CN102153427A - Excitation powder of flying plate type electric detonator without detonating powder - Google Patents

Excitation powder of flying plate type electric detonator without detonating powder Download PDF

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Publication number
CN102153427A
CN102153427A CN 201010593541 CN201010593541A CN102153427A CN 102153427 A CN102153427 A CN 102153427A CN 201010593541 CN201010593541 CN 201010593541 CN 201010593541 A CN201010593541 A CN 201010593541A CN 102153427 A CN102153427 A CN 102153427A
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China
Prior art keywords
powder
penthrite
electric detonator
detonator
medicine
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CN 201010593541
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CN102153427B (en
Inventor
刘明全
高欣
李学平
曾光伟
徐纯媛
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Yahua Group Mianyang Industrial Co Ltd
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Yahua Group Mianyang Industrial Co Ltd
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Abstract

The invention discloses excitation powder of a flying plate type electric detonator without detonating powder, relating to a detonator explosive. The invention aims to provide excitation powder which can be loaded under a certain pressure without obviously influencing the sensitivity, can be compacted to avoid powder leakage and can ensure the detonator to be reliably ignited. The technical scheme of the invention is as follows: the excitation powder comprises the following components in parts by weight: 3-7 parts of penthrite, 1-2 parts of potassium chlorate and 0-1 part of expanded perlite, wherein 350-450 milliliters of adhesive are added to every one kilogram of the mixed components; the apparent density of the penthrite is 0.7-0.9g/cm<3>; the purity of the potassium chlorate is no less than 90%; the adhesive is polyvinyl alcohol resin of which the concentration is 3-7%; and the penthrite is a coarse penthrite of which the particle size is 20-60 meshes or a mixture containing 50-70% of 20-60-mesh penthrite and 30-50% of 100-300-mesh penthrite. The invention is mainly used for producing the excitation powder of an electric detonator.

Description

A kind of fling chip electric detonator without primary explosive excites medicine
Technical field
The present invention relates to a kind of cap explosive, particularly relate to a kind of at the used medicine that excites in the fling chip electric detonator without primary explosive.
Technical background
In the prior art, the initiation mechanism of fling chip electric detonator without primary explosive is: the electric igniting assembly energising is got angry electric igniter, impel and excite the medicine detonation in the excitation apparatus, under electric igniter and the high temperature and high pressure gas effect that excites the medicine detonation to produce, in the rigidity of excitation apparatus break because of high pressure in the pipe bottom, forms High Speed Flyer, the charging explosive in detonator of High Speed Flyer initiation by impact below, propagation of explosion is finished the detonation transmission step by step.
As the technological core of fling chip electric detonator without primary explosive, the medicine that excites of excitation apparatus is the energy that produces High Speed Flyer, plays a part to form a connecting link in blasting cap initiation.For guaranteeing reliable initiation, excite medicine must satisfy two conditions simultaneously: one, have certain sensitivity, be beneficial to electric igniter and excite; Its two, have the higher energy that detonates, be beneficial to produce High Speed Flyer.
At above-mentioned condition, fling chip electric detonator without primary explosive in advance adopts RDX(onit, i.e. Cyclotrimethylene trinitramine usually) excite medicine with the mixture of oxygenant or pure too peace.Because these two kinds excite medicine all to have behind the pressurized sensitivity defective that obviously descends, for guaranteeing the detonator reliable initiation, relevant filling process all requires the two to keep state of nature filling (following abbreviation " pine dress "), and can not the pressure-bearing filling.
Owing to excite medicine to be in the powder charge top layer of non-priming basal detonator, if it is uncovered that basal detonator keeps, what be prone to " pine dress " in transhipment basal detonator and detonator assembling process excites the medicine phenomenon of spreading pesticides, obvious to the quality product influence, also has certain potential safety hazard; If the medicine top that excites at " pine dress " installs shutoff elements such as igniting lead for retractable pencil additional, not only operation and cost can obviously increase, and also there is certain threat in the pressure that press-fits the transmission of shutoff element to the reliability that excites that excites medicine.
Summary of the invention
The object of the present invention is to provide a kind of novel fling chip electric detonator without primary explosive to excite medicine, it can bear certain pressure filling and not obvious its sensitivity that influences, and the energy compacting prevents to spread pesticides and guarantees the detonator reliable initiation, has production adaptability widely.
The technical solution used in the present invention is: a kind of fling chip electric detonator without primary explosive excites medicine, each component that comprises the following weight ratio example: pacify very much: Potcrate: pearlstone=3-7:1-2:0-1, said components is mixed each kilogram the inside, back and is added tackiness agent 350-450 milliliter.
In such scheme, the described too apparent density of peace is 0.7-0.9g/cm 3The purity of described Potcrate is not less than 90%; Described tackiness agent is a polyvinyl alcohol resin, and its concentration is 3%-7%; Described too the peace for granularity the 20-60 purpose slightly too the peace, or the 50%-70% granularity be the 20-60 order pacify very much with the 30%-50% granularity be the mixture that the 100-300 order is pacified very much.
The technological process of production of the present invention is summarized as:
Too peace, Potcrate and perlite sieve and are mixed in proportion, and add tackiness agent then and carry out granulation, cross the 20-40 mesh sieve, and through oven dry, the medicine that dries in the air sieves by the 80-100 mesh sieve then, temporary getting final product.
The medicine that excites of the present invention obtains following performance data through experiment and detection:
1, consistency and stability: under 20 ℃ ± 5 ℃, relative humidity 90%~95% envrionment conditions, the present invention with cover copper shell, flange steel and igniting head coexistence, long storage 24 months does not have the generation of obvious color change and corrosion phenomenon, balance moisture content 0.45%.
2, heat resistance: store 2h under 100~120 ℃ of environment, do not have blast and take place with combustion phenomena, medicament outward appearance, color and free-running property all do not have obvious change.
3, electrostatic sensitivity: the assembling short electric detonator is that 2000pF, series resistance are 0 Ω, charging voltage under-12kV the condition at electric capacity, and to payment to a porter-shell discharge of electrical detonator, detected result is qualified.
4, mechanical sensitivity: under " 1.96MPa, 90 °, 20mg " test conditions, friction sensitivity measured value of the present invention is that 16%(DDNP is 100%); Under " 2kg, 25cm, 30mg " test conditions, impact sensitivity measured value of the present invention is that 20%(DDNP is 100%).
5, resistance to pressure: when compacted density≤1.4 g/cm3, under airtight charging condition, the present invention can reliably be excited by electric igniter.
Can draw from every technical characterictic of foregoing invention, advantage of the present invention is: it is basic medicine that the present invention pacifies very much with high explosive, make sensitizing agent with Potcrate, make density with pearlstone and adjust agent, add the polyvinyl alcohol tackiness agent system of mixing and form, it can bear certain pressure filling and not obvious its sensitivity that influences, the energy compacting prevents to spread pesticides and guarantees the detonator reliable initiation, has production adaptability widely, and its manufacturing process is simple, cost is lower, reliable in quality.
Embodiment
The present invention will be further described below in conjunction with specific embodiment:
Embodiment 1
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=3:1:0.2, said components is mixed each kilogram the inside, back and is added 350 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 20 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 80 mesh sieves then, temporary getting final product.
Embodiment 2
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=4:1.2:0.3, said components is mixed each kilogram the inside, back and is added 370 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 25 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 85 mesh sieves then, temporary getting final product.
Embodiment 3
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=5:1.5:0.5, said components is mixed each kilogram the inside, back and is added 390 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 30 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 88 mesh sieves then, temporary getting final product.
Embodiment 4
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=6:1.6:0.8, said components is mixed each kilogram the inside, back and is added 400 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 33 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 90 mesh sieves then, temporary getting final product.
Embodiment 5
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=7:1.8:0.9, said components is mixed each kilogram the inside, back and is added 420 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 35 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 95 mesh sieves then, temporary getting final product.
Embodiment 6
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=5:2:1, said components is mixed each kilogram the inside, back and is added 450 milliliters in tackiness agent.
Too peace, Potcrate and perlite sieve and mix according to the above ratio, add tackiness agent then and carry out granulation, cross 40 mesh sieves, and through oven dry, the medicine that dries in the air sieves by 100 mesh sieves then, temporary getting final product.
Embodiment 7
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=3:2:1, said components is mixed each kilogram the inside, back and is added 450 milliliters in tackiness agent.
Embodiment 8
In the present embodiment, we adopt each component of following weight ratio: pacify very much: Potcrate: pearlstone=3:2:0, said components is mixed each kilogram the inside, back and is added 450 milliliters in tackiness agent.
To pacify very much, Potcrate mixes according to the above ratio, adds tackiness agent then and carries out granulation, crosses 40 mesh sieves, through oven dry, the medicine that dries in the air sieves by 100 mesh sieves then, temporary getting final product.
In the various embodiments described above, the specification of each component that we adopt can be adjusted according to actual needs, such as can changing according to different needs in the size composition of pacifying very much, when being used for short electric detonator, too peace of the present invention can by 20~60 orders slightly too peace directly forms, with simplification technology saving cost; When being used for millisecond delay cap and since the extension body excite ability relatively a little less than, excite medicine need improve its sensitivity, can in the thick too peace of 20~60 orders, introduce that 30%~50% 100~300 orders are refining carefully pacifies very much and mix this moment; In addition, the purity of described Potcrate is not less than 90%; Tackiness agent can be other tackiness agents of polyvinyl alcohol resin or similar performance, and its concentration is 3%-7%.
Disclosed all features in this specification sheets except mutually exclusive feature, all can make up by any way.
Disclosed arbitrary feature in this specification sheets (comprising any accessory claim, summary) is unless special narration all can be replaced by other equivalences or the alternative features with similar purpose.That is, unless special narration, each feature is an example in a series of equivalences or the similar characteristics.

Claims (5)

1. a fling chip electric detonator without primary explosive excites medicine, it is characterized in that comprising each component of following weight ratio example: pacify very much: Potcrate: pearlstone=3-7:1-2:0-1, said components is mixed each kilogram the inside, back and is added tackiness agent 350-450 milliliter.
2. a kind of fling chip electric detonator without primary explosive according to claim 1 excites medicine, it is characterized in that the described too apparent density of peace is 0.7-0.9g/cm 3
3. a kind of fling chip electric detonator without primary explosive according to claim 1 and 2 excites medicine, it is characterized in that the purity of described Potcrate is not less than 90%.
4. a kind of fling chip electric detonator without primary explosive according to claim 3 excites medicine, it is characterized in that described tackiness agent is a polyvinyl alcohol resin, and its concentration is 3%-7%.
5. a kind of fling chip electric detonator without primary explosive according to claim 1 and 2 excites medicine, it is characterized in that described too the peace for granularity the 20-60 purpose slightly too the peace, or the 50%-70% granularity be the 20-60 order pacify very much with the 30%-50% granularity be the mixture that the 100-300 order is pacified very much.
CN 201010593541 2010-12-17 2010-12-17 Excitation powder of flying plate type electric detonator without detonating powder Active CN102153427B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102278920A (en) * 2011-08-24 2011-12-14 安徽理工大学 Non-primary explosive detonator
CN110028995A (en) * 2019-04-25 2019-07-19 梅丽中 A kind of alkaline biological particles and special equipment for incineration disposal organic liquid waste
CN110056879A (en) * 2019-04-25 2019-07-26 梅丽中 A kind of biological particles and special equipment for incineration disposal organic liquid waste

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3106892A (en) * 1961-12-27 1963-10-15 Du Pont Initiator
GB990706A (en) * 1963-02-11 1965-04-28 Ici Ltd New explosive compositions
CA893063A (en) * 1972-02-15 H. Paasch Julius Explosive compositions
CN86102717A (en) * 1986-04-17 1987-10-28 华东工学院 Industrial detonator using no priming charge
CN1032234A (en) * 1987-09-22 1989-04-05 淮南矿业学院 Simple flying-piece auget without detonating agent
CN1043562A (en) * 1988-12-20 1990-07-04 阜新矿务局十二厂 Industrial detonator using no priming charge

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA893063A (en) * 1972-02-15 H. Paasch Julius Explosive compositions
US3106892A (en) * 1961-12-27 1963-10-15 Du Pont Initiator
GB990706A (en) * 1963-02-11 1965-04-28 Ici Ltd New explosive compositions
CN86102717A (en) * 1986-04-17 1987-10-28 华东工学院 Industrial detonator using no priming charge
CN1032234A (en) * 1987-09-22 1989-04-05 淮南矿业学院 Simple flying-piece auget without detonating agent
CN1043562A (en) * 1988-12-20 1990-07-04 阜新矿务局十二厂 Industrial detonator using no priming charge

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《含能材料》 20080630 马宏昊,沈兆武,陈文川,周光辉,方锦雄 PETN和RDX在无起爆药雷管中作为激发药的对比性研究 285-289 1-5 第16卷, 第3期 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102278920A (en) * 2011-08-24 2011-12-14 安徽理工大学 Non-primary explosive detonator
CN110028995A (en) * 2019-04-25 2019-07-19 梅丽中 A kind of alkaline biological particles and special equipment for incineration disposal organic liquid waste
CN110056879A (en) * 2019-04-25 2019-07-26 梅丽中 A kind of biological particles and special equipment for incineration disposal organic liquid waste

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