CN102191159A - Chitosan oligosaccharide health wine and preparation method thereof - Google Patents
Chitosan oligosaccharide health wine and preparation method thereof Download PDFInfo
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- CN102191159A CN102191159A CN2011100357532A CN201110035753A CN102191159A CN 102191159 A CN102191159 A CN 102191159A CN 2011100357532 A CN2011100357532 A CN 2011100357532A CN 201110035753 A CN201110035753 A CN 201110035753A CN 102191159 A CN102191159 A CN 102191159A
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- chitosan oligosaccharide
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Abstract
The invention relates to a chitosan oligosaccharide health wine and a preparation method thereof, and in particular a health wine containing chitosan oligosaccharide and main chitosan oligosaccharide derivatives, and a preparation method thereof. The preparation method comprises: step 1): carrying out a degrading process and a separating process to obtain a low molecular chitosan oligosaccharide which is soluble in water and ethanol; step 2): carrying out a blending process with edible alcohol to obtain the chitosan oligosaccharide health wine, wherein a weight ratio of the chitosan oligosaccharide to the edible alcohol is 1% to 2.5%. According to the present invention, the chitosan oligosaccharide can be absorbed through digestive function in a body when drinking the chitosan oligosaccharide health wine, so as to provide a plurality of health functions for people.
Description
The present invention relates to health promoting wine, refer in particular to the health promoting wine and the method for making thereof that contain oligochitosan and main derivative composition thereof.
Estimate at 1.4 hundred million people in the world and rely on alcohol, 78% does not obtain medical treatment, and also has the excessive drinking of people more than 400,000,000, and can cause the accident, damage, painful and dead, alcohol causes in all dead cases of the world and accounts for 1.5%.Often habitual consumption of alcohol, or the often edible high confectionery thing of high fat all can cause fatty liver and liver cirrhosis.The health care drinks is a lot, and especially Chinese medicine health-care wine is more general in China's application, and these wine are more or less all benefited to the person.The life of oligochitosan wants raw material sources in sea crab, Prawn shell, and the molecular formula of oligochitosan is: (C6H14O4N)
n, major ingredient is the chitin oligochitosan, (oligochitosan is a chitosan) wherein, chitinous Chemical Composition is: poly--the ethanoyl glucosamine; The Chemical Composition of chitosan is: a poly-deacetylation glucosamine.Oligochitosan has the immunologic facilitation function to human body, and inhibition is aging, preventing disease promotes disease recovery from illness, mediator's body weight function, and cancer is had restraining effect, the reducing cholesterol hypotensive activity, hypoglycemic activity is strengthened liver function, and neural, endocrine system are had regulating effect.Oligochitosan has application in food such as cake, candy, yet there are no in wine and use.Reason is that its indissoluble problem is not resolved.It is a kind of natural high molecular substance that has positive charge, and its molecular weight generally ten million between the hundreds of thousands of, is insoluble to and contains water and alcoholic acid solution.
The objective of the invention is a kind of oligochitosan health promoting wine and the method for making thereof that can regulate multiple usefulness such as alcohol metabolism, cholesterol and blood fat effectively.
The object of the present invention is achieved like this, technical process:
The first step: degraded, separation.Polymer shell oligosaccharides glycosidic link is disconnected, resolve into the low molecule of little water soluble of molecular weight and alcoholic acid.Adding concentration is 3～5% citric acid in pulverous oligochitosan, the weight ratio of oligochitosan and citric acid is 1: 7～8, heat up and temperature is remained between 50～80 ℃, evenly stirred 7～8 hours, oxidative degradation is degraded to molecular weight smaller or equal to 3000 low molecule oligochitosan with polymer.Adding alcoholic strength again is 85%～95.5% (V/V) edible ethanol, make that concentration of ethanol reaches 75～85% in the solution, the oligochitosan that is degraded is separated out from solution and is separated, carry out spraying drying, obtain molecular-weight average≤3000, the low molecule oligochitosan of deacetylation 90～95%, this oligochitosan dissolve in and contain in water and the alcoholic acid solution.
Second step: edible ethanol is blent and is made the oligochitosan health promoting wine.The program of blending is: earlier blending water being transferred pH value with citric acid is 3～5, to hang down the molecule oligochitosan again is dissolved in and is in the acid blending water, by weight few back is many earlier, slowly add edible ethanol, oligochitosan and alcoholic acid weight ratio are 1 ‰～2.5%, under the condition of 20～50 ℃ of solvent temperatures, evenly stir dissolving fully within 3 hours.
The oligochitosan health promoting wine that makes through aforesaid method contains oligochitosan and the alcoholic acid weight ratio is 1 ‰～2.5%.
Advantage of the present invention is: water insoluble and polymer shell oligosaccharides ethanolic soln are carried out oxidative degradation handle, make it to become the low molecule in water soluble and the ethanolic soln, convert and make wine, human body is when drinking wine, can absorb by digestive function in the body, and then play various health-care effects.(1) effect of adjusting alcohol metabolism, the oligochitosan in the wine can strengthen liver function greatly, and the aldehyde radical oxydase quantity of hepatic secretion is increased, and enough aldehyde radical oxydase have been arranged, and just can the whole or big portion of deleterious acetaldehyde be oxidized away and detoxify.(2) cholesterol regulating effect, oligochitosan strengthen after the liver function, and the effect that makes cholesterol be converted into bile acide is strengthened thereupon on the one hand, cause cholesterol minimizing in the liver, must draw cholesterol from blood, so can reduce serum cholesterol; On the other hand, the bile acide of positively charged oligochitosan chitosan adsorption zone negative charge excretes after the absorption, causes bile acide to reduce, and must force the liver cholesterol further to transform bile acide, to replenish the deficiency of bile acide.(3) effect of regulating blood fat, oligochitosan be by 2-ethanamide-2 deoxyglucose monomer by the straight-chain polysaccharide that the glycoside bond of β-(1-4) couples together, animal is all had the effect of reducing blood-fat.(4) help the rehabilitation of osteoarthropathy and the healing of fracture, the main derivative of oligochitosan can be by capacity for liquor, enter human circulation rapidly, promote the synthetic of chondrocyte's protein-polysaccharide, improve knuckle synovia viscosity, improve the joint cartilage metabolism, the formation of accelerated bone cell skeletonization and fiber poroma, thus help the rehabilitation of osteoarthropathy or the healing of fracture.(5) do not influence wine body note gas.
The present invention is described in detail below in conjunction with embodiment.
Embodiment 1
The first step: degraded, separation.In Powdered polymer shell oligosaccharides, slowly pour concentration into and be 3% citric acid solution, weight ratio is 1: 8, and warming while stirring is degraded under 60 ℃ temperature condition, and after 8 hours, the polymer shell oligosaccharides is degraded to low molecule oligochitosan.At this moment, adding alcoholic strength again is 95.5% (V/V) edible ethanol, make that concentration of ethanol reaches 85% in the solution, the oligochitosan that is degraded is separated out from solution and is separated, carry out spraying drying, obtain molecular-weight average≤3000, the low molecule oligochitosan of deacetylation 95%, this oligochitosan dissolve in and contain in water and the alcoholic acid solution.
Second step: edible ethanol is blent and is made the oligochitosan health promoting wine.In the 594kg tap water, adding concentration is 4% citric acid, and transferring pH value is 3～5, and then the adding deacetylation is 95%, the low molecule oligochitosan that dissolves in wine of weight 10.2kg, under the condition of 50 ℃ of liquid temperature, stir on the limit, the edible ethanol that alcoholic strength is 95.5% (V/V) is slowly poured on the limit into, pour 405.95kg ethanol in 1 hour altogether into, stirred through 3 hours and blend, oligochitosan dissolves fully, make the wine that alcoholic strength is 45% (V/V), wherein oligochitosan and alcoholic acid weight ratio are 2.5%.Carry out seasoning afterwards again, and add total acid, total ester, acetic ester, make it to reach respectively 1.5g/L, 3g/L, 2g/L, conform with the physical and chemical standards requirement of GB 10781.1-89 top grade aromatic Chinese spirit, do not have cotton-shaped suspension and precipitation, become as clear as crystal or little flavol thick, the lasting cup of hanging with how many color and lusters of content of oligochitosan, mouthfeel is pure, has the strong compound fragrance based on acetic ester.This wine packing net content is the 500rnl/ bottle, is dissolved with the 0.01k oligochitosan in every bottle of wine.The best amount of drinking of this wine is every day one or two, drinks at the most weekly 5 times.In experimental stage, taste through the up to a hundred people, generally reflect not the higher authorities of this wine, it is fast to sober up.Wherein, the alcohol user that some suffer from hyperlipidemia, hypertension, sacroiliitis and cardiovascular and cerebrovascular diseases drinks this wine tens days to after two months, and illness has all obtained alleviation in various degree.
Embodiment 2
The first step: degraded, separation.In Powdered polymer shell oligosaccharides, slowly pour concentration into and be 5% citric acid solution, weight ratio is 1: 7, and warming while stirring is degraded under 50 ℃ temperature condition, and after 8 hours, the polymer shell oligosaccharides is degraded to low molecule oligochitosan.At this moment, adding alcoholic strength again is 90% (V/V,) edible ethanol, make that concentration of ethanol reaches about 80% in the solution, the oligochitosan that is degraded is separated out from solution and is separated, and carries out spraying drying, obtains molecular-weight average≤3000, the low molecule oligochitosan of deacetylation 93%, this oligochitosan dissolve in and contain in water and the alcoholic acid solution.
Second step: edible ethanol is blent and is made the oligochitosan health promoting wine.In concentration is to add tap water 90.53kg in 50% the original grape juice, transferring pH value with citric acid is 5～6, adding deacetylation is 95%, and the low molecule oligochitosan that dissolves in wine that weight makes for the 0.02kg the first step is under 40 ℃ the condition in temperature, stir on the limit, the edible ethanol that alcoholic strength is 95% (V/V) is slowly poured on the limit into, pours 9.48kg ethanol altogether into, stirs through 3 hours and blends, oligochitosan dissolves fully, and making alcoholic strength is the health wine that 11% (V/V) contains oligochitosan.Wherein oligochitosan and ethanol weight ratio are 0.2%.
Embodiment 3
The first step: degraded, separation.In Powdered polymer shell oligosaccharides, slowly pour concentration into and be 3.5% citric acid solution, weight ratio is 1: 7.5, and warming while stirring is degraded under 80 ℃ temperature condition, and after 8 hours, the polymer shell oligosaccharides is degraded to low molecule oligochitosan.At this moment, adding alcoholic strength again is 85% (V/V) edible ethanol, make that concentration of ethanol reaches 75% in the solution, the oligochitosan that is degraded is separated out from solution and is separated, carry out spraying drying, obtain molecular-weight average≤3000, the low molecule oligochitosan of deacetylation 90%, this oligochitosan dissolve in and contain in water and the alcoholic acid solution.
Second step: edible ethanol is blent and is made the oligochitosan health promoting wine.In the 14.4kg tap water, be 3～5 with the citric acid pH value, adding deacetylation is 95%, and the low molecule oligochitosan that dissolves in wine that weight makes for the 0.004kg the first step is under 20 ℃ the condition in temperature, stir on the limit, the fresh beer 100kg that alcoholic strength is 4% (V/V) is slowly poured on the limit into, and through 2 hours, the stirring under 20 ℃ the condition was blent, oligochitosan dissolves fully, pasteurizing temperature is 65 ℃, and 30 minutes, getting alcoholic strength was the health-care beer that contains oligochitosan of 3.5% (V/V).Wherein oligochitosan and ethanol weight ratio are 1 ‰.
Claims (3)
1. oligochitosan health promoting wine method for making is characterized in that:
The first step: degraded, separation, polymer shell oligosaccharides glycosidic link is disconnected, resolve into the low molecule oligochitosan of little water soluble of molecular weight and alcoholic acid: adding concentration is 3～5% citric acid in pulverous oligochitosan, with the weight ratio of citric acid be 1: 7～8, heat up and temperature is remained between 50～80 ℃, evenly stir oxidative degradation in 7～8 hours, polymer is degraded to molecular weight smaller or equal to 3000 low molecule oligochitosan; Adding alcoholic strength again is 85%～95.5% (V/V) edible ethanol, make that concentration of ethanol reaches 75～85% in the solution, the oligochitosan that is degraded is separated out from solution and is separated, obtain molecular-weight average≤6000, the low molecule oligochitosan of deacetylation 90～95%, this oligochitosan dissolve in and contain in water and the alcoholic acid solution;
Second step: edible ethanol is blent and is made the oligochitosan health promoting wine, the program of blending is: earlier blending water being transferred pH value with citric acid is 3～5, to hang down the molecule oligochitosan again is dissolved in and is in the tart blending water, by weight few back is many earlier, slowly add edible ethanol, oligochitosan and alcoholic acid weight ratio are 1 ‰～2.5%, under the condition of 20～50 ℃ of solvent temperatures, evenly stir dissolving fully within 3 hours.
2. the oligochitosan health promoting wine that method for making as claimed in claim 1 makes is characterized in that: containing oligochitosan and alcoholic acid weight ratio is 1 ‰～2.5%.
3. oligochitosan health promoting wine according to claim 2 is characterized in that: oligochitosan and alcoholic acid weight ratio preferred value are 0.2%.
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| CN2011100357532A CN102191159A (en) | 2011-01-27 | 2011-01-27 | Chitosan oligosaccharide health wine and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893936A (en) * | 2015-06-30 | 2015-09-09 | 青岛浩大海洋保健食品有限公司 | Chitosan compound wine with effect of delaying senescence |
| CN107083311A (en) * | 2017-06-08 | 2017-08-22 | 青岛琅琊台集团股份有限公司 | Chitosan oligosaccharide health care's wine and preparation method thereof |
| CN109943455A (en) * | 2018-04-25 | 2019-06-28 | 江西天帝仁医药科技有限公司 | One kind being based on chitin chitosan oligosaccharide health-care white spirit |
| WO2021065386A1 (en) * | 2019-09-30 | 2021-04-08 | サントリーホールディングス株式会社 | Packaged alcoholic beverage |
-
2011
- 2011-01-27 CN CN2011100357532A patent/CN102191159A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893936A (en) * | 2015-06-30 | 2015-09-09 | 青岛浩大海洋保健食品有限公司 | Chitosan compound wine with effect of delaying senescence |
| CN107083311A (en) * | 2017-06-08 | 2017-08-22 | 青岛琅琊台集团股份有限公司 | Chitosan oligosaccharide health care's wine and preparation method thereof |
| CN109943455A (en) * | 2018-04-25 | 2019-06-28 | 江西天帝仁医药科技有限公司 | One kind being based on chitin chitosan oligosaccharide health-care white spirit |
| WO2021065386A1 (en) * | 2019-09-30 | 2021-04-08 | サントリーホールディングス株式会社 | Packaged alcoholic beverage |
| CN114729290A (en) * | 2019-09-30 | 2022-07-08 | 三得利控股株式会社 | Packaged alcoholic beverage |
| JP7361558B2 (en) | 2019-09-30 | 2023-10-16 | サントリーホールディングス株式会社 | packaged alcoholic beverages |
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Application publication date: 20110921 |