CN102167384A - Method for preparing precipitated barium sulfate coproduced with hydrochloric acid by using barium mud - Google Patents
Method for preparing precipitated barium sulfate coproduced with hydrochloric acid by using barium mud Download PDFInfo
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- CN102167384A CN102167384A CN 201010561918 CN201010561918A CN102167384A CN 102167384 A CN102167384 A CN 102167384A CN 201010561918 CN201010561918 CN 201010561918 CN 201010561918 A CN201010561918 A CN 201010561918A CN 102167384 A CN102167384 A CN 102167384A
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- barium
- hydrochloric acid
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- mud
- process white
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Abstract
The invention belongs to the technical field of three-waste treatment and comprehensive utilization of inorganic chemical industry, in particular relates to a method for preparing precipitated barium sulfate coproduced with hydrochloric acid by using barium mud. The method mainly comprises the following steps of: reacting the barium mud with hydrochloric acid, filtering to obtain filtrate, reacting the obtained filtrate with sulfuric acid to obtain a filter cake, washing, dripping, drying and crushing the filter cake, weighing and packaging to obtain a precipitated barium sulfate product. By utilizing the method, the barium mud residues can be thoroughly removed so as to lighten the pollution of the barium mud residues to the environment; the valuable precipitated barium sulfate product can be prepared; especially in the production process, the obtained hydrochloric acid can be recycled; and therefore, the method disclosed by the invention not only has remarkable social and economic benefits, but also has simple process and production equipment and is a more practical treatment and utilization method.
Description
Technical field
The invention belongs to the technical field of the inorganic chemical industry disposal of three wastes and comprehensive utilization, particularly a kind of with the clay method that is equipped with the process white co-production of hydrochloric of barium.
Technical background
Barium salt is a kind of that purposes is wide in the inorganic salts product, output is bigger, but no matter is bariumchloride, barium carbonate, or the production of barium sulfate, all will produce a large amount of body refuses inevitably---barium mud; And quantity discharged is very big, produce 20000 tons of barium carbonates per year for one, the factory of eight kiloton barium sulfate, at least need to discharge useless barium mud (butt) four kilotons every year, barium slag (butt) eight kilotons, owing to contain small amounts of water soluble barium or solubility in acid barium in the barium mud more, as not handling, both wasted the barium resource, the while is serious environment pollution also.Chinese patent application number is 93117305.1 document, having announced the method for a kind of barium mud co-producing sulfuric acid barium, magnesiumcarbonate, refined salt or ammonium chloride, Ba brick and other product, mainly is with the barium mud that is rich in bariumchloride and the halogen wadding (all being waste material) and other raw material co-producing sulfuric acid barium, magnesiumcarbonate, refined salt or the ammonium chloride that are rich in sal epsom.Other is water-soluble with being rich in, the barium mud of solubility in acid barium thing and organic acid, solubility organic acid salt, mineral acid, solubility inorganic acid salt, soda ash, caustic soda, lime-kiln gas, liming reaction also can be produced various organic and inorganic barium salts, barium thing.Though this method is handled filter residue certain effect, complex manufacturing are arranged.The clay relevant report that is equipped with the method for process white co-production of hydrochloric of present barium also of no use.
Summary of the invention
The invention provides with the clay method that is equipped with the process white co-production of hydrochloric of barium, this method not only technology is simple, and can also make multiple value product when can effectively handle waste residue.
To achieve the above object, technical scheme of the present invention is:
A kind of with the clay method that is equipped with the process white co-production of hydrochloric of barium, comprise being prepared as follows step:
Steps A, with barium mud by pure barium sulfate, put in first corrosion-resistant reactor with pure mass ratio 1: 0.17~0.57 with hydrochloric acid and to stir, reaction generates the mixing solutions of bariumchloride, carbonic acid gas and water;
Step B, gained mixing solutions in the steps A is filtered with first strainer;
Step C, send to and burn or buried filtering the gained filter cake among the step B;
Step D, drop into successively in second corrosion-resistant reactor with pure mass ratio 1: 0.27~0.47 with sulfuric acid and stir reaction generation process white and hydrochloric acid mixed solution filtering gained filtrate among the step B;
Step e, gained mixing solutions among the step D is filtered with second strainer;
Step F, the white filter cake that filters gained in the step e washed to check the weight after dryings, drying and the pulverizing with washing and spin-drying machine, moisture eliminator and pulverizer successively be packaged to be the process white product.
Wherein, the filtrate that filtration obtains in the described step step e is returned in first corrosion-resistant reactor and is recycled.
Reaction principle of the present invention is:
BaCO
3+2HCl=BaCl
2+CO
2+H
2O
BaCl
2+H
2SO
4=BaSO
4+2HCl
Contain solubility in acid barium salt (in barium sulfate) in the barium mud and be respectively about 50%, 30%, so the barium mudstone is made the good raw material source of barium compound.The present invention mainly is that barium mud and hydrochloric acid react in elder generation, filters, and then gained filtrate and sulfuric acid react, and the gained filter cake is checked the weight through washing drying, drying with after pulverizing and is packaged to be the process white product; The present invention can as clean as a pennyly gulp down barium mud waste residue, alleviates the pollution of barium mud waste residue to environment; Can make valuable process white product again, especially in the production process, the hydrochloric acid that is produced can also recycle, and not only has remarkable social benefit and economic benefit, and technology and production unit are simple, are a kind of relatively actual processing and utilize method.
Description of drawings
Fig. 1 is with the clay process flow sheet that is equipped with the method for process white co-production of hydrochloric of barium;
Wherein:
1-first corrosion-resistant reactor, 2-first strainer, 3-second corrosion-resistant reactor, 4-second strainer, 5-washing and spin-drying machine, 6-moisture eliminator, 7-pulverizer, 8-process white product.
Concrete embodiment
Embodiment 1
A kind of with the clay method that is equipped with the process white co-production of hydrochloric of barium, comprise being prepared as follows step:
Steps A, with barium mud by the pure barium sulfate of 500kg, put into first corrosion-resistant reactor with hydrochloric acid at 1: 0.17 with pure mass ratio and stir for 1 li, reaction generates the mixing solutions of bariumchloride, carbonic acid gas and water;
Step B, gained mixing solutions in the steps A is filtered with first strainer 2;
Step C, send to and burn or buried filtering the gained filter cake among the step B;
Step D, successively drop into second corrosion-resistant reactor with sulfuric acid at 1: 0.27 with pure mass ratio and stir reaction generation process white and 32.50kg hydrochloric acid mixed solution for 3 li filtering gained 161.86kg bariumchloride filtrate among the step B;
Step e, gained mixing solutions among the step D is filtered with second strainer 4;
Step F, the white filter cake that filters gained in the step e washed to check the weight after dryings, drying and the pulverizing with washing and spin-drying machine 5, moisture eliminator 6 and pulverizer 7 successively be packaged to be 104.04kg process white product 8.
The filtrate that filtration obtains in the described step step e is returned first corrosion-resistant reactor and is recycled for 1 li.
Embodiment 2
A kind of with the clay method that is equipped with the process white co-production of hydrochloric of barium, comprise being prepared as follows step:
Steps A, with barium mud by the pure barium sulfate of 500kg, put into first corrosion-resistant reactor with hydrochloric acid at 1: 0.37 with pure mass ratio and stir for 1 li, reaction generates the mixing solutions of bariumchloride, carbonic acid gas and water;
Step B, gained mixing solutions in the steps A is filtered with first strainer 2;
Step C, send to and burn or buried filtering the gained filter cake among the step B;
Step D, successively drop into second corrosion-resistant reactor with sulfuric acid at 1: 0.37 with pure mass ratio and stir reaction generation process white and 145.41kg hydrochloric acid mixed solution for 3 li filtering gained 528.43kg bariumchloride filtrate among the step B;
Step e, gained mixing solutions among the step D is filtered with second strainer 4;
Step F, the white filter cake that filters gained in the step e washed to check the weight after dryings, drying and the pulverizing with washing and spin-drying machine 5, moisture eliminator 6 and pulverizer 7 successively be packaged to be 465.46kg process white product 8.
The filtrate that filtration obtains in the described step step e is returned first corrosion-resistant reactor and is recycled for 1 li.
Embodiment 3
A kind of with the clay method that is equipped with the process white co-production of hydrochloric of barium, comprise being prepared as follows step:
Steps A, with barium mud by the pure barium sulfate of 500kg, put into first corrosion-resistant reactor with hydrochloric acid at 1: 0.57 with pure mass ratio and stir for 1 li, reaction generates the mixing solutions of bariumchloride, carbonic acid gas and water;
Step B, gained mixing solutions in the steps A is filtered with first strainer 2;
Step C, send to and burn or buried filtering the gained filter cake among the step B;
Step D, successively drop into second corrosion-resistant reactor with sulfuric acid at 1: 0.47 with pure mass ratio and stir reaction generation process white and 284.56kg hydrochloric acid mixed solution for 3 li filtering gained 814.07kg bariumchloride filtrate among the step B;
Step e, gained mixing solutions among the step D is filtered with second strainer 4;
Step F, the white filter cake that filters gained in the step e washed to check the weight after dryings, drying and the pulverizing with washing and spin-drying machine 5, moisture eliminator 6 and pulverizer 7 successively be packaged to be 910.86kg process white product 8.
The filtrate that filtration obtains in the described step step e is returned first corrosion-resistant reactor and is recycled for 1 li.
The foregoing description is preferred embodiment of the present invention, is not to be used for limiting the scope of the present invention, so all equivalences of being done with described feature of claim of the present invention and principle change or modify, all should be included within the claim scope of the present invention.
Claims (2)
1. one kind with the clay method that is equipped with the process white co-production of hydrochloric of barium, it is characterized in that, comprises being prepared as follows step:
Steps A, with barium mud by pure barium sulfate, put into first corrosion-resistant reactor (1) lining with hydrochloric acid with pure mass ratio 1: 0.17~0.57 and stir, reaction generates the mixing solutions of bariumchloride, carbonic acid gas and water;
Step B, gained mixing solutions in the steps A is filtered with first strainer (2);
Step C, send to and burn or buried filtering the gained filter cake among the step B;
Step D, drop into second corrosion-resistant reactor (3) lining with sulfuric acid successively with pure mass ratio 1: 0.27~0.47 and stir reaction generation process white and hydrochloric acid mixed solution filtering gained filtrate among the step B;
Step e, gained mixing solutions among the step D is filtered with second strainer (4);
Step F, the white filter cake that filters gained in the step e used washing and spin-drying machine (5), moisture eliminator (6) and pulverizer (7) to wash to check the weight after dryings, drying and the pulverizing successively be packaged to be process white product (8).
2. according to claim 1 with the clay method that is equipped with the process white co-production of hydrochloric of barium, it is characterized in that the filtrate that filtration obtains in the described step step e is returned first corrosion-resistant reactor (1) lining and recycled.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108176700A (en) * | 2017-11-08 | 2018-06-19 | 贵州昊华工程技术有限公司 | A kind of method for innocent treatment of barium slag |
CN110775995A (en) * | 2019-12-04 | 2020-02-11 | 新晃鲁湘钡业有限公司 | Treatment method for producing building material by using barium-containing slag mud |
CN110883061A (en) * | 2019-12-04 | 2020-03-17 | 新晃鲁湘钡业有限公司 | Barium-containing slag mud innocent treatment system |
CN115676868A (en) * | 2022-10-25 | 2023-02-03 | 河北誉东涂料有限公司 | Method for recovering barium sulfate from solid waste barium-containing salt mud |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101823755A (en) * | 2009-04-13 | 2010-09-08 | 王嘉兴 | Method for preparing precipitated barium sulfate and coproducing hydrochloric acid by using barium mineral waste residue |
-
2010
- 2010-11-25 CN CN 201010561918 patent/CN102167384A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101823755A (en) * | 2009-04-13 | 2010-09-08 | 王嘉兴 | Method for preparing precipitated barium sulfate and coproducing hydrochloric acid by using barium mineral waste residue |
Non-Patent Citations (1)
Title |
---|
《天津化工》 19901231 魏青松 钡泥治理的初步研究及应用 52-54 1-2 , 第2期 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108176700A (en) * | 2017-11-08 | 2018-06-19 | 贵州昊华工程技术有限公司 | A kind of method for innocent treatment of barium slag |
CN110775995A (en) * | 2019-12-04 | 2020-02-11 | 新晃鲁湘钡业有限公司 | Treatment method for producing building material by using barium-containing slag mud |
CN110883061A (en) * | 2019-12-04 | 2020-03-17 | 新晃鲁湘钡业有限公司 | Barium-containing slag mud innocent treatment system |
CN115676868A (en) * | 2022-10-25 | 2023-02-03 | 河北誉东涂料有限公司 | Method for recovering barium sulfate from solid waste barium-containing salt mud |
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Application publication date: 20110831 |