CN102127687B - Method for producing hot-rolled steel coil - Google Patents
Method for producing hot-rolled steel coil Download PDFInfo
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- CN102127687B CN102127687B CN2011100418644A CN201110041864A CN102127687B CN 102127687 B CN102127687 B CN 102127687B CN 2011100418644 A CN2011100418644 A CN 2011100418644A CN 201110041864 A CN201110041864 A CN 201110041864A CN 102127687 B CN102127687 B CN 102127687B
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Abstract
The invention relates to a method for producing a hot-rolled steel coil, which comprises the following steps of: 1) designing components, pretreating molten iron, smelting in a converter, switching nitrogen and argon, and tapping to obtain molten steel; 2) performing continuous casting on the molten steel to obtain a plate blank, wherein the content of the molten steel in a continuously cast intermediate ladle is controlled to be between 8 and 15t and the liquid level is controlled to be between 200 and 350mm when the intermediate ladle is not poured; and pouring is protected in the whole process, and the insertion depth of a long nozzle is between 300 and 400mm; 3) heating the plate blank; and 4) rolling and curling the heated plate blank. The content of C and Mn is greatly reduced through niobium microalloying by a thermo-mechanical controlled process-relaxed precipitation control (TMCP-RPC) rolling process, and production cost is reduced; the obtained Q345q-D hot-rolled steel coil has high plasticity and toughness, and the elongation of the hot-rolled steel coil is improved by over 8 percent; meanwhile, the welding performance of the material is improved, and the high surface quality of a continuously cast blank is ensured.
Description
Technical field
The invention belongs to the coil of strip preparation field, particularly a kind of working method of coils of hot-rolled steel.
Background technology
C is high in existing each steel mill's composition of production ys 345MPa level series coil of strip, and slab surface crack is many, and the intensity surplus capacity is big, and plasticity and toughness are low.The intensity surplus capacity is big, influences cold-forming property; Casting billet surface has the crackle probability can not directly adorn greatly, is unfavorable for energy-saving and emission-reduction; C content is high, and welding property is poor; Mn content is high in the steel, and production cost is high, the product market competition ability; Any rolling technology is adopted in steel rolling, and the performance of products fluctuation range is big, is unfavorable for user's use.The investigation of Q345 series coil of strip production performance actual achievement
Table 1Q345 Series Steel thickness, performance range cartogram
Can find out from table 1:
Q345 produces main thickness below 16mm, and ys is at 290~540MPa, and tensile strength is at 450~665MPa, unit elongation 9.5~50%; The performance inconsistency scope is big aborning, the performance inconsistency lattice that have simultaneously.
Table 2Q345 Series Steel thickness and performance index frequency table
Can find out from table 2:
The ys of Q345 mainly be in 370~490MPa, tensile strength mainly at 490~630MPa scope, unit elongation mainly 14~34%, to produce main thickness be 3-17mm;
Q345 series coil of strip produces the investigation of branch actual achievement
625 stove Q345 are carried out C, Si, Mn element statistics.
Table 3Q345 Series Steel C, Si, Mn content range cartogram
Can find out from table 3:
Q345 steel C average content is 0.16%, the Mn average content is 1.39%;
Table 4C, Si, the Mn composition frequency
Can find out from table 4:
Q345 Series Steel heat analysis C content is main 0.15~0.18%, Mn content is mainly 1.32~1.52%.National standard (GB714) is to Q345 composition, performance requriements and the contrast of production actual achievement
Table 5 composition, performance requriements and production actual achievement
Can find out from table 5: the rich amount of coils of hot-rolled steel Q345 intensity is big, and unit elongation is low, and the material over-all properties is poor, and Mn is high in the composition.
Summary of the invention
Technical problem to be solved by this invention provides a kind of working method of coils of hot-rolled steel; This method has reduced C in the Q345q-D composition of steel, Mn content; Adopt suitable rolling technology and cooling control technology; Improve the over-all properties of Q345q-D steel, produce low cost, high performance Q345q-D coils of hot-rolled steel, in line with the theory realization energy-saving and emission-reduction of green iron and steel.
The working method of a kind of coils of hot-rolled steel of the present invention comprises:
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow≤1 time tapping time 4.5~8.0min before the tapping; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the slag that arrives at a station is thick≤80mm; The omnidistance time 17~30min of Argon is handled at the argon station;
2) molten steel after the above-mentioned tapping is carried out continuous casting and gets slab, wherein connect water unwrap when watering in first stove in the water yield 25~30t of Baogang, liquid level 550~580mm; In bag during quick change in the water yield 15~20t of Baogang, liquid level 350~400mm; Normally water the water yield 42~50t of Baogang in time cast maintenance, liquid level 950~1000mm; Change the big Bao Shizhong water yield 35~40t of Baogang, liquid level 800~850mm; Baogang's water yield is controlled at 8~15t, liquid level 200~350mm in when bag stops watering in the continuous casting; The whole process protection cast, long nozzle depth of penetration 300~400mm;
3) with above-mentioned slab heating, 3mm≤slab thickness≤16mm, tapping temperature is controlled at 1230 ± 30 ℃, time inside furnace 160~200min, soaking time 22~30min;
4) with the slab rolling after the above-mentioned heating, curling promptly gets coils of hot-rolled steel; 3mm≤slab thickness≤16mm, finish rolling temperature in are controlled at 1050 ± 30 ℃, and finishing temperature is controlled at 850 ± 30 ℃, and curling temperature is controlled to be 580 ± 30 ℃, and cooling strategy is a back segment.
Above-mentioned steps 1) in, blows Ar time 5~8min, its bright circle≤200mm a little less than the ladle before the molten steel processing finishes in the converter smelting; Reinforced adjustment composition and temperature in the converter smelting, ladle blows Ar time 5~8min, its bright circle≤200mm; The Argon processing finishes to unwrap the time of watering 10~13min to continuous casting steel.
Above-mentioned steps 1) weight percent of each composition of molten steel of tapping is as shown in table 6 in:
Table 6 ingredient standard
Above-mentioned steps 2) in, liquidus temperature is controlled to be 1526 ℃ during continuous casting, and the bag temperature is controlled to be 1551 ± 7 ℃ in the target, and crystallizer protecting residue adopts low-carbon steel protecting slag.
Above-mentioned steps 4) in, the gained coils of hot-rolled steel is the Q345q-D coils of hot-rolled steel.
Q345q-D coils of hot-rolled steel of the present invention utilizes little niobium to handle, and reduces the content of C, Mn significantly, is aided with suitable rolling technology and guarantees that coil of strip has good plasticity and toughness, and its unit elongation improves more than 8%, and-20 ℃ of ballistic works are enhanced about more than once; Low carbon component design (C≤0.08%) has improved the material welding property, guarantees surface quality of continuously cast slab good (traditional Q345q-D composition is in inferior peritectoid scope, and casting billet surface produces a large amount of crackles), realizes straight dress simultaneously, energy-saving and emission-reduction; Low Mn design reduces the alloy consumption, reduces production costs.
Rolling technology adopts TMCP+RPC technology, will roll back relaxation-control phase transformation technology (RPC) technology first and be applied to the production of (P+F) steel, and low finishing temperature and curling temperature guarantee that coil of strip organizes tiny, even; Coil of strip has kept the microstructure characteristic of P+F, and coil of strip performance anisotropy is little; The Q345q-D steel of low C, low Mn composition has good combination of strength and toughness.This composition design and rolling technology will be that China is low-cost, a kind of new working method of high-performance low-alloy coils of hot-rolled steel.
Beneficial effect
1, the inventive method is simple, adopts the TMCP+RPC rolling technology, utilizes little niobium to handle the content that reduces C, Mn in the composition design, reduces the consumption of alloy, reduces production costs.
2, Q345q-D coils of hot-rolled steel of the present invention has good plasticity and toughness, has improved cold-forming property, avoids the bending cracking problem of gross distortion in the use of Q345q-D coil of strip, reduces quality objection; Improve the material welding property, guaranteed that simultaneously surface quality of continuously cast slab is good, realized directly dress, energy-saving and emission-reduction.
Description of drawings
Fig. 1 is metallographic structure (500 times of amplifications) behind the Q345q-D steel rolling of sample number into spectrum 1, and grain fineness number is 11 grades.
Fig. 2 is metallographic structure (500 times of amplifications) behind the Q345q-D steel rolling of sample number into spectrum 2, and grain fineness number is 10 grades.
Fig. 3 is metallographic structure (500 times of amplifications) behind the Q345q-D steel rolling of sample number into spectrum 3, and grain fineness number is 10 grades.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 4.5min before the tapping 1 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 80mm of the slag that arrives at a station; The omnidistance time 17min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.06%, and Si 0.15%, and Mn 0.90%, P0.010%, and S 0.005%, and Nb+Ti+V 0.040%, and Als 0.020%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 25t of Baogang, liquid level 550mm; In bag during quick change in the water yield 15t of Baogang, liquid level 350mm; Normally water time cast keep in the water yield 42t of Baogang, liquid level 950mm changes the big Bao Shizhong water yield 35t of Baogang, liquid level 800mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 8t, liquid level 200mm; The whole process protection cast, long nozzle depth of penetration 300mm;
3) with above-mentioned slab heating, time inside furnace 160min, soaking time 22min, slab thickness 3.55mm, tapping temperature is controlled at 1260 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1080 ℃, and finishing temperature is controlled at 880 ℃; Curling temperature is controlled to be 610 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be 1 Q345q-D coils of hot-rolled steel.Accompanying drawing 1 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts the check assay and sees table 8.
Embodiment 2
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 6.0min before the tapping 0 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 60mm of the slag that arrives at a station; The omnidistance time 25min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.07%, and Si 0.23%, and Mn 1.0%, P0.015%, and S 0.010%, and Nb+Ti+V 0.050%, and Als 0.025%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 30t of Baogang, liquid level 560mm; In bag during quick change in the water yield 18t of Baogang, liquid level 380mm; Normally water time cast keep in the water yield 45t of Baogang, liquid level 980mm changes the big Bao Shizhong water yield 38t of Baogang, liquid level 830mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 10t, liquid level 270mm; The whole process protection cast, long nozzle depth of penetration 350mm;
3) with above-mentioned slab heating, time inside furnace 180min, soaking time 25min, slab thickness 7.05mm, tapping temperature is controlled at 1230 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1050 ℃, and finishing temperature is controlled at 850 ℃; Curling temperature is controlled to be 580 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be 2 Q345q-D coils of hot-rolled steel.Accompanying drawing 2 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts the check assay and sees table 8.
Embodiment 3
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow tapping time 8.0min before the tapping 1 time; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the thick 30mm of the slag that arrives at a station; The omnidistance time 30min of Argon is handled at the argon station;
2) weight percent of each composition of molten steel after the above-mentioned tapping is followed successively by: C 0.08%, and Si 0.30%, and Mn 1.10%, P0.020%, and S 0.015%, and Nb+Ti+V 0.060%, and Als 0.030%, and all the other are iron and unavoidable impurities; Said molten steel is carried out continuous casting gets slab, wherein connect water unwrap when watering in first stove in the water yield 28t of Baogang, liquid level 580mm; In bag during quick change in the water yield 20t of Baogang, liquid level 400mm; Normally water time cast keep in the water yield 50t of Baogang, liquid level 1000mm changes the big Bao Shizhong water yield 40t of Baogang, liquid level 850mm, when bag stops watering in the continuous casting in Baogang's water yield be controlled at 15t, liquid level 350mm; The whole process protection cast, long nozzle depth of penetration 400mm;
3) with above-mentioned slab heating, time inside furnace 200min, soaking time 30min, during slab thickness 10.55mm, tapping temperature is controlled at 1200 ℃;
4) with the slab rolling after the above-mentioned heating, the finish rolling temperature in is controlled at 1020 ℃, and finishing temperature is controlled at 820 ℃; Curling temperature is controlled to be 550 ℃, and cooling strategy is a back segment, and curling at last, promptly to get sample number into spectrum be 3 Q345q-D coils of hot-rolled steel.Accompanying drawing 3 is seen in its metallographic structure, and the tensile property assay is seen table 7, impacts assay and sees table 8.Tensile property assay of the present invention is seen table 7, table 8 respectively with the impact assay.
Table 7 tensile property assay
Table 8 impacts assay
Claims (2)
1. the working method of a coils of hot-rolled steel comprises:
1) after composition designs, molten iron is carried out pre-treatment, converter smelting then, the nitrogen argon switches, tap molten steel; Re-blow≤1 time tapping time 4.5~8.0min before the tapping; Add alloy before the tapping 4/5; The two pushing off the slag of tapping, the slag that arrives at a station is thick≤80mm; The omnidistance time 17~30min of Argon is handled at the argon station; Wherein the weight percent of each composition of gained molten steel is followed successively by: C 0.06~0.08%, and Si 0.15~0.30%, and Mn 0.90~1.10%; P≤0.020%, S≤0.015%, Nb+Ti+V≤0.060%; Als 0.020~0.030%, and all the other are iron and unavoidable impurities;
2) molten steel after the above-mentioned tapping is carried out continuous casting and gets slab, wherein connect water unwrap when watering in first stove in the water yield 25~30t of Baogang, liquid level 550~580mm; In bag during quick change in the water yield 15~20t of Baogang, liquid level 350~400mm; Normally water the water yield 42~50t of Baogang in time cast maintenance, liquid level 950~1000mm; Change the big Bao Shizhong water yield 35~40t of Baogang, liquid level 800~850mm; Baogang's water yield is controlled at 8~15t, liquid level 200~350mm in when bag stops watering in the continuous casting; The whole process protection cast, long nozzle depth of penetration 300~400mm;
3) with above-mentioned slab heating, 3mm≤slab thickness≤16mm, tapping temperature is controlled at 1230 ± 30 ℃, time inside furnace 160~200min, soaking time 22~30min;
4) with the slab rolling after the above-mentioned heating, curling promptly gets coils of hot-rolled steel; 3mm≤slab thickness≤16mm, finish rolling temperature in are controlled at 1050 ± 30 ℃, and finishing temperature is controlled at 850 ± 30 ℃, and curling temperature is controlled to be 580 ± 30 ℃, and cooling strategy is a back segment;
Blow Ar time 5~8min, its bright circle≤200mm a little less than the ladle before the molten steel processing finishes in the said step 1) converter smelting; Reinforced adjustment composition and temperature in the converter smelting, ladle blows Ar time 5~8min, its bright circle≤200mm; The Argon processing finishes to unwrap the time of watering 10~13min to continuous casting steel;
Said step 2) in, liquidus temperature is controlled to be 1526 ℃ during continuous casting, and middle bag temperature is controlled to be 1551 ± 7 ℃, and crystallizer protecting residue adopts low-carbon steel protecting slag.
2. the working method of a kind of coils of hot-rolled steel according to claim 1, it is characterized in that: the weight percent of each composition of molten steel of tapping in the said step 1) is followed successively by: C 0.07%, and Si 0.23%; Mn 1.0%; P≤0.015%, S≤0.010%, Nb+Ti+V≤0.060%; Als 0.025%, and all the other are iron and unavoidable impurities.
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Citations (1)
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CN101549364A (en) * | 2009-05-15 | 2009-10-07 | 首钢总公司 | Method of using hot tandem rolling broad strip mill to produce steel plate for ship hull structure use |
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CN101549364A (en) * | 2009-05-15 | 2009-10-07 | 首钢总公司 | Method of using hot tandem rolling broad strip mill to produce steel plate for ship hull structure use |
Non-Patent Citations (2)
Title |
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乔世奇.B级船体结构用热轧钢带的生产实践.《2010年全国炼钢—连铸生产技术会议文集》.2010,第332-337页. * |
张本亮等.宁钢生产集装箱用钢B480GNQR工艺技术研究.《第十六届全国炼钢学术会议论文集》.2010,第514-518页. * |
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