CN102199456A - Biological liquid fuel - Google Patents
Biological liquid fuel Download PDFInfo
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- CN102199456A CN102199456A CN2011100983184A CN201110098318A CN102199456A CN 102199456 A CN102199456 A CN 102199456A CN 2011100983184 A CN2011100983184 A CN 2011100983184A CN 201110098318 A CN201110098318 A CN 201110098318A CN 102199456 A CN102199456 A CN 102199456A
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- liquid fuel
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Abstract
The invention relates to liquid fuel, in particular to biological liquid fuel. The biological liquid fuel consists of the following components in percentage by mass: 30 to 65 percent of methanol, 5 to 15 percent of dimethyl benzene, 3 to 5 percent of additive, and the balance of naphtha, wherein the concentration of methanol is more than or equal to 99.5 percent; and the additive consists of the following components in percentage by weight: 10 percent of preservative, 10 to 20 percent of octane promoter, 5 to 20 percent of ethylene glycol, 10 to 20 percent of acetone, 3 to 5 percent of polyetheramine and the balance of dimethyl benzene. The biological liquid fuel has the advantages of high power, energy conservation, low content of pollutants in tail gas and less corrosion to the oil pipes of the engine and the oil delivery system.
Description
[technical field]
The present invention relates to a kind of liquid fuel, relate in particular to a kind of biological liquid fuel.
[background technology]
Alcohols is considered to have most the fuel of internal combustion engine alternative fuel of application prospect, and developing the New-type fuel of alternative gasoline and improving energy-saving and emission-reduction all is the problem that the Chinese government pays special attention to.In order to satisfy the gasoline demand amount that constantly raises, China has carried out closed popularization Aalcohols fuel in part provinces and cities, and the traditional Aalcohols fuel of stand youngster is blent a certain proportion of methyl alcohol in gasoline China exactly.There is following problem in this Aalcohols fuel: 1, methyl alcohol and gasoline mutual solubility are poor; 2, be short of power; 3, there is corrodibility in methyl alcohol, and the oil pipe of engine and fuel transfer system is all had corrosion; 4, methyl alcohol is heated and easily evaporates.
[summary of the invention]
At the problems referred to above, the purpose of this invention is to provide that a kind of power is big, the lower new bio liquid fuel of pollutant load in the discharging tail gas.
For achieving the above object, the present invention takes following technical scheme:
A kind of biological liquid fuel, be made up of following proportion of masses: methyl alcohol 30～65%, dimethylbenzene 5～15%, additive 3～5%, surplus are petroleum naphtha, the concentration of described methyl alcohol is more than or equal to 99.5%, and described additive is made up of following proportion of masses: sanitas 10%, octane enhancer 10～20%, ethylene glycol 5-20%, acetone 10-20%, polyetheramine 3-5, surplus are dimethylbenzene.
Preferably, described biological liquid fuel is made up of following proportion of masses: methyl alcohol 45～50%, dimethylbenzene 10～12%, additive 4%, surplus are petroleum naphtha.
Preferably, described sanitas comprises the component of following weight part: 5 parts of whiterusss, 5 parts of oleic acid, 1 part of ditertbutylparacresol.
Preferably, described octane enhancer comprises the component of following weight part: mix 4 parts of benzene, 10 parts of dimethyl tertbutyl ethers, 1 part of ferrocene, 1 part of octanol.
Preferably, the preparation method of described additive may further comprise the steps:
(1) sanitas, ethylene glycol and acetone are put into the reactor that contains dimethylbenzene, stir;
(2) in reactor, add octane enhancer and polyetheramine, form mixture;
(3) mixture that forms in the step (2) is heated to 30 ℃ of postcooling in encloses container, restir is even, promptly makes described additive.
Wherein, the preparation method of described sanitas is: whiteruss, oleic acid, the ditertbutylparacresol of described weight part are put into a container, stir.
Wherein, the preparation method of described octane enhancer is: to mix benzene is solvent, dimethyl tertbutyl ether, ferrocene and octanol is put into mixed benzene, stirs.
Described additive also can be used for other methanol gasolines applicable to gasoline.
The used methyl alcohol of the present invention is a kind of clean fuel, and petroleum naphtha is as basic material, and dimethylbenzene not only can improve the power of fuel, and can methyl alcohol and petroleum naphtha is molten to together; Because the additive of above-mentioned unique formula adopts petroleum naphtha to replace gasoline product, can alleviate to a certain extent that gasoline demand is big, the nervous problem of resource among the present invention.Not only power is bigger, energy-conservation for biological liquid fuel of the present invention, pollutant load is less in the tail gas, and the additive that is added can cleaner engines oil supply system parts, reduce the corrosion to engine and fuel transfer system oil pipe.
[embodiment]
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
(1) measures whiteruss 50g, oleic acid 50g and ditertbutylparacresol 10g and put into a container, stir, get the 110g sanitas; Measure and mix benzene 80g, dimethyl tertbutyl ether 200g, ferrocene 20g, octanol 20g, say that earlier mixing benzene puts into a container, add dimethyl tertbutyl ether, ferrocene and octanol then, stir, get the 320g octane enhancer;
(2) measure ethylene glycol 50g, acetone 200g, polyetheramine 50g, dimethylbenzene 400g, from step (1), measure sanitas 100g, octane enhancer 200g respectively in the sanitas of preparation and the octane enhancer;
(3) dimethylbenzene of measuring is put into reactor, then sanitas, ethylene glycol and the acetone of measuring are put into the reactor that contains dimethylbenzene, stir; In reactor, add octane enhancer and polyetheramine, form mixture;
(4) mixture that forms in the step (3) is heated to 30 ℃ of postcooling in encloses container, restir promptly makes the 1000g additive;
(5) get 300g in the additive that from step (4), makes, and to measure concentration respectively be 99.5% methyl alcohol 650g, dimethylbenzene 50g, petroleum naphtha 270g;
(6) methyl alcohol of measuring in the step (5) is put into reactor, then dimethylbenzene, petroleum naphtha and the additive of measuring joined in the reactor that contains methyl alcohol, stir, promptly get biological liquid fuel.
Embodiment 2
(1) measures whiteruss 50g, oleic acid 50g and ditertbutylparacresol 10g and put into a container, stir, get the 110g sanitas; Measure and mix benzene 80g, dimethyl tertbutyl ether 200g, ferrocene 20g, octanol 20g, say that earlier mixing benzene puts into a container, add dimethyl tertbutyl ether, ferrocene and octanol then, stir, get the 320g octane enhancer;
(2) measure ethylene glycol 200g, acetone 100g, polyetheramine 30g, dimethylbenzene 470g, from step (1), measure sanitas 100g, octane enhancer 100g respectively in the sanitas of preparation and the octane enhancer;
(3) dimethylbenzene of measuring is put into reactor, then sanitas, ethylene glycol and the acetone of measuring are put into the reactor that contains dimethylbenzene, stir; In reactor, add octane enhancer and polyetheramine, form mixture;
(4) mixture that forms in the step (3) is heated to 30 ℃ of postcooling in encloses container, restir promptly makes the 1000g additive;
(5) get 500g in the additive that from step (4), makes, and to measure concentration respectively be 99.9% methyl alcohol 300g, dimethylbenzene 150g, petroleum naphtha 500g;
(6) methyl alcohol of measuring in the step (5) is put into reactor, then dimethylbenzene, petroleum naphtha and the additive of measuring joined in the reactor that contains methyl alcohol, stir, promptly get biological liquid fuel.
Embodiment 3
(1) measures whiteruss 50g, oleic acid 50g and ditertbutylparacresol 10g and put into a container, stir, get the 110g sanitas; Measure and mix benzene 80g, dimethyl tertbutyl ether 200g, ferrocene 20g, octanol 20g, say that earlier mixing benzene puts into a container, add dimethyl tertbutyl ether, ferrocene and octanol then, stir, get the 320g octane enhancer;
(2) measure ethylene glycol 100g, acetone 150g, polyetheramine 40g, dimethylbenzene 460g, from step (1), measure sanitas 100g, octane enhancer 150g respectively in the sanitas of preparation and the octane enhancer;
(3) dimethylbenzene of measuring is put into reactor, then sanitas, ethylene glycol and the acetone of measuring are put into the reactor that contains dimethylbenzene, stir; In reactor, add octane enhancer and polyetheramine, form mixture;
(4) mixture that forms in the step (3) is heated to 30 ℃ of postcooling in encloses container, restir promptly makes the 1000g additive;
(5) get 400g in the additive that from step (4), makes, and to measure concentration respectively be 99.6% methyl alcohol 450g, dimethylbenzene 100g, petroleum naphtha 410g;
(6) methyl alcohol of measuring in the step (5) is put into reactor, then dimethylbenzene, petroleum naphtha and the additive of measuring joined in the reactor that contains methyl alcohol, stir, promptly get biological liquid fuel.
Embodiment 4
(1) measures whiteruss 50g, oleic acid 50g and ditertbutylparacresol 10g and put into a container, stir, get the 110g sanitas; Measure and mix benzene 80g, dimethyl tertbutyl ether 200g, ferrocene 20g, octanol 20g, say that earlier mixing benzene puts into a container, add dimethyl tertbutyl ether, ferrocene and octanol then, stir, get the 320g octane enhancer;
(2) measure ethylene glycol 150g, acetone 180g, polyetheramine 45g, dimethylbenzene 465g, from step (1), measure sanitas 100g, octane enhancer 160g respectively in the sanitas of preparation and the octane enhancer;
(3) dimethylbenzene of measuring is put into reactor, then sanitas, ethylene glycol and the acetone of measuring are put into the reactor that contains dimethylbenzene, stir; In reactor, add octane enhancer and polyetheramine, form mixture;
(4) mixture that forms in the step (3) is heated to 30 ℃ of postcooling in encloses container, restir promptly makes the 1000g additive;
(5) get 500g in the additive that from step (4), makes, and to measure concentration respectively be 99.8% methyl alcohol 500g, dimethylbenzene 120g, petroleum naphtha 330g;
(6) methyl alcohol of measuring in the step (5) is put into reactor, then dimethylbenzene, petroleum naphtha and the additive of measuring joined in the reactor that contains methyl alcohol, stir, promptly get biological liquid fuel.
Embodiment 5
Biological liquid fuel of the present invention and gasoline tail gas simultaneous test
Entrust and detect unit: Guangzhou Environmental Protection Agency environment measuring junction centre
Detect foundation: GB18285-2005 spark ignition engine automobile exhaust pollutant discharge limit value and measuring method (double idle method and simple and easy operating condition method).
Testing process explanation and requirement:
1, replaces No. 93 gasoline with embodiment 1,2,3,4 gained biological liquid fuels respectively, supervise the implementation of by Guangzhou Environmental Protection Agency environment measuring junction centre;
2, test process and fuel oil do not allow testing vehicle is carried out any adjustment that influences emission behavior before and after replacing;
3, detection is that former vehicle exhaust detection is carried out in first use " No. 93 gasoline " in proper order, and then uses this car to carry out exhaust with embodiment 1,2,3,4 gained biological liquid fuel samples respectively and detect;
4, after fuel oil was replaced, vehicle travelled and carried out the exhaust detection in about 30 minutes again.
Detected result: carry out double idle real vehicle contrast test with " No. 93 gasoline " and embodiment 1,2,3,4 gained " biological liquid fuel " samples, the purification rate of its idling CO, HC is respectively 75.3%, 63.9%, 62.4%, 64.2%, 61.9%; The purification rate of high idle speed CO, HC is respectively 69.1%, 62.5%, 61.3%, 61.9%, 62.1%.
By detected result as can be known, the purification rate of CO, the HC of the embodiment of the invention 1,2,3,4 gained " biological liquid fuel " is starkly lower than " No. 93 gasoline ".
Embodiment 6
Liquid fuel and petrol power performance and oil consumption simultaneous test
Test method: add 20L gasoline and liquid fuel respectively at same road traveling with same car (Guangdong Z101K), test travel milimeter number and dynamic performance.
Test-results: add 20L gasoline, the milimeter number that automobile runs is 165 kilometers; Add 20L embodiment 1 gained biological liquid fuel, the milimeter number that automobile runs is 167 kilometers; Add 20L embodiment 2 gained biological liquid fuels, the milimeter number that automobile runs is 168 kilometers; Add 20L embodiment 3 gained biological liquid fuels, the milimeter number that automobile runs is 169 kilometers; Add 20L embodiment 4 gained biological liquid fuels, the milimeter number that automobile runs is 167 kilometers; When adding embodiment 1,2,3,4 gained biological liquid fuels, dynamic performance is bigger than the power that adds gasoline during driving.
Claims (7)
1. biological liquid fuel, it is characterized in that being made up of following proportion of masses: methyl alcohol 30～65%, dimethylbenzene 5～15%, additive 3～5%, surplus are petroleum naphtha, the concentration of described methyl alcohol is more than or equal to 99.5%, and described additive is made up of following proportion of masses: sanitas 10%, octane enhancer 10～20%, ethylene glycol 5-20%, acetone 10-20%, polyetheramine 3-5, surplus are dimethylbenzene.
2. biological liquid fuel as claimed in claim 1 is characterized in that being made up of following proportion of masses: methyl alcohol 45～50%, dimethylbenzene 10～12%, additive 4%, surplus are petroleum naphtha.
3. biological liquid fuel as claimed in claim 1 is characterized in that described sanitas comprises the component of following weight part: 5 parts of whiterusss, 5 parts of oleic acid, 1 part of ditertbutylparacresol.
4. biological liquid fuel as claimed in claim 1 is characterized in that described octane enhancer comprises the component of following weight part: mix 4 parts of benzene, 10 parts of dimethyl tertbutyl ethers, 1 part of ferrocene, 1 part of octanol.
5. as claim 3 or 4 described biological liquid fuels, it is characterized in that the preparation method of described additive may further comprise the steps:
(1) sanitas, ethylene glycol and acetone are put into the reactor that contains dimethylbenzene, stir;
(2) in reactor, add octane enhancer and polyetheramine, form mixture;
(3) mixture that forms in the step (2) is heated to 30 ℃ of postcooling in encloses container, restir is even, promptly makes described additive.
6. biological liquid fuel as claimed in claim 5 is characterized in that the preparation method of described sanitas is: whiteruss, oleic acid, the ditertbutylparacresol of described weight part are put into a container, stir.
7. biological liquid fuel as claimed in claim 5 is characterized in that the preparation method of described octane enhancer is: to mix benzene is solvent, dimethyl tertbutyl ether, ferrocene and octanol is put into mixed benzene, stirs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100983184A CN102199456A (en) | 2011-04-19 | 2011-04-19 | Biological liquid fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100983184A CN102199456A (en) | 2011-04-19 | 2011-04-19 | Biological liquid fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102199456A true CN102199456A (en) | 2011-09-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100983184A Pending CN102199456A (en) | 2011-04-19 | 2011-04-19 | Biological liquid fuel |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329667A (en) * | 2011-09-06 | 2012-01-25 | 姜立广 | Fuel oil additive and preparation method thereof |
| CN102719281A (en) * | 2012-07-03 | 2012-10-10 | 庞英才 | Fuel composition for vehicles and preparation method of fuel composition |
| CN103589464A (en) * | 2012-08-18 | 2014-02-19 | 韦维 | High energy liquid fuel and manufacturing method thereof |
| CN108359503A (en) * | 2018-04-20 | 2018-08-03 | 北京安途行科技有限公司 | A kind of automobile exhaust detergent manufacture craft |
| CN110218591A (en) * | 2019-06-20 | 2019-09-10 | 桂林千升元环保能源有限公司 | A kind of low oil consumption F- T synthesis crude liquid ceryl alcohol ether fuel of automobile |
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| CN1621500A (en) * | 2004-11-03 | 2005-06-01 | 肖丽 | Environment protection type methanol gasoline |
| CN101270305A (en) * | 2008-05-19 | 2008-09-24 | 兖矿集团有限公司 | Methanol gasoline |
| CN101906330A (en) * | 2010-07-28 | 2010-12-08 | 叶景榕 | Methanol gasoline |
| CN101906329A (en) * | 2010-08-23 | 2010-12-08 | 漳州泽涛新能源科技有限公司 | Methanol gasoline for vehicles and preparation method thereof |
-
2011
- 2011-04-19 CN CN2011100983184A patent/CN102199456A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1621500A (en) * | 2004-11-03 | 2005-06-01 | 肖丽 | Environment protection type methanol gasoline |
| CN101270305A (en) * | 2008-05-19 | 2008-09-24 | 兖矿集团有限公司 | Methanol gasoline |
| CN101906330A (en) * | 2010-07-28 | 2010-12-08 | 叶景榕 | Methanol gasoline |
| CN101906329A (en) * | 2010-08-23 | 2010-12-08 | 漳州泽涛新能源科技有限公司 | Methanol gasoline for vehicles and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329667A (en) * | 2011-09-06 | 2012-01-25 | 姜立广 | Fuel oil additive and preparation method thereof |
| CN102719281A (en) * | 2012-07-03 | 2012-10-10 | 庞英才 | Fuel composition for vehicles and preparation method of fuel composition |
| CN103589464A (en) * | 2012-08-18 | 2014-02-19 | 韦维 | High energy liquid fuel and manufacturing method thereof |
| CN103589464B (en) * | 2012-08-18 | 2016-08-10 | 韦维 | High energy liquid fuel and preparation method thereof |
| CN108359503A (en) * | 2018-04-20 | 2018-08-03 | 北京安途行科技有限公司 | A kind of automobile exhaust detergent manufacture craft |
| CN110218591A (en) * | 2019-06-20 | 2019-09-10 | 桂林千升元环保能源有限公司 | A kind of low oil consumption F- T synthesis crude liquid ceryl alcohol ether fuel of automobile |
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