CN102161794A - Low-smoke halogen-free flame-retardant polyethylene cable material - Google Patents
Low-smoke halogen-free flame-retardant polyethylene cable material Download PDFInfo
- Publication number
- CN102161794A CN102161794A CN 201110060346 CN201110060346A CN102161794A CN 102161794 A CN102161794 A CN 102161794A CN 201110060346 CN201110060346 CN 201110060346 CN 201110060346 A CN201110060346 A CN 201110060346A CN 102161794 A CN102161794 A CN 102161794A
- Authority
- CN
- China
- Prior art keywords
- retardant
- cable material
- flame
- low
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 39
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 21
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 18
- 239000000779 smoke Substances 0.000 title claims abstract description 13
- -1 polyethylene Polymers 0.000 title claims abstract description 11
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 230000002687 intercalation Effects 0.000 claims abstract description 7
- 238000009830 intercalation Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 5
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 12
- 150000002367 halogens Chemical class 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract 4
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000000979 retarding effect Effects 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Insulated Conductors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
Embodiment | Tensile strength/MPa | Elongation at break/% | Fire-retardant rank |
2 | 14 | 212 | V0 |
3 | 14 | 257 | V1 |
4 | 13 | 229 | V1 |
5 | 13 | 267 | V1 |
6 | 12 | 308 | V2 |
7 | 11 | 580 | There is not fire-retardant effect |
8 | 12 | 296 | V2 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110060346A CN102161794B (en) | 2011-03-14 | 2011-03-14 | Low-smoke halogen-free flame-retardant polyethylene cable material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110060346A CN102161794B (en) | 2011-03-14 | 2011-03-14 | Low-smoke halogen-free flame-retardant polyethylene cable material |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102161794A true CN102161794A (en) | 2011-08-24 |
CN102161794B CN102161794B (en) | 2012-09-05 |
Family
ID=44463273
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110060346A Active CN102161794B (en) | 2011-03-14 | 2011-03-14 | Low-smoke halogen-free flame-retardant polyethylene cable material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102161794B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103788451A (en) * | 2014-01-07 | 2014-05-14 | 苏州奥凯材料技术有限公司 | PE (polyethylene) flame-retardant cable material and preparation method thereof |
CN103923376A (en) * | 2014-04-24 | 2014-07-16 | 上海交通大学 | Dynamic vulcanized inflaming retarding nylon/ethylene vinyl acetate rubber thermoplastic elastomer and preparation method thereof |
CN105778242A (en) * | 2016-05-10 | 2016-07-20 | 国网四川省电力公司自贡供电公司 | Composite flame-retardant cable material |
CN106832517A (en) * | 2017-01-13 | 2017-06-13 | 饶德生 | A kind of nano-meter flame retardantses master batch and preparation method thereof |
CN109103290A (en) * | 2018-08-09 | 2018-12-28 | 苏州福斯特光伏材料有限公司 | Fire-retardant backboard used for encapsulation of solar battery and solar cell module |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1465616A (en) * | 2002-06-21 | 2004-01-07 | 中国科学院化学研究所 | Magnetsium hydroxide halogen-free polythene flame redardant composite material |
WO2005054361A1 (en) * | 2003-11-25 | 2005-06-16 | E. I. Du Pont De Nemours And Company | Flame retardant, halogen-free compositions |
CN1704448A (en) * | 2004-05-25 | 2005-12-07 | 鲍文波 | Formulation of low-smoke halogen-free nontoxic environmentally-friendly cable materials and process for producing same |
CN101286377A (en) * | 2008-05-29 | 2008-10-15 | 浙江大学 | Irradiation cross-linking low smoke halogen-free fire retardant polyolefin cable material |
-
2011
- 2011-03-14 CN CN201110060346A patent/CN102161794B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1465616A (en) * | 2002-06-21 | 2004-01-07 | 中国科学院化学研究所 | Magnetsium hydroxide halogen-free polythene flame redardant composite material |
WO2005054361A1 (en) * | 2003-11-25 | 2005-06-16 | E. I. Du Pont De Nemours And Company | Flame retardant, halogen-free compositions |
CN1704448A (en) * | 2004-05-25 | 2005-12-07 | 鲍文波 | Formulation of low-smoke halogen-free nontoxic environmentally-friendly cable materials and process for producing same |
CN101286377A (en) * | 2008-05-29 | 2008-10-15 | 浙江大学 | Irradiation cross-linking low smoke halogen-free fire retardant polyolefin cable material |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103788451A (en) * | 2014-01-07 | 2014-05-14 | 苏州奥凯材料技术有限公司 | PE (polyethylene) flame-retardant cable material and preparation method thereof |
CN103923376A (en) * | 2014-04-24 | 2014-07-16 | 上海交通大学 | Dynamic vulcanized inflaming retarding nylon/ethylene vinyl acetate rubber thermoplastic elastomer and preparation method thereof |
CN105778242A (en) * | 2016-05-10 | 2016-07-20 | 国网四川省电力公司自贡供电公司 | Composite flame-retardant cable material |
CN106832517A (en) * | 2017-01-13 | 2017-06-13 | 饶德生 | A kind of nano-meter flame retardantses master batch and preparation method thereof |
CN109103290A (en) * | 2018-08-09 | 2018-12-28 | 苏州福斯特光伏材料有限公司 | Fire-retardant backboard used for encapsulation of solar battery and solar cell module |
Also Published As
Publication number | Publication date |
---|---|
CN102161794B (en) | 2012-09-05 |
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C06 | Publication | ||
PB01 | Publication | ||
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Low-smoke halogen-free flame-retardant polyethylene cable material Effective date of registration: 20140905 Granted publication date: 20120905 Pledgee: Hebei Shengyuan pawn Co.,Ltd. Pledgor: ANHUI JOY SENSE CABLE Co.,Ltd. Registration number: 2014130000006 |
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Effective date of registration: 20200805 Granted publication date: 20120905 |
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