CN102225510A - Method for producing exploded/rolled big area titanium steel composite plate - Google Patents

Method for producing exploded/rolled big area titanium steel composite plate Download PDF

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Publication number
CN102225510A
CN102225510A CN2011101530603A CN201110153060A CN102225510A CN 102225510 A CN102225510 A CN 102225510A CN 2011101530603 A CN2011101530603 A CN 2011101530603A CN 201110153060 A CN201110153060 A CN 201110153060A CN 102225510 A CN102225510 A CN 102225510A
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CN
China
Prior art keywords
welding
titanium
steel composite
rolling
titanium plate
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Pending
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CN2011101530603A
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Chinese (zh)
Inventor
王小华
徐宇皓
王军
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LUOYANG SHUANGRUI METAL COMPOSITE MATERIAL CO Ltd
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LUOYANG SHUANGRUI METAL COMPOSITE MATERIAL CO Ltd
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Priority to CN2011101530603A priority Critical patent/CN102225510A/en
Publication of CN102225510A publication Critical patent/CN102225510A/en
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Abstract

The invention introduces a method for producing an exploded/rolled big area titanium steel composite plate. The method including includes the steps of titanium plate splicing, nondestructive testing after welding, explosive welding, nondestructive testing after explosive welding, rolling, nondestructive testing after rolling, and tissue and performance detecting, wherein, when the titanium plate is not more than 7 mm in thickness, the titanium plate is welded by adopting plasma arc welding, thereby finishing the step for titanium plate splicing; when the titanium plate is more than 7 mm in thickness, performing backing weld by using plasma arc welding and then welding the cover surface by employing automatic argon tungsten-arc welding, thereby finishing the step for titanium plate splicing. The method capable of meeting the demands of users for the titanium steel composite plates with different sizes, is unlimited to supply sizes of titanium materials in the current market, less in welding workload, low in production cost and beautiful in welding seam formation; the joints with good toughness can bear the action of great impact of a detonation wave during the explosive welding process and repeated rolling during the rolling process; the heat affected zone of welding is small; and the welding seam is good in quality. By using the process, the problem of the composite layer titanium for the exploded/rolled big area titanium steel composite plate in which the joints are split after the composite plate is exploded and rolled, is solved successfully.

Description

The preparation method of a kind of blast-rolling large tracts of land titanium steel composite board
Technical field
The present invention relates to the manufacturing technology of a kind of blast-rolling large tracts of land composite, the preparation method of particularly a kind of blast-rolling large tracts of land titanium steel composite board.
Background technology
The titanium steel composite board that adopts blast-milling method to make is subjected to the restriction of existing market titanium plate supply of material size,
In order to satisfy the different size requirement of user, following two kinds of solutions are arranged to titanium-steel composite board:
The one, the titanium steel composite board of blast-after rolling is spliced.This method has increased the welding capacity of follow-up titanium steel composite board greatly, and a not only multiple layer titanium needs welding, and basic unit's steel also needs welding, and iron solubility in titanium is very low, generally has only the 0.1%(mass fraction), surpass this limit, can generate TiFe, TiFe 2Intermetallic compound makes the serious embrittlement of weld seam.When therefore titanium steel composite board welds, could realize that base steel layer and titanium do not fuse for multiple layer mutually by structural design and the rational welding parameter of selecting, promptly titanium and titanium, steel and steel weld separately.Therefore this method welding job amount is big, production cost is high, production efficiency is low.
The 2nd, an original multiple layer titanium plate of purchasing is spliced.This method only need will be original be answered a layer titanium plate and spliced and get final product before blast-rolling.But with the welding point after such titanium plate welding, must stand the enormous impact effect of detonation wave in the postorder explosive welding process and the roll-in repeatedly in the operation of rolling, therefore require the titanium welding point must have good toughness and ductility.But because titanium has the fusing point height, thermal capacitance is big, special natures such as poor thermal conductivity and chemism height, and its solder technology is popularized far away from the stainless steel welding, and is complicated stricter than the stainless steel welding aspect requiring in weld seam protection measure, technological specification and operation.During welding titanium material, weld seam and high-temperature heat-affected zone metal are easily had an effect with gases such as airborne oxygen, hydrogen, nitrogen on the one hand, and the compound effects that contains elements such as oxygen, carbon, nitrogen, hydrogen that adheres to the workpiece welding wire surface, by oxygen, carbon, nitrogen, hydrogen contaminating impurity, the intensity and the hardness of joint are raise, plasticity descends, and easily produces defectives such as pore, crackle; On the other hand, titanium weld seam and high-temperature heat-affected zone crystal grain are easily grown up, and the plasticity of joint is descended.Except that guaranteeing the performance of weld metal, also must guarantee the performance of welding heat affected zone during welding.This welding method technology requires complicated strict.
Through patent retrieval, still do not explode at present-the rolling large tracts of land titanium steel composite board relevant patent documentation report of multiple layer titanium plate welding method.
Summary of the invention
Technical problem to be solved by this invention provides the welding method of a kind of blast-rolling large tracts of land titanium steel composite board with multiple layer titanium plate, to satisfy the requirement of user to the titanium steel composite board different size.
For the purpose that realizes solving the problems of the technologies described above, the present invention has adopted following technical scheme:
The preparation method of a kind of blast of the present invention-rolling large tracts of land titanium steel composite board comprises following technology:
1), titanium plate splicing:
When the titanium plate thickness is not more than 7mm, adopt square groove not have the welding that the titanium plate is carried out in the gap plasma arc welding (PAW), finish the splicing of titanium plate;
When titanium plate thickness during, adopt automatic tungsten anode argon arc welding to carry out cover welding again after adopting bevel Y type plasma arc welding (PAW) carrying out backing welding, to guarantee that appearance of weld is attractive in appearance greater than 7mm;
2), postwelding Non-Destructive Testing: it is qualified to press JB4730-2005 I level;
3), explosive welding: carry out explosive welding for multiple layer with basic unit's steel plate with the titanium plate after the welding;
4), Non-Destructive Testing after the explosive welding: the multiple layer titanium weld seam after the explosive welding is carried out Non-Destructive Testing, and it is qualified to press JB4730-2005 I level;
5), rolling; Titanium steel composite board to Non-Destructive Testing after qualified is rolled;
6), rolling back Non-Destructive Testing: the multiple layer weld seam to the titanium steel composite board after rolling carries out Non-Destructive Testing, and it is qualified to press JB4730-2005 I level;
7), tissue and Performance Detection: the titanium steel composite board to Non-Destructive Testing after qualified is organized and Performance Detection, and it is qualified to press GB/T8547-2006 I level, promptly finishes the manufacturing of blast-rolling large tracts of land titanium steel composite board.
When adopting plasma arc welding (PAW) to carry out the welding of titanium plate, titanium plate limiting thickness that can a through welding is 7mm, therefore when titanium plate thickness during greater than 7mm, the employing plasma arc welding (PAW) is carried out need carrying out cover welding again behind the backing welding, is not less than titanium mother metal thickness to guarantee effective throat thickness.
The preparation method of blast of the present invention-rolling large tracts of land titanium steel composite board, titanium plate splicing concrete steps are: adopt frock clamp to compress two blocks of titanium plates to be welded; Dirts such as the oil before the welding in cleaning groove district and the peripheral 20mm scope, water, rust, oxide layer; When being not more than 7mm, adopt the titanium plate thickness isoionic welding method to weld; After the titanium plate thickness adopts during greater than 7mm plasma arc welding (PAW) to carry out backing welding, adopt automatic tungsten anode argon arc welding to carry out cover welding again, finish the splicing of titanium plate.
Further, when the titanium plate thickness is not more than 7mm, adopt plasma arc welding (PAW) to carry out the welding of titanium plate, adopt " I " type groove, do not stay the gap, before the welding, the groove district of titanium plate should be clean, do not have dirt; If finished edge is contaminated, should clean or be cleared up with mechanical means, the cleaning scope should be not less than 20mm from toe.
Further, when titanium plate thickness during greater than 7mm, adopt plasma arc welding (PAW) to carry out the welding of titanium plate, adopt " Y " type groove, root face is 6mm ~ 7mm; Before the welding, the groove district of titanium plate should be clean, do not have dirt; If finished edge is contaminated, should clean or be cleared up with mechanical means, the cleaning scope should be not less than 20mm from toe.
The preparation method of blast of the present invention-rolling large tracts of land titanium steel composite board, the bonded area of the titanium steel composite board of blast-after rolling reaches the requirement of I class composite plate, and every mechanical property satisfies the requirement of GB/T8547-2006 standard B I level.Further, the former splicing welding joint of the multiple layer of titanium-steel composite board of blast-after rolling do not have cracking phenomena, and the requirement of JB/T4730-2005 I level is satisfied in Non-Destructive Testing.
These technical schemes also can make up mutually or combination, thereby reach better technique effect.
By adopting technique scheme, the present invention has following beneficial effect:
Use this method that multiple layer titanium welded, can satisfy the requirement of user to the titanium steel composite board different size, be not subjected to the restriction of existing market titanium material supply of material size in developing titanium steel composite material field, the welding job amount is less, and production cost is relatively low.Adopt the joint after this method is welded to have good toughness, stand the percussion of postorder explosive welding and the roll-in repeatedly in the operation of rolling; Blast-rolling large tracts of land titanium steel composite board has been adopted the welding method of plasma arc welding (PAW) or plasma arc welding (PAW)+automatic tungsten anode argon arc welding with multiple layer titanium plate, adopt the welding of this method to have the advantage that the heat affected area is little, weldquality good, appearance of weld is attractive in appearance, solved the difficult problem of multiple layer titanium welding point at explosive welding, rolling or blast+rolling back cracking.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
Fried-rolling large tracts of land titanium steel composite board is made.Two titanium board sizes to be spliced are respectively 6 * 1500 * 2050mm and 6 * 1000 * 2050mm, adopt the welding tooling anchor clamps to compress two blocks of titanium plates, two titanium plate square grooves to be spliced, do not stay the gap, dirts such as the oil before the welding in cleaning groove district and the peripheral 20mm scope, water, rust, oxide layer; Adopt the welding method of plasma arc welding (PAW) to weld earlier, carry out Non-Destructive Testing after the welding, carry out explosive welding by JB4730-2005 I level after qualified, base material is Q235B, be of a size of 70 * 2480 * 2030mm, the detonation wave direction is vertical with multiple layer titanium bead direction; After the explosive welding the multiple layer of titanium weld seam carried out Non-Destructive Testing, testing result is rolled after satisfying the requirement of JB/T4730-2005 I level, the multiple layer of titanium steel composite board titanium after rolling weld seam carried out Non-Destructive Testing, organize and Performance Detection after qualified by JB4730-2005 I level, testing result all satisfies the index of correlation requirement of standard GB/T8547-2006 I class composite plate, adopts this technology successfully to solve the blast-rolling large tracts of land titanium steel composite board problem of multiple layer titanium in blast, rolling back joint cracking.The manufacturing of blast-rolling large tracts of land titanium steel composite board is finished.
Embodiment 2:
Blast-rolling large tracts of land titanium steel composite board is made.Two titanium board sizes to be spliced are respectively 8 * 1020 * 1480mm and 8 * 1020 * 1480mm, finished edge is " Y " type, bevel angle is 60o, root face is 6mm, adopt the welding tooling anchor clamps to compress two blocks of titanium plates, do not stay the gap between two blocks of titanium plates to be spliced, dirts such as the oil before the welding in cleaning groove district and the peripheral 20mm scope, water, rust oxide layer; Adopt earlier the welding that feels secure of the welding method of plasma arc welding (PAW), and then adopt the welding method of automatic tungsten anode argon arc welding to carry out cover welding, carry out Non-Destructive Testing after the welding, carrying out the explosive welding base material by JB4730-2005 I level after qualified is Q235B, be of a size of 60 * 2020 * 1460mm, the detonation wave direction is parallel with multiple layer titanium bead direction; After the explosive welding the multiple layer of titanium weld seam carried out Non-Destructive Testing, testing result is rolled after satisfying the requirement of JB/T4730-2005 I level, the multiple layer of titanium steel composite board titanium after rolling weld seam carried out Non-Destructive Testing, organize and Performance Detection after qualified by JB4730-2005 I level, testing result all satisfies the index of correlation requirement of standard GB/T8547-2006 I class composite plate, adopts this technology successfully to solve the blast-rolling large tracts of land titanium steel composite board problem of multiple layer titanium in blast, rolling back joint cracking.The manufacturing of blast-rolling large tracts of land titanium steel composite board is finished.
Comparative Examples:
Blast-rolling large tracts of land titanium steel composite board is made.Titanium board size to be spliced is respectively 6 * 1500 * 2050mm and 6 * 1000 * 2050mm, adopts the method for traditional automatic tungsten anode argon arc welding to weld, and carries out Non-Destructive Testing after the welding, carries out explosive welding by JB4730-2005 I level after qualified; Base material is Q235B, is of a size of 70 * 2480 * 2030mm, and the detonation wave direction is vertical with multiple layer titanium bead direction; After the explosive welding the multiple layer of titanium weld seam carried out Non-Destructive Testing, testing result is rolled after satisfying the requirement of JB/T4730-2005 I level, the multiple layer of titanium steel composite board titanium after rolling weld seam carried out Non-Destructive Testing, the multiple layer of titanium steel composite board titanium is comparatively serious along weld seam parallel direction cracking, through Non-Destructive Testing, find the obvious crackle in five places, crack length is in 40mm ~ 220mm scope.

Claims (5)

1. the preparation method of blast-rolling large tracts of land titanium steel composite board is characterized in that comprising following technology:
1), titanium plate splicing:
When the titanium plate thickness is not more than 7mm, adopt square groove not have the welding that the titanium plate is carried out in the gap plasma arc welding (PAW), finish the splicing of titanium plate;
When titanium plate thickness during, adopt automatic tungsten anode argon arc welding to carry out cover welding again after adopting bevel Y type plasma arc welding (PAW) carrying out backing welding, to guarantee that appearance of weld is attractive in appearance greater than 7mm;
2), postwelding Non-Destructive Testing: it is qualified to press JB4730-2005 I level;
3), explosive welding: carry out explosive welding for multiple layer with basic unit's steel plate with the titanium plate after the welding;
4), Non-Destructive Testing after the explosive welding: the multiple layer titanium weld seam after the explosive welding is carried out Non-Destructive Testing, and it is qualified to press JB4730-2005 I level;
5), rolling; Titanium steel composite board to Non-Destructive Testing after qualified is rolled;
6), rolling back Non-Destructive Testing: the multiple layer weld seam to the titanium steel composite board after rolling carries out Non-Destructive Testing, and it is qualified to press JB4730-2005 I level;
7), tissue and Performance Detection: the titanium steel composite board to Non-Destructive Testing after qualified is organized and Performance Detection, and it is qualified to press GB/T8547-2006 I level, promptly finishes the manufacturing of blast-rolling large tracts of land titanium steel composite board.
2. according to the preparation method of the described blast of claim 1-rolling large tracts of land titanium steel composite board, it is characterized in that: described titanium plate splicing concrete steps are: adopt frock clamp to compress two blocks of titanium plates to be welded; Dirts such as the oil before the welding in cleaning groove district and the peripheral 20mm scope, water, rust, oxide layer; When being not more than 7mm, adopt the titanium plate thickness isoionic welding method to weld; After the titanium plate thickness adopts during greater than 7mm plasma arc welding (PAW) to carry out backing welding, adopt automatic tungsten anode argon arc welding to carry out cover welding again, finish the splicing of titanium plate.
3. according to the preparation method of the described blast of claim 2-rolling large tracts of land titanium steel composite board, it is characterized in that: when the titanium plate thickness is not more than 7mm, adopt plasma arc welding (PAW) to carry out the welding of titanium plate, " I " type of employing groove, do not stay the gap, before the welding, the groove district of titanium plate should be clean, do not have dirt; If finished edge is contaminated, should clean or be cleared up with mechanical means, the cleaning scope should be not less than 20mm from toe; When titanium plate thickness during greater than 7mm, adopt plasma arc welding (PAW) to carry out the welding of titanium plate, adopt " Y " type groove, root face is 6mm ~ 7mm; Before the welding, the groove district of titanium plate should be clean, do not have dirt; If finished edge is contaminated, should clean or be cleared up with mechanical means, the cleaning scope should be not less than 20mm from toe.
4. according to the preparation method of claim 1,2 or 3 each described blast-rolling large tracts of land titanium steel composite boards, it is characterized in that: the bonded area of the titanium-steel composite board of blast-after rolling reaches the requirement of I class composite plate, and every mechanical property satisfies the requirement of GB/T8547-2006 standard B I level.
5. according to the preparation method of claim 1,2 or 3 each described blast-rolling large tracts of land titanium steel composite boards, it is characterized in that: the former splicing welding joint of the multiple layer of titanium-steel composite board of blast-after rolling do not have cracking phenomena, and the requirement of JB/T4730-2005 I level is satisfied in Non-Destructive Testing.
CN2011101530603A 2011-06-09 2011-06-09 Method for producing exploded/rolled big area titanium steel composite plate Pending CN102225510A (en)

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Cited By (12)

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CN102489852A (en) * 2011-11-15 2012-06-13 湖南湘投金天钛金属有限公司 Plasma gas protection titanium plate welding process
CN102679134A (en) * 2012-05-17 2012-09-19 国际辊轧成型学会有限公司 Titanium steel composite slab and manufacturing method thereof
CN102785017A (en) * 2012-08-02 2012-11-21 中国石油化工集团公司 Composite welding process used in narrow space
CN103464881A (en) * 2013-08-20 2013-12-25 南京理工大学 Tailor welding device for titanium-steel composite plate
CN103785962A (en) * 2014-01-17 2014-05-14 南京理工大学 Full penetration welding method for titanium-steel composite board
CN104368600A (en) * 2014-10-27 2015-02-25 南京钢铁股份有限公司 Method for preparing titanium steel cladding board with thin coating
CN105057353A (en) * 2015-08-04 2015-11-18 南京钢铁股份有限公司 Rolling method for explosive cladding titanium-steel-titanium double-faced composite board
CN108127276A (en) * 2017-12-20 2018-06-08 鲁西工业装备有限公司 A kind of welding method of zircaloy pressure vessel
CN109332923A (en) * 2018-09-26 2019-02-15 洛阳双瑞金属复合材料有限公司 A kind of explosive welding ferritic stainless steel method for automatically split-jointing
CN110814061A (en) * 2019-10-22 2020-02-21 洛阳双瑞金属复合材料有限公司 Manufacturing method of corrosion-resistant metal composite plate for construction industry
CN112171092A (en) * 2020-09-11 2021-01-05 中国核工业第二二建设有限公司 Efficient tailor-welding equipment and method for nuclear power stainless pool steel clad plate
CN112935726A (en) * 2021-02-05 2021-06-11 西安交通大学 Method for manufacturing super-long plate based on explosive welding and obtained super-long plate

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102489852A (en) * 2011-11-15 2012-06-13 湖南湘投金天钛金属有限公司 Plasma gas protection titanium plate welding process
CN102679134A (en) * 2012-05-17 2012-09-19 国际辊轧成型学会有限公司 Titanium steel composite slab and manufacturing method thereof
CN102679134B (en) * 2012-05-17 2015-04-01 国际辊轧成型学会有限公司 Titanium steel composite slab and manufacturing method thereof
CN102785017A (en) * 2012-08-02 2012-11-21 中国石油化工集团公司 Composite welding process used in narrow space
CN102785017B (en) * 2012-08-02 2015-07-08 中国石油化工集团公司 Composite welding process used in narrow space
CN103464881A (en) * 2013-08-20 2013-12-25 南京理工大学 Tailor welding device for titanium-steel composite plate
CN103785962B (en) * 2014-01-17 2016-03-02 南京理工大学 A kind of titanium-steel composite board full impregnated welding method
CN103785962A (en) * 2014-01-17 2014-05-14 南京理工大学 Full penetration welding method for titanium-steel composite board
CN104368600A (en) * 2014-10-27 2015-02-25 南京钢铁股份有限公司 Method for preparing titanium steel cladding board with thin coating
CN105057353A (en) * 2015-08-04 2015-11-18 南京钢铁股份有限公司 Rolling method for explosive cladding titanium-steel-titanium double-faced composite board
CN108127276A (en) * 2017-12-20 2018-06-08 鲁西工业装备有限公司 A kind of welding method of zircaloy pressure vessel
CN108127276B (en) * 2017-12-20 2020-11-03 鲁西工业装备有限公司 Welding method of zirconium alloy pressure container
CN109332923A (en) * 2018-09-26 2019-02-15 洛阳双瑞金属复合材料有限公司 A kind of explosive welding ferritic stainless steel method for automatically split-jointing
CN110814061A (en) * 2019-10-22 2020-02-21 洛阳双瑞金属复合材料有限公司 Manufacturing method of corrosion-resistant metal composite plate for construction industry
CN112171092A (en) * 2020-09-11 2021-01-05 中国核工业第二二建设有限公司 Efficient tailor-welding equipment and method for nuclear power stainless pool steel clad plate
CN112935726A (en) * 2021-02-05 2021-06-11 西安交通大学 Method for manufacturing super-long plate based on explosive welding and obtained super-long plate
CN112935726B (en) * 2021-02-05 2022-12-09 西安交通大学 Method for manufacturing super-long plate based on explosive welding and obtained super-long plate

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Application publication date: 20111026