CN102173640B - Composite storage stabilizer for resin anchoring agent - Google Patents
Composite storage stabilizer for resin anchoring agent Download PDFInfo
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- CN102173640B CN102173640B CN 201110039837 CN201110039837A CN102173640B CN 102173640 B CN102173640 B CN 102173640B CN 201110039837 CN201110039837 CN 201110039837 CN 201110039837 A CN201110039837 A CN 201110039837A CN 102173640 B CN102173640 B CN 102173640B
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- stabilizer
- anchoring agent
- cement
- storage stabilizer
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Abstract
The invention discloses a composite storage stabilizer for a resin anchoring agent, which is prepared from a heat stabilizer, a thixotropic additive and a metal ion chelating agent at a certain proportion. By adding the cement composite storage stabilizer provided by the invention to the cement of the anchoring agent, the storage period of the anchoring agent product is increased to more than 1 year. During the storage period, the gel time of the cement is maintained against gel shift, the consistency retention rate of the cement is more than 90%, and the cement does not delaminate. The composite storage stabilizer does not affect the performances of the anchoring agent, such as the strength of the cement of the anchoring agent; greatly improves the storage stability and the quality of the anchoring agent product; and is significant in economic benefit and social benefit.
Description
Technical field
The present invention relates to a kind of stablizer, be specifically related to a kind of compound storage stabilizer of resin anchoring agent.
Background technology
Resin anchoring agent is as a kind of anchoring product, be mainly used in the underworkings supporting, Hydraulic and Hydro-Power Engineering, become an important component part of supporting industry, but we find in production in recent years: annual have a large amount of Anchor Agents to scrap the phenomenon of large-tonnage product because package stability is poor, mainly is the reason of Anchor Agent clay.The storage period of Anchor Agent clay part is short, what have can only reach 3 months Anchor Agent clay with regard to hardening, has plenty of the clay layering, situation about also having be the gel time of Anchor Agent clay when harsh product gel time at 2-3 minute, and be less than storage period about 10 days, the gel time of doing clay under same condition has just become 8-10 second, and significantly " skew " occured gel time, and this situation is especially in easier generation in summer.
Though in the Anchor Agent clay, add the storage period that stopper can prolong Anchor Agent, but adding seldom, the stopper of amount will greatly prolong the gel time of Anchor Agent clay, also affect Anchor Agent and require quick-setting characteristic, can not solve simultaneously Anchor Agent clay gel time " drift ", the problem that clay layering and clay denseness diminish occur.
Summary of the invention
The object of the invention is to provide a kind of compound storage stabilizer of resin anchoring agent.
The present invention adopts following technical scheme to achieve these goals:
The compound storage stabilizer of resin anchoring agent is characterized in that its constitutive material weight ratio is:
(1) thermo-stabilizer:
Naphthenic acid ketone 1
ESCALOL 567 0.1-1
Phosphoesterase 30 .1-0.5
Pentanoic 0.1-1
(2) thixotroping auxiliary agent:
Glycerol 1
Polyvinyl chloride powder 2-3
(3) metal chelating agent:
Potassium permanganate 1
Whiteruss 0.1-0.5;
The part by weight of described thermo-stabilizer, thixotroping auxiliary agent, metal chelating agent is 1: 1: 2.
Above ratio stirs into uniform liquid in stirring tank, be contained in the plastic tank of sealing, shake up in bucket during use, this compound storage stabilizer is poured in the clay Preblend cabin by normal stirring together by 2%-6% and the resin of amount of resin when producing the Anchor Agent clay.
Beneficial effect of the present invention:
Utilize the compound storage stabilizer of clay among the present invention to join in the Anchor Agent clay, improved the package stability of Anchor Agent, can be reached more than 1 year the storage period of Anchor Agent, greatly prolong 3-6 month storage period than prior art Anchor Agent, on clay consistency change impact very little, the problem that can not cause Anchor Agent resin and filler layering within storage period, significantly " skew " can not occur in the gel time of clay yet simultaneously, improved quality product, reduce the financial loss that short product rejection brings because of storage period, improved the image of enterprise.
Embodiment
Embodiment 1
Gel time is that the compound storage stabilizer of 8～40 seconds Anchor Agent comprises thermo-stabilizer, thixotroping auxiliary agent and complexing of metal ion agent, and its raw material is by weight ratio:
Thermo-stabilizer:
Naphthenic acid ketone 1
ESCALOL 567 0.1-1
Phosphoesterase 30 .1-0.5
Pentanoic 0.1-1
The thixotroping auxiliary agent:
Glycerol 1
Polyvinyl chloride powder 2-3
Metal chelating agent:
Potassium permanganate 1
Whiteruss 0.1-0.5
Above-mentioned compound storage stabilizer is thermo-stabilizer in mass ratio: thixotroping auxiliary agent: metal chelating agent :=1: 1: 2,
Above ratio stirs into uniform liquid in stirring tank, be contained in the plastic tank of sealing, shakes up in bucket during use.This compound storage stabilizer is poured in the clay Preblend cabin by normal stirring together by 2% and resin of amount of resin when producing the Anchor Agent clay.Other press the normal production technique production of Anchor Agent.
Embodiment 2
Gel time is that the compound storage stabilizer of 41～90 seconds Anchor Agent comprises thermo-stabilizer, thixotroping auxiliary agent and complexing of metal ion agent, and its raw material is by weight ratio:
Thermo-stabilizer:
Naphthenic acid ketone 1
ESCALOL 567 0.1-1
Phosphoesterase 30 .1-0.5
Pentanoic 0.1-1
The thixotroping auxiliary agent:
Glycerol 1
Polyvinyl chloride powder 2-3
Metal chelating agent:
Potassium permanganate 1
Whiteruss 0.1-0.5
Above-mentioned compound storage stabilizer is thermo-stabilizer in mass ratio: thixotroping auxiliary agent: metal chelating agent :=1: 1: 2,
Above ratio stirs into uniform liquid in stirring tank, be contained in the plastic tank of sealing, shake up in bucket during use, this compound storage stabilizer is poured in the clay Preblend cabin by normal stirring together by 4% and resin of amount of resin when producing the Anchor Agent clay.Other press the normal production technique production of Anchor Agent.
Embodiment 3
Gel time is that the compound storage stabilizer of 91～180 seconds Anchor Agent comprises thermo-stabilizer, thixotroping auxiliary agent and complexing of metal ion agent, and its raw material is by weight ratio:
Thermo-stabilizer:
Naphthenic acid ketone 1
ESCALOL 567 0.1-1
Phosphoesterase 30 .1-0.5
Pentanoic 0.1-1
The thixotroping auxiliary agent:
Glycerol 1
Polyvinyl chloride powder 2-3
Metal chelating agent:
Potassium permanganate 1
Whiteruss 0.1-0.5
Above-mentioned compound storage stabilizer is thermo-stabilizer in mass ratio: thixotroping auxiliary agent: metal chelating agent :=1: 1: 2.
Above ratio stirs into uniform liquid in stirring tank, be contained in the plastic tank of sealing, in bucket, shake up during use, this compound storage stabilizer is poured in the clay Preblend cabin by normal stirring together by 6% and resin of amount of resin when producing the Anchor Agent clay, and other press the normal production technique production of Anchor Agent.
The performance comparison of following table for not adding compound storage stabilizer and adding the Anchor Agent clay package stability of compound storage stabilizer.(temperature is 22 ± 1 ℃)
Example formulations Anchor Agent clay performance comparison
Claims (1)
1. the compound storage stabilizer of a resin anchoring agent is characterized in that its constitutive material mass ratio is:
(1) thermo-stabilizer:
The part by weight of naphthenic acid ketone, ESCALOL 567, phosphoric acid ester, pentanoic is 1:(0.1-1): (0.1-0.5): (0.1-1)
(2) thixotroping auxiliary agent
The part by weight of glycerol, polyvinyl chloride powder is 1:(2-3)
(3) metal chelating agent
The part by weight of potassium permanganate, whiteruss is 1:(0.1-0.5)
The part by weight of described thermo-stabilizer, thixotroping auxiliary agent, metal chelating agent is 1:1:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110039837 CN102173640B (en) | 2011-02-17 | 2011-02-17 | Composite storage stabilizer for resin anchoring agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110039837 CN102173640B (en) | 2011-02-17 | 2011-02-17 | Composite storage stabilizer for resin anchoring agent |
Publications (2)
| Publication Number | Publication Date |
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| CN102173640A CN102173640A (en) | 2011-09-07 |
| CN102173640B true CN102173640B (en) | 2013-01-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110039837 Active CN102173640B (en) | 2011-02-17 | 2011-02-17 | Composite storage stabilizer for resin anchoring agent |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584110B (en) * | 2011-12-29 | 2013-06-12 | 安徽淮河化工股份有限公司 | Method for dispersing thixotropic agent in resin anchoring agent |
| CN107117849A (en) * | 2017-05-12 | 2017-09-01 | 淮南舜天合成材料有限责任公司 | A kind of resin anchoring agent dispersant special |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041745A (en) * | 2007-02-13 | 2007-09-26 | 耿会英 | Water-resistant type resin anchoring agent |
| CN101792284A (en) * | 2010-01-12 | 2010-08-04 | 上海大屯能源股份有限公司 | Stepless speed change resin anchoring agent |
-
2011
- 2011-02-17 CN CN 201110039837 patent/CN102173640B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041745A (en) * | 2007-02-13 | 2007-09-26 | 耿会英 | Water-resistant type resin anchoring agent |
| CN101792284A (en) * | 2010-01-12 | 2010-08-04 | 上海大屯能源股份有限公司 | Stepless speed change resin anchoring agent |
Non-Patent Citations (4)
| Title |
|---|
| 周海涛 * |
| 王继勇.促进剂用量对树脂锚杆锚固剂凝胶时间的影响.《煤炭科学技术》.2008,(第11期),24. * |
| 耿会英.树脂锚固剂有效贮存期快速测定.《煤炭科学技术》.1998,(第6期),50. * |
| 黄乃炯 * |
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| CN102173640A (en) | 2011-09-07 |
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Address after: 232046 Wang Feng Gang Town, Huainan City, Anhui Province Patentee after: MEIYA UPDATED HIGH-TECH MATERIAL INDUSTRY Co.,Ltd. Address before: 232046 Wang Feng Gang Town, Huainan City, Anhui Province Patentee before: Anhui Huaihe Chemical Co.,Ltd. |
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Effective date of registration: 20230904 Address after: 232000 south side of woyuan Road, Xiejiaji District, Huainan City, Anhui Province Patentee after: MEIYA UPDATED HIGH-TECH MATERIAL INDUSTRY Co.,Ltd. Patentee after: HUAINAN SHUNTIAN SYNTHETIC MATERIAL CO.,LTD. Address before: 232046 Wang Feng Gang Town, Huainan City, Anhui Province Patentee before: MEIYA UPDATED HIGH-TECH MATERIAL INDUSTRY Co.,Ltd. |