CN102120900A - Ultraviolet curing nano transparent heat-insulating composite coating - Google Patents
Ultraviolet curing nano transparent heat-insulating composite coating Download PDFInfo
- Publication number
- CN102120900A CN102120900A CN2011100927485A CN201110092748A CN102120900A CN 102120900 A CN102120900 A CN 102120900A CN 2011100927485 A CN2011100927485 A CN 2011100927485A CN 201110092748 A CN201110092748 A CN 201110092748A CN 102120900 A CN102120900 A CN 102120900A
- Authority
- CN
- China
- Prior art keywords
- nano
- transparent heat
- composite coating
- ultraviolet light
- insulation composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to an ultraviolet curing nano transparent heat-insulating composite coating. The ultraviolet curing nano transparent heat-insulating composite coating mainly comprises the following substances in percentage by weight: 30 to 75 percent of oligomer, 0.01 to 15 percent of photoinitiator, 10 to 55 percent of activated monomer, 0.1 to 15 percent of tin stibium oxide and 0.01 to 10 percent of nano material. The ultraviolet curing nano transparent heat-insulating composite coating can be prepared into a transparent heat-insulating coating within one minute through ultraviolet irradiation at normal temperature, so the curing speed is high and the cost is low. The coating has selectivity on solar spectrum and forms a coating film of about 2 to 7 mu m on the surface of a material. When the coating is applied to glass, visible light transmissivity of the glass is still more than 75 percent and the infrared heat shielding rate is more than 70 percent, so the coating maintains the transparency of the original glass, can effectively isolate infrared heat radiation of sunlight, and has the advantages of excellent aging resistance, stain resistance, self cleaning, static resistance, glare resistance, radiation resistance, high curing speed, environmental friendliness and the like.
Description
Technical field
The present invention relates to a kind of heat insulation composite coating, is a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization particularly.
Background technology
Nano transparent heat-insulation composite coating is the high-tech energy-saving coatings that development in recent years is got up.This coating is to utilize the shielding properties of nano material to the infrared rays excellence, selects good coating system for use, makes the nano transparent heat-insulation composite coating that makes have strong adhesion, transparent, shielding infrared rays, heat insulation, performances such as environmental protection.According to surveying and determination, the coating that scribbles this coating can make the testee tow sides temperature difference reach 9 degrees centigrade, and energy-efficient performance is very superior.This coating is used for glass to prevent ultrared transmission, effectively cuts down the consumption of energy, have crucial meaning.
At present, the domestic research that has a lot of people to carry out this respect, a kind of thermal-insulating external-wall coating of nano-composite water of CN101029206 invention and preparation method thereof, the CN1903958 disclosure of the Invention a kind of synthesized polyurethane glass heat insulating paint and preparation method thereof, the CN101205419 disclosure of the Invention a kind of Sb-doped nano aqueous ATO heat-proof slurry and preparation method thereof, the CN101219859 disclosure of the Invention nano-oiliness ATO heat-insulating slurry and preparation method and application thereof.More than these coating all have the characteristics that visible light transmissivity is very high, the infrared light transmitance is very low.But, they or water-borne coatings or do not adopt the oil paint of ultraviolet light polymerization technology, set time is long, the contaminate environment if the oiliness system also needs to expend than multi-solvent.
Ultraviolet-curing paint is to obtain flourish new high-tech industry over past ten years at home, and nanotechnology is at the 21st century focus competitively studied of various countries.Come the nano transparent heat-insulation composite coating of modified ultraviolet curing with nanotechnology, can not only make the coating products upgrading, and can impel coating to expand to high-tech sector fields such as (as aerospace, electronic materials).
Summary of the invention
The technical problem to be solved in the present invention is: a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization is provided, wherein has characteristics such as excellent ageing-resistant, anti-electrostatic, anti-dazzle, curing speed be fast.
In order to solve the problems of the technologies described above, the invention provides a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, mainly comprise the following material of weight percent content: oligomer 30-75%, light trigger 1-5% and reactive monomer 10-55%, its tin-antiomony oxide and weight percent that contains that also weight percent is 0.1-15% is the nano material of 0.1-10%.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention is preferably, and described nano material is a kind of in nano silicon, nano zirconium dioxide, nano titanium oxide, the nano aluminium oxide or several.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention, be preferably, it also contains weight percent 0.1-0.5% with interior defoamer, and described defoamer is a kind of in silicone antifoam agent, vinyl polymer and the acrylic acid copolymer defoamer or several.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention is preferably, and it also contains weight percent 0.1-0.5% with interior dispersion moisture agent, and described dispersion moisture agent is a kind of in carboxylic acid, the amide polymer or several.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention is preferably, and it also contains weight percent 0.1-0.5% with interior vinylformic acid tertiary amine salt light-sensitive catalyst.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention, be preferably, described oligomer is to contain the resin that two keys can ultraviolet light polymerization, and it is mixed by a kind of or several materials in acrylic acid epoxy resin, acroleic acid polyurethane, polyester acrylate, organosilicon-modified acrylate and the amino acrylates and forms.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention, be preferably, reactive monomer is a kind of in pentaerythritol triacrylate, Viscoat 295, ethoxylated trimethylolpropane triacrylate, propoxylation Viscoat 295, the hexanediyl ester or several.
Nano transparent heat-insulation composite coating according to ultraviolet light polymerization of the present invention is preferably, and light trigger is a benzophenone.
The nano transparent heat-insulation composite coating of ultraviolet light polymerization of the present invention, select nano inorganic material for use, solar spectrum is had selectivity, form filming about the 2-70 micron at glass surface, the visible light transmissivity of glass still is higher than 75%, and the infra-red heat shielding rate is higher than 70%.Its this not only kept the transparency of original glass, and can effectively completely cut off the infrared emanation of sunlight, have excellent ageing-resistant, anti-stain self-cleaning, anti-electrostatic, anti-dazzle, radioprotective, quick solidifying, environmental protection etc.
Embodiment
Below, for a more detailed description with embodiment to the present invention.Present embodiment only is the description to best mode for carrying out the invention, scope of the present invention is not had any restriction.
Embodiment 1
Preparation process of the present invention is: 55-65 ℃ of control stirring tank, earlier from acrylic acid epoxy resin, acroleic acid polyurethane, polyester acrylate, select a kind of in organosilicon-modified acrylate and the amino acrylates or several are for oligomer, weight is 30g, selecting benzophenone is light trigger, weight is 5g, from pentaerythritol triacrylate, Viscoat 295, ethoxylated trimethylolpropane triacrylate, the propoxylation Viscoat 295, select a kind of in the hexanediyl ester or several are for reactive monomer, weight is 15g, tin-antiomony oxide weight is 5g, from nano silicon, nano zirconium dioxide, nano titanium oxide, select a kind of in the nano aluminium oxide or several are for nano material, after weight 5g carries out high speed dispersion 1 hour (1000-2000rpm), add the residue batching again, continue stirring and get final product after 1-4 hour.
Embodiment 2
As different from Example 1, also added select a kind of in the described batching or several are defoamer from silicone antifoam agent, vinyl polymer and acrylic acid copolymer defoamer, its weight is 1g.
Embodiment 3
Different with embodiment 1 or 2 is, also having added in the described batching from dispersion moisture agent is that a kind of carboxylic acid, the amide polymer or several are dispersion moisture agent, and its weight is 1g.
Embodiment 4
Different with embodiment 1 to 3 is that also having added weight in the described batching is the vinylformic acid tertiary amine salt light-sensitive catalyst of 3g.
Claims (8)
1. the nano transparent heat-insulation composite coating of a ultraviolet light polymerization, mainly comprise the following material of weight percent content: oligomer 30-75%, light trigger 0.01-15% and reactive monomer 10-55% is characterized in that: its tin-antiomony oxide and weight percent that contains that also weight percent is 0.1-15% is the nano material of 0.1-10%.
2. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1 is characterized in that: described nano material is a kind of in nano silicon, nano zirconium dioxide, nano titanium oxide, the nano aluminium oxide or several.
3. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1, it is characterized in that: it also contains weight percent 0.1-0.5% with interior defoamer, and described defoamer is a kind of in silicone antifoam agent, vinyl polymer and the acrylic acid copolymer defoamer or several.
4. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1, it is characterized in that: it also contains weight percent 0.1-0.5% with interior dispersion moisture agent, and described dispersion moisture agent is a kind of in carboxylic acid, the amide polymer or several.
5. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1, it is characterized in that: it also contains weight percent 1-5% with interior vinylformic acid tertiary amine salt light-sensitive catalyst.
6. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1 to 5, it is characterized in that: described oligomer is to contain the resin that two keys can ultraviolet light polymerization, and it is mixed by a kind of or several materials in acrylic acid epoxy resin, acroleic acid polyurethane, polyester acrylate, organosilicon-modified acrylate and the amino acrylates and forms.
7. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1 to 5, it is characterized in that: reactive monomer is a kind of in pentaerythritol triacrylate, Viscoat 295, ethoxylated trimethylolpropane triacrylate, propoxylation Viscoat 295, the hexanediyl ester or several.
8. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1 to 5, it is characterized in that: light trigger is a benzophenone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100927485A CN102120900A (en) | 2011-04-13 | 2011-04-13 | Ultraviolet curing nano transparent heat-insulating composite coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100927485A CN102120900A (en) | 2011-04-13 | 2011-04-13 | Ultraviolet curing nano transparent heat-insulating composite coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102120900A true CN102120900A (en) | 2011-07-13 |
Family
ID=44249571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100927485A Pending CN102120900A (en) | 2011-04-13 | 2011-04-13 | Ultraviolet curing nano transparent heat-insulating composite coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102120900A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408806A (en) * | 2011-11-03 | 2012-04-11 | 浙江大学 | High-emission transparent heat-insulating paint in atmospheric window regions and preparation method thereof |
| CN103059713A (en) * | 2011-10-20 | 2013-04-24 | 珠海东诚光固化材料有限公司 | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof |
| CN103897577A (en) * | 2012-12-24 | 2014-07-02 | 深圳市嘉达高科产业发展有限公司 | Glass paint and preparation method thereof |
| CN104327610A (en) * | 2014-10-20 | 2015-02-04 | 徐妍玲 | Thermal insulation coating capable of being quickly cured |
| CN105754389A (en) * | 2016-03-22 | 2016-07-13 | 湖州国信物资有限公司 | Ultraviolet curing coating material for electronic device and preparation method of ultraviolet curing coating material |
| CN106772849A (en) * | 2016-12-14 | 2017-05-31 | 江苏俊知光电通信有限公司 | The oversheath material of micro optical cable and preparation method thereof and the micro optical cable |
| CN106752193A (en) * | 2017-01-06 | 2017-05-31 | 浙江新迪在龙涂料科技有限公司 | A kind of preparation of UV curing chromatics nano transparent insulating coating |
| CN106752875A (en) * | 2017-01-06 | 2017-05-31 | 浙江新迪在龙涂料科技有限公司 | A kind of preparation of UV curing nanos transparent heat insulating dope |
| CN107236425A (en) * | 2017-06-23 | 2017-10-10 | 南京工业大学 | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof |
| CN107446488A (en) * | 2017-09-08 | 2017-12-08 | 蚌埠玻璃工业设计研究院 | A kind of glass anti-dazzle coating liquid |
| CN107936817A (en) * | 2017-11-13 | 2018-04-20 | 惠州市李唐科技发展有限公司 | A kind of nano water-proof is heat-insulated to reinforce liquid and its application method |
| CN108137946A (en) * | 2015-10-14 | 2018-06-08 | 陶氏环球技术有限责任公司 | Coating composition |
| CN111304966A (en) * | 2020-03-26 | 2020-06-19 | 厦门金锐奇工贸有限公司 | Pure white card and preparation method thereof |
| CN118063820A (en) * | 2024-04-19 | 2024-05-24 | 海安浩驰科技有限公司 | Impact-resistant heat-insulating film, preparation method and application |
-
2011
- 2011-04-13 CN CN2011100927485A patent/CN102120900A/en active Pending
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059713A (en) * | 2011-10-20 | 2013-04-24 | 珠海东诚光固化材料有限公司 | Ultraviolet light-cured self-cleaning coating, and preparation method and application thereof |
| CN102408806B (en) * | 2011-11-03 | 2013-10-23 | 浙江大学 | High-emission transparent heat-insulating paint in atmospheric window regions and preparation method thereof |
| CN102408806A (en) * | 2011-11-03 | 2012-04-11 | 浙江大学 | High-emission transparent heat-insulating paint in atmospheric window regions and preparation method thereof |
| CN103897577A (en) * | 2012-12-24 | 2014-07-02 | 深圳市嘉达高科产业发展有限公司 | Glass paint and preparation method thereof |
| CN103897577B (en) * | 2012-12-24 | 2016-05-18 | 深圳市嘉达高科产业发展有限公司 | glass coating and preparation method thereof |
| CN104327610A (en) * | 2014-10-20 | 2015-02-04 | 徐妍玲 | Thermal insulation coating capable of being quickly cured |
| CN108137946A (en) * | 2015-10-14 | 2018-06-08 | 陶氏环球技术有限责任公司 | Coating composition |
| CN108137946B (en) * | 2015-10-14 | 2021-02-09 | 陶氏环球技术有限责任公司 | Coating composition |
| CN105754389A (en) * | 2016-03-22 | 2016-07-13 | 湖州国信物资有限公司 | Ultraviolet curing coating material for electronic device and preparation method of ultraviolet curing coating material |
| CN106772849A (en) * | 2016-12-14 | 2017-05-31 | 江苏俊知光电通信有限公司 | The oversheath material of micro optical cable and preparation method thereof and the micro optical cable |
| CN106752193A (en) * | 2017-01-06 | 2017-05-31 | 浙江新迪在龙涂料科技有限公司 | A kind of preparation of UV curing chromatics nano transparent insulating coating |
| CN106752875A (en) * | 2017-01-06 | 2017-05-31 | 浙江新迪在龙涂料科技有限公司 | A kind of preparation of UV curing nanos transparent heat insulating dope |
| CN107236425A (en) * | 2017-06-23 | 2017-10-10 | 南京工业大学 | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof |
| CN107236425B (en) * | 2017-06-23 | 2019-12-24 | 南京工业大学 | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof |
| CN107446488A (en) * | 2017-09-08 | 2017-12-08 | 蚌埠玻璃工业设计研究院 | A kind of glass anti-dazzle coating liquid |
| CN107936817A (en) * | 2017-11-13 | 2018-04-20 | 惠州市李唐科技发展有限公司 | A kind of nano water-proof is heat-insulated to reinforce liquid and its application method |
| CN111304966A (en) * | 2020-03-26 | 2020-06-19 | 厦门金锐奇工贸有限公司 | Pure white card and preparation method thereof |
| CN118063820A (en) * | 2024-04-19 | 2024-05-24 | 海安浩驰科技有限公司 | Impact-resistant heat-insulating film, preparation method and application |
| CN118063820B (en) * | 2024-04-19 | 2024-07-02 | 海安浩驰科技有限公司 | Impact-resistant heat-insulating film, preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102120900A (en) | Ultraviolet curing nano transparent heat-insulating composite coating | |
| CN101760110A (en) | Ultraviolet curing nano transparent heat-insulation composite coating | |
| CN102311688B (en) | Aqueous transparent heat insulation paint | |
| CN103224722B (en) | Ultraviolet light polymerization fluorine carbon solar cell backside protecting film coating | |
| CN107236425B (en) | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof | |
| CN104070734B (en) | A kind of coated glass with high reflectivity and preparation method thereof | |
| CN103387787A (en) | Organic/inorganic hybrid transparent heat-insulating coating material, and preparation method and application thereof | |
| CN102585574B (en) | Method for preparing ultraviolet (UV) curing flame-retardant coating material and UV curing flame-retardant coating material | |
| CN102816551A (en) | Ultraviolet (UV)-moisture double-curing liquid optical transparent adhesive and preparation method thereof | |
| CN103725245A (en) | Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof | |
| CN105259737A (en) | Transfer processing method for glass base material of cover board | |
| CN105176375B (en) | A kind of LED UV woodenware repairing transparent matt top coat top coat and preparation method | |
| CN104140746A (en) | Composite type functional infrared reflection engineering machine powder coating and production technology thereof | |
| US20200157288A1 (en) | Fluorine-containing copolymer composition | |
| CN103333314A (en) | Cation photocuring fluorinated polyurethane resin and preparation method thereof | |
| CN104829776A (en) | Resin for UV-cured strippable protection film, preparation method and applications thereof | |
| CN104109453A (en) | Compound functional agricultural machinery finishing powder coating and production process thereof | |
| CN104149453A (en) | Ultraviolet-blocking window film | |
| CN101870760A (en) | Method for preparing microgel resin and UV-cured contamination resistant coating prepared from microgel resin | |
| CN100371402C (en) | Infrared resistant coating and preparation process | |
| CN104497866A (en) | Silicone sealant base coat liquid suitable for fiber cement board | |
| CN104774522B (en) | Heat insulation paint preparation method | |
| CN104004429B (en) | Based on the normal temperature solidified composite coating and preparation method thereof of modification 107 silicon rubber | |
| CN103436080A (en) | UV decorative ink used for PC/PMMA sheets and preparation method thereof | |
| CN102336528A (en) | Vanadium dioxide film, its preparation and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110713 |