CN102127700B - Method for producing hot rolled steel coils for ship building - Google Patents
Method for producing hot rolled steel coils for ship building Download PDFInfo
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- CN102127700B CN102127700B CN2011100434280A CN201110043428A CN102127700B CN 102127700 B CN102127700 B CN 102127700B CN 2011100434280 A CN2011100434280 A CN 2011100434280A CN 201110043428 A CN201110043428 A CN 201110043428A CN 102127700 B CN102127700 B CN 102127700B
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Abstract
The invention relates to a method for producing hot rolled steel coils for ship building. The method comprises the following steps: 1) designing the components, pretreating molten iron, then carrying out converter smelting, carrying out nitrogen/argon changing over and carrying out tapping to obtain molten steel; 2) continuously casting the molten steel to obtain slabs, controlling the weight of the molten steel in the tundish to be 8-15t when casting of the continuous casting tundish is stopped, ensuring the liquid level to be 200-350mm; carrying out protective casting in the whole course and ensuring the insertion depth of the long nozzle to be 300-400mm; 3) heating the slabs; and 4) finally rolling and curling the heated slabs, thus obtaining the hot rolled steel coils. The method has the following beneficial effects: the TMCP (thermo-mechanical control process)+RPC (relaxation-precipitation-controlling phase transformation) rolling processes are adopted and the contents of C and Mn are substantially reduced by utilizing micro-niobium treatment, thus reducing the production cost; and the E32 hot rolled steel coils for ship building obtained by the method have excellent plasticity and toughness, the elongation of the hot rolled steel coils is improved by more than 8%, and at the same time, the welding property of the materials is improved and good surface quality of the continuous casting slabs is ensured.
Description
Technical field
The invention belongs to the coils of hot-rolled steel preparation field, particularly a kind of shipbuilding is with the working method of coils of hot-rolled steel.
Background technology
C is high in existing each steel mill's composition of production ys 345MPa level series coil of strip, and slab surface crack is many, and the intensity surplus capacity is big, and plasticity and toughness are low.The intensity surplus capacity is big, influences cold-forming property; Casting billet surface has the crackle probability can not directly adorn greatly, is unfavorable for energy-saving and emission-reduction; C content is high, and welding property is poor; Mn content is high in the steel, and production cost is high, the product market competition ability; Any rolling technology is adopted in steel rolling, and the performance of products fluctuation range is big, is unfavorable for user's use.The investigation of Q345 series coil of strip production performance actual achievement
Table 1Q345 Series Steel thickness, performance range cartogram
Can find out from table 1:
Q345 produces main thickness below 16mm, and ys is at 290～540MPa, and tensile strength is at 450～665MPa, unit elongation 9.5～50%; The performance inconsistency scope is big aborning, the performance inconsistency lattice that have simultaneously.
Table 2Q345 Series Steel thickness and performance index frequency table
Can find out from table 2:
The ys of Q345 mainly be in 370～490MPa, tensile strength mainly at 490～630MPa scope, unit elongation mainly 14～34%, to produce main thickness be 3-17mm;
Q345 series coil of strip produces the investigation of branch actual achievement
625 stove Q345 are carried out C, Si, Mn element statistics.
Table 3Q345 Series Steel C, Si, Mn content range cartogram
Can find out from table 3:
Q345 steel C average content is 0.16%, the Mn average content is 1.39%;
Table 4C, Si, the Mn composition frequency
Can find out from table 4:
Q345 Series Steel heat analysis C content is main 0.15～0.18%, Mn content is mainly 1.32～1.52%.
National standard (GB712) is to Q345 composition, performance requriements and the contrast of production actual achievement
Table 5 composition, performance requriements and production actual achievement
Can find out from table 5: the rich amount of coils of hot-rolled steel Q345 intensity is big, and unit elongation is low, and the material over-all properties is poor, and Mn is high in the composition.
Summary of the invention
Technical problem to be solved by this invention provides the working method of a kind of shipbuilding with coils of hot-rolled steel; This method has reduced C in the E32 composition of steel, Mn content; Adopt suitable rolling technology and cooling control technology; Improve the over-all properties of E32 steel, produce low cost, high performance E32 coils of hot-rolled steel, in line with the theory realization energy-saving and emission-reduction of green iron and steel.
A kind of shipbuilding of the present invention comprises with the working method of coils of hot-rolled steel:
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow≤1 time tapping time 4.5～8.0min before the tapping; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the slag that arrives at a station is thick≤80mm; The omnidistance time 17～30min of Argon is handled at the argon station;
2) molten steel after the above-mentioned tapping is carried out continuous casting and gets slab, wherein connect water unwrap when watering in first stove in the water yield 25～30t of Baogang, liquid level 550～580mm; In bag during quick change in the water yield 15～20t of Baogang, liquid level 350～400mm; Normally water the water yield 42～50t of Baogang in time cast maintenance, liquid level 950～1000mm; Change the big Bao Shizhong water yield 35～40t of Baogang, liquid level 800～850mm; Baogang's water yield is controlled at 8～15t, liquid level 200～350mm in when bag stops watering in the continuous casting; The whole process protection cast, long nozzle depth of penetration 300～400mm;
3) with above-mentioned slab heating, 3mm≤slab thickness≤16mm, tapping temperature is controlled at 1230 ± 30 ℃, time inside furnace 160～200min, soaking time 22～30min;
4) with the slab rolling after the above-mentioned heating, curling promptly gets coils of hot-rolled steel; 3mm≤slab thickness≤16mm, finish rolling temperature in are controlled at 1050 ± 30 ℃, and finishing temperature is controlled at 850 ± 30 ℃, and curling temperature is controlled to be 580 ± 30 ℃, and cooling strategy is a back segment.
Above-mentioned steps 1) in, blows Ar time 5～8min, its bright circle≤200mm a little less than the ladle before the molten steel processing finishes in the converter smelting; Reinforced adjustment composition and temperature in the converter smelting, ladle blows Ar time 5～8min, its bright circle≤200mm; The Argon processing finishes to unwrap the time of watering 10～13min to continuous casting steel.
Above-mentioned steps 1) weight percent of each composition of molten steel of tapping is as shown in table 6 in:
Table 6 ingredient standard
Above-mentioned steps 2) in, liquidus temperature is controlled to be 1526 ℃ during continuous casting, and the bag temperature is controlled to be 1551 ± 7 ℃ in the target, and crystallizer protecting residue adopts low-carbon steel protecting slag.
Above-mentioned steps 4) in, the gained coils of hot-rolled steel is that coils of hot-rolled steel is used in the shipbuilding of E32 level.
E32 level coils of hot-rolled steel of the present invention utilizes little niobium to handle, and reduces the content of C, Mn significantly, is aided with suitable rolling technology and guarantees that coil of strip has good plasticity and toughness, and its unit elongation improves more than 8%, and-40 ℃ of ballistic works are enhanced about more than once; Low carbon component design (C≤0.08%) has improved the material welding property, guarantees surface quality of continuously cast slab good (in inferior peritectoid scope, casting billet surface produces a large amount of crackles with composition of steel in traditional E32 level shipbuilding), realizes straight dress simultaneously, energy-saving and emission-reduction; Low Mn design reduces the alloy consumption, reduces production costs.
Rolling technology adopts TMCP+RPC technology, will roll back relaxation-control phase transformation technology (RPC) technology first and be applied to the production of (P+F) steel, and low finishing temperature and curling temperature guarantee that coil of strip organizes tiny, even; Coil of strip has kept the microstructure characteristic of P+F, and coil of strip performance anisotropy is little; The E32 level steel of low C, low Mn composition has good combination of strength and toughness.This composition design and rolling technology will be that China is low-cost, a kind of new working method of high-performance low-alloy coils of hot-rolled steel.
Beneficial effect
1, the inventive method is simple, adopts the TMCP+RPC rolling technology, utilizes little niobium to handle the content that reduces C, Mn in the composition design, reduces the consumption of alloy, reduces production costs.
2, E32 level of the present invention shipbuilding has good plasticity and toughness with coils of hot-rolled steel, has improved cold-forming property, avoids the bending cracking problem of gross distortion in the use of E32 level coil of strip, reduces quality objection; Improve the material welding property, guaranteed that simultaneously surface quality of continuously cast slab is good, realized directly dress, energy-saving and emission-reduction.
Description of drawings
Fig. 1 is metallographic structure (500 times of amplifications) behind the E32 level steel rolling of sample number into spectrum 1, and grain fineness number is 11 grades.
Fig. 2 is metallographic structure (500 times of amplifications) behind the E32 level steel rolling of sample number into spectrum 2, and grain fineness number is 10 grades.
Fig. 3 is metallographic structure (500 times of amplifications) behind the E32 level steel rolling of sample number into spectrum 3, and grain fineness number is 10 grades.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 4.5min before the tapping 1 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 80mm of the slag that arrives at a station; The omnidistance time 17min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.06%, and Si 0.20%, and Mn 0.90%, P0.010%, and S 0.005%, and Nb+Ti+V 0.040%, and Als 0.018%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 25t of Baogang, liquid level 550mm; In bag during quick change in the water yield 15t of Baogang, liquid level 350mm; Normally water time cast keep in the water yield 42t of Baogang, liquid level 950mm changes the big Bao Shizhong water yield 35t of Baogang, liquid level 800mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 8t, liquid level 200mm; The whole process protection cast, long nozzle depth of penetration 300mm;
3) with above-mentioned slab heating, time inside furnace 160min, soaking time 22min, slab thickness 3.55mm, tapping temperature is controlled at 1260 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1080 ℃, and finishing temperature is controlled at 880 ℃; Curling temperature is controlled to be 610 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be that coils of hot-rolled steel is used in 1 E32 level shipbuilding.Accompanying drawing 1 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts assay and sees table 8.
Embodiment 2
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 6.0min before the tapping 0 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 60mm of the slag that arrives at a station; The omnidistance time 25min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.07%, and Si 0.25%, and Mn 1.0%, P0.015%, and S 0.010%, and Nb+Ti+V 0.050%, and Als 0.027%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 30t of Baogang, liquid level 560mm; In bag during quick change in the water yield 18t of Baogang, liquid level 380mm; Normally water time cast keep in the water yield 45t of Baogang, liquid level 980mm changes the big Bao Shizhong water yield 38t of Baogang, liquid level 830mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 10t, liquid level 270mm; The whole process protection cast, long nozzle depth of penetration 350mm;
3) with above-mentioned slab heating, time inside furnace 180min, soaking time 25min, slab thickness 7.05mm, tapping temperature is controlled at 1230 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1050 ℃, and finishing temperature is controlled at 850 ℃; Curling temperature is controlled to be 580 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be that coils of hot-rolled steel is used in 2 E32 level shipbuilding.Accompanying drawing 2 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts assay and sees table 8.
Embodiment 3
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 8.0min before the tapping 1 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 30mm of the slag that arrives at a station; The omnidistance time 30min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.08%, and Si 0.30%, and Mn 1.10%, P0.020%, and S 0.015%, and Nb+Ti+V 0.060%, and Als 0.030%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 28t of Baogang, liquid level 580mm; In bag during quick change in the water yield 20t of Baogang, liquid level 400mm; Normally water time cast keep in the water yield 50t of Baogang, liquid level 1000mm changes the big Bao Shizhong water yield 40t of Baogang, liquid level 850mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 15t, liquid level 350mm; The whole process protection cast, long nozzle depth of penetration 400mm;
3) with above-mentioned slab heating, time inside furnace 200min, soaking time 30min, during slab thickness 10.55mm, tapping temperature is controlled at 1200 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1020 ℃, and finishing temperature is controlled at 820 ℃; Curling temperature is controlled to be 550 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be that coils of hot-rolled steel is used in 3 E32 level shipbuilding.Accompanying drawing 3 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts assay and sees table 8.
Tensile property assay of the present invention is seen table 7, table 8 respectively with the impact assay.
Table 7 tensile property assay
Table 8 impacts assay
Claims (4)
1. a shipbuilding comprises with the working method of coils of hot-rolled steel:
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow≤1 time tapping time 4.5～8.0min before the tapping; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the slag that arrives at a station is thick≤80mm; The omnidistance time 17～30min of Argon is handled at the argon station; Wherein the weight percent of each composition of gained molten steel is followed successively by: C0.06～0.08%, and Si 0.20～0.30%, and Mn 0.90～1.10%; P≤0.020%, S≤0.015%, Nb+Ti+V≤0.060%; Als 0.018～0.030%, and all the other are iron and unavoidable impurities;
2) molten steel after the above-mentioned tapping is carried out continuous casting and gets slab, wherein connect water unwrap when watering in first stove in the water yield 25～30t of Baogang, liquid level 550～580mm; In bag during quick change in the water yield 15～20t of Baogang, liquid level 350～400mm; Normally water the water yield 42～50t of Baogang in time cast maintenance, liquid level 950～1000mm; Change the big Bao Shizhong water yield 35～40t of Baogang, liquid level 800～850mm; Baogang's water yield is controlled at 8～15t, liquid level 200～350mm in when bag stops watering in the continuous casting; The whole process protection cast, long nozzle depth of penetration 300～400mm;
3) with above-mentioned slab heating, 3mm≤slab thickness≤16mm, tapping temperature is controlled at 1230 ± 30 ℃, time inside furnace 160～200min, soaking time 22～30min;
4) with the slab rolling after the above-mentioned heating, curling promptly gets coils of hot-rolled steel; 3mm≤slab thickness≤16mm, finish rolling temperature in are controlled at 1050 ± 30 ℃, and finishing temperature is controlled at 850 ± 30 ℃, and curling temperature is controlled to be 580 ± 30 ℃, and cooling strategy is a back segment.
2. a kind of shipbuilding according to claim 1 is characterized in that with the working method of coils of hot-rolled steel: blow Ar time 5～8min, its bright circle≤200mm a little less than the ladle before the molten steel processing finishes in the said step 1) converter smelting; Reinforced adjustment composition and temperature in the converter smelting, ladle blows Ar time 5～8min, its bright circle≤200mm; The Argon processing finishes to unwrap the time of watering 10～13min to continuous casting steel.
3. a kind of shipbuilding according to claim 1 is characterized in that with the working method of coils of hot-rolled steel: the weight percent of each composition of molten steel of tapping in the said step 1) is followed successively by: C 0.07%, and Si 0.25%; Mn 1.0%; P≤0.015%, S≤0.010%, Nb+Ti+V≤0.060%; Als 0.027%, and all the other are iron and unavoidable impurities.
4. a kind of shipbuilding according to claim 1 is characterized in that with the working method of coils of hot-rolled steel: said step 2), liquidus temperature is controlled to be 1526 ℃ during continuous casting, and middle bag temperature is controlled to be 1551 ± 7 ℃, and crystallizer protecting residue adopts low-carbon steel protecting slag.
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| CN2011100434280A CN102127700B (en) | 2011-02-21 | 2011-02-21 | Method for producing hot rolled steel coils for ship building |
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| CN2011100434280A CN102127700B (en) | 2011-02-21 | 2011-02-21 | Method for producing hot rolled steel coils for ship building |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6315946B1 (en) * | 1999-10-21 | 2001-11-13 | The United States Of America As Represented By The Secretary Of The Navy | Ultra low carbon bainitic weathering steel |
| CN1970818A (en) * | 2006-12-08 | 2007-05-30 | 武汉钢铁(集团)公司 | High-strength weathering steel and method of manufacturing same |
| CN101619417A (en) * | 2008-06-30 | 2010-01-06 | 上海梅山钢铁股份有限公司 | Economical weather-resistant checkered plate and production method thereof |
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2011
- 2011-02-21 CN CN2011100434280A patent/CN102127700B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6315946B1 (en) * | 1999-10-21 | 2001-11-13 | The United States Of America As Represented By The Secretary Of The Navy | Ultra low carbon bainitic weathering steel |
| CN1970818A (en) * | 2006-12-08 | 2007-05-30 | 武汉钢铁(集团)公司 | High-strength weathering steel and method of manufacturing same |
| CN101619417A (en) * | 2008-06-30 | 2010-01-06 | 上海梅山钢铁股份有限公司 | Economical weather-resistant checkered plate and production method thereof |
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