CN102181112A - Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof - Google Patents
Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof Download PDFInfo
- Publication number
- CN102181112A CN102181112A CN 201110137076 CN201110137076A CN102181112A CN 102181112 A CN102181112 A CN 102181112A CN 201110137076 CN201110137076 CN 201110137076 CN 201110137076 A CN201110137076 A CN 201110137076A CN 102181112 A CN102181112 A CN 102181112A
- Authority
- CN
- China
- Prior art keywords
- composite material
- maskable
- electromagnetic
- base composite
- conduct electricity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a plastic-based composite material capable of conducting electricity and shielding electromagnetic waves. The composite material consists of the following raw materials in parts by mass: 80-95 parts of plastic substrate, 1-20 parts of surface-modified high-efficiency conductive agent and 0.5-1 part of antioxidant. A product in the invention has high conductivity and high mechanical property, can be used for shielding electromagnetic waves to a greater extent, and can be widely applied to the fields of electronic consumables, remote monitoring/communication, military affairs and outdoor/indoor power supply.
Description
Technical field
The present invention relates to a kind ofly conduct electricity, the electromagnetic plastic base composite material of maskable and preparation method thereof.
Background technology
Along with the development of electronic industry, electronic products such as various household electrical appliances, office electrical equipment, plant and instrument obtain popularizing widely and using, and also discharge a large amount of electromagnetic radiation when offering convenience to people, are endangering people's health.
For this reason, people constantly seek the matrix material with better capability of electromagnetic shielding, with plastics is that the matrix material with conduction and electro-magnetic screen function of matrix is owing to have less density, lower cost receives the concern of society gradually, people seek the whole bag of tricks plastics are carried out modification, as in plastic substrate, adding conductive metal powder, conductive mica powder or the like obtains the matrix material of corresponding function, yet, because the consistency of conducting particles and plastic substrate, the dispersiveness of conducting particles, and processing conditions or the like problem, the shielding properties of the matrix material that obtains at last, mechanical properties etc. are often not good.
Summary of the invention
The purpose of this invention is to provide a kind ofly conduct electricity, the electromagnetic plastic base composite material of maskable.
The technical solution used in the present invention is:
A kind ofly conduct electricity, the electromagnetic plastic base composite material of maskable, its raw material by following mass parts is formed: the high-effective conductive agent of the surface modification of the plastic substrate of 80-95 part, 1-20 part, the oxidation inhibitor of 0.5-1 part.
Described plastic substrate is a kind of among PTFE, PP, PET, the PC.
Described oxidation inhibitor is at least a in 1010,1135,168.
A kind ofly conduct electricity, the preparation method of the electromagnetic plastic base composite material of maskable, may further comprise the steps:
1) high-effective conductive agent, the oxidation inhibitor with plastic substrate, surface modification mixes;
2) material that step 1) is obtained is extruded in forcing machine.
The invention has the beneficial effects as follows: product of the present invention, have excellent conducting performance, mechanical property, shielding electromagnetic wave can be widely used in consumer electronics, remote monitoring/communication, military affairs, field/indoor power supply field largely.
Embodiment
A kind ofly conduct electricity, the preparation method of the electromagnetic plastic base composite material of maskable, may further comprise the steps:
1) high-effective conductive agent, the oxidation inhibitor with plastic substrate, surface modification placed the mixing machine mixing 2-3 minute;
2) material that step 1) is obtained is extruded in parallel dual-screw extruding machine, and the screw slenderness ratio of forcing machine is 1:30-40.
When carrying out Composite Preparation with the prescription among the embodiment, among the embodiment 1-3, the temperature of forcing machine is 300-350 ℃, among the embodiment 4, the temperature of forcing machine is 180-210 ℃, among the embodiment 5, the temperature of forcing machine is 270-285 ℃, and among the embodiment 6, the temperature of forcing machine is 250-300 ℃.
Below in conjunction with specific embodiment prescription of the present invention is described further:
Embodiment 1:
Can conduct electricity, the prescription table 1 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 1: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 20 |
PTFE | 80 |
Antioxidant 1010 | 0.5 |
Embodiment 2:
Can conduct electricity, the prescription table 2 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 2: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 10 |
PTFE | 90 |
Antioxidant 1010 | 0.5 |
Embodiment 3:
Can conduct electricity, the prescription table 3 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 3: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 5 |
PTFE | 95 |
Oxidation inhibitor 168 | 0.5 |
Embodiment 4:
Can conduct electricity, the prescription table 4 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 4: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 1 |
PP | 85 |
Oxidation inhibitor 168 | 0.6 |
Embodiment 5:
Can conduct electricity, the prescription table 5 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 5: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 5 |
PET | 80 |
Oxidation inhibitor 168 | 1 |
Embodiment 6:
Can conduct electricity, the prescription table 6 composed as follows of the electromagnetic plastic base composite material of maskable:
Table 6: can conduct electricity, the prescription of the electromagnetic plastic base composite material of maskable forms
Raw material | Mass parts |
The high-effective conductive agent of surface modification | 10 |
PC | 90 |
Oxidation inhibitor 168 | 0.7 |
Performance of composites such as following table 7 by embodiment 1-3 preparation:
Table 7: the performance of the conducting electricity of the present invention preparation, the electromagnetic plastic base composite material of maskable
Performance | Unit | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Tensile strength | Mpa | 20 | 20 | 20 |
Modulus in flexure | Mpa | 850 | 800 | 600 |
The simply supported beam notch shock | KJ/m 2 | 35 | 38 | 43 |
Surface resistivity | Ω | <10 | <10 | <10 |
Electromagnetic shielding efficiency | dB | >60 | >60 | >60 |
Among the present invention, the high-effective conductive agent of surface modification makes by the following method: with Graphene (model: GS-1) place the high-speed mixer mixing to get final product in 2-3 minute with the titanate coupling agent that accounts for Graphene quality 1%.
As can be seen from Table 7, product of the present invention, have excellent conducting performance, mechanical property, can well shielding electromagnetic wave, simultaneously, that this matrix material has is durable, the characteristics such as product of light specific gravity, plastic complex construction, can be widely used in consumer electronics, remote monitoring/communication, military affairs, field/indoor power supply field.Meet the strategic plan of nation-building resource-conserving and environment-friendly society fully.
Claims (4)
- One kind can conduct electricity, the electromagnetic plastic base composite material of maskable, it is characterized in that: its raw material by following mass parts is formed: the high-effective conductive agent of the surface modification of the plastic substrate of 80-95 part, 1-20 part, the oxidation inhibitor of 0.5-1 part.
- 2. according to claim 1ly a kind ofly conduct electricity, the electromagnetic plastic base composite material of maskable, it is characterized in that: described plastic substrate is a kind of among PTFE, PP, PET, the PC.
- 3. according to claim 1ly a kind ofly conduct electricity, the electromagnetic plastic base composite material of maskable, it is characterized in that: described oxidation inhibitor is at least a in 1010,1135,168.
- Claim 1 describedly a kind ofly conduct electricity, the preparation method of the electromagnetic plastic base composite material of maskable, it is characterized in that: may further comprise the steps:1) high-effective conductive agent, the oxidation inhibitor with plastic substrate, surface modification mixes;2) material that step 1) is obtained is extruded in forcing machine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110137076 CN102181112B (en) | 2011-05-25 | 2011-05-25 | Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110137076 CN102181112B (en) | 2011-05-25 | 2011-05-25 | Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102181112A true CN102181112A (en) | 2011-09-14 |
CN102181112B CN102181112B (en) | 2013-06-05 |
Family
ID=44567418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110137076 Active CN102181112B (en) | 2011-05-25 | 2011-05-25 | Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102181112B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102963096A (en) * | 2012-11-19 | 2013-03-13 | 湖北祥源新材科技有限公司 | Omni-directional metallic-coating polyolefin conductive foam and preparation method thereof |
CN103738023A (en) * | 2014-01-20 | 2014-04-23 | 苏州新区特氟龙塑料制品厂 | Teflon film |
CN103756216A (en) * | 2014-01-20 | 2014-04-30 | 苏州新区特氟龙塑料制品厂 | Polytetrafluoroethylene formula capable of improving mechanical property |
CN103834094A (en) * | 2012-11-21 | 2014-06-04 | 合肥杰事杰新材料股份有限公司 | Graphene-filled polypropylene composite material, and preparation method thereof |
CN104530557A (en) * | 2014-11-26 | 2015-04-22 | 苏州新区佳合塑胶有限公司 | Electric-conduction PP (polypropylene) material and preparation method thereof |
CN109492504A (en) * | 2017-09-12 | 2019-03-19 | 南昌欧菲生物识别技术有限公司 | Ultrasonic wave biological identification device and preparation method thereof and electronic equipment |
CN109492500A (en) * | 2017-09-12 | 2019-03-19 | 南昌欧菲生物识别技术有限公司 | Ultrasonic wave biological identification device and preparation method thereof and electronic equipment |
CN109593326A (en) * | 2018-11-21 | 2019-04-09 | 南京工业职业技术学院 | A kind of high-efficiency electromagnetic screened film and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1772798A (en) * | 2005-08-03 | 2006-05-17 | 北京纳盛通新材料科技有限公司 | Conductive plastic and its processing method and apparatus |
CN101072493A (en) * | 2007-05-22 | 2007-11-14 | 北京理工大学 | Polyethylene composite film for shielding wideband electromagnetic wave and its preparing method |
CN101469109A (en) * | 2007-12-28 | 2009-07-01 | 上海杰事杰新材料股份有限公司 | Polyester / metal fibre conductive, heat conducting and fast crystallization composite material and preparation thereof |
EP2216358A1 (en) * | 2009-01-30 | 2010-08-11 | Stichting Dutch Polymer Institute | Conductive polymer composition |
KR20100108868A (en) * | 2009-03-30 | 2010-10-08 | 인하대학교 산학협력단 | Conductive polymeric nanocomposite with excellent mechanical and electrical properties |
-
2011
- 2011-05-25 CN CN 201110137076 patent/CN102181112B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1772798A (en) * | 2005-08-03 | 2006-05-17 | 北京纳盛通新材料科技有限公司 | Conductive plastic and its processing method and apparatus |
CN101072493A (en) * | 2007-05-22 | 2007-11-14 | 北京理工大学 | Polyethylene composite film for shielding wideband electromagnetic wave and its preparing method |
CN101469109A (en) * | 2007-12-28 | 2009-07-01 | 上海杰事杰新材料股份有限公司 | Polyester / metal fibre conductive, heat conducting and fast crystallization composite material and preparation thereof |
EP2216358A1 (en) * | 2009-01-30 | 2010-08-11 | Stichting Dutch Polymer Institute | Conductive polymer composition |
KR20100108868A (en) * | 2009-03-30 | 2010-10-08 | 인하대학교 산학협력단 | Conductive polymeric nanocomposite with excellent mechanical and electrical properties |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102963096A (en) * | 2012-11-19 | 2013-03-13 | 湖北祥源新材科技有限公司 | Omni-directional metallic-coating polyolefin conductive foam and preparation method thereof |
CN102963096B (en) * | 2012-11-19 | 2014-08-06 | 湖北祥源新材科技有限公司 | Omni-directional metallic-coating polyolefin conductive foam and preparation method thereof |
CN103834094A (en) * | 2012-11-21 | 2014-06-04 | 合肥杰事杰新材料股份有限公司 | Graphene-filled polypropylene composite material, and preparation method thereof |
CN103738023A (en) * | 2014-01-20 | 2014-04-23 | 苏州新区特氟龙塑料制品厂 | Teflon film |
CN103756216A (en) * | 2014-01-20 | 2014-04-30 | 苏州新区特氟龙塑料制品厂 | Polytetrafluoroethylene formula capable of improving mechanical property |
CN104530557A (en) * | 2014-11-26 | 2015-04-22 | 苏州新区佳合塑胶有限公司 | Electric-conduction PP (polypropylene) material and preparation method thereof |
CN109492504A (en) * | 2017-09-12 | 2019-03-19 | 南昌欧菲生物识别技术有限公司 | Ultrasonic wave biological identification device and preparation method thereof and electronic equipment |
CN109492500A (en) * | 2017-09-12 | 2019-03-19 | 南昌欧菲生物识别技术有限公司 | Ultrasonic wave biological identification device and preparation method thereof and electronic equipment |
CN109492504B (en) * | 2017-09-12 | 2023-07-04 | 江西欧迈斯微电子有限公司 | Ultrasonic biological recognition device, preparation method thereof and electronic equipment |
CN109593326A (en) * | 2018-11-21 | 2019-04-09 | 南京工业职业技术学院 | A kind of high-efficiency electromagnetic screened film and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN102181112B (en) | 2013-06-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102181112B (en) | Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof | |
CN102250414B (en) | Plastic-based composite material with electricity conducting and electromagnetic shielding functions and preparation method thereof | |
CN102250415B (en) | Plastic-based composite material capable of conducting electricity and shielding electromagnetic waves and preparation method thereof | |
CN104845361B (en) | Chopped carbon fiber, conductive nano carbon black/graphene collaboration strengthen highly conductive thermoplastic and preparation method thereof | |
CN102206413B (en) | Plastic-based composite material with electric conduction and electromagnetic shielding functions and preparation method thereof | |
CN104231587B (en) | A kind of for shielding casing thermoplastic composite and preparation method thereof | |
CN102250416A (en) | Electromagnetic shielding composite material capable of heating and preparation method thereof | |
KR101212671B1 (en) | Emi/rfi shielding polymer composite | |
CN103788642A (en) | Insulated and flame-retardant nylon composite material with high thermal conductivity and preparation method thereof | |
CN103694697B (en) | A kind of Heat Conduction Material with selectivity deposition metal and preparation method and application | |
CN111087790B (en) | Graphene-metal powder composite electric and heat conducting plastic and preparation method thereof | |
CN105462246A (en) | Graphene/metal powder composite-modification ultrahigh-heat-conductivity nylon and preparing method thereof | |
CN101812214A (en) | Electromagnetic shielding material and preparation method thereof | |
CN106987149B (en) | A kind of preparation method of antistatic wood moulding | |
CN102206414B (en) | Calorific electromagnetic shielding plastic-based composite material and preparation method thereof | |
CN104629304A (en) | ABS modified polycarbonate alloy plastic | |
CN104448772B (en) | A kind of composite for household appliance shell | |
WO2008111194A1 (en) | Conductive composite material and process for producing the same | |
CN105199564A (en) | Thermoset electromagnetic shielding powder coating | |
CN102190827A (en) | Polyethylene material with antistatic performance | |
CN105330963A (en) | Preparation method of wear-resistant and anti-static PP (polypropylene) sheet | |
CN109651700A (en) | A kind of permanent conductive plastics particle and preparation method thereof | |
CN105199563A (en) | Electromagnetic shielding material adopting thermoset powder | |
CN111978712A (en) | Electromagnetic protection plastic and preparation method thereof | |
Kandasubramanian et al. | An electroconductive filler for shielding plastics |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |