CN102219383B - Enamel glaze material - Google Patents
Enamel glaze material Download PDFInfo
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- CN102219383B CN102219383B CN 201110091110 CN201110091110A CN102219383B CN 102219383 B CN102219383 B CN 102219383B CN 201110091110 CN201110091110 CN 201110091110 CN 201110091110 A CN201110091110 A CN 201110091110A CN 102219383 B CN102219383 B CN 102219383B
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- CN
- China
- Prior art keywords
- enamel
- glaze material
- frit
- enamel glaze
- porcelain
- Prior art date
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- 210000003298 dental enamel Anatomy 0.000 title abstract description 36
- 239000000463 material Substances 0.000 title abstract description 10
- 239000000037 vitreous enamel Substances 0.000 claims description 25
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 12
- 239000010959 steel Substances 0.000 abstract description 12
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 abstract 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 238000004534 enameling Methods 0.000 description 5
- 229910052573 porcelain Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002320 enamel (paints) Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229910000714 At alloy Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to an enamel glaze material for a steel plate. After the glaze material is calcinated, an enameled product has corrosion resistance, chemical resistance, weather resistance and decorative property, and the service life of the enamel can be prolonged. The technical problem to be solved is to provide the enamel glaze material. The enamel glaze material overcomes the defects that the conventional enamel glaze material is easy to deform and soften in high-temperature high-humidity environments. The enamel glaze material capable of resisting corrosion, softening and deformation is provided. The enamel glaze material comprises Ba2O3, Li2O, Na2O, MgO, Al2O3, SiO2, P2O5, SO3, K2O, CaO, TiO2, Cr2O3 and the like.
Description
Technical field
The present invention relates to the frit for porcelain enamel that a kind of steel plate is used, this glaze can be given enamel and ceramic products solidity to corrosion, chemical resistant properties, weathering resistance and decorate properties after calcining, can improve the work-ing life of enamel.
Background technology
As everyone knows, japanning and enamel the porcelain method and can be given steel plate various performances, such as solidity to corrosion, chemical resistant properties, weathering resistance and ornamental, and can improve its work-ing life.And enamel that the porcelain steel plate compares with painted steel sheet be more excellent in many aspects, for example hardness, weathering resistance, cleaning Restoration, thermotolerance and flame retardant resistance, but also have corresponding problem, production cost costliness and enamel layer are easily peeled off.
At present, enamel the porcelain product and also is called rear coated article, by first process steel plate then enamel coating prepare.Compare its manufacturing cost with the precoating goods quite expensive, during the precoating goods, first continuous coating coiled material steel plate then carries out the making of sheet material after enamel porcelain and calcining.On the other hand, the film of painted steel sheet is poisonous to post-treatment to a certain extent.Therefore, by pre-coated steel plate, can manufacture slight fabricated product, reduce manufacturing cost, so be widely used painted steel sheet.In other words, enamel and painting products have limited the broadened application of enamel technical field at price differentials.But, the height had due to enamelware itself suppress contamination and by clean can excellent recovery chemical resistant properties, still be widely used in hospital.
For this reason, at present, in the urgent need to developing a kind of enamel, the porcelain steel plate, when this enameling sheet carries out bending machining after calcining enamel figure layer, still can keep enamel figure layer not peel off.
In order to solve the problem of above-mentioned existence, mainly for the formula of frit for porcelain enamel, taked improvement.But, do not have at present.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of frit for porcelain enamel, has solved current frit for porcelain enamel yielding, softening defect in high temperature, high humidity environment, and a kind of frit for porcelain enamel of corrosion-resistant, anti-softening, distortion is provided.
The invention provides following technical scheme: a kind of frit for porcelain enamel is characterized in that it is comprised of the compound of following mass percent:
B
2O
3 4.0～5.0%、 Li
2O
6.0～7.0%、 Na
2O
12.0～13.0%、
MgO
0.30～0.80%、 Al
2O
3 1.50～2.0%、 SiO
2 60.0～62.0%、
P
2O
5 0.08～0.15%、 SO
3 0.05～0.10%、 K
2O 1.40～1.60% 、
CaO
2.10～2.40%、 TiO
2 2.10～2.40%、 Cr
2O
3 0.03～0.08%、
MnO 0.60～1.0%、 Fe
2O
3 0.20～0.60% 、 Co
3O
4 1.20～1.50%、
NiO
0.20～0.50%、 CuO 0.60～1.0%、 ZnO
0.20～0.50% 、
SrO
0.20～0.40%、 ZrO
2 1.50～2.0%、 Nb
2O
5 0.005～0.02%、
MoO
3 0.30～0.60%、 BaO
2.0～2.50%、 HfO
2 0.04～0.10%。
Described frit for porcelain enamel is comprised of the compound of following mass percent:
B
2O
3 4.0～4.5%、 Li
2O
6.0～6.5%、 Na
2O
12.0～12.5%、
MgO
0.30～0.60%、 Al
2O
3 1.50～1.80%、 SiO
2 60.0～61.0%、
P
2O
5 0.08～0.12%、 SO
3 0.05～0.08%、 K
2O 1.45～1.55% 、
CaO
2.20～2.30%、 TiO
2 2.20～2.30%、 Cr
2O
3 0.03～0.06%、
MnO 0.60～0.80%、 Fe
2O
3 0.30～0.50% 、 Co
3O
4 1.30～1.50%、
NiO
0.20～0.40%、 CuO 0.60～0.80% 、 ZnO
0.25～0.40% 、
SrO
0.25～0.30%、 ZrO
2 1.60～1.80%、 Nb
2O
5 0.08～0.015%、
MoO
3 0.40～0.50%、 BaO
2.10～2.40%、 HfO
2 0.04～0.08%。
Described frit for porcelain enamel is comprised of the compound of following mass percent:
B
2O
3 4.0～4.4%、 Li
2O
6.0～6.4%、 Na
2O
12.0～12.5%、
MgO
0.30～0.50%、 Al
2O
3 1.50～1.70%、 SiO
2 60.0～60.8%、
P
2O
5 0.09～0.11%、 SO
3 0.05～0.07%、 K
2O 1.50～1.55% 、
CaO
2.25～2.30%、 TiO
2 2.25～2.30%、 Cr
2O
3 0.04～0.06%、
MnO 0.65～0.75%、 Fe
2O
3 0.35～0.38% 、 Co
3O
4 1.30～1.50%、
NiO
0.20～0.30%、 CuO 0.65～0.75% 、 ZnO
0.25～0.35% 、
SrO
0.25～0.28%、 ZrO
2 1.70～1.80%、 Nb
2O
5 0.01～0.012%、
MoO
3 0.40～0.45%、 BaO
2.20～2.30%、 HfO
2 0.04～0.06%。
Described frit for porcelain enamel is comprised of the compound of following mass percent:
B
2O
3 4.2%、 Li
2O
6.2%、 Na
2O
12.28%、 MgO
0.45%、
Al
2O
3 1.60%、 SiO
2 60.50%、 P
2O
5 0.10%、 SO
3 0.06%、
K
2O 1.53% 、 CaO
2.27%、 TiO
2 2.28%、 Cr
2O
3 0.05%、
MnO 0.70%、 Fe
2O
3 0.36% 、 Co
3O
4 1.40%、 NiO
0.25%、
CuO 0.70% 、 ZnO
0.30% 、 SrO
0.27%、 ZrO
2 1.75%、
Nb
2O
5 0.01%、 MoO
3 0.44%、 BaO
2.25%、 HfO
2 0.05%。
Contain ZnO in frit for porcelain enamel provided by the invention, because the existence of zinc in al-zn alloy coating can reduce the adhesion between coating and enamel layer, therefore add man-hour in the laggard line bend of enamelization when the gained enameling sheet, can strengthen the problem that enamel layer is peeled off.Due to zinc to oxidizing reaction have the height susceptibility, so its easily in the enamel step with enamel coating in inorganic oxide coating generation oxidizing reaction; The layer formed by oxidation can damage the adhesion between coating and enamel layer at its boundary.By interlayer middle layer between coating and uppermost enamel layer, can control the oxidizing reaction of these layers, just can suppress any excessive oxidation of al-zn alloy coating and enamel coating.
Exist and there is the zinc of sacrificing the solidity to corrosion effect in the alloy layer of contact steel plate, and exist enamel is adhered to excellent aluminium with high-content at alloy layer and enamel layer boundary, therefore obtain the enameling sheet of precoating type.The enameling sheet of this interpolation aluminium sesquioxide not only has excellent enamel adherence and suppresses the end face corrosion, and suppresses in addition the effect that bending machining is partly got rusty.
The Na contained in enamel provided by the invention
2o, Li
2o is the solubility promoter of frit for porcelain enamel, and it has expansion and burns till amplitude, affects glossiness and the weather resistance of enamel firing temperature, generation enamel.
Contain NiO, Co in frit for porcelain enamel provided by the invention
3o
4, MnO, P
2o
5, these compounds belong to adhesive agent, have and suppress reacting of al-zn alloy coating and enamel layer.
The CaO contained in frit for porcelain enamel provided by the invention is the raw material of well fluxing, and it can reduce the viscosity of melts in enamel significantly.
The BaO contained in frit for porcelain enamel provided by the invention is the component that impact generates chemical durability, mechanical property and the thermal expansivity of enamel layer.
SiO in frit for porcelain enamel of the present invention
2that impact generates the chemical durability of enamel layer and the component of mechanical property.
The CaO contained in frit for porcelain enamel provided by the invention and TiO
2use together the effect that plays inferior light.
The proportioning the present invention relates to and percentage composition thereof are all by percentage to the quality.
In sum, the present invention has and compares the existing more resistant to elevated temperatures characteristic of enameling sheet, has and shows, high temperature resistant, in long-time hot environment, the softening time of surperficial enamel glaze is long, corrosion resistance nature is good simultaneously, and glaze is in hot environment, can keep for a long time corrosion resistant characteristic.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described further.In these embodiments, unless otherwise indicated, all percentage compositions all by weight.
Embodiment 1:
A kind of frit for porcelain enamel, it is comprised of the compound of following mass percent: B
2o
34.5%, Li
2o6.5%, Na
2o
12.5%, MgO
0.30%, Al
2o
31.50%, SiO
260.0%, P
2o
50.12%, SO
30.08%, K
2o 1.55%, CaO
2.20%, TiO
22.20%, Cr
2o
30.03%, MnO 0.80%, Fe
2o
30.50%, Co
3o
41.50%, NiO
0.20%, CuO 0.60%, ZnO
0.25%, SrO
0.30%, ZrO
21.80%, Nb
2o
50.015%, MoO
30.40%, BaO
2.100%, HfO
20.04%, all the other are water.
The frit for porcelain enamel that above-mentioned formula makes, while being in 750 ℃, can keep not softening in 10 hours, indeformable in 24 hours.Be in the environment of humidity 80%, does not corrode on surface simultaneously.
Embodiment 2:
A kind of frit for porcelain enamel, it is comprised of the compound of following mass percent: B
2o
34.0%, Li
2o6.4%, Na
2o
12.0%, MgO
0.50%, Al
2o
31.50%, SiO
260.8%, P
2o
50.09%, SO
30.07%, K
2o1.50%, CaO
2.30%, TiO
22.25%, Cr
2o
30.06%, MnO 0.65%, Fe
2o
30.38%, Co
3o
41.30%, NiO
0.30%, CuO 0.655%, ZnO
0.35%, SrO
0.25%, ZrO
21.80%, Nb
2o
50.01%, MoO
30.45%, BaO
2.20%, HfO
20.06%, all the other are water.
The frit for porcelain enamel that above-mentioned formula makes, while being in 750 ℃, can keep not softening in 10 hours, indeformable in 24 hours.Be in the environment of humidity 80%, does not corrode on surface simultaneously.
Embodiment 3:
A kind of frit for porcelain enamel, it is comprised of the compound of following mass percent: B
2o
34.2%, Li
2o
6.2%, Na
2o
12.28%, MgO
0.45%, Al
2o
31.60%, SiO
260.50%, P
2o
50.10%, SO
30.06%, K
2o 1.53%, CaO
2.27%, TiO
22.28%, Cr
2o
30.05%, MnO 0.70%, Fe
2o
30.36%, Co
3o
41.40%, NiO
0.25%, CuO 0.70%, ZnO
0.30%, SrO
0.27%, ZrO
21.75%, Nb
2o
50.01%, MoO
30.44%, BaO
2.25%, HfO
20.05%, all the other are water.
The frit for porcelain enamel that above-mentioned formula makes, while being in 750 ℃, can keep not softening in 10 hours, indeformable in 24 hours.Be in the environment of humidity 80%, does not corrode on surface simultaneously.
Claims (2)
1. a frit for porcelain enamel is characterized in that it is comprised of the compound of following mass percent:
B
2O
3 4.0～4.5%、 Li
2O
6.0～6.5%、 Na
2O
12.0～12.5%、
MgO
0.30～0.60%、 Al
2O
3 1.50～1.80%、 SiO
2 60.0～61.0%、
P
2O
5 0.08～0.12%、 SO
3 0.05～0.08%、 K
2O 1.45～1.55%、
CaO
2.20～2.30%、 TiO
2 2.20～2.30%、 Cr
2O
3 0.03～0.06%、
MnO 0.60～0.80%、 Fe
2O
3 0.30～0.50%、 Co
3O
4 1.30～1.50%、
NiO
0.20～0.40%、 CuO 0.60～0.80%、 ZnO
0.25～0.40%、
SrO
0.25～0.30%、 ZrO
2 1.60～1.80%、 Nb
2O
5 0.01～0.015%、
MoO
30.40～0.50%, BaO
2.10～2.40%, HfO
20.04～0.08%, all the other are water.
2. frit for porcelain enamel according to claim 1 is characterized in that being comprised of the compound of following mass percent:
B
2O
3 4.2%、 Li
2O
6.2%、 Na
2O
12.28%、 MgO
0.45%、
Al
2O
3 1.60%、 SiO
2 60.50%、 P
2O
5 0.10%、 SO
3 0.06%、
K
2O 1.53% 、 CaO
2.27%、 TiO
2 2.28%、 Cr
2O
3 0.05%、
MnO 0.70%、 Fe
2O
3 0.36% 、 Co
3O
4 1.40%、 NiO
0.25%、
CuO 0.70% 、 ZnO
0.30% 、 SrO
0.27%、 ZrO
2 1.75%、
Nb
2o
50.01%, MoO
30.44%, BaO
2.25%, HfO
20.05%, all the other are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110091110 CN102219383B (en) | 2011-04-12 | 2011-04-12 | Enamel glaze material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110091110 CN102219383B (en) | 2011-04-12 | 2011-04-12 | Enamel glaze material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102219383A CN102219383A (en) | 2011-10-19 |
| CN102219383B true CN102219383B (en) | 2013-12-18 |
Family
ID=44776127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110091110 Active CN102219383B (en) | 2011-04-12 | 2011-04-12 | Enamel glaze material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102219383B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2599895C1 (en) * | 2015-10-19 | 2016-10-20 | Юлия Алексеевна Щепочкина | Glaze |
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| KR102172460B1 (en) | 2019-02-22 | 2020-10-30 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof and cooking appliance |
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| KR102172459B1 (en) | 2019-02-22 | 2020-10-30 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof and cooking appliance |
| KR102310341B1 (en) | 2019-02-22 | 2021-10-07 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof and cooking appliance |
| KR102172417B1 (en) | 2019-02-22 | 2020-10-30 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof |
| KR102172418B1 (en) | 2019-02-22 | 2020-10-30 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof and cooking appliance |
| KR102172416B1 (en) | 2019-02-22 | 2020-10-30 | 엘지전자 주식회사 | Composition for enamel, method for preparation thereof and cooking appliance |
| CN110484027B (en) * | 2019-06-27 | 2020-08-11 | 浙江大学 | Active inorganic anticorrosive coating for improving bonding strength between steel bar and concrete and coating method thereof |
| CN110790510A (en) * | 2019-12-16 | 2020-02-14 | 黄奕雯 | Wear-resistant high-hardness ceramic glaze and preparation method thereof |
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| CN1056477A (en) * | 1990-05-12 | 1991-11-27 | 邓念东 | Colour-decorated glass composite material with crystalline lustre |
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| DE3710608C1 (en) * | 1987-03-31 | 1988-08-25 | Bayer Ag | Enamel frits for sheet steel with improved adhesion and their use |
| US4828596A (en) * | 1987-10-01 | 1989-05-09 | Giba-Geigy Corporation | Use of glass enamel coating compositions as an anti-sticking agent |
| EP0916624B1 (en) * | 1997-11-11 | 2001-07-25 | Kawasaki Steel Corporation | Porcelain-enameled steel sheets and frits for enameling |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056477A (en) * | 1990-05-12 | 1991-11-27 | 邓念东 | Colour-decorated glass composite material with crystalline lustre |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2599895C1 (en) * | 2015-10-19 | 2016-10-20 | Юлия Алексеевна Щепочкина | Glaze |
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| Publication number | Publication date |
|---|---|
| CN102219383A (en) | 2011-10-19 |
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