent in corrosion resistance and stress corrosion cracking resistance and method of heat treatment of the steels
JP2000328202A (en) * 1999-05-19 2000-11-28 Sumitomo Metal Ind Ltd Low carbon martensitic stainless steel sheet excellent in formability, corrosion resistance and toughness, its production and welded steel pipe
JP2001179485A (en) * 1999-12-27 2001-07-03 Sumitomo Metal Ind Ltd Martensitic welded stainless steel pipe and producing method therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0386728A1 (en) * 1989-03-08 1990-09-12 Nippon Steel Corporation Martensitic stainless steels excellent in corrosion resistance and stress corrosion cracking resistance and method of heat treatment of the steels
JP2000328202A (en) * 1999-05-19 2000-11-28 Sumitomo Metal Ind Ltd Low carbon martensitic stainless steel sheet excellent in formability, corrosion resistance and toughness, its production and welded steel pipe
JP2001179485A (en) * 1999-12-27 2001-07-03 Sumitomo Metal Ind Ltd Martensitic welded stainless steel pipe and producing method therefor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102839333A (en) * 2012-09-28 2012-12-26 浙江睿智钢业有限公司 Steel, oil pumping rod containing same and application of steel
CN102839333B (en) * 2012-09-28 2014-03-12 浙江睿智钢业有限公司 Steel, oil pumping rod containing same and application of steel
CN106011685A (en) * 2016-07-07 2016-10-12 浙江睿智钢业有限公司 High-strength anticorrosive steel and application
CN106734667A (en) * 2016-12-24 2017-05-31 无锡市通亦和精密机械有限公司 A kind of pipe expanding equipment
CN107043896A (en) * 2017-03-04 2017-08-15 蒋培丽 Anticorrosion steel and its forging technology
CN108998747A (en) * 2018-08-17 2018-12-14 南京力同重工机械有限公司 A kind of corrosion-resistant steel and preparation method thereof

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