CN102228026B - Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates - Google Patents
Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates Download PDFInfo
- Publication number
- CN102228026B CN102228026B CN201110136786.6A CN201110136786A CN102228026B CN 102228026 B CN102228026 B CN 102228026B CN 201110136786 A CN201110136786 A CN 201110136786A CN 102228026 B CN102228026 B CN 102228026B
- Authority
- CN
- China
- Prior art keywords
- careless ether
- benzoates
- pyriftalid
- sulphur
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- -1 pyrimidinyloxy (thio) benzoates Chemical class 0.000 title abstract description 31
- 238000009333 weeding Methods 0.000 title abstract description 7
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 title abstract description 5
- RRKHIAYNPVQKEF-UHFFFAOYSA-N Pyriftalid Chemical compound COC1=CC(OC)=NC(SC=2C=3C(=O)OC(C)C=3C=CC=2)=N1 RRKHIAYNPVQKEF-UHFFFAOYSA-N 0.000 claims abstract description 72
- USSIUIGPBLPCDF-KEBDBYFISA-N pyriminobac-methyl Chemical group CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC USSIUIGPBLPCDF-KEBDBYFISA-N 0.000 claims abstract description 55
- 241000196324 Embryophyta Species 0.000 claims abstract description 39
- 239000000375 suspending agent Substances 0.000 claims abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 21
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 287
- 230000002363 herbicidal effect Effects 0.000 claims description 55
- OCJJVKGBCJDUSA-UHFFFAOYSA-N OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.C1=CN=CN=C1.O.S Chemical class OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.OC(C1=CC=CC=C1)=O.C1=CN=CN=C1.O.S OCJJVKGBCJDUSA-UHFFFAOYSA-N 0.000 claims description 38
- 239000000843 powder Substances 0.000 claims description 25
- 238000009736 wetting Methods 0.000 claims description 22
- 239000004530 micro-emulsion Substances 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
- 241000234653 Cyperus Species 0.000 claims description 6
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- 241000173219 Paspalum distichum Species 0.000 claims description 5
- 244000237956 Amaranthus retroflexus Species 0.000 claims description 2
- 235000013479 Amaranthus retroflexus Nutrition 0.000 claims description 2
- 244000285790 Cyperus iria Species 0.000 claims description 2
- 244000058871 Echinochloa crus-galli Species 0.000 claims description 2
- 241001553700 Euphorbia lathyris Species 0.000 claims description 2
- 241000234642 Festuca Species 0.000 claims description 2
- 244000207740 Lemna minor Species 0.000 claims description 2
- 235000006439 Lemna minor Nutrition 0.000 claims description 2
- 241000091577 Mexicana Species 0.000 claims description 2
- 240000000178 Monochoria vaginalis Species 0.000 claims description 2
- 235000001855 Portulaca oleracea Nutrition 0.000 claims description 2
- 241001290610 Abildgaardia Species 0.000 claims 1
- 244000150195 Cyperus longus Species 0.000 claims 1
- 235000018109 Cyperus longus Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 33
- 239000002552 dosage form Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 description 26
- 239000003814 drug Substances 0.000 description 19
- 241000192043 Echinochloa Species 0.000 description 17
- 239000003995 emulsifying agent Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 230000002528 anti-freeze Effects 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 241000209094 Oryza Species 0.000 description 9
- 210000000481 breast Anatomy 0.000 description 9
- 239000013530 defoamer Substances 0.000 description 9
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 239000000080 wetting agent Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 150000004996 alkyl benzenes Chemical class 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 230000002401 inhibitory effect Effects 0.000 description 6
- 239000000575 pesticide Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 230000003449 preventive effect Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- 229940077388 benzenesulfonate Drugs 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 229920001732 Lignosulfonate Polymers 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000007884 disintegrant Substances 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 231100000572 poisoning Toxicity 0.000 description 4
- 230000000607 poisoning effect Effects 0.000 description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 4
- 229920000053 polysorbate 80 Polymers 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 240000003377 Shepherdia canadensis Species 0.000 description 3
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000012827 research and development Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- 241000234646 Cyperaceae Species 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- 241000400644 Echinochloa oryzicola Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 229940000406 drug candidate Drugs 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000003777 experimental drug Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 description 1
- 239000005564 Halosulfuron methyl Substances 0.000 description 1
- FMGZEUWROYGLAY-UHFFFAOYSA-N Halosulfuron-methyl Chemical group ClC1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC FMGZEUWROYGLAY-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 1
- 235000011999 Panicum crusgalli Nutrition 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 239000012490 blank solution Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000012395 formulation development Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000000442 meristematic effect Effects 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- ONDBSQWZWRGVIL-UHFFFAOYSA-N o-pyrimidin-2-yl benzenecarbothioate Chemical compound C=1C=CC=CC=1C(=S)OC1=NC=CC=N1 ONDBSQWZWRGVIL-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical class [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- HTSABYAWKQAHBT-UHFFFAOYSA-N trans 3-methylcyclohexanol Natural products CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates. The composition is characterized by containing 1-60% of bispyribac-sodium, 1-70% of pyrimidinyloxy (thio) benzoate, auxiliary agents and other excipients. Wherein, the pyrimidinyloxy (thio) benzoates are selected from pyriminobac-methyl and pyriftalid. And the weeding composition can be prepared into the dosage forms of wettable powder, water dispersible granule, suspending agent, suspended emulsion, micron emulsion and emulsion in water. The weeding composition provided in the invention can be used for controlling weeds in paddy fields.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of Herbicidal combinations containing two careless ether and pyrimidine oxygen (sulphur) benzoates, for preventing and treating paddy field weed.
Background technology
The direction of pesticide developing was to embody efficient, low toxicity, low-residual and pollution-free in recent years.Be embodied in pursuit " three height ", (1) is safe, and this not only requires toxicity low, residual low, and nuisanceless; (2) biologically active is high; (3) selectivity is high.Therefore continue to improve the performance of current Pesticidal products, reach efficient, low toxicity, free of contamination requirement.So, select the agricultural chemicals of composite mixture just to become current first-selection and a kind of effective approach, by adjusting the proportioning of different agricultural chemicals, be that the agricultural chemicals of performance complement obtains best synergistic effect.
Two careless ethers (bispyribac-sodium), molecular formula: C
19h
17n
4naO
8, two (4, the 6-SDM base-2-oxygen base) Sodium Benzoates of chemical name: 2,6-.Two careless ether belongs to benzoic acid herbicide, this product is absorbed and is suppressed sour synthesizing of vinegar milk and hindered aminoacid biosynthesis side chain by root leaf. and be selective herbicide, rice direct-seeding Tanaka, use, efficiently, wide spectrum, consumption are extremely low, after this product dispenser, can by the cauline leaf of weeds, be absorbed very soon, and conduct to whole plant, suppress the growth of plant meristematic tissue, thereby kill weeds.
KIH 6127 (pyriminobac-methyl), molecular formula: C
17h
19n
3o
6chemical name: 2-[(4,6-dimethoxypyridin-2-yl) oxygen]-6-[1-(N-methoxyimino) ethyl] methyl benzoate, KIH 6127 is that a kind of inner sucting conduction type specialty of Japanese combinatorial chemistry Co., Ltd. research and development is except barnyard grass agent, belong to pyrimidinylthiobenzoate herbicides, it can pass through cauline leaf and the root absorption of weeds, and conduct to rapidly complete stool, suppress acetolactate synthestase (ALS) and amino acid whose biosynthesis, thereby the cell division in inhibition and obstruction weeds body, weeds are stopped growing, finally make weeds albefaction and withered.
Pyriftalid (pyriftalid), molecular formula: C
15h
14n
2o
4s, belongs to post-emergence herbicide, and its chemical constitution is close with pyrimidine oxybenzene formic acid, and this compounds Main Function is suppress acetolactate synthestase (ALS) synthetic.Be used for preventing and treating paddy field grassy weed and part broad leaved weed, at paddy field, pyriftalid is absorbed by paddy rice root tip, and seldom a part can be transmitted on blade, and the grass cutting blade that small part medicament can be sprouted absorbs.Through toxicity biologic test and field control effectiveness test, result shows that the annual gramineous weed in transplanting rice field, sedge family and part broad leaved weed are had to good control efficiency.
The chemical composition of each weed killer herbicide, formation and physic-chemical property are all distinguishing.Therefore, their herbicide ability and scope are also different.Some weed killer herbicide herbicide spectrum is narrower, but has one's own knack, and can eradicate with other weed killer herbicide and be difficult to the weeds of eliminating.
In recent years, the frequent use of people has concurrently the safety of useful crop and the so-called selective herbicide to the herbicidal effect of undesirable plant, even but there is the weed killer herbicide of high selectivity, because of various conditions such as the kind of meteorological condition, soil condition, crop, chemicals treatment periods, sometimes also produce poisoning in use.People are studying the use of the various poisoning palliatives of the so less desirable state of affairs of reply.At present, China also comparatively payes attention to aspect the mixed research of weed killer herbicide, is widely regarded as one of important measures of rationally use of weed killer herbicide, has worked out a series of Herbicidal compositions, has obtained greater advance.
My company is also devoted to the research and development of Herbicidal compositions.At present, about two careless ether, have no report to the relevant composite product of KIH 6127, pyriftalid.
Summary of the invention
The Herbicidal combinations containing two careless ethers that the object of this invention is to provide a kind of control of weeds.
Technical scheme of the present invention is:
A Herbicidal combinations containing two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: Herbicidal combinations contains two careless ether 1～60%, pyrimidine oxygen (sulphur) benzoates 1～70%, auxiliary agent and other excipient surpluses.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: pyrimidine oxygen (sulphur) benzoates is selected from: KIH 6127, pyriftalid, AC322140, halosulfuronmethyl.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: Herbicidal combinations contains two careless ether 1～60%, KIH 6127 1～70%, auxiliary agent and excipient.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: Herbicidal combinations contains two careless ether 2～40%, KIH 6127 2～50%, auxiliary agent and excipient.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, it is characterized in that: Herbicidal combinations contains two careless ether 5～20%, KIH 6127 5～25%, auxiliary agent and excipient, the formulation of Herbicidal combinations is selected from: wetting powder, water dispersible granules, suspending agent.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: Herbicidal combinations contains two careless ether 1～60%, pyriftalid 1～70%, auxiliary agent and excipient.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: Herbicidal combinations contains two careless ether 2～40%, pyriftalid 2～50%, auxiliary agent and excipient.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, it is characterized in that: Herbicidal combinations contains two careless ether 5～20%, pyriftalid 5～40%, auxiliary agent and excipient, the formulation of Herbicidal combinations is selected from: wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, emulsifier, solvent, antifreeze, defoamer, thickener, filler, deionized water.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: while making wetting powder, comprise following constituent content: two careless ether 1～60%, pyrimidine oxygen (sulphur) benzoates 1～70%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
Two careless ether, pyrimidine oxygen (sulphur) benzoates, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into wetting powder product of the present invention.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: when composition is made water dispersible granules, comprise following constituent content: two careless ether 1～60%, pyrimidine oxygen (sulphur) benzoates 1～70%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, filler 10～93%.
Two careless ether, pyrimidine oxygen (sulphur) benzoates, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make water dispersible granules product of the present invention.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: when composition is made suspending agent, comprise following constituent content: two careless ether 1～30%, pyrimidine oxygen (sulphur) benzoates 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in above-mentioned formulation material are mixed through high speed shear, add two careless ether, pyrimidine oxygen (sulphur) benzoates, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, it is characterized in that: when composition is made suspension emulsion, comprise following constituent content: two careless ether 1～30%, pyrimidine oxygen (sulphur) benzoates 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add two former medicines of careless ether, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make two careless ether suspending agents, then by the former medicine of pyrimidine oxygen (sulphur) benzoates, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, is characterized in that: while making microemulsion, comprise: two careless ether 1～30%, pyrimidine oxygen (sulphur) benzoates 1～40%, solvent 3～30%, emulsifier 3～15%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Former medicine is dissolved in the reactor that solvent and cosolvent are housed; After anion emulsifier, nonionic emulsifier and stabilizing agent, antifreeze, water being joined in the reactor that above-mentioned solution is housed, give strong mixing and homogenize, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.
The described Herbicidal combinations that contains two careless ether and pyrimidine oxygen (sulphur) benzoates, comprises while it is characterized in that making aqueous emulsion: two careless ether 1～30%, pyrimidine oxygen (sulphur) benzoates 1～40%, solvent 3～30%, emulsifier 1～8%, antifreeze 1～4%, defoamer 0.01～1%, thickener 0.2～2%, deionized water add to 100%.
Two careless ether, pyrimidine oxygen (sulphur) benzoates, solvent, emulsifier in formula are added together, make to be dissolved into even oil phase; Water, antifreeze, defoamer, thickener are mixed, become homogeneous water; Under high-speed stirred, water is added to oil phase or oil phase is added to water, after good dispersion, make aqueous emulsion product of the present invention.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, glucose.
Described solvent is selected from: DMF, cyclohexanone, methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile.
Described emulsifier is selected from: agriculture breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful breast 36
#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34
#one or more in (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), AEO series (fat alcohol alcohol APEO).
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10aliphatic alcohols, C
10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Herbicidal combinations of the present invention compared with prior art, produces following beneficial effect:
So herbicide mixture is one of important measures in the weeds comprehensive regulation, by weed killer herbicide mixed, can expand herbicidal spectrum, improve herbicidal effect, extend the optimum period for applying fertilizer, reduce poisoning, reduce residual activity, delay the drug-fast generation of weed killer herbicide and development, as remarkably productive in barnyard grass, moleplant seed, Paspalum distichum, herba setariae viridis grass, nutgrass flatsedge, different in nature nutgrass flatsedge, Herba Cyperi Glomerati, cyperus iria, fescue, flat stalk Fischer grass, four leaf duckweeds, mexicana, Amaranthus retroflexus, Monochoria vaginalis to paddy field grass family, sedge family, broad leaved weed class.Wetting powder the key technical indexes of the present invention:
Table 1
Water dispersible granules the key technical indexes of the present invention:
Table 2
Suspending agent the key technical indexes of the present invention:
Table 3
Suspension emulsion the key technical indexes of the present invention:
Table 4
Aqueous emulsion the key technical indexes of the present invention:
Table 5
Microemulsion the key technical indexes of the present invention:
Table 6
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Implementation of an application example one:
Two careless ether and pyrimidine oxygen (sulphur) benzoates are mixed the active determination test of rice weed are reported
Test objective: measured two careless ether and pyrimidine oxygen (sulphur) benzoates and different blended combo thereof and close the herbicidal effect to barnyard grass under greenhouse pot culture condition, and evaluated its synergy, for formulation development and the agriculture chemical registration field control effectiveness test of Mixed Pharmacy provides scientific basis.
For trying target: barnyard grass (Echinochloa crusgalli L.).
Test medicine: two careless ethers (bispyribac-sodium) 95% former medicine, KIH 6127 (pyriminobac-methyl) 97% former medicine, pyriftalid (pyriftalid) 96% former medicine, provides by Shaanxi Welch Crop Protection Co., Ltd..
Medicament configuration:
Two careless ethereal solutions: accurately take the two former medicines of careless ether of 0.0059g95%, with 0.2mLDMF, dissolve, add the clear water 400mL containing 0.1%TWEEN80 emulsifier, stir, be configured to two careless ether 22g a.i./ha solution, then with clear water be diluted to 15,10,4a.i./ha concentration is standby.
KIH 6127 solution: accurately take the former medicine of 0.0079g97% KIH 6127, with 0.2mLDMF, dissolve, add the clear water 400mL containing 0.1%TWEEN80 emulsifier, stir, be configured to KIH 6127 30g a.i./ha solution, then with clear water be diluted to 20,12,5a.i./ha concentration is standby.
Pyriftalid solution: accurately take the former medicine of 0.0495g96% pyriftalid, with 0.2mLDMF, dissolve, add the clear water 400mL containing 0.1%TWEEN80 emulsifier, stir, be configured to pyriftalid 187g a.i./ha solution, then with clear water be diluted to 130,90,50a.i./ha concentration is standby.
Blank solution: 0.2mLDMF adds the water of 80mL0.1%TWEEN80 emulsifier.
Test method: adopt potted plant cauline leaf facture (NY/T1155.4-2006): at the in-built quantitative soil of polypots of high 6cm, diameter 9cm, will be for 15～20 sowings of examination target weed seed in polypots, after covering the fine earth that 0.5～1cm is thick, be placed on cultivation in greenhouse, treat that weeds grew to for 1～3 leaf phase and carry out cauline leaf spraying processing, every alms bowl spraying liquid 1mL, every processing repeats 4 times, and establishes the contrast that is treated to that does not contain medicament.After processing, examination is just placed in cultivation greenhouse in, and the growing state of routine observation target weeds is estimated target be injured symptom and growth inhibition situation, and claimed acrial part fresh weight or strain fresh weight, the toxicity action with form fresh weight inhibiting rate evaluation medicament to target weeds after 15d.
Investigation method:
Test is processed and to be estimated target be injured symptom and growth inhibition situation after 15d, and claims acrial part fresh weight, calculates fresh weight inhibiting rate (%).
Synergy evaluation method:
According to Gowing method, evaluate weed killer herbicide mode of application (NY/T1155.7-2006), its formula is as follows:
E
0＝X+Y－XY/100
In formula, X is two careless ether fresh weight inhibiting rate to target weeds when alone with certain dosage; Y is KIH 6127 fresh weight inhibiting rate to target weeds when alone with certain dosage; E
0theoretical value to target weeds fresh weight inhibiting rate during for a kind of two kinds of pharmacy mix in two careless ether and KIH 6127, pyriftalid; Measured value to target weeds fresh weight inhibiting rate when E is a kind of two kinds of pharmacy mix in two careless ether and KIH 6127, pyriftalid.
Evaluation criterion: work as E-E
0during > 10%, be expressed as synergistic effect, as 10%≤E-E
0in the time of≤10%, be expressed as summation action, work as E-E
0during <-10%, be expressed as antagonism.
Table 7 pair careless ether and KIH 6127 and the toxicity test result of combination to barnyard grass that be mixed thereof
Table 7 pair careless ether and KIH 6127 and the toxicity test result of combination to barnyard grass that be mixed thereof
Evaluating drug effect: two careless ether and KIH 6127 and the composition that is mixed thereof to the herbicidal effect measurement result of barnyard grass in Table 7.Visible, two careless ether and KIH 6127 show synergistic effect to barnyard grass, its E-E with 15+12,15+20,22+5,22+12,22+20, the 22+30 composition that is mixed
0value is respectively 10.82,12.76,25.47,25.99,19.46,14.64, and the composition of other mixed ratios shows addition to barnyard grass, wherein best to the effect of barnyard grass with the composition that is mixed of 22+12, its E-E
0value is 25.99.
Table 8 pair careless ether and pyriftalid and the toxicity test result of combination to barnyard grass that be mixed thereof
Table 8 pair careless ether and pyriftalid and the toxicity test result of combination to barnyard grass that be mixed thereof
Evaluating drug effect: two careless ether and pyriftalid and the composition that is mixed thereof to the herbicidal effect measurement result of barnyard grass in Table 8.Visible, two careless ether and pyriftalid show synergistic effect to barnyard grass, its E-E with 10+187,15+90,15+130,15+187,22+50,22+90,22+130, the 22+187 composition that is mixed
0value is respectively 10.18,12.01,14.33,10.91,27.32,29.03,20.44,15.78, and the composition of other mixed ratios shows addition to barnyard grass, wherein best to the effect of barnyard grass with the composition that is mixed of 22+90, its E-E
0value is 29.03.
Application Example two: two careless ether and KIH 6127, the relevant composite product embodiments of pyriftalid (following content is folding hundred percentage compositions).
1 30% pair of careless ether KIH 6127 wetting powder of embodiment
Two careless ether 10%, KIH 6127 20%, alkyl benzene sulfonate calcium salt 6%, spaonin powder 4%, attapulgite add to 100%, make 30% pair of careless ether KIH 6127 wetting powder.
2 60% pairs of careless ether KIH 6127 wetting powders of embodiment
Two careless ether 20%, KIH 6127 40%, polycarboxylate 7%, wetting and penetrating agent F5%, kaolin add to 100%, make 60% pair of careless ether KIH 6127 wetting powder.
3 71% pairs of careless ether KIH 6127 wetting powders of embodiment
Two careless ether 1%, KIH 6127 70%, aliphatic amine polyoxyethylene are phonetic 10%, soapberry powder 5%, white carbon add to 100%, make 71% pair of careless ether KIH 6127 wetting powder.
4 45% pairs of careless ether KIH 6127 water dispersible granules of embodiment
Two careless ether 20%, KIH 6127 25%, naphthalene sulfonic acid-formaldehyde condensation product 6%, lauryl sodium sulfate 4%, ammonium sulfate 3%, bentonite add to 100%, make 45% pair of careless ether KIH 6127 water dispersible granules.
5 55% pairs of careless ether KIH 6127 water dispersible granules of embodiment
Two careless ether 40%, KIH 6127 15%, ester polyoxyethylene are phonetic 7%, silkworm excrement 5%, aluminium chloride 2.5%, diatomite add to 100%, make 55% pair of careless ether KIH 6127 water dispersible granules.
6 60% pairs of careless ether KIH 6127 water dispersible granules of embodiment
Two careless ether 10%, KIH 6127 50%, alkylnaphthalene sulfonate 9%, Nekal BX 4%, urea 3%, kaolin add to 100%, make 60% pair of careless ether KIH 6127 water dispersible granules.
7 10% pairs of careless ether KIH 6127 suspending agents of embodiment
Two careless ether 5%, KIH 6127 5%, lignosulfonates 7%, xanthans 0.8%, C
8～10aliphatic alcohols 0.4%, glycerine 2%, water adds to 100%, makes 10% pair of careless ether KIH 6127 suspending agent.
8 32% pairs of careless ether KIH 6127 suspending agents of embodiment
Two careless ether 2%, KIH 6127 30%, neopelex 8%, methylcellulose 0.9%, silicone compound 0.2%, ethylene glycol 2.3%, water adds to 100%, makes 32% pair of careless ether KIH 6127 suspending agent.
9 35% pairs of careless ether KIH 6127 suspending agents of embodiment
Two careless ether 15%, KIH 6127 20%, lauryl sodium sulfate 6%, Magnesiumaluminumsilicate 0.7%, silicone oil 0.3%, polyethylene glycol 2%, water adds to 100%, makes 35% pair of careless ether KIH 6127 suspending agent.
10 55% pairs of careless ether pyriftalid wetting powders of embodiment
Two careless ether 5%, pyriftalid 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, soapberry powder 4%, bentonite add to 100%, make 55% pair of careless ether pyriftalid wetting powder.
11 71% pairs of careless ether pyriftalid wetting powders of embodiment
Two careless ether 1%, pyriftalid 70%, polyoxyethylene carboxylate 8%, wetting and penetrating agent F6%, diatomite add to 100%, and mixture carries out air-flow crushing, make 71% pair of careless ether pyriftalid wetting powder.
12 80% pairs of careless ether pyriftalid wetting powders of embodiment
Two careless ether 20%, pyriftalid 60%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 5%, white carbon add to 100%, and mixture carries out air-flow crushing, make 80% pair of careless ether pyriftalid wetting powder.
13 50% pairs of careless ether Pyriftalid water dispersible granules of embodiment
Two careless ether 10%, pyriftalid 40%, lignosulfonates 4%, polycarboxylate 5%, lauryl sodium sulfate 3%, glucose 2%, starch 10%, attapulgite add to 100%, mix and make 50% pair of careless ether Pyriftalid water dispersible granule.
14 52% pairs of careless ether Pyriftalid water dispersible granules of embodiment
Two careless ether 2%, pyriftalid 50%, alkyl benzene sulfonate calcium salt 7%, neopelex 5%, aluminium chloride 3%, kaolin add to 100%, mix and make 52% pair of careless ether Pyriftalid water dispersible granule.
15 65% pairs of careless ether Pyriftalid water dispersible granules of embodiment
Two careless ether 5%, pyriftalid 60%, alkylphenol-polyethenoxy are phonetic 8%, lauryl sodium sulfate 6%, bentonite add to 100%, make 65% pair of careless ether Pyriftalid water dispersible granule.
16 22% pairs of careless ether pyriftalid suspending agents of embodiment
Two careless ether 2%, pyriftalid 20%, alkyl benzene sulfonate calcium salt 7%, neopelex 5%, C
10～20saturated fat acids 0.2%, CMC 0.6%, deionized water adds to 100%, mixes and makes 22% pair of careless ether pyriftalid suspending agent.
17 45% pairs of careless ether pyriftalid suspending agents of embodiment
Two careless ether 5%, pyriftalid 40%, lignosulfonates 8%, lauryl sodium sulfate 4%, silicone compound 0.3%, Magnesiumaluminumsilicate 0.8%, propane diols 1.5%, deionized water add to 100%, mix and make 45% pair of careless ether pyriftalid suspending agent.
18 48% pairs of careless ether pyriftalid suspending agents of embodiment
Two careless ether 3%, pyriftalid 45%, neopelex 6%, spaonin powder 4%, silicone oil 0.4%, xanthans 0.7%, glycerine 3%, deionized water add to 100%, mix and make 48% pair of careless ether pyriftalid suspending agent.
19 11% pairs of careless ether pyriftalid suspension emulsions of embodiment
Two careless ether 10%, pyriftalid 1%, lauryl sodium sulfate 7%, 600
#phosphate 8%, silicone compound 0.1%, polyvinyl alcohol 1.5%, ethylene glycol 2%, water adds to 100%, and aforementioned formula material is mixed, and makes 11% pair of careless ether pyriftalid suspension emulsion.
20 44% pairs of careless ether pyriftalid suspension emulsions of embodiment
Two careless ether 4%, pyriftalid 40%, neopelex 6%, sodium lignin sulfonate 2%, agriculture breast 1600
#8%, xanthans 2%, water add to 100%, mix and make 44% pair of careless ether pyriftalid suspension emulsion.
21 21% pairs of careless ether pyriftalid aqueous emulsions of embodiment
Two careless ether 1%, pyriftalid 20%, methyl alcohol 12%, ethylene oxide-propylene oxide block copolymer 7%, isobutanol 3%, polyethylene glycol 2%, Magnesiumaluminumsilicate 0.8%, silicone oil 0.3%, water is mended to 100%, makes 21% pair of careless ether pyriftalid aqueous emulsion.
22 50% pairs of careless ether pyriftalid aqueous emulsions of embodiment
Two careless ether 5%, pyriftalid 45%, DMF 7%, propyl alcohol 2%, agriculture breast 1600
#8%, butanols 5%, glycerine 2%, CMC 1.2%, silicone compound 0.4%, water is mended to 100%, makes 50% pair of careless ether pyriftalid aqueous emulsion.
23 10% pairs of careless ether pyriftalid microemulsions of embodiment
Two careless ether 5%, pyriftalid 5%, ethanol 10%, diethylene glycol 5%, Nongru-700
#8%, xanthans 1.3%, water supplies 100%, makes 10% pair of careless ether pyriftalid microemulsion.
24 45% pairs of careless ether pyriftalid microemulsions of embodiment
Two careless ether 10%, pyriftalid 35%, ethylene glycol monomethyl ether 9%, butanols 12%, fat fat alcohol APEO 10%, silicone oil 0.2%, Magnesiumaluminumsilicate 1%, ethylene glycol 3%, water supplies 100%, makes 45% pair of careless ether pyriftalid microemulsion.
Application Example three: two careless ether and pyrimidine oxygen (sulphur) benzoates control paddy rice annual weed field control effectiveness test
Control medicament: the complex composition of two careless ether and pyrimidine oxygen (sulphur) benzoates, by Shaanxi Welch Crop Protection Co., Ltd.'s research and development, produced;
Contrast medicament: the two careless ether suspending agents of 100 grams per liters; 10% KIH 6127 wetting powder; 24.3% pyriftalid suspending agent.
If artificial weeding and clear water control treatment.
Using method: every mu be watered 30 liters after evenly cauline leaf sparge in each community
Spraying time: on July 21st, 2010, in the paddy rice 7-8 leaf phase, the field annual weed 1-3 leaf phase, carry out cauline leaf spraying 1 time.
Investigation method and drug effect are calculated
Investigation weeds object is: the annual weed such as barnyard grass, nutgrass flatsedge, Paspalum distichum, investigate latter 15 days, the 40 days fresh weight preventive effects to the strain preventive effect of weeds and 30 days.
Visual test medicament occurs without poisoning paddy rice.
Test results and analysis respectively in Table 9, table 10.
The table 9 pair careless ether KIH 6127 control paddy field annual weed test of pesticide effectiveness
The table 9 pair careless ether KIH 6127 built composition for preventing and controlling paddy field annual weed test of pesticide effectiveness
Two careless ether and KIH 6127 is composite that paddy rice barnyard grass, nutgrass flatsedge, Paspalum distichum are had to good control efficiency as shown in Table 9, preventive effect is better than single dose preventive effect, with contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and there is good quick-acting and lasting effect, in this experimental drug scope, to rice safety.
The table 10 pair careless ether pyriftalid control paddy field annual weed test of pesticide effectiveness
The table 10 pair careless ether pyriftalid built composition for preventing and controlling paddy field annual weed test of pesticide effectiveness
Two careless ether and pyriftalid is composite that paddy rice barnyard grass, nutgrass flatsedge, Paspalum distichum are had to good control efficiency as shown in Table 10, preventive effect is better than single dose preventive effect, with contrast medicament, artificial weeding, with respect to significant difference between the rate of growth of clear water control treatment, and there is good quick-acting and lasting effect, in this experimental drug scope, to rice safety.
Claims (4)
1. the Herbicidal combinations containing two careless ether and pyrimidine oxygen (sulphur) benzoates, it is characterized in that: Herbicidal combinations contains two careless ether, pyrimidine oxygen (sulphur) benzoates, auxiliary agent and other excipient surpluses, wherein pyrimidine oxygen (sulphur) benzoates is selected from: a kind of in KIH 6127, pyriftalid, the weight ratio of two careless ether and KIH 6127 is 15:12,22:5,22:12,22:20,22:30, and the weight ratio of two careless ether and pyriftalid is 10:187,15:90,15:130,15:187,22:50,22:90,22:130,22:187.
2. the Herbicidal combinations containing two careless ether and pyrimidine oxygen (sulphur) benzoates according to claim 1, is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, microemulsion, aqueous emulsion.
3. the Herbicidal combinations containing two careless ether and pyrimidine oxygen (sulphur) benzoates according to claim 1 is for preventing and treating the application of paddy field grassy weed, sedge weed, broad leaved weed.
4. application according to claim 3, is characterized in that: described weeds are barnyard grass, moleplant seed, Paspalum distichum, herba setariae viridis grass, nutgrass flatsedge, difformed galingale herb, Herba Cyperi Glomerati, cyperus iria, fescue, flat stalk Fischer grass, four leaf duckweeds, mexicana, Amaranthus retroflexus or Monochoria vaginalis.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110136786.6A CN102228026B (en) | 2011-05-25 | 2011-05-25 | Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110136786.6A CN102228026B (en) | 2011-05-25 | 2011-05-25 | Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102228026A CN102228026A (en) | 2011-11-02 |
| CN102228026B true CN102228026B (en) | 2014-11-12 |
Family
ID=44840663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110136786.6A Expired - Fee Related CN102228026B (en) | 2011-05-25 | 2011-05-25 | Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102228026B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102669187B (en) * | 2012-05-25 | 2014-10-29 | 国际竹藤中心 | Botanical herbicide soluble powder and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003020035A2 (en) * | 2001-08-30 | 2003-03-13 | Bayer Cropscience Ag | Selective herbicide comprising a tetrazolinone derivative |
| WO2005092101A2 (en) * | 2004-03-26 | 2005-10-06 | Syngenta Participations Ag | A herbicidal combination |
| CN102461512A (en) * | 2010-11-19 | 2012-05-23 | 南京华洲药业有限公司 | Mixed herbicide composition containing bispyribac-sodium and pyriftalid |
| CN102461506A (en) * | 2010-11-19 | 2012-05-23 | 南京华洲药业有限公司 | Mixed herbicide composition containing bispyribac-sodium and pyriminobac-methyl |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101084750A (en) * | 2007-07-12 | 2007-12-12 | 徐开云 | Synergistic herbicide |
-
2011
- 2011-05-25 CN CN201110136786.6A patent/CN102228026B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003020035A2 (en) * | 2001-08-30 | 2003-03-13 | Bayer Cropscience Ag | Selective herbicide comprising a tetrazolinone derivative |
| WO2005092101A2 (en) * | 2004-03-26 | 2005-10-06 | Syngenta Participations Ag | A herbicidal combination |
| CN102461512A (en) * | 2010-11-19 | 2012-05-23 | 南京华洲药业有限公司 | Mixed herbicide composition containing bispyribac-sodium and pyriftalid |
| CN102461506A (en) * | 2010-11-19 | 2012-05-23 | 南京华洲药业有限公司 | Mixed herbicide composition containing bispyribac-sodium and pyriminobac-methyl |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102228026A (en) | 2011-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102283217B (en) | Weeding composition containing florasulam and pinoxaden | |
| CN101999361B (en) | Herbicide composition containing cyhalofop-butyl and pyrimidyloxy (sulfur) benzoate | |
| CN101999389B (en) | Cyhalofop-butyl and sulfonylurea herbicide-containing herbicide composition | |
| CN101999400A (en) | Cyhalofop-butyl-containing weeding composition | |
| CN102293212B (en) | Weeding composition containing rimsulfuron and triazine | |
| CN102326574B (en) | Weeding composition containing florasulam and sulfonylurea | |
| CN102283219A (en) | Weeding composition containing florasulam and praflufenethyl | |
| CN102283203A (en) | Weeding composition containing mesotrione and fluroxypyr | |
| CN102265875B (en) | Weeding composition containing florasulam and bromoxynil octanoate | |
| CN102428936A (en) | Herbicide compound containing flumioxazin and acetochlor | |
| CN102318631B (en) | Weeding composition containing florasulam and thifensulfuron | |
| CN102326561A (en) | Weeding composition containing carfentrazone-ethyl and mefenacet | |
| CN102258045A (en) | Weedicide composition containing rimsulfuron and bromoxynil octanoate | |
| CN102273476B (en) | Pesticide composition containing bispyribac-sodium | |
| CN102326573B (en) | Weeding composition containing rimsulfuron | |
| CN102217629B (en) | Synergistic herbicidal composition containing bispyribac-sodium and sulfonylurea | |
| CN102326572A (en) | Weeding composition containing rimsulfuron and fluroxypyr | |
| CN102334479A (en) | Herbicidal composition containing bispyribac-sodium and sulfonylureas | |
| CN102326563B (en) | Weeding composition containing diflufenican and flumetsulam | |
| CN102228026B (en) | Weeding composition containing bispyribac-sodium and pyrimidinyloxy (thio) benzoates | |
| CN102150665B (en) | Herbicidal composition containing cyhalofop-butyl and triazines | |
| CN102334483B (en) | Weeding composition containing beflubutamid and terbutryn | |
| CN102415390A (en) | Weeding composition containing flumioxazin and quizalofop-p-ethyl | |
| CN102258021B (en) | Beflubutamid-containing weeding composition | |
| CN102326560A (en) | Weeding composition containing carfentrazone-ethyl and metamifop |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141112 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |