CN102212289A - Preparation method of paint used for coating environmentally-friendly paper - Google Patents
Preparation method of paint used for coating environmentally-friendly paper Download PDFInfo
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- CN102212289A CN102212289A CN2011101065194A CN201110106519A CN102212289A CN 102212289 A CN102212289 A CN 102212289A CN 2011101065194 A CN2011101065194 A CN 2011101065194A CN 201110106519 A CN201110106519 A CN 201110106519A CN 102212289 A CN102212289 A CN 102212289A
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- light calcium
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- calcium carbonate
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Abstract
The invention relates to a preparation method of a paint used for coating environmentally-friendly paper, and the method is characterized by comprising the following steps: dispersing 40-60 parts by weight of light calcium carbonate in water, simultaneously adding 0.1-1.0 part by weight of dispersant, and dispersing for 30-60 minutes by virtue of a high-speed dispersing machine to obtain a light calcium carbonate slurry; and transferring the light calcium carbonate slurry to a stirring kettle, adding 20-30 parts by weight of styrene butadiene latex, 0.5-2.0 parts by weight of tween, 0.2-0.8 part by weight of silane coupling agent and 0.05-0.2 part by weight of organosilicone antifoaming agent into the light calcium carbonate slurry while continuously stirring, and uniformly stirring to obtain the paint used for coating the environmentally-friendly paper. The paint used for coating the environmentally-friendly paper prepared by the preparation method provided by the invention has high adhesion force, and a coating formed by the paint has good ink absorption property.
Description
Technical field
The present invention relates to the manufacture method of a kind of environmental protection paper coating with coating.
Background technology
The environmental protection synthetic paper is a kind of plastic material novel product, by various The application of new technique, makes it have the characteristic of plastics and paper simultaneously.As novel paper kind, the premium properties of environmental protection synthetic paper is more and more obvious, and purposes also more and more widely has been extended to many frontiers, and many product innovations constantly are developed.The environmental protection synthetic paper has had the development history of three more than ten years abroad, along with the reinforcement of global environmental consciousness,, accelerated the development of synthetic paper because of the normal wood fibrous paper causes a large amount of pollutions, new environmental protection synthetic paper kind constantly occurs, and has enlarged the range of application of environmental protection synthetic paper.At present, world's sales volume every year of environmental protection synthetic paper product, the environmental protection synthetic paper partly replaces the paces of fibrous paper to be accelerated with 10% speed increase.
Environmental protection synthetic paper intensity is higher than common plant fiber paper, and is very excellent aspect tensile strength, tear strength and tensile strength; And good weathering resistance, water tolerance, chemicals-resistant, oil resistance arranged; But environmental protection synthetic paper long period of soaking performance in water is constant, also is not afraid of oil immersion, and is very strong to the resistibility of solution such as acid, alkali; Printing effect is good after the environmental protection synthetic paper surface coated, and its surface is pure white, opaque, thickness even, the printed matter tone is soft, effect is distinct; Dimensional stabilizing, indeformable under wet condition, color and luster is constant, the outward appearance retentivity is good.
Chinese invention patent CN1931949 discloses a kind of water-based petroleum resin tackiness agent and preparation method thereof.The component of this tackiness agent and weight percent thereof are: petroleum resin 10～20%, vinyl-acetic ester 5～10%, colloid protective agent 2～5%, emulsifying agent 1.0～3%, anion surfactant A 0.25～1%, anion surfactant B 0.05～0.5%, initiator 0.25～0.5%, water 65～75%.Its preparation method is that main raw material and vinyl-acetic ester prepare through emulsion copolymerization with petroleum resin, prepared tackiness agent is under the low temperature of room temperature or 70 ℃, can obtain stable bonding strength in short period of time, it is to the bonding strength of the whole wood pulp printer paper internal bond strength greater than paper itself.The tackiness agent of this invention is applicable to paper and the bonding processing of cardboard, paper tube production, papery packing, apply the field such as bonding with tackiness agent, synthetic paper and synthon film in the coating.
Chinese invention patent CN101457056 discloses a kind of synthetic paper coating and its production and use, this coating comprises 10～20% waste polystyrene foam plastics, 20～30% kaolin, 50～60% toluene, 0.2～0.5% static inhibitor, 0.1～0.3% surface slip agent, 2～3% composite assistants, and above per-cent is mass percent.After in polystyrene foamed plastics, adding toluene, melt polystyrene foamed plastics being no more than under 150 ℃ the temperature, add composite assistant again, make AK modified resin; Kaolin and the AK modified resin that makes fully are uniformly dispersed, are ground to fineness≤15 micron then; At last surface slip agent, static inhibitor and ground material are uniformly dispersed together and promptly make synthetic paper coating.Synthetic paper coating is formed printable layer on the synthetic paper top layer, improve the printability of synthetic paper, make things convenient for synthetic paper to be suitable for general mode of printing and common ink printing, enlarge the use range of synthetic paper.
The present invention adopts light calcium carbonate as filler, can strengthen the ink absorption of coating greatly; The styrene-butadiene latex of use is that caking agent not only helps improving the bonding strength of coating but also helps environmental protection; Silane coupling agent can play the effect of bridge coupling together between light calcium carbonate particle and the styrene-butadiene latex molecular chain; Tween can make coating sprawl in that the surface of environmental protection paper is easier, also helps improving bonding strength.
Summary of the invention
A kind of environmental protection paper coating manufacture method of coating, it is characterized in that: in weight part 40～60 parts of light calcium carbonates are dispersed in 40 parts the water, add 0.1～1.0 part of dispersion agent simultaneously, disperse to make in 30～60 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry is transferred in the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 20～30 parts of styrene-butadiene latexes, 0.5～2.0 part of tween, 0.2～0.8 part of silane coupling agent, 0.05～0.2 part of silicone antifoam agent, stir, obtain environmental protection paper coating coating.
The order number of described light calcium carbonate is 800～2500 orders.
Described dispersion agent is a kind of in sodium polyacrylate, Sodium hexametaphosphate 99, the trisodium phosphate.
Described tween is one or more in the polysorbas20,40,60,80.
Described silane coupling agent is a kind of in amino silicane coupling agent, the epoxy silane coupling.
The resulting environmental protection paper coating ADHESION OF PAINTS power height of aforesaid method, the ink absorption of coating is good.
Embodiment
Embodiment 1
40kg 800 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 0.1kg Sodium hexametaphosphate 99 is dissolved with little water, disperse to make in 30 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 20kg styrene-butadiene latex, 0.5kg polysorbas20,0.2kg amino silicane coupling agent KH550,0.05kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 100.8kg.
Embodiment 2
60kg 2500 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 1.0kg sodium polyacrylate is diluted with little water, disperse to make in 60 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 30kg styrene-butadiene latex, 2.0kg tween 80,0.8kg epoxy silane coupling KH560,0.2kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 134.0kg.
Embodiment 3
50kg 1500 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 0.5kg sodium polyacrylate is diluted with little water, disperse to make in 50 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 25kg styrene-butadiene latex, 1.5kg polysorbate60,0.6kg epoxy silane coupling KH560,0.1kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 117.7kg.
Embodiment 4
45kg 1000 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 0.4kg trisodium phosphate is dissolved with little water, disperse to make in 40 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 24kg styrene-butadiene latex, 0.8kg polysorbate40,0.5kg amino silicane coupling agent KH550,0.08kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 110.7kg.
Embodiment 5
55kg 2000 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 0.6kg Sodium hexametaphosphate 99 is dissolved with little water, disperse to make in 45 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 26kg styrene-butadiene latex, 1.6kg polysorbate60,0.3kg amino silicane coupling agent KH550,0.15kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 123.6kg.
Embodiment 6
48kg 1500 purpose light calcium carbonates are dispersed in the water of 40kg, join in the slurry after the 0.9kg sodium polyacrylate is diluted with little water, disperse to make in 38 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry transferred in 150 liters the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 27kg styrene-butadiene latex, 0.6kg tween 80,0.5kg epoxy silane coupling KH560,0.08kg silicone antifoam agent, stir, obtain environmental protection paper coating coating 117.0kg.
Claims (6)
1. an environmental protection paper is coated with the manufacture method of using coating, it is characterized in that: in weight part 40～60 parts of light calcium carbonates are dispersed in 40 parts the water, add 0.1～1.0 part of dispersion agent simultaneously, disperse to make in 30～60 minutes light calcium carbonate slurry with high speed dispersor; Light calcium carbonate slurry is transferred in the stirring tank, under constantly stirring, in light calcium carbonate slurry, add 20～30 parts of styrene-butadiene latexes, 0.5～2.0 part of tween, 0.2～0.8 part of silane coupling agent, 0.05～0.2 part of silicone antifoam agent, stir, obtain environmental protection paper coating coating.
2. the described method of claim 1, wherein the order number of light calcium carbonate is 800～2500 orders.
3. the described method of claim 1, wherein dispersion agent is a kind of in sodium polyacrylate, Sodium hexametaphosphate 99, the trisodium phosphate.
4. the described method of claim 1, wherein tween is one or more in the polysorbas20,40,60,80.
5. the described method of claim 1, wherein silane coupling agent is a kind of in amino silicane coupling agent, the epoxy silane coupling.
6. the described method of claim 1, wherein resulting environmental protection paper coating are with ADHESION OF PAINTS power height, and the ink absorption of coating is good.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110106519 CN102212289B (en) | 2011-04-27 | 2011-04-27 | Preparation method of paint used for coating environmentally-friendly paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110106519 CN102212289B (en) | 2011-04-27 | 2011-04-27 | Preparation method of paint used for coating environmentally-friendly paper |
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| Publication Number | Publication Date |
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| CN102212289A true CN102212289A (en) | 2011-10-12 |
| CN102212289B CN102212289B (en) | 2013-06-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110106519 Expired - Fee Related CN102212289B (en) | 2011-04-27 | 2011-04-27 | Preparation method of paint used for coating environmentally-friendly paper |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675989A (en) * | 2012-06-05 | 2012-09-19 | 孔令发 | Coating liquid used for surface of environment-friendly rich mineral paper |
| CN104861781A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method for preparing environment-friendly paper ink-jet printing coating |
| CN104861858A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Preparation method of novel ink-jet printing coating |
| CN104861857A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method for preparing environment-friendly synthetic paper ink-jet printing coating |
| CN110230235A (en) * | 2019-06-27 | 2019-09-13 | 河北方大包装股份有限公司 | A kind of dumb light PP synthetic paper of coating and preparation method thereof |
| CN113321981A (en) * | 2021-05-28 | 2021-08-31 | 江苏万宝瑞达高新技术有限公司 | Coating for matte PP synthetic paper coating, preparation method and coating method of coating |
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| CN1307153A (en) * | 2000-01-27 | 2001-08-08 | 山东晨鸣纸业集团股份有限公司 | Production process of high-grade featherweight coated paper |
| CN101008164A (en) * | 2007-01-24 | 2007-08-01 | 张光华 | Starch graft copolymer adhesive for coating paper |
| CN101205693A (en) * | 2006-12-23 | 2008-06-25 | 山东晨鸣纸业集团股份有限公司 | Coated newsprint paper |
| CN101397765A (en) * | 2007-09-28 | 2009-04-01 | 中国制浆造纸研究院 | Coating kraft liner board paper |
| CN101806013A (en) * | 2010-04-19 | 2010-08-18 | 远通纸业(山东)有限公司 | Top coating for coating layer of double-sided coating white board as well as preparation method and application thereof |
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2011
- 2011-04-27 CN CN 201110106519 patent/CN102212289B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1307153A (en) * | 2000-01-27 | 2001-08-08 | 山东晨鸣纸业集团股份有限公司 | Production process of high-grade featherweight coated paper |
| CN101205693A (en) * | 2006-12-23 | 2008-06-25 | 山东晨鸣纸业集团股份有限公司 | Coated newsprint paper |
| CN101008164A (en) * | 2007-01-24 | 2007-08-01 | 张光华 | Starch graft copolymer adhesive for coating paper |
| CN101397765A (en) * | 2007-09-28 | 2009-04-01 | 中国制浆造纸研究院 | Coating kraft liner board paper |
| CN101806013A (en) * | 2010-04-19 | 2010-08-18 | 远通纸业(山东)有限公司 | Top coating for coating layer of double-sided coating white board as well as preparation method and application thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102675989A (en) * | 2012-06-05 | 2012-09-19 | 孔令发 | Coating liquid used for surface of environment-friendly rich mineral paper |
| CN102675989B (en) * | 2012-06-05 | 2014-04-02 | 孔令发 | Coating liquid used for surface of environment-friendly rich mineral paper |
| CN104861781A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method for preparing environment-friendly paper ink-jet printing coating |
| CN104861858A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Preparation method of novel ink-jet printing coating |
| CN104861857A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method for preparing environment-friendly synthetic paper ink-jet printing coating |
| CN104861857B (en) * | 2015-06-16 | 2017-03-15 | 华东理工大学 | A kind of preparation method of environmental protection synthetic paper inkjet printing coating |
| CN110230235A (en) * | 2019-06-27 | 2019-09-13 | 河北方大包装股份有限公司 | A kind of dumb light PP synthetic paper of coating and preparation method thereof |
| CN110230235B (en) * | 2019-06-27 | 2021-10-08 | 河北方大包装股份有限公司 | Coated matte PP synthetic paper and preparation method thereof |
| CN113321981A (en) * | 2021-05-28 | 2021-08-31 | 江苏万宝瑞达高新技术有限公司 | Coating for matte PP synthetic paper coating, preparation method and coating method of coating |
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| Publication number | Publication date |
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| CN102212289B (en) | 2013-06-19 |
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Granted publication date: 20130619 Termination date: 20170427 |