CN102225637A - Application method for hologram pattern paper and novel hologram pattern paper - Google Patents
Application method for hologram pattern paper and novel hologram pattern paper Download PDFInfo
- Publication number
- CN102225637A CN102225637A CN2011100936376A CN201110093637A CN102225637A CN 102225637 A CN102225637 A CN 102225637A CN 2011100936376 A CN2011100936376 A CN 2011100936376A CN 201110093637 A CN201110093637 A CN 201110093637A CN 102225637 A CN102225637 A CN 102225637A
- Authority
- CN
- China
- Prior art keywords
- paper
- film
- modifier
- layer
- holographic pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 72
- 239000010410 layer Substances 0.000 claims abstract description 134
- 239000012790 adhesive layer Substances 0.000 claims abstract description 49
- 239000012528 membrane Substances 0.000 claims abstract description 39
- 230000000694 effects Effects 0.000 claims abstract description 22
- 238000007747 plating Methods 0.000 claims abstract description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 52
- 229920000178 Acrylic resin Polymers 0.000 claims description 49
- 229920005749 polyurethane resin Polymers 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 42
- 239000003822 epoxy resin Substances 0.000 claims description 41
- 229920000647 polyepoxide Polymers 0.000 claims description 41
- 239000003607 modifier Substances 0.000 claims description 40
- 239000000758 substrate Substances 0.000 claims description 36
- 239000011241 protective layer Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 27
- 229920001577 copolymer Polymers 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 238000001704 evaporation Methods 0.000 claims description 17
- 230000008020 evaporation Effects 0.000 claims description 17
- 239000005083 Zinc sulfide Substances 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 15
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 238000013329 compounding Methods 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims description 8
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229920002799 BoPET Polymers 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 150000004706 metal oxides Chemical class 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 6
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 238000007738 vacuum evaporation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 16
- 210000004379 membrane Anatomy 0.000 description 33
- 239000004593 Epoxy Substances 0.000 description 10
- 238000010586 diagram Methods 0.000 description 8
- 238000003825 pressing Methods 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- 210000002469 basement membrane Anatomy 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000007591 painting process Methods 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 206010021703 Indifference Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Abstract
The invention relates to an application method for a hologram pattern paper and a novel hologram pattern paper, and more specifically relates to an application method for a hologram pattern paper which is obtained by duplicating the groove structure of hologram pattern on the surface of a mother film and a novel hologram pattern paper. The method comprises the following steps: applying an information transfer layer on the surface of a hologram pattern paper by vapor plating; applying a second protection layer on the information transfer layer and combining the hologram pattern paper with a film; peeling the film so as to obtain a novel hologram pattern paper. The method is characterized in that: the groove structure of hologram pattern on the surface of a mother film reproduced on an adhesive layer is duplicated and transferred onto the information transfer layer. According to the invention, the groove structure of hologram pattern on the surface of the mother film can be precisely duplicated, which can substantially reduce production cost and increase production efficiency; the novel hologram pattern paper can obtain a same membrane surface (minute surface) effect after transfer as a hologram pattern paper prepared by the conventional transfer membrane process do.
Description
Technical field
The present invention relates to a kind of application process and new holographic figure line paper, in particular, relate to a kind of application process and new holographic figure line paper the holographic pattern paper that utilizes microscopic information layer groove structure to duplicate to obtain to holographic pattern paper.
Background technology
In the prior art; when making roll type holographic pattern paper; the following technology of main employing: make holographic film earlier with holographic pattern; this holographic film comprises the structure as lower floor successively: base membrane layer, transfer layer, Information Level, information protection layer; again in compounding machine; to carry out compound with paper substrate behind this holographic film coating adhesive adhesion coating; again basement membrane is peeled off; holographic pattern on the holographic film is printed to paper substrate, and the layer structure of this paper substrate comprises successively: paper substrate, adhesive layer, information protection layer, Information Level and transfer layer.Existing techniques in realizing be: the disposable transfer of holographic pattern is about to whole the transferring on the paper substrate of holographic pattern of information layer surface, thereby makes paper substrate have holographic pattern, and has the effect of holographic pattern.Peel off the remaining basement membrane in back, finish the making of a reel after, when carrying out the making of next reel holographic pattern paper, need repeat above-mentioned operation again, promptly repeat coating, impression, compound or the like operation.Utilize the characteristic of some resin, transfer layer and Information Level also can be unified.Above-mentioned base membrane layer also can replace with metal forming.
But obviously, the cost that above-mentioned operation needs is huge, and the making of each reel all need repeat above-mentioned operation, particularly needs to repeat the mold pressing procedure of information layer surface holographic pattern, production efficiency is low, according to statistics, go up according to the manufacture craft of stating operation, with existing production capacity, a moulding press can only be produced 30000 meters films in one day, and the efficient of mold pressing procedure has only 1/3 of painting process.
But in fact, when carrying out the making of holographic pattern paper, be exist to save cost, raise the efficiency possible.Reason is: so-called holographic pattern, be meant the employing mould pressing process, and holographic interference fringes is impressed into that base material (plastic sheeting, paper or other materials) is gone up and the hologram that obtains with the form of embossment structure.It from macroscopic view visually is presented as various hologram patterns, but from microcosmic, it is presented as groove, promptly has the interference fringe groove of certain depth; And the above-mentioned interference stripe groove can duplicate.
The applicant thinks that above-mentioned groove structure can be replicated fully from microcosmic after above-mentioned groove structure is researched and analysed between each layer.Therefore, can realize duplicating of holographic pattern, thereby reduce production costs greatly, and enhance productivity accurately the duplicating of holographic pattern information groove structure as long as can realize.
And the mirror-image structure that duplicates out has high accuracy, therefore can utilize fully to be used for making novel holographic pattern paper.
Summary of the invention
Purpose of the present invention is as follows:
Provide a kind of and produce new holographic figure line paper, and a kind of new holographic figure line paper that utilizes said method to make is provided utilizing female film surface hologram groove groove structure to duplicate the application process of the holographic pattern paper that obtains.
Technical scheme of the present invention is as follows:
1, a kind of application process to holographic pattern paper is characterized in that, comprises the steps:
The making step of holographic pattern paper is as follows:
1.1, carry out itself and paper substrate compound again at female film surface-coated adhesive layer;
1.2 female film is peeled off, is obtained holographic pattern paper;
Described female film is a roll type, and the surface has the groove structure of holographic pattern, and described groove structure is copied to adhesive layer;
Described holographic pattern paper structure is as follows:
Paper substrate;
Adhesive layer;
Described adhesive layer have be replicated the groove structure on female film surface;
Application process to holographic pattern paper is as follows:
1.3 at holographic pattern paper surface evaporation information transfer layer;
1.4 on the information transfer layer, apply second protective layer, again itself and film are carried out compound after, film is peeled off, obtain new holographic figure line paper;
It is characterized in that: duplicate on the described adhesive layer the groove structure on female film surface be copied to the information transfer layer.
Technique scheme can further be improved to, described female membrane structure is followed successively by from top to bottom: paper tinsel rete, Information Level, wherein information layer surface impression have that holographic pattern, described paper tinsel rete can be that PET film, BOPP film, PI film, PC film or other are multi-layer co-extruded, the composite membrane of modified film or metal forming or above-mentioned film and metal forming.The composite membrane of the preferred roll type film of female film of the present invention or metal forming or film and metal forming, with respect to female film of other materials, the female film surface grating with above-mentioned paper tinsel rete is full, and groove structure is stable, more helps realizing accurately duplicating of groove structure.And the female film of roll type is applicable to and the continuity production application of large molded machine, coating machine, compounding machine can improves efficiency of operation greatly.
Technique scheme can further be improved to, described female membrane structure is followed successively by from top to bottom: paper tinsel rete, Information Level, wherein information layer surface impression have that holographic pattern, described paper tinsel rete can be that PET film, BOPP film, PI film, PC film or other are multi-layer co-extruded, the composite membrane of modified film or metal forming or above-mentioned film and metal forming.Surface-coated has female film of information protection layer can avoid in process of production, the destruction that surface groove structures may be subjected to, and can not exert an influence to duplicating of groove structure.
Technique scheme can further be improved to, described technology can further be improved as follows: apply a transfer layer earlier on female film surface, coating adhesive adhesion coating again, described transfer layer material is celluosic resin or its modifier, acrylic resin or its modifier, polyamine fat resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture or wax class, adopts coating machine to be applied to wet amount 1-20 gram/m
2, 80-200 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.Increasing by a transfer layer can be so that female film and adhesive layer has better separating effect.And the transfer layer material of above-mentioned selection all has transferability and can both be applicable to the intaglio plate coating.Technological parameter in the above-mentioned scope is the preferred parameter of transfer layer bed thickness and coating; the transfer layer that above-mentioned technological parameter is made had both guaranteed that female film and adhesive layer were fast, separate completely; simultaneously, can keep again that the holographic pattern groove structure duplicates accurately on female film between information protection layer and information transfer layer.
Technique scheme can further be improved to, described adhesive layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture, combination process is as follows: in compounding machine, 80-150 ℃ of oven dry, be 10-60 second drying time, and operating speed is 20-150m/min.The adhesive layer material of above-mentioned selection all has thermosetting, makes in combination process, and female film and paper substrate adhesion-tight, easy to operate, and be industrial materials commonly used, provide cost savings.Above-mentioned selection of process parameters has reached following technique effect: temperature is too high, longly can destroy the adhesive layer interlayer structure drying time, temperature is low excessively, drying time the too short effect that then can't reach adhesion-tight; The too fast meeting of operating speed makes the coating inequality of adhesive layer, oven dry not saturating, and crossing then influences efficient slowly; Therefore 80-150 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min, not only the adhesive layer effect is more superior with respect to the parameter area in the general technology, particularly can not destroy the microcosmic groove structure that adhesive layer duplicates, guarantee that the holographic pattern groove structure duplicates accurately on female film between female film and adhesive layer, thereby realize accurately duplicating holographic pattern on female film.
Technique scheme can further be improved to, it is characterized in that, in the described step 1.3, described information transfer layer material is metal or metal oxide or zinc sulphide or silica or both mixtures of back, thickness is the 50-1000 dust, concrete evaporation process is as follows: in vacuum evaporation plating machine, vacuum is lower than 10
-2Millibar, speed 60-1000m/min.The information transfer layer of above-mentioned material evaporation forms stable, even, fine and close adhering on the adhesive layer groove structure of holographic pattern paper, therefore the holographic pattern groove structure on copying hologram line paper surface accurately, and more be applicable to the evaporation of high speed reel, therefore can obtain better evaporation effect.And the following significant technique effect that above-mentioned evaporation process parameter and bed thickness have been obtained: evaporation layer thickness 50-1000 dust, with respect to microcosmic groove structure for female film surface, the holographic pattern groove structure that duplicates that this thickness forms is more accurate from microcosmic, can obtain better visual effect on macroscopic view, cross Bao Zehui and cause holographic pattern groove structure distortion visually in subsequent duplicate, blocked uply not only can increase cost, and the groove structure that duplicates is also stable inadequately, impact effect.Therefore, the carrier that the information transfer layer duplicates as female film surface groove structures, the stable and level of the groove structure that it duplicates is particularly crucial.Zinc sulphide or silica then are material transparent, and these two kinds of materials make the product of this technology have more effect selection, can make the paper tinsel film have transparent or opaque effect according to the needs of practical application.
Technique scheme can further be improved to; it is characterized in that; in the described step 1.4; second protective layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture, and concrete coating processes is as follows: adopt coating machine to be applied to wet amount 1-20 gram/m
2, 80-200 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.Second protective layer material of above-mentioned selection can form fine and close structure on new holographic figure line paper surface, forms protection thereby can fill and lead up its surperficial groove structure uniformly, and can both be applicable to the intaglio plate coating.Technological parameter in the above-mentioned scope is the preferred parameter of transfer layer bed thickness and coating, second protective layer that above-mentioned technological parameter is made can be obtained following technique effect: the bed thickness that second protective layer applies is even, fine and close, the excessive waste material of bed thickness, and can the holographic pattern visual effect on new holographic figure line paper surface be exerted an influence; Bed thickness is too small then can't to play effective protective effect, can influence the effect of the holographic pattern that duplicates on the contrary.
Technique scheme can further be improved to, and it is characterized in that, in the described step 1.4, combination process is as follows: in compounding machine, and 80-150 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.Above-mentioned selection of process parameters has reached following technique effect: temperature is too high, longly can destroy the second protective layer interlayer structure drying time, temperature is low excessively, drying time the too short effect that then can't reach multiple film; The too fast meeting of operating speed makes the coating inequality of second protective layer, oven dry not saturating, and crossing then influences efficient slowly; Therefore 80-150 ℃ of oven dry; be 10-60 second drying time; operating speed is 20-150m/min; not only the second protective layer effect is more superior with respect to the parameter area in the general technology; particularly can the microcosmic groove structure; guarantee that holographic pattern groove structure interlayer duplicates accurately on female film, thereby realize accurately duplicating holographic pattern on the transfer membrane.
Technique scheme can further be improved to, and it is characterized in that: in the described step 1.4, can apply second protective layer as required on selectable transferable information mirror image layer top and realize different effects.Promptly groove structure is carried out filling and leading up of part, promptly can realize different visual effects as required.
A kind of new holographic figure line paper, described new holographic figure line paper structure is as follows successively from top to bottom:
Paper substrate;
Adhesive layer;
The information transfer layer;
Second protective layer;
It is characterized in that: described information transfer layer has the groove structure of the female film surface hologram line that is replicated.
Technique scheme can further be improved to, also can comprise a transfer layer, between adhesive layer and information transfer layer, described transfer layer material is celluosic resin or its modifier, acrylic resin or its modifier, polyamine fat resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture or wax class, and described transfer layer has the groove structure of the female film surface hologram line that duplicates.
Technique scheme can further be improved to, and described adhesive layer is the copolymer/mixture of acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or above-mentioned substance.
Technique scheme can further be improved to, and described transferable information mirror image layer material is metal or metal oxide or zinc sulphide or silica or both mixtures of back, and thickness is the 50-1000 dust.
Technique scheme can further be improved to, and described second protective layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture.
Beneficial effect of the present invention is as follows: the utilization of the invention the holographic pattern groove structure that has of female film surface can be by accurate replicability, when making roll type holographic pattern paper in the prior art, the operation that need repeat is holographic pattern impression operation particularly, be improved to duplicating to female film surface hologram groove groove structure, utilize painting process to carry out the making of roll type holographic pattern paper, thereby can reduce production costs greatly, enhance productivity, this is the most loaded down with trivial details particularly to have saved the repetition mold pressing, influence most production efficiency, increase most the link of production cost.According to statistics, realizing impression is improved under the situation of coating, production efficiency will be than improving at least more than 3 times originally.
Description of drawings
Fig. 1 is a transfer membrane microstructure schematic diagram of the present invention.
Fig. 2 is the microstructure schematic diagram of another preferred embodiment of transfer membrane of the present invention.
Fig. 3 is the microstructure schematic diagram of holographic pattern paper of the present invention.
Fig. 4 is the microstructure schematic diagram of another preferred embodiment of holographic pattern paper of the present invention.
Fig. 5 is the microstructure schematic diagram of new holographic figure line paper of the present invention.
Fig. 6 is the microstructure schematic diagram of another preferred embodiment of new holographic figure line paper of the present invention.
Fig. 7 is a process flow diagram of the present invention.
In the above-mentioned schematic diagram, the female film of 1-; The groove structure of the female film surface hologram of 2-line; The 3-transfer layer; The 4-adhesive layer; 5-information transfer layer; 6-second protective layer; The 7-paper substrate.
The specific embodiment
The manufacture craft of a kind of roll type holographic pattern of the present invention paper paper, its principle is: the characteristic of utilizing holographic pattern microcosmic groove structure accurately to be duplicated, utilize the information transfer layer to duplicate the holographic pattern groove structure on female film surface, formation has the transfer membrane of the microcosmic groove structure of the holographic pattern that is replicated, and utilizes this transfer membrane to make holographic pattern paper again.The hologram lamina of female film then is retained in female film.On technology, substituted imprint process of the prior art with coating process, improved production efficiency greatly, provide cost savings.
Accurately duplicate requirement for what reach the holographic pattern groove structure, the application is in the treatment process to female film, the selection of layers of material and the technological parameter of layers of material are all optimized, both improved production efficiency, what is more important is in follow-up technology, guaranteed the accuracy that the holographic pattern groove structure duplicates between each layer, well arranged, the Stability Analysis of Structures of the groove structure that duplicates under the above-mentioned technological parameter, the accuracy of repetition height duplicates the high accuracy of female film holographic pattern from visually then being presented as.
Specifically, as shown in Figure 7, the surface of female film 1 has holographic pattern groove structure 2, at female film surface-coated adhesive layer 4, utilize the characteristic that can accurately be duplicated between structure sheaf of holographic pattern microcosmic groove structure, above-mentioned groove structure 2 is copied to adhesive layer 4 accurately.Having this kind layer constructed products and can be referred to as transfer membrane, is the basis of carrying out subsequent technique of the present invention.
Above-mentioned transfer membrane and paper substrate are carried out compound, more female film is peeled off, can obtain holographic pattern paper.After peeling off, adhesive layer 4 is attached on the paper substrate, because adhesive layer 4 is the holographic pattern groove structures 2 on the female film that duplicates, therefore, this holographic pattern paper has also promptly been realized duplicating holographic pattern on female film.And female film of this moment still also remains with complete holographic pattern, can continue to use and carry out follow-up technology.
On the basis that makes above-mentioned holographic pattern paper, the application has proposed the application process to above-mentioned holographic pattern paper.Though above-mentioned holographic pattern paper surface has the information transfer layer 4 that has duplicated holographic pattern groove structure 2, also can be presented as the effect of having duplicated holographic pattern on female film from vision, but this holographic pattern paper is compared with the holographic pattern paper that traditional transfer membrane technology makes, because it is not through multiple membrane process, therefore its surface does not have minute surface (face) effect that traditional transfer membrane technology is had, and this is a weak point of utilizing the holographic pattern paper that this technology makes.Therefore, as the improvement to above-mentioned technology, the application is as follows to the application process of above-mentioned holographic pattern paper: at above-mentioned holographic pattern paper surface evaporation information transfer layer; On the information transfer layer, apply second protective layer, again itself and film are carried out compound after, film is peeled off, obtain new holographic figure line paper.So, then duplicate on the adhesive layer the groove structure on female film surface be copied to the information transfer layer.The information transfer layer material is metal or metal oxide or zinc sulphide or silica or both mixtures of back, and thickness is the 50-1000 dust.
So the information transfer layer not only has the holographic pattern groove structure identical with female film, and grating is just full, groove structure is stable, well arranged, and this new holographic figure line paper can reach face (minute surface) effect after the same transfer of the holographic pattern paper that makes with traditional transfer membrane technology.
As a kind of improvement, can apply a transfer layer 3 between female film 1 and the adhesive layer 4, thereby make that duplicating with transfer effect of female film surface hologram groove groove structure is more superior.
Female film preferred surface among the present invention has the roll type paper tinsel film of holographic pattern groove structure or the composite membrane of metal forming or film and metal forming, because its surface grating is full, groove structure is more stable, more helps realizing accurately duplicating of groove structure.And the female film of roll type is applicable to and the continuity production application of large molded machine, coating machine, compounding machine can improves efficiency of operation greatly.Film wherein, can adopt PET film, BOPP film, PI film or other multi-layer co-extruded, modified films, metal forming wherein then can be all kinds of common metal paper tinsels of aluminium foil, Copper Foil or the like, as long as processing requests such as Information Level adhesion-tight, the follow-up heatproof stretch-proof of adaptation all can.
First group of embodiment (1-3)
Female membrane structure: paper tinsel rete, Information Level, wherein the paper tinsel film adopts the PET film; The information transfer layer adopts metallic copper; Adhesive layer adopts acrylic resin; Second protective layer adopts polyurethane resin; Holographic pattern paper structure: paper substrate, acrylate resin layer; New holographic figure line paper structure: paper substrate, acrylate resin layer, copper layer, urethane resin layer.
Information transfer layer evaporation thickness 50 dusts, evaporation process: vacuum 10
-2Millibar, speed 60m/min; The adhesive layer combination process: 80 ℃ of oven dry, be 10 seconds drying time, operating speed is 20m/min; The second protective layer coating processes: adopt coating machine to be applied to wet amount 2 gram/m
2, 80 ℃ of oven dry, be 10 seconds drying time, operating speed is 20m/min; Combination process: in compounding machine, 80 ℃ of oven dry, be 10 seconds drying time, operating speed is 20m/min.
Information transfer layer evaporation thickness 500 dusts, evaporation process: vacuum 10
-3Millibar, speed 500m/min; The adhesive layer combination process: 120 ℃ of oven dry, be 30 seconds drying time, operating speed is 100m/min; The second protective layer coating processes: adopt coating machine to be applied to wet amount 10 gram/m
2, 150 ℃ of oven dry, be 30 seconds drying time, operating speed is 100m/min; Combination process: in compounding machine, 100 ℃ of oven dry, be 30 seconds drying time, operating speed is 100m/min.
Information transfer layer evaporation thickness 1000 dusts, evaporation process: vacuum 10
-3Millibar, speed 1000m/min; The adhesive layer combination process: 150 ℃ of oven dry, be 60 seconds drying time, operating speed is 150m/min; The second protective layer coating processes: adopt coating machine to be applied to wet amount 20 gram/m
2, 200 ℃ of oven dry, be 60 seconds drying time, operating speed is 150m/min; Combination process: in compounding machine, 150 ℃ of oven dry, be 60 seconds drying time, operating speed is 150m/min.
Second group of embodiment (4-6)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, and wherein the paper tinsel rete adopts the PI film; The information transfer layer adopts metallic aluminium; The adhesive layer polyurethane resin; Second protective layer adopts epoxy resin; Holographic pattern paper structure: paper substrate, urethane resin layer; New holographic figure line paper structure: paper substrate, urethane resin layer, aluminium lamination, epoxy resin layer.
The 3rd group of embodiment (7-9)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, and wherein the paper tinsel rete adopts aluminium foil; The information transfer layer adopts metal oxide silicium; Adhesive layer adopts epoxy resin; Second protective layer adopts acrylic resin; Holographic pattern paper structure: paper substrate, epoxy resin layer; New holographic figure line paper structure: paper substrate, epoxy resin layer, silicon oxide layer, acrylate resin layer.
The 4th group of embodiment (10-12)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, and wherein the paper tinsel rete adopts the composite membrane of PET film and metal forming; The information transfer layer adopts the mixture of metal oxide silicium and zinc sulphide; The copolymer of adhesive layer acrylic resin and polyurethane resin; Second protective layer adopts polyurethane resin and epoxy resin copolymer; Holographic pattern paper structure: the copolymer layer of paper substrate, acrylic resin and polyurethane resin; New holographic figure line paper structure: paper substrate, polyurethane resin and epoxy resin copolymer, silicon oxide layer, urethane resin layer.
The 5th group of embodiment (13-15)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, and wherein the paper tinsel rete adopts the composite membrane of BOPP film and metal forming; The information transfer layer adopts metallic zinc; Adhesive layer adopts the copolymer of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts the mixture of acrylic resin and polyurethane resin and epoxy resin; Holographic pattern paper structure: the copolymer layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the mixture layer of the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin, metallic zinc layer, acrylic resin and polyurethane resin and epoxy resin.
The 6th group of embodiment (16-18)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, wherein paper tinsel rete metal forming; The information transfer layer adopts zinc sulphide; Adhesive layer adopts the copolymer of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts the copolymer of acrylic resin and polyurethane resin; Transfer membrane structure: the mixture layer of female film, silica and zinc sulphide; Holographic pattern paper structure: the copolymer layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the copolymer layer of copolymer layer, zinc sulfide layer, acrylic resin and the polyurethane resin of paper substrate, olefin(e) acid resin and polyurethane resin and epoxy resin.
At the 7th group of embodiment (19-21)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, the wherein composite membrane of paper tinsel rete BOPP film and metal forming; The information transfer layer adopts silica; Adhesive layer adopts the mixture of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts mixture acrylic resin modified and modified polyurethane resin and modified epoxy; Holographic pattern paper structure: the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the mixture layer of the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin, silicon oxide layer, acrylic resin and modified polyurethane resin and modified epoxy.
The 8th group of embodiment (22-24)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, wherein paper tinsel rete metal forming; The information transfer layer adopts zinc sulphide; Adhesive layer adopts the mixture of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts mixture acrylic resin modified and modified polyurethane resin and modified epoxy; Holographic pattern paper structure: the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the mixture layer of the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin, zinc sulfide layer, acrylic resin modified and modified polyurethane resin and modified epoxy.
The 9th group of embodiment (25-27)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, wherein paper tinsel rete BOPP film; The information transfer layer adopts the mixture of zinc sulphide and silica; Adhesive layer adopts the mixture of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts mixture acrylic resin modified and modified polyurethane resin and modified epoxy; Holographic pattern paper structure: the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the mixture layer of the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin, zinc sulfide layer, acrylic resin modified and modified polyurethane resin and modified epoxy.
The tenth group of embodiment (28-30)
Different with first group of embodiment is female membrane structure: paper tinsel rete, Information Level, wherein paper tinsel rete metal forming; The information transfer layer adopts zinc sulphide; Adhesive layer adopts the mixture of acrylic resin and polyurethane resin and epoxy resin; Second protective layer adopts copolymer acrylic resin modified and modified polyurethane resin and modified epoxy; Holographic pattern paper structure: the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin; New holographic figure line paper structure: the copolymer layer of the mixture layer of paper substrate, acrylic resin and polyurethane resin and epoxy resin, zinc sulfide layer, acrylic resin and modified polyurethane resin and modified epoxy.
In embodiment 1-30, apply a transfer layer, evaporation information transfer layer more earlier on female film surface.Transfer layer adopts celluosic resin, acrylic resin, polyurethane resin, epoxy resin, the acrylic resin modified and copolymer of modified epoxy, acrylic resin modified and mixture, celluosic resin and the acrylic resin of modified polyamine fat tree copolymer, modified cellulose resin and modified epoxy and copolymer, the wax class of polyurethane resin and epoxy resin successively, process conditions recycle above-mentioned transfer layer material and get embodiment 31-60 as described in the 1-30.
The foregoing description product detects through microcosmic, and holographic pattern paper is to the accuracy that accurately reaches more than 95% of duplicating of female film holographic pattern groove structure, from contrast visually, the holographic pattern indifference on the holographic pattern on the holographic pattern paper and the female film.
Claims (14)
1. the application process to holographic pattern paper is characterized in that, comprises the steps:
The making step of holographic pattern paper is as follows:
1.1, carry out itself and paper substrate compound again at female film surface-coated adhesive layer;
1.2 female film is peeled off, is obtained holographic pattern paper;
Described female film is a roll type, and the surface has the groove structure of holographic pattern, and described groove structure is copied to adhesive layer;
Described holographic pattern paper structure is as follows:
Paper substrate;
Adhesive layer;
Described adhesive layer have be replicated the groove structure on female film surface;
Application process to holographic pattern paper is as follows:
1.3 at holographic pattern paper surface evaporation information transfer layer;
1.4 on the information transfer layer, apply second protective layer, again itself and film are carried out compound after, film is peeled off, obtain new holographic figure line paper;
It is characterized in that: duplicate on the described adhesive layer the groove structure on female film surface be copied to the information transfer layer.
2. a kind of application process according to claim 1 to holographic pattern paper, it is characterized in that, described female membrane structure is followed successively by from top to bottom: paper tinsel rete, Information Level, wherein information layer surface impression have that holographic pattern, described paper tinsel rete can be that PET film, BOPP film, PI film or other are multi-layer co-extruded, the composite membrane of modified film or metal forming or above-mentioned film and metal forming.
3. a kind of application process according to claim 1 to holographic pattern paper, it is characterized in that, described female membrane structure is followed successively by from top to bottom: paper tinsel rete, Information Level, wherein information layer surface impression have that holographic pattern, described paper tinsel rete can be that PET film, BOPP film, PI film or other are multi-layer co-extruded, the composite membrane of modified film or metal forming or above-mentioned film and metal forming.
4. a kind of application process according to claim 1 to holographic pattern paper, it is characterized in that, described technology can further be improved as follows: apply a transfer layer earlier on female film surface, coating adhesive adhesion coating again, described transfer layer material is celluosic resin or its modifier, acrylic resin or its modifier, polyamine fat resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture or wax class, adopts coating machine to be applied to wet amount 1-20 gram/m
2, 80-200 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.
5. a kind of application process according to claim 1 to holographic pattern paper, it is characterized in that, described adhesive layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture, combination process is as follows: in compounding machine, 80-150 ℃ of oven dry, be 10-60 second drying time, and operating speed is 20-150m/min.
6. a kind of application process according to claim 1 to holographic pattern paper, it is characterized in that, in the described step 1.3, described information transfer layer material is metal or metal oxide or zinc sulphide or silica or both mixtures of back, thickness is the 50-1000 dust, concrete evaporation process is as follows: in vacuum evaporation plating machine, vacuum is lower than 10-2 millibar, speed 60-1000m/min.
7. a kind of application process according to claim 1 to holographic pattern paper; it is characterized in that; in the described step 1.4; second protective layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture, and concrete coating processes is as follows: adopt coating machine to be applied to wet amount 1-20 gram/m
2, 80-200 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.
8. a kind of application process to holographic pattern paper according to claim 1 is characterized in that in the described step 1.4, combination process is as follows: in compounding machine, and 80-150 ℃ of oven dry, be 10-60 second drying time, operating speed is 20-150m/min.
9. a kind of application process to holographic pattern paper according to claim 1 is characterized in that: in the described step 1.4, can apply second protective layer as required on selectable transferable information mirror image layer top and realize different effects.
10. according to the new holographic figure line paper of claim 1 method making, described new holographic figure line paper structure is as follows successively from top to bottom:
Paper substrate;
Adhesive layer;
The information transfer layer;
Second protective layer;
It is characterized in that: described information transfer layer has the groove structure of the female film surface hologram line that is replicated.
11. new holographic figure line paper according to claim 10, it is characterized in that: also can comprise a transfer layer, between adhesive layer and information transfer layer, described transfer layer material is celluosic resin or its modifier, acrylic resin or its modifier, polyamine fat resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture or wax class, and described transfer layer has the groove structure of the female film surface hologram line that duplicates.
12. new holographic figure line paper according to claim 10 is characterized in that: described adhesive layer is the copolymer/mixture of acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or above-mentioned substance.
13. new holographic figure line paper according to claim 10 is characterized in that: described transferable information mirror image layer material is metal or metal oxide or zinc sulphide or silica or both mixtures of back, and thickness is the 50-1000 dust.
14. according to the described new holographic figure of claim 10 line paper, it is characterized in that: described second protective layer material is acrylic resin or its modifier, polyurethane resin or its modifier, epoxy resin or its modifier or aforementioned substances copolymer/mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110093637.6A CN102225637B (en) | 2011-04-14 | 2011-04-14 | Application method for hologram pattern paper and novel hologram pattern paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110093637.6A CN102225637B (en) | 2011-04-14 | 2011-04-14 | Application method for hologram pattern paper and novel hologram pattern paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102225637A true CN102225637A (en) | 2011-10-26 |
| CN102225637B CN102225637B (en) | 2014-01-15 |
Family
ID=44806654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110093637.6A Expired - Fee Related CN102225637B (en) | 2011-04-14 | 2011-04-14 | Application method for hologram pattern paper and novel hologram pattern paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102225637B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5624076A (en) * | 1992-05-11 | 1997-04-29 | Avery Dennison Corporation | Process for making embossed metallic leafing pigments |
| CN1632222A (en) * | 2004-12-11 | 2005-06-29 | 汕头市龙湖区东南实业有限公司 | Process for preparing composite transfer straightly plated cardboard |
| CN101100144A (en) * | 2007-07-23 | 2008-01-09 | 深圳劲嘉彩印集团股份有限公司 | Moulded holographic graphics and text positioning transfer printing machine |
| CN101270557A (en) * | 2008-04-22 | 2008-09-24 | 博源科技材料（烟台）有限公司 | Method for preparing holography sputtering internal lining paper |
| CN101481574A (en) * | 2009-01-21 | 2009-07-15 | 汕头市龙湖昌丰化工有限公司 | Coating capable of repetitively copying and transferring molding grating pattern and template film including the same |
| CN101564946A (en) * | 2009-05-11 | 2009-10-28 | 浙江亚欣纸业有限公司 | Producing technique of films for aluminized anti-fake wrapping paper |
-
2011
- 2011-04-14 CN CN201110093637.6A patent/CN102225637B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5624076A (en) * | 1992-05-11 | 1997-04-29 | Avery Dennison Corporation | Process for making embossed metallic leafing pigments |
| CN1632222A (en) * | 2004-12-11 | 2005-06-29 | 汕头市龙湖区东南实业有限公司 | Process for preparing composite transfer straightly plated cardboard |
| CN101100144A (en) * | 2007-07-23 | 2008-01-09 | 深圳劲嘉彩印集团股份有限公司 | Moulded holographic graphics and text positioning transfer printing machine |
| CN101270557A (en) * | 2008-04-22 | 2008-09-24 | 博源科技材料（烟台）有限公司 | Method for preparing holography sputtering internal lining paper |
| CN101481574A (en) * | 2009-01-21 | 2009-07-15 | 汕头市龙湖昌丰化工有限公司 | Coating capable of repetitively copying and transferring molding grating pattern and template film including the same |
| CN101564946A (en) * | 2009-05-11 | 2009-10-28 | 浙江亚欣纸业有限公司 | Producing technique of films for aluminized anti-fake wrapping paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102225637B (en) | 2014-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102230307B (en) | Production process for reel type hologram pattern paper, hologram pattern paper and system | |
| CN201941283U (en) | Transfer film | |
| CN102225668B (en) | Reel type holographic pattern paper, manufacturing process and system of reel holographic pattern paper and transfer film | |
| CN102350853B (en) | Production technique of holographic pattern film, holographic pattern film and system | |
| CN202081346U (en) | Novel holographic pattern paper | |
| CN102225636B (en) | Application method of holographic pattern paper, and novel holographic pattern paper | |
| CN102350890B (en) | Production technique of rolled holographic pattern film, holographic pattern film and system | |
| CN102285157B (en) | Roll-type hologram paper manufacturing process, hologram paper and system | |
| CN102225637B (en) | Application method for hologram pattern paper and novel hologram pattern paper | |
| CN102390161B (en) | Prepare process of holographic pattern film, holographic pattern film and system | |
| CN202242137U (en) | Simple line die manufacture structure | |
| CN202123720U (en) | Holographic pattern film | |
| CN202180611U (en) | Holographic pattern film | |
| CN201941284U (en) | Transfer film | |
| CN201933362U (en) | Holographic pattern paper | |
| CN201933363U (en) | Holographic graph paper | |
| CN102350891B (en) | Reel-type holographic pattern film, and its manufacturing technology and manufacturing system | |
| CN202055115U (en) | Holographic graph paper | |
| CN202180612U (en) | Holographic pattern film | |
| CN202144118U (en) | Holographic patterned paper | |
| CN202592977U (en) | High production efficiency transfer membrane | |
| CN202174770U (en) | Holographic pattern paper | |
| CN202123721U (en) | Holographic pattern membrane | |
| CN111665974A (en) | Flexible touch display screen | |
| CN102225667A (en) | Reel type holographic pattern paper, manufacturing process and system of reel holographic pattern paper and transfer film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140115 |