CN102176298A - Matrix electroluminescent flat-panel display - Google Patents
Matrix electroluminescent flat-panel display Download PDFInfo
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- CN102176298A CN102176298A CN2011100348124A CN201110034812A CN102176298A CN 102176298 A CN102176298 A CN 102176298A CN 2011100348124 A CN2011100348124 A CN 2011100348124A CN 201110034812 A CN201110034812 A CN 201110034812A CN 102176298 A CN102176298 A CN 102176298A
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Abstract
The invention discloses a matrix electroluminescent flat-panel display which comprises a transparent flexible plastic base layer (1), a transverse transparent conductive stripe layer (2) fabricated on the transparent flexible plastic base layer (1), a luminescent layer (3) made of an inorganic alternating-current inorganic powder electroluminescent material, a dielectric layer (4) made of an insulating material, a longitudinal back electrode stripe layer (6) made of a conductive material and fabricated on the surface of the dielectric layer (4), and a covered protective layer (7); all the layers are completely sealed by using a plastic film (9) to form a flexible matrix inorganic electroluminescent display; the back electrode (5) and a transparent electrode (13) of the display are respectively connected with a matrix scanning circuit device, controlled by an electronic chip and driven by an electric field to emit light so as to form a dynamic image formed by independent luminescent pixels; and the matrix electroluminescent flat-panel display disclosed by the invention can be applied in the fields of dynamic advertising, luminescent clothes, computer terminals, large-screen image displaying and the like.
Description
Technical field
The invention belongs to dull and stereotyped electro-luminescence display device applied technical field.
Background technology
Flat-plate luminous display device has been widely used in mobile phone, televisor, computing machine etc. as the terminal device of infotech.Technical indicators such as the continuous pursuit of present stage novel flat-plate display technique is big, light, thin, economize on electricity.Mostly flat-panel monitor is based on glass baseplate at present, as: Field Emission Display (FED), LCD (LCD), display of organic electroluminescence (OEL or OLED), plasma scope (PDP).Its shortcoming is that glass is easily broken, area is limited, weight is big, work heating, inflexibility, production cycle are grown, cost is more high.Existing electroluminescent display also is equally based on the glass basis, as: inorganic thick film electroluminescent display, inorganic thin-film electrofluorescence display, display of organic electroluminescence.
Existing plastics inorganic EL sheet (screen) technology, it is a kind of plane luminescence device that is based upon on the inorganic powder electroluminescent material basis, it uses screen printing technique to be made into fixedly luminous pattern, realize that by circuit control simplex switch flashes, existing a large amount of elaboration the in open source information, as: patent WO9626627, JP31-157070, China 87107413.3,87105208.3,96122380.4,89106585.7 etc.; The device of above method preparation can only simply use as: lamp box advertisement, back illumination, safe Warning Mark etc. are located.Its not enough place is the dynamic change that can't realize literal, pattern, color, gray scale, can not be used for terminal display.
A kind of matrix electroluminescent flat-panel monitor of the present invention, it by silk-screen printing technique, produces a kind of flat luminous display device based on plastic film substrate.It has flexible, in light weight, power savings good, production technology is simple, advantage such as with low cost.
A kind of matrix electroluminescent flat-panel monitor of the present invention can the display color pattern, literal, dynamic image.It can be applied in fields such as dynamic advertising, luminous clothes, terminal, large-screen image demonstration.
Summary of the invention
A kind of matrix electroluminescent flat-panel monitor, it comprises: at transparent flexible plastics basal layer (1), the horizontal electrically conducting transparent stripe layer of making on it (2), use inorganic AC powder electroluminescence made luminescent layer (3), use insulating material to make dielectric layer (4), use conductive material on the dielectric layer surface, to make vertical back electrode stripe layer (6), protective mulch (7), and seal formation flexible matrix inorganic electroluminescent display afterwards fully with plastic sheeting (9); The back electrode of display (5), transparency electrode (13) are connected with the matrix-scanning circuit device respectively, are controlled by electronic chip, and be luminous by the electric field driven generation, forms the dynamic image by the first combination of independent light emitting pixel.
Transparent flexible plastics basal layer (1) is to use the water white transparency degree good, a kind of in the smooth PET film of smooth surface, fluorine plastic film, PE film, the PVC film.Wherein PET film, fluorine plastic film have good moisture resistance and temperature tolerance, as: polytetrafluoroethylene, its compactness can be moistureproof, the serviceable life of improving display.Film also can be other material.
At the colourless transparent plastic film surface, cover transparency conducting layer (2), the electrically conducting transparent stripe layer is to use a kind of in transparent polymeric conducting objects or the ITO electrically conducting transparent masking liquid, form travers by serigraphy, inkjet printing, laser ablation, sputtering method, its dry back forms the transparent conducting coating tape.Each electrically conducting transparent tape all can independently form electrode (13), and electrode can be the metal with satisfactory electrical conductivity, as: copper alms bowl, aluminium flake, electric wire etc.The electrically conducting transparent layer material can be organic and inorganic material, and its resistance should be less than 100 Europe mothers.The electrically conducting transparent fringe spacing requires size to determine according to light emitting pixel unit.
Transparency conducting layer (2) is also to use nanometer transparent conductive materials such as zinc paste, ATO to realize.
Electrically conducting transparent stripe layer (2) also can be to use the ITO transparent conductive film, forms travers by the laser ablation method, and its dry back forms the transparent conducting coating tape; Each electrically conducting transparent tape all independently forms electrode (13).
Luminescent layer (3) is by method for printing screen, and inorganic AC electroluminescence dusty material is mixed with colloid, evenly is printed on the transparency conducting layer and finishes after the drying.The electroluminescence dusty material is the 5-30 micron particles, and the luminescent powder color can be blue-green, blueness, green, orange etc., and wherein blue-green, blue emitting material can form colorful light-emitting by the light conversion.In the electroluminescence dusty material, add organic fluorescent dye and also can form colorful light-emitting, as: white, redness etc.The colloid that uses among the present invention can be epoxy resin, fluoro-containing coating class, contain silicon coating class etc., wherein adds cyanoethyl sugar, cyanoethyl ether can improve luminous intensity.
Dielectric layer (4) is by method for printing screen, dielectric material evenly is printed on the luminescent layer, and finishes after the drying.Dielectric material can be one or more mix powder materials in barium titanate, titanium white, lead titanates, the strontium titanates.It mixes with colloid, and the colloid that the present invention uses can be epoxy resin, fluoro-containing coating class, contain silicon coating class etc., wherein adds cyanoethyl sugar, cyanoethyl ether can improve luminous intensity.
Not during working medium layer (4), luminous intensity can descend 30% among the present invention, and be transparent conductive material when dorsum electrode layer (6) uses this moment, can produce two-sided luminous effect.
Dorsum electrode layer (6) is that conductive material is made, conductive material is a kind of in polymerization conducting objects, ITO conducting resinl, silver slurry, metallic conduction coating, the metal material, form longitudinal stripe by serigraphy, inkjet printing, laser ablation, vacuum sputtering method, its dry back forms back electrode conductive coating tape.Each conductive strip all can independently form electrode (5), and electrode can be the metal with satisfactory electrical conductivity, as: copper alms bowl, aluminium flake, electric wire etc.Dorsum electrode layer conductive stripe spacing requires size to determine according to light emitting pixel unit, and is normally identical with the transparent conducting coating strip width.
Electrically conducting transparent travers and back electrode conduction longitudinal stripe form 90 degree angles, and all electrode tapes are connected with the matrix-scanning circuit device respectively and drive, and can form the dynamic image by the first combination of independent light emitting pixel.The matrix-scanning circuit device can be by computer control.The flexible matrix inorganic electroluminescent display produces when luminous by the control of matrix-scanning circuit device and electronic chip, and its condition of work is voltage 70-220V, frequency 50-4000Hz, does not produce heat when it is luminous.
At dorsum electrode layer surface silk-screen dielectric ink, dry back forms protective seam (7).Protective seam can protection device preserve from test is adjusted.
Use band glue plastic sheeting (9) that device is sealed fully at last, form complete electroluminescent flat-panel display.Band glue plastic sheeting is a fluorine plastic film, and it has good moisture resistance and temperature tolerance, as: polytetrafluoroethylene, its compactness can be moistureproof, and in the serviceable life of improving display, plastic sheeting also can be other material.
Can print or print the fluorescent color coating (8) that red (10), blue (11), green (12) are formed in transparent flexible plastics basal layer outside, its corresponding respectively independent light emitting pixel unit of every kind of color forms the flexible matrix color image display.When the preparation color monitor, electroluminescent material should be selected blue-green or blueness, and its emission spectrum is 430-490nm, and the fluorescent color coating material can produce absorption at 430-490nm, forms colorful light-emitting.When using this method to prepare the colorful light-emitting display, pixel elements should be tiny as far as possible, and the colorful light-emitting that is produced is effective.
Description of drawings
Fig. 1 flexible matrix inorganic electroluminescent flat-panel display structural drawing
Fig. 2 transparency conducting layer
Fig. 3 dorsum electrode layer
Embodiment
A kind of matrix electroluminescent flat-panel monitor, it comprises: at transparent flexible plastics basal layer (1), the horizontal electrically conducting transparent stripe layer of making on it (2), use inorganic AC powder electroluminescence made luminescent layer (3), use insulating material to make dielectric layer (4), use conductive material on the dielectric layer surface, to make vertical back electrode stripe layer (6), protective mulch (7), and seal formation flexible matrix inorganic electroluminescent display afterwards fully with plastic sheeting (9); The back electrode of display (5), transparency electrode (13) are connected with the matrix-scanning circuit device respectively, are controlled by electronic chip, and be luminous by the electric field driven generation, forms the dynamic image by the first combination of independent light emitting pixel.
Select transparent flexible plastics basal layers (1) to be to use the water white transparency degree good, a kind of in the smooth PET film of smooth surface, fluorine plastic film, PE film, the PVC film.Wherein PET film, fluorine plastic film have good moisture resistance and temperature tolerance, as: polytetrafluoroethylene, its good compactness can be moistureproof, the serviceable life of improving display.Plastic sheeting also can be other material, and its heatproof and Shen draw characteristic to get well.When basal layer is selected the inflexibility plastics, as: acrylic plate, glass plate, it also can realize display effect, but can't reach the flexible bending effect.
At the colourless transparent plastic film surface, cover transparency conducting layer (2), the electrically conducting transparent stripe layer is to use a kind of in transparent polymeric conducting objects or the ITO electrically conducting transparent masking liquid, form travers by serigraphy, inkjet printing, laser ablation, sputtering method, its dry back forms the transparent conducting coating tape, and its thickness is usually less than 2 microns.Transparency conducting layer also can use the ito thin film by the vacuum sputtering preparation, and it is compared with method for printing screen and wants complicated.Each electrically conducting transparent tape all can independently form electrode (13), and electrode can be the metal with satisfactory electrical conductivity, as: copper alms bowl, aluminium flake, electric wire etc. are connected with the electrically conducting transparent tape by conducting resinl.The electrically conducting transparent layer material can be organic and inorganic material, and as using CLEVIOS model JOF7194, KPT model ITO2 etc., its resistance should be easy to generate heating and manifest less than 100 Europe mothers when resistance is big.The electrically conducting transparent fringe spacing requires size to determine according to light emitting pixel unit.
Electrically conducting transparent stripe layer (2) also can be to use the ITO transparent conductive film, forms travers by the laser ablation method, and its dry back forms the transparent conducting coating tape; Each electrically conducting transparent tape all independently forms electrode (13).
Cover luminescent layer (3) on transparency conducting layer, luminescent layer is by method for printing screen, and AC electroluminescence dusty material of the same race is mixed with colloid, and weight blending ratio 1: 1 evenly is printed on the transparency conducting layer again, finishes after the heating 100 degree dryings.Screen mesh is at the 200-300 order, and the serigraphy light emitting layer thickness is usually less than 60 microns, and luminous intensity can reduce when thickness was too big, and voltage-resistent characteristic was bad when thickness was too thin.Electroluminescence dusty material granularity is the 5-30 micron, and the luminescent powder color can be blue-green, blueness, green, orange etc., and wherein blue-green, blue emitting material can form colorful light-emitting by the light conversion.The electroluminescent powder model can be used commercially available prod: GG44, GG23, D502, D417.In the electroluminescence dusty material, add organic fluorescent dye and also can form colorful light-emitting, orange red etc. as: D330 white, D611.The colloid that uses among the present invention can be epoxy resin, fluoro-containing coating class, contain silicon coating class etc., is common commercially available prod; Wherein add cyanoethyl sugar, cyanoethyl ether can improve luminous intensity.
Dielectric layer (4) is by method for printing screen, dielectric material evenly is printed on the luminescent layer, and finishes after heating 100 degree dryings.Dielectric material can be one or more mix powder materials in barium titanate, titanium white, lead titanates, the strontium titanates, and medium powder powder material granularity is usually less than 5 microns.It mixes with colloid, mixed weight ratio 1: 1.The colloid that the present invention uses can be epoxy resin, fluoro-containing coating class, contain silicon coating class etc., is common commercially available prod; Wherein add cyanoethyl sugar, cyanoethyl ether can improve luminous intensity.Screen mesh is at the 300-400 order, and the serigraphy thickness of dielectric layers is usually less than 30 microns, and luminous intensity can reduce when thickness was too big, and voltage-resistent characteristic was bad when thickness was too thin.
Not during working medium layer (4), luminous intensity can descend 30% among the present invention, and be transparent conductive material when dorsum electrode layer (6) uses this moment, can produce two-sided luminous effect.
Dorsum electrode layer (6) is that conductive material is made, conductive material is a kind of in polymerization conducting objects, ITO conducting resinl, silver slurry, metallic conduction coating, the metal material, form longitudinal stripe by methods such as serigraphy, inkjet printing, laser ablation, vacuum sputterings, its dry back forms back electrode conductive coating tape.Each conductive strip all can independently form electrode (5), and electrode can be the metal with satisfactory electrical conductivity, as: copper alms bowl, aluminium flake, electric wire etc. are connected with the electrically conducting transparent tape by conducting resinl.Dorsum electrode layer conductive stripe spacing requires size to determine according to light emitting pixel unit, and is normally identical with the transparent conducting coating strip width.
Electrically conducting transparent travers and back electrode conduction longitudinal stripe form 90 degree angles, and all electrode tapes are connected with the matrix-scanning circuit device respectively and drive, and form the dynamic image by the first combination of independent light emitting pixel.The matrix-scanning circuit device can be by computer control.The flexible matrix inorganic electroluminescent display produces when luminous by the control of matrix-scanning circuit device and electronic chip, and as commercially available DURELPLEX model D520A, its condition of work is voltage 70-150V, frequency 50-4000Hz, does not produce heat when it is luminous.
At dorsum electrode layer surface silk-screen dielectric ink, dry back forms protective seam (7).Protective seam can protection device preserve from test is adjusted.
Use band glue plastic sheeting (9) that device is sealed fully at last, form complete electroluminescent flat-panel display.Band glue plastic sheeting can be a fluorine plastic film, and it has good moisture resistance and temperature tolerance, as: polytetrafluoroethylene, its compactness can moistureproofly resist, the ultraviolet ray irradiation, and in the serviceable life of improving display, plastic sheeting also can be other material.
Can print or print red (10), blue (11), green (12) fluorescent color coatings (8) in transparent flexible plastics basal layer outside, its corresponding respectively independent light emitting pixel unit forms the flexible matrix color image display.When the preparation color monitor, luminescent material should be selected blue-green or blueness, and its emission spectrum is 430-490nm, and the fluorescent color coating material can produce absorption at 430-490nm, forms colorful light-emitting.When using this method to prepare the colorful light-emitting display, pixel elements should be tiny as far as possible, and the colorful light-emitting that is produced is effective.
Advantage of the present invention
Flexible matrix inorganic electroluminescent flat-panel display of the present invention, it by silk-screen printing technique, produces a kind of flat luminous display device based on plastic film substrate, and its thickness has only the 0.3-0.8 millimeter.It has flexible, and the energy recovery of elasticity, is fit to various environment and pastes use.Its weight is lighter than device products such as LCD, PDP, and every square metre is had only 0.5 kilogram.Power savings is good, and every square metre of power is 50 watts.Production technology is simple, and this product all uses silk-screen printing technique in a large number, and it is simple, and with low cost.It is unrestricted to manufacture luminous display area.
Flexible matrix inorganic electroluminescent flat-panel display of the present invention can the display color pattern, literal, dynamic image.It can be applied in fields such as dynamic advertising, traffic indication, automobile instrument, luminous clothes, TV and household electrical appliances demonstration, terminal, large-screen image demonstration.
Embodiment
Select the PET plastic sheeting, use ITO conductive liquid printing transparent conductive layer, transparency electrode bandwidth 2mm is cut apart live width 0.5mm, and in temperature 100 degree oven dry.Electrode is drawn and is used elargol to be connected with electric wire.
Use the D502 luminescent material to mix, use the silk-screen printing technique printing with fluorine coating glue, and in temperature 100 degree oven dry.
Use barium titanate to mix, use the silk-screen printing technique printing with fluorine coating glue, and in temperature 100 degree oven dry.
Use the vertical serigraphy back electrode of silver slurry, back electrode bandwidth 2mm is cut apart live width 0.5mm, and electrode uses elargol to be connected with electric wire.And in temperature 100 degree oven dry.
Use dielectric ink printing protective mulch.
Can print or print red, blue, green fluorescence coloured coating in transparent flexible plastics basal layer outside, its respectively corresponding independent light emitting pixel unit.
Use the sealing of fluoroplastic belt glue film.
Use the D520A connection electrode also to drive its work, flexible matrix inorganic electroluminescent flat-panel display can the display color character pattern, image.
After embodiment has been done to illustrate preferably at the present invention in the above, what should understand to one skilled in the art is, under situation without departing from the spirit and scope of the present invention, all within the scope of the invention to any changes and improvements that the present invention did.
Claims (8)
1. matrix electroluminescent flat-panel monitor, it comprises: at transparent flexible plastics basal layer (1), the horizontal electrically conducting transparent stripe layer of making on it (2), use inorganic AC powder electroluminescence made luminescent layer (3), use insulating material to make dielectric layer (4), use conductive material on the dielectric layer surface, to make vertical back electrode stripe layer (6), protective mulch (7), and seal formation flexible matrix inorganic electroluminescent display afterwards fully with plastic sheeting (9); The back electrode of display (5), transparency electrode (13) are connected with the matrix-scanning circuit device respectively, are controlled by electronic chip, and be luminous by the electric field driven generation, forms the dynamic image by the first combination of independent light emitting pixel.
2. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, transparent flexible plastics basal layer (1) is to use the water white transparency degree, a kind of in the smooth PET film of smooth surface, fluorine plastic film, PE film, the PVC film.
3. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, electrically conducting transparent stripe layer (2) is to use a kind of in transparent polymeric conducting objects or the ITO electrically conducting transparent masking liquid, form travers by serigraphy, inkjet printing, laser ablation, sputtering method, its dry back forms the transparent conducting coating tape; Each electrically conducting transparent tape all independently forms electrode (13).
4. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, electrically conducting transparent stripe layer (2) is to use the ITO transparent conductive film, forms travers by the laser ablation method, and its dry back forms the transparent conducting coating tape; Each electrically conducting transparent tape all independently forms electrode (13).
5. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, luminescent layer (3) is by method for printing screen, and inorganic AC powder electroluminescence material is mixed with colloid, evenly is printed on the transparency conducting layer and finishes after the drying; Dielectric layer (4) is by method for printing screen, and one or more mix powder materials in barium titanate, titanium white, lead titanates, the strontium titanates are mixed with colloid, evenly is printed on the luminescent layer.
6. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, back electrode stripe layer (6) is a kind of in polymerization conducting objects, ITO conducting resinl, silver slurry, metallic conduction coating, the metal material, form longitudinal stripe by serigraphy, inkjet printing, laser ablation, sputtering method, its dry back forms back electrode conductive coating tape; Each conductive strip all independently forms electrode (5).
7. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, electrically conducting transparent travers and back electrode conduction longitudinal stripe form 90 degree angles, all electrode tapes are connected with the matrix-scanning circuit device respectively and drive, and form the dynamic image by the first combination of independent light emitting pixel; By the matrix-scanning circuit device by computer control.
8. a kind of according to claim 1 matrix electroluminescent flat-panel monitor, in the outside fluorescent color coating (8) of printing or printing red (10), blue (11), green (12) composition of transparent flexible plastics basal layer, the corresponding respectively independent light emitting pixel of every kind of color unit forms the flexible matrix color image display.
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| CN2011100348124A CN102176298A (en) | 2010-01-26 | 2011-01-24 | Matrix electroluminescent flat-panel display |
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| CN2010101012737A CN101894501A (en) | 2010-01-26 | 2010-01-26 | Flexible matrix inorganic electroluminescent flat-panel display |
| CN201010101273.7 | 2010-01-26 | ||
| CN2011100348124A CN102176298A (en) | 2010-01-26 | 2011-01-24 | Matrix electroluminescent flat-panel display |
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| CN2011100348124A Pending CN102176298A (en) | 2010-01-26 | 2011-01-24 | Matrix electroluminescent flat-panel display |
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| CN104507194A (en) * | 2014-12-10 | 2015-04-08 | 上海洞舟实业有限公司 | Fabrication method of third-dimensional (3D) electroluminescent device |
| CN105963073A (en) * | 2016-04-22 | 2016-09-28 | 济南圣泉集团股份有限公司 | Microcurrent band-aid |
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| CN102855827B (en) * | 2012-09-26 | 2015-10-28 | 华东师范大学 | A kind of transparent display screen and preparation method thereof |
| CN103152891B (en) * | 2013-02-16 | 2015-10-28 | 上海科润光电技术有限公司 | A kind of inorganic powder electroluminescence flexible matrix display |
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| Publication number | Publication date |
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| CN101894501A (en) | 2010-11-24 |
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Application publication date: 20110907 |