CN102144817A - Protective facial mask containing nano silver and chitosan and production method of protective facial mask - Google Patents
Protective facial mask containing nano silver and chitosan and production method of protective facial mask Download PDFInfo
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- CN102144817A CN102144817A CN2011100843973A CN201110084397A CN102144817A CN 102144817 A CN102144817 A CN 102144817A CN 2011100843973 A CN2011100843973 A CN 2011100843973A CN 201110084397 A CN201110084397 A CN 201110084397A CN 102144817 A CN102144817 A CN 102144817A
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- chitosan
- gauze
- silver
- containing nano
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229920001661 Chitosan Polymers 0.000 title claims abstract description 34
- 230000001681 protective effect Effects 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 230000001815 facial effect Effects 0.000 title 2
- 229920000742 Cotton Polymers 0.000 claims abstract description 38
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000010410 layer Substances 0.000 claims description 54
- 239000000243 solution Substances 0.000 claims description 47
- 238000005238 degreasing Methods 0.000 claims description 32
- 101710134784 Agnoprotein Proteins 0.000 claims description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- 239000002346 layers by function Substances 0.000 claims description 20
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 13
- 238000004108 freeze drying Methods 0.000 claims description 13
- 238000005303 weighing Methods 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 9
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 8
- 239000012279 sodium borohydride Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004745 nonwoven fabric Substances 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 239000000428 dust Substances 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 208000035473 Communicable disease Diseases 0.000 abstract 1
- 241000700605 Viruses Species 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 230000001877 deodorizing effect Effects 0.000 abstract 1
- 210000000214 mouth Anatomy 0.000 abstract 1
- 210000003928 nasal cavity Anatomy 0.000 abstract 1
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 21
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 12
- 238000011010 flushing procedure Methods 0.000 description 6
- 229910001961 silver nitrate Inorganic materials 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- -1 cationic polysaccharide Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006196 deacetylation Effects 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Respiratory Apparatuses And Protective Means (AREA)
- Cosmetics (AREA)
Abstract
本发明公开了属于卫生用品制备技术领域的一种含纳米银和壳聚糖的防护口罩及其制备方法。本发明的防护口罩由五层纱布构成，其中包含两层含有纳米银和壳聚糖的功能性脱脂棉纱布。本发明防护口罩具有抗菌、除异味、吸附尘埃的功效，可有效地防止病菌或病毒经过口腔、鼻腔侵入人体，预防各类传染性疾病，同时具有良好的透气性能。本发明防护口罩的制备方法简单，材料来源广，适合工业化生产。
The invention discloses a protective mask containing nano-silver and chitosan and a preparation method thereof, which belong to the technical field of sanitary product preparation. The protective mask of the present invention consists of five layers of gauze, including two layers of functional absorbent cotton gauze containing nano-silver and chitosan. The protective mask of the present invention has the functions of antibacterial, deodorizing and dust absorption, can effectively prevent germs or viruses from invading the human body through oral cavity and nasal cavity, prevent various infectious diseases, and has good air permeability at the same time. The preparation method of the protective mask of the invention is simple, the source of materials is wide, and it is suitable for industrialized production.
Description
Technical field
The invention belongs to the amenities preparing technical field, be specifically related to a kind of protective mask that contains Nano Silver and shitosan and preparation method thereof.
Background technology
Mouth mask is the articles for daily use during people live, and can prevent the invasion to human body of bacterium and dust.Common mouth mask only possesses general filtering function, and function ratio is more single.In use respiration makes mouth mask cover body humidity simultaneously, thereby is beneficial to the growth of bacterial micro-organism.
Nano Silver is a kind of nontoxic, environment-friendly material, and has good antibacterial property, is widely used in the various anti-biotic materials.Shitosan is the unique cationic polysaccharide of nature, has good cell compatibility and histocompatbility, has stronger antibacterial activity simultaneously.Add Nano Silver and shitosan simultaneously during the preparation mouth mask, can play good antibacterial action.
Summary of the invention
The object of the present invention is to provide a kind of protective mask that contains Nano Silver and shitosan.
The present invention also aims to provide a kind of preparation method who contains the protective mask of Nano Silver and shitosan.
A kind of protective mask that contains Nano Silver and shitosan, it is made up of cover body and frenulum, be characterised in that, cover body is made of 5 layer materials: ground floor is the degreasing cotton gauze layer, the second layer, the 3rd layer are for containing the gauze functional layer of Nano Silver and shitosan, the 4th layer is the degreasing cotton gauze layer, and layer 5 is a nonwoven layer.
The particle diameter of described Nano Silver is 2-80nm.
The thickness of described functional layer material is 0.2-2mm, and porosity is greater than 80%.
A kind of preparation method who contains the protective mask of Nano Silver and shitosan is characterized in that, carries out according to following steps:
(1) take by weighing shitosan and be dissolved in 1% the acetic acid solution, the preparation mass concentration is the chitosan solution of 1-3%;
(2) take by weighing AgNO
3Be dissolved in the chitosan solution, after fully stirring, forming concentration is the AgNO of 0.01-1M
3-shitosan mixed solution left standstill 6-12 hour;
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution, after 4-24 hour under-20 ℃～-40 ℃ conditions pre-freeze, freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan;
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 0.5-6 hour postlyophilization;
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution more than 6 hours, take out, it is immersed in 1% the sodium hydroxide solution 3-8 hour, after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan;
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
Beneficial effect of the present invention: protective mask of the present invention contains Nano Silver and shitosan, can suppress microbial growth effectively, while good air permeability, comfortable wearing.The preparation method of protective mask of the present invention is simple, and the preparation material source is extensive, is fit to large-scale industrial production.
Description of drawings
Fig. 1 mouth mask overall schematic;
Among the figure, 1-cover body, 2-frenulum.
Fig. 2 contains the layer structure schematic diagram of the antibacterial and protective mouth mask of Nano Silver and shitosan;
Among the figure, 1-degreasing cotton gauze layer, 2-contain gauze functional layer, 3-degreasing cotton gauze layer, the 4-nonwoven layer of Nano Silver and shitosan.
The specific embodiment
The present invention will be further described below in conjunction with the drawings and specific embodiments.
Implementing used primary raw material is shitosan (deacetylation 95% molecular weight 200,000), silver nitrate, NaOH, glutaraldehyde, sodium borohydride, acetate, medical absorbent cotton gauze and nonwoven.Chemical reagent is chemical pure.
Embodiment one
(1) shitosan that takes by weighing 0.5g is dissolved in the acetic acid solution of 50ml 1%, and the preparation mass concentration is 1% chitosan solution.
(2) take by weighing 0.085g silver nitrate (AgNO
3) be dissolved in the 50ml chitosan solution, after fully stirring, forming concentration is the AgNO of 0.01M
3-chitosan solution left standstill 6-12 hour.
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution ,-20 ℃ of pre-freezes, and freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan after 4 hours.
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 0.5 hour postlyophilization.
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution 6 hours, remove the little molecule of residual glutaraldehyde, simultaneously with AgNO
3Be reduced to Nano Silver, the particle diameter of Nano Silver is 2-80nm, takes out, and then it is immersed in 1% the sodium hydroxide solution 3-8 hour, and after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan.
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
Embodiment two
(1) shitosan that takes by weighing 1g is dissolved in the acetic acid solution of 50ml 1%, and the preparation mass concentration is 2% chitosan solution.
(2) take by weighing 3.4g silver nitrate (AgNO
3) be dissolved in the 50ml chitosan solution, after fully stirring, forming concentration is the AgNO of 0.4M
3-chitosan solution left standstill 6-12 hour.
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution ,-25 ℃ of pre-freezes, and freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan after 8 hours.
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 1 hour postlyophilization.
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution 7 hours, remove the little molecule of residual glutaraldehyde, simultaneously with AgNO
3Be reduced to Nano Silver, the particle diameter of Nano Silver is 2-80nm, takes out, and then it is immersed in 1% the sodium hydroxide solution 3-8 hour, and after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan.
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
Embodiment three
(1) shitosan that takes by weighing 1.5g is dissolved in the acetic acid solution of 50ml 1%, and the preparation mass concentration is 3% chitosan solution.
(2) take by weighing 0.85g silver nitrate (AgNO
3) be dissolved in the 50ml chitosan solution, after fully stirring, forming concentration is the AgNO of 0.1M
3-chitosan solution left standstill 6-12 hour.
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution ,-30 ℃ of pre-freezes, and freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan after 12 hours.
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 2 hours postlyophilizations.
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution 8 hours, remove the little molecule of residual glutaraldehyde, simultaneously with AgNO
3Be reduced to Nano Silver, the particle diameter of Nano Silver is 2-80nm, takes out, and then it is immersed in 1% the sodium hydroxide solution 3-8 hour, and after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan.
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
Embodiment four
(1) shitosan that takes by weighing 1.5g is dissolved in the acetic acid solution of 50ml 1%, and the preparation mass concentration is 3% chitosan solution.
(2) take by weighing 6.8g silver nitrate (AgNO
3) be dissolved in the 50ml chitosan solution, after fully stirring, forming concentration is the AgNO of 0.8M
3-chitosan solution left standstill 6-12 hour.
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution ,-35 ℃ of pre-freezes, and freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan after 12 hours.
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 4 hours postlyophilizations.
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution 8 hours, remove the little molecule of residual glutaraldehyde, simultaneously with AgNO
3Be reduced to Nano Silver, the particle diameter of Nano Silver is 2-80nm, takes out, and then it is immersed in 1% the sodium hydroxide solution 3-8 hour, and after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan.
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
Embodiment five
(1) shitosan that takes by weighing 1.5g is dissolved in the acetic acid solution of 50ml 1%, and the preparation mass concentration is 3% chitosan solution.
(2) take by weighing 8.5g silver nitrate (AgNO
3) be dissolved in the 50ml chitosan solution, after fully stirring, forming concentration is the AgNO of 1M
3-chitosan solution left standstill 6-12 hour.
(3) double-deck degreasing cotton gauze is immersed in AgNO
3In-shitosan the mixed solution ,-40 ℃ of pre-freezes, and freeze drying makes the double-deck degreasing cotton gauze that contains Nano Silver and shitosan after 12 hours.
(4) the double-deck degreasing cotton gauze that will contain Nano Silver and shitosan is soaked in 2.5% the glutaraldehyde solution, 6 hours postlyophilizations.
(5) will take out through the degreasing cotton gauze that step (4) is handled, be soaked in mass concentration and be in 3% the sodium borohydride solution 12 hours, remove the little molecule of residual glutaraldehyde, simultaneously with AgNO
3Be reduced to Nano Silver, the particle diameter of Nano Silver is 2-80nm, takes out, and then it is immersed in 1% the sodium hydroxide solution 3-8 hour, and after the water flushing, freeze drying obtains to contain the gauze functional layer of Nano Silver and shitosan.
(6) make cover body according to the order of gauze layer, the gauze functional layer that contains Nano Silver and shitosan, gauze layer, nonwoven layer, the frenulum perforation is left in the cover body both sides, then frenulum is passed frenulum perforation and seam knot.
The protective mask that contains Nano Silver and shitosan of above embodiment preparation is made of cover body and frenulum, and overall schematic as shown in Figure 1; Cover body constitutes (as shown in Figure 2) by 5 layers of gauze material: ground floor is the degreasing cotton gauze layer, and the second layer, the 3rd layer are for containing the gauze functional layer of Nano Silver and shitosan, and the 4th layer is the degreasing cotton gauze layer, and layer 5 is a nonwoven layer.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110084397 CN102144817B (en) | 2011-04-02 | 2011-04-02 | Protective facial mask containing nano silver and chitosan and production method of protective facial mask |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110084397 CN102144817B (en) | 2011-04-02 | 2011-04-02 | Protective facial mask containing nano silver and chitosan and production method of protective facial mask |
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| Publication Number | Publication Date |
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| CN102144817A true CN102144817A (en) | 2011-08-10 |
| CN102144817B CN102144817B (en) | 2013-09-11 |
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| CN 201110084397 Active CN102144817B (en) | 2011-04-02 | 2011-04-02 | Protective facial mask containing nano silver and chitosan and production method of protective facial mask |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104893331A (en) * | 2015-05-20 | 2015-09-09 | 广东省微生物研究所 | Antibacterial wood-plastic composite and preparation method thereof |
| CN104947418A (en) * | 2015-06-09 | 2015-09-30 | 中国林业科学研究院林产化学工业研究所 | Preparation method of chitosan quaternary ammonium salt-silver nanoparticle antibacterial cotton fibers |
| CN104997196A (en) * | 2014-04-22 | 2015-10-28 | 冒华 | Mask used for bacteria suppression and dust prevention |
| CN105231527A (en) * | 2015-11-10 | 2016-01-13 | 梧株茉 | High-function filter film and preparation method thereof and mask with multiple filter functions |
| CN105433472A (en) * | 2015-12-01 | 2016-03-30 | 中国工程物理研究院材料研究所 | Safe rope-free mask |
| CN107232666A (en) * | 2017-08-01 | 2017-10-10 | 大连轶德科技有限公司 | A kind of fungi-proofing, antibacterial, haze mouth mask based on biogenic amine material and preparation method thereof |
| CN107670506A (en) * | 2017-10-25 | 2018-02-09 | 成都圻坊生物科技有限公司 | A kind of preparation method of the resistant to pollution PVDF ultrafiltration membrane of water filtration antibacterial |
| CN107965263A (en) * | 2017-12-21 | 2018-04-27 | 大连轶德科技有限公司 | Multifunctional sanitary environmental protection screen window and preparation method thereof |
| CN110628075A (en) * | 2019-09-27 | 2019-12-31 | 杭州电子科技大学 | Chitosan porous functional layer of a dust-proof antibacterial mask and preparation method thereof |
| CN111409341A (en) * | 2020-02-21 | 2020-07-14 | 杭州路先非织造股份有限公司 | Medical mask material based on spunlace nonwoven material and preparation method thereof |
| CN112970745A (en) * | 2020-12-31 | 2021-06-18 | 上海大学 | Metal nano particle based on branched chitosan microreactor and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105433472A (en) * | 2015-12-01 | 2016-03-30 | 中国工程物理研究院材料研究所 | Safe rope-free mask |
| CN107232666A (en) * | 2017-08-01 | 2017-10-10 | 大连轶德科技有限公司 | A kind of fungi-proofing, antibacterial, haze mouth mask based on biogenic amine material and preparation method thereof |
| CN107670506A (en) * | 2017-10-25 | 2018-02-09 | 成都圻坊生物科技有限公司 | A kind of preparation method of the resistant to pollution PVDF ultrafiltration membrane of water filtration antibacterial |
| CN107965263A (en) * | 2017-12-21 | 2018-04-27 | 大连轶德科技有限公司 | Multifunctional sanitary environmental protection screen window and preparation method thereof |
| CN110628075A (en) * | 2019-09-27 | 2019-12-31 | 杭州电子科技大学 | Chitosan porous functional layer of a dust-proof antibacterial mask and preparation method thereof |
| CN111409341A (en) * | 2020-02-21 | 2020-07-14 | 杭州路先非织造股份有限公司 | Medical mask material based on spunlace nonwoven material and preparation method thereof |
| CN111409341B (en) * | 2020-02-21 | 2022-12-23 | 杭州路先非织造股份有限公司 | Medical mask material based on spunlace nonwoven material and preparation method thereof |
| EP3984526A1 (en) * | 2020-10-14 | 2022-04-20 | Indian Oil Corporation Limited | Anti-viral formulation of active nano ingredients for coating on personal protective equipment and for aerosol based disinfectant composition |
| US11968981B2 (en) | 2020-10-14 | 2024-04-30 | Indian Oil Corporation Limited | Anti-viral formulation of active nano ingredients for coating on personal protective equipment and for aerosol based disinfectant composition |
| CN112970745A (en) * | 2020-12-31 | 2021-06-18 | 上海大学 | Metal nano particle based on branched chitosan microreactor and preparation method thereof |
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|---|---|
| CN102144817B (en) | 2013-09-11 |
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