CN105837141A - Acid-resistant dry-mixed mortar - Google Patents

Acid-resistant dry-mixed mortar Download PDF

Info

Publication number
CN105837141A
CN105837141A CN201610260972.3A CN201610260972A CN105837141A CN 105837141 A CN105837141 A CN 105837141A CN 201610260972 A CN201610260972 A CN 201610260972A CN 105837141 A CN105837141 A CN 105837141A
Authority
CN
China
Prior art keywords
cement
mixed mortar
dry
slag
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610260972.3A
Other languages
Chinese (zh)
Inventor
沈圣祥
李凤必
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kunlong Building Materials Co Ltd
Original Assignee
Anhui Kunlong Building Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Kunlong Building Materials Co Ltd filed Critical Anhui Kunlong Building Materials Co Ltd
Priority to CN201610260972.3A priority Critical patent/CN105837141A/en
Publication of CN105837141A publication Critical patent/CN105837141A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/40Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
    • C04B24/42Organo-silicon compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses acid-resistant dry-mixed mortar which comprises the following components in percentage by mass: combined cement, casting waste sand, yellow ground, coal ash, slag powder, lithium slag, wood fiber, cellulose ether, a redispersible polymer and polysiloxane powder. Compared with the prior art, the acid-resistant dry-mixed mortar has the following advantages that the addition ratio of the combined cement is appropriately increased; a part of the yellow ground is replaced by the casting waste slag and the lithium slag, so that the difficulty that the yellow ground is in supply shortage is alleviated, and the preparation cost is lowered; meanwhile, under the action of the polysiloxane powder and on premise that the strength of the dry-mixed mortar is ensured, the lithium slag and the combined cement can improve the acid resistance of the dry-mixed mortar, and after the dry-mixed mortar is used normally, the erosion rate of the dry-mixed mortar in an acid environment is less than 1% within two years, and the compressive strength of the dry-mixed mortar is reduced by about 8% after two years, being of relatively optimal levels.

Description

A kind of acid resistance dry powder and mortar
Technical field
The invention belongs to building material technical field, be specifically related to a kind of acid resistance dry powder and mortar.
Background technology
Dry powder and mortar refers to the aggregate that drying screening processes, a kind of graininess that inorganic coagulation material and additive etc. mix by a certain percentage or powdery, wherein additive is water-retaining agent, thickening agent, polymer etc., it is transported to building site with form packed or in bulk, add water the material that i.e. can be used directly after mixing and stirring, compare with conventional on-site stirring mortar, dry powder and mortar has: best in quality, wide in variety, have good workability, easy to use, environmental protection, economic dispatch feature, wherein the aggregate used by dry powder and mortar is mainly natural yellow ground, its demand is bigger, but yellow ground is non-renewable resources, its price is also constantly rising violently, along with country's protection to natural river course, the exploitation of natural yellow ground will necessarily be limited, the resource making yellow ground is more and more nervous, therefore, need to research and develop other materials and replace the use of a small amount of even major part yellow ground.
Additionally, along with science and technology develops rapidly with industrial, construction material is on the rise by the corrosion of adverse circumstances, it is generally the case that construction material is all in alkalescence or alkalescence, more sensitive to sour environment, by studying existing data, acids corrosion affects the performance of construction material to a certain extent, in order to ensure safe operation and the life-time service of building, need to be improved in conventional dry powder and mortar, thus play the purpose of use antiacid, lasting.
Summary of the invention
It is an object of the invention to for existing dry powder and mortar material source not enough, the problem that acid-resisting is poor, it is provided that a kind of acid resistance dry powder and mortar.
The present invention is achieved by the following technical solutions: a kind of acid resistance dry powder and mortar, comprise following component, and the mass percent of each composition is: combination cement 25-35%, cast waste sand 25-35%, yellow ground 30-40%, flyash 2-6%, slag powders 10-15%, lithium slag 10-15%, wood fibre 0.6-0.8%, cellulose ether 0.2-0.4%, redispersible polymer 0.02-0.04%, polysiloxanes powder 0.06-0.08%;
Wherein, described combination cement is crystallization cement, high sulfuric-resisting portland cement and the compositions of quick hardening sulphoaluminate cement, and portfolio ratio is 1:1.2-1.5:1.8-2, and combination mortar can keep stable under the sour environment of PH > 2;
Wherein, described flyash is I level flyash;
Wherein, described lithium slag is acid slag, and particle diameter is less than 0.08mm, generates jello in lithium slag when active component and ripening mineral aquation, and gelinite compactness is relatively strong, improves mortar and uses the comprcssive strength in later stage;
Wherein, described wood fibre is ash color fibre, a length of 800-1500 μm, this wood fibre can build 3-D solid structure in mortar, improves workability, it is possible to effectively water guide, preventing Mortar shrinkage from ftractureing, auxiliary strengthens combination cement, lithium slag and the Antacid effectiveness of polysiloxanes powder.
As further improvement of these options, described redispersible polymer is ethylene carbonate-vinyl acetate copoly type high molecular polymer.
The present invention has the advantage that the adding proportion suitably adding combination cement in this invention compared to existing technology, casting waste residue and lithium slag is selected to replace part yellow ground, alleviate yellow ground and reduce a difficult problem for supply, reduce cost of manufacture, simultaneously, lithium slag and combination cement are under the effect of polysiloxanes powder, on the premise of ensureing dry powder and mortar strength character, the acid-resisting of reinforced mortar, after normal use, within 2 years, in sour environment, erosion ratio is less than 1%, and its comprcssive strength reduces about 8% after two years, belongs to more excellent level.
Detailed description of the invention
Embodiment 1
A kind of acid resistance dry powder and mortar, comprises following component, and the mass percent of each composition is: combination cement 25%, cast waste sand 10%, yellow ground 34%, flyash 3%, slag powders 12%, lithium slag 15%, wood fibre 0.6%, cellulose ether 0.3%, redispersible polymer 0.03%, polysiloxanes powder 0.07%;
Wherein, described combination cement is crystallization cement, high sulfuric-resisting portland cement and the compositions of quick hardening sulphoaluminate cement, and portfolio ratio is 1:1.2:2.
Embodiment 2
A kind of acid resistance dry powder and mortar, comprises following component, and the mass percent of each composition is: combination cement 28%, cast waste sand 6%, yellow ground 36%, flyash 5%, slag powders 10%, lithium slag 12%, wood fibre 0.7%, cellulose ether 0.2%, redispersible polymer 0.04%, polysiloxanes powder 0.06%;
Wherein, described combination cement is crystallization cement, high sulfuric-resisting portland cement and the compositions of quick hardening sulphoaluminate cement, and portfolio ratio is 1:1.3:1.9.
Embodiment 3
A kind of acid resistance dry powder and mortar, comprises following component, and the mass percent of each composition is: combination cement 30%, cast waste sand 5%, yellow ground 38%, flyash 2%, slag powders 14%, lithium slag 10%, wood fibre 0.7%, cellulose ether 0.2%, redispersible polymer 0.02%, polysiloxanes powder 0.08%;
Wherein, described combination cement is crystallization cement, high sulfuric-resisting portland cement and the compositions of quick hardening sulphoaluminate cement, and portfolio ratio is 1:1.5:1.8.
The combination cement of 25% is replaced with single sand, respectively matched group 1-3, replaces with two kinds of sand, respectively 4-6, concrete corresponding as follows:
Group Cement Proportioning
Matched group 1 Crystallization cement /
Matched group 2 High sulfuric-resisting portland cement /
Matched group 3 Quick hardening sulphoaluminate cement /
Matched group 4 Crystallization cement and high sulfuric-resisting portland cement 1:1.5
Matched group 5 Crystallization cement and quick hardening sulphoaluminate cement 1:2
Matched group 6 High sulfuric-resisting portland cement and quick hardening sulphoaluminate cement 1:1.2
Table 1
Under the experimental situation of PH=2, respectively in 7 days, 14 days, 28 days, 56 days, 84 days and the extent of corrosion of 126 days detection mortars and resistance to compression degree, result is as follows:
Table 1
Table 2
Be can be seen that by data in Tables 1 and 2, in embodiment 1-3, acid resistance is higher, and persistence is preferable, comprcssive strength just started on a declining curve after 28 days, and matched group 1-6, comprcssive strength begins on a declining curve after 28 days, and matched group 4-6, degree is declined big in comprcssive strength, it follows that three groups of cement composition are better than being used alone or using two-by-two, it are used alone and are better than using two-by-two at anaphase effect, three kinds of cement composition are mainly selected to use, it is also possible to select other compound modes according to different needs.

Claims (2)

1. an acid resistance dry powder and mortar, it is characterised in that comprise following component, and the mass percent of each composition is: combination cement 25-35%, cast waste sand 5-10%, yellow ground 30-40%, flyash 2-6%, slag powders 10-15%, lithium slag 10-15%, wood fibre 0.6-0.8%, cellulose ether 0.2-0.4%, redispersible polymer 0.02-0.04%, polysiloxanes powder 0.06-0.08%;
Wherein, described combination cement is crystallization cement, high sulfuric-resisting portland cement and the compositions of quick hardening sulphoaluminate cement, and portfolio ratio is 1:1.2-1.5:1.8-2;
Wherein, described flyash is I level flyash;
Wherein, described lithium slag is acid slag, and particle diameter is less than 0.08mm;
Wherein, described wood fibre is ash color fibre, a length of 800-1500 μm.
2. a kind of acid resistance dry powder and mortar, it is characterised in that described redispersible polymer is ethylene carbonate-vinyl acetate copoly type high molecular polymer.
CN201610260972.3A 2016-04-26 2016-04-26 Acid-resistant dry-mixed mortar Pending CN105837141A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610260972.3A CN105837141A (en) 2016-04-26 2016-04-26 Acid-resistant dry-mixed mortar

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610260972.3A CN105837141A (en) 2016-04-26 2016-04-26 Acid-resistant dry-mixed mortar

Publications (1)

Publication Number Publication Date
CN105837141A true CN105837141A (en) 2016-08-10

Family

ID=56590311

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610260972.3A Pending CN105837141A (en) 2016-04-26 2016-04-26 Acid-resistant dry-mixed mortar

Country Status (1)

Country Link
CN (1) CN105837141A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109369110A (en) * 2018-12-06 2019-02-22 江西省建筑材料工业科学研究设计院 A kind of reinforcement type cement base lithium slag grouting material
CN109665792A (en) * 2019-02-28 2019-04-23 莒县铭通建材有限公司 A kind of plastering mortar and preparation method thereof
CN111848029A (en) * 2020-07-07 2020-10-30 深圳市汉工造技术有限公司 Lithium slag modified ultra-high performance concrete product and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838129A (en) * 2010-04-30 2010-09-22 常州市众华建材科技有限公司 Premixed dry mortar
CN102126848A (en) * 2011-02-10 2011-07-20 乌鲁木齐市建筑建材科学研究院有限责任公司 Cement-based self-leveling dry powder mortar for high-cracking-resistance ground
CN102173690A (en) * 2011-01-05 2011-09-07 广东美涂士建材股份有限公司 Acid-rain-resistant mortar for exterior wall base material processing
KR20130057024A (en) * 2011-11-23 2013-05-31 엔아이테크 주식회사 The giopolymer binder using waste disc and the fireproofing mortar composition using thereof
CN104030644A (en) * 2014-06-09 2014-09-10 中国铁道科学研究院铁道建筑研究所 Polymer cement mortar for slab ballastless track of high-speed railway

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838129A (en) * 2010-04-30 2010-09-22 常州市众华建材科技有限公司 Premixed dry mortar
CN102173690A (en) * 2011-01-05 2011-09-07 广东美涂士建材股份有限公司 Acid-rain-resistant mortar for exterior wall base material processing
CN102126848A (en) * 2011-02-10 2011-07-20 乌鲁木齐市建筑建材科学研究院有限责任公司 Cement-based self-leveling dry powder mortar for high-cracking-resistance ground
KR20130057024A (en) * 2011-11-23 2013-05-31 엔아이테크 주식회사 The giopolymer binder using waste disc and the fireproofing mortar composition using thereof
CN104030644A (en) * 2014-06-09 2014-09-10 中国铁道科学研究院铁道建筑研究所 Polymer cement mortar for slab ballastless track of high-speed railway

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109369110A (en) * 2018-12-06 2019-02-22 江西省建筑材料工业科学研究设计院 A kind of reinforcement type cement base lithium slag grouting material
CN109665792A (en) * 2019-02-28 2019-04-23 莒县铭通建材有限公司 A kind of plastering mortar and preparation method thereof
CN111848029A (en) * 2020-07-07 2020-10-30 深圳市汉工造技术有限公司 Lithium slag modified ultra-high performance concrete product and preparation method thereof

Similar Documents

Publication Publication Date Title
CN103011637A (en) Bare concrete binding material and corrosion-resistant bare concrete utilizing same
CN103553454A (en) High performance concrete with steel slag as admixture and aggregate and preparation method thereof
CN105693173B (en) A kind of sleeve grouting material for assembled architecture
CN102092984B (en) Energy-saving environmental-protection thickener for mortar preblending and dry-mixing
CN103694830A (en) Polymer cement waterproof coating
CN104876500A (en) Self-compacting powder concrete for ocean engineering as well as preparation method and application
CN102731046A (en) Preparation method for nano concrete
CN108585592A (en) A kind of Concrete synergist and preparation method thereof
JP4906374B2 (en) Secondary concrete product and method for determining its composition
CN105541232A (en) Waterborne epoxy emulsion repairing mortar and preparation method thereof
CN105110730A (en) Modified organic silicon reinforced cement-based permeable crystallization type waterproof coating and preparation method therefor
CN104387005A (en) Carbon nanotube/cement composite material and preparation method thereof
CN108793857A (en) A kind of shield-tunneling construction synchronous grouting dry-mixed mortar and preparation method thereof
CN105837141A (en) Acid-resistant dry-mixed mortar
CN106082795A (en) Graphene oxide strengthens prestressed pore passage grouting material and preparation method thereof
CN105837140A (en) Brick making mortar
CN103396060A (en) Concrete mixture for mass concrete construction
CN105271852A (en) Seawater erosion resistant sulphoaluminate cement
CN105218002A (en) A kind of have from ultra high performance cementitious of perception repairing effect and preparation method thereof
CN108203282A (en) A kind of preparation method of high intensity non-dispersible underwater concrete
CN103979827B (en) A kind of manganese slag base concrete adulterant function regulator and preparation method thereof
CN110451840B (en) Composite type compacting agent
CN104045276A (en) Concrete with dense framework highly doped admixture
CN106746948A (en) A kind of premixing mortar of high-efficiency corrosion-resistant
CN108546030B (en) High-strength concrete with low consumption of cementing materials and easy pumping and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160810

RJ01 Rejection of invention patent application after publication