CN102113505B - 含有啶虫脒的防治椰心叶甲的组合物 - Google Patents
含有啶虫脒的防治椰心叶甲的组合物 Download PDFInfo
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- CN102113505B CN102113505B CN 201010003849 CN201010003849A CN102113505B CN 102113505 B CN102113505 B CN 102113505B CN 201010003849 CN201010003849 CN 201010003849 CN 201010003849 A CN201010003849 A CN 201010003849A CN 102113505 B CN102113505 B CN 102113505B
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- acetamiprid
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- brontispa longissima
- flufenoxuron
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了含有啶虫脒的防治椰心叶甲的组合物，包含有效组分I和组分II，其特征在于：所述组分I为啶虫脒，组分II氟虫脲或甲氨基阿维菌素苯甲酸盐为，所述组分I和组分II的重量比为1∶60～60∶1，所述组分I和组分II的重量比为4∶1～20∶1。本发明的优点在于利用两种活性组分及助剂按一定比例混配成各种剂型，不但有效的防治椰心叶甲，具有明显的增效作用，而且可减少有效成份用药量，降低用药成本，有利于人身、环境及生态的安全。
Description
技术领域
本发明涉及一种农药组合物，尤其是涉及一种含有啶虫脒的防治椰心叶甲的组合物，可用于防治水稻、棉花、蔬菜、果树等上的害虫，特别是对棕榈科植物上发生的椰心叶甲更有特效。
背景技术
啶虫脒(acetamiprid)，属硝基亚甲基杂环类化合物，用于防治农业上重要的害虫，如蚜虫、蓟马、粉虱、跳甲等。
甲氨基阿维菌素苯甲酸盐(emamectin-benzoate)，从发酵产品阿维菌素B1开始合成的一种新型高效半合成抗生素杀虫剂，它具有超高效、低毒、无残留、无公害等生物农药的特点，对鳞翅目害虫和螨类既有胃毒又兼触杀活性。
氟虫脲(flufenoxuron)，属苯甲酰脲类化合物，是几丁质合成抑制剂。有很好的叶面滞留性，因抑制昆虫表皮几丁质的合成，使昆虫不能正常蜕皮或变态而死亡，成虫接触后，即使其卵孵化，幼虫也很快死亡。杀虫谱较广，对鳞翅目、鞘翅目、双翅目、半翅目、蜱螨亚纲等多种害虫有效。对高等动物低毒，对鱼类、鸟类和蜜蜂低毒。
农业是我国国民经济的基础。目前，我国生态与环境状况依然严峻，严重制约农业的可持续发展，其中食物安全、生态安全问题尤为突出。
椰风海韵构筑了海南秀美的风光，海南是我国棕榈科植物的主要分布区。棕榈科植物害虫椰心叶甲是我省有史以来危害最为严重的外来林业害虫，在国家林业局最新公布的19种林业检疫性有害生物名单中名列第三位。椰心叶甲的入侵和不断扩散蔓延，已给海南的自然景观、生态环境、农林业经济发展和旅游业造成严重影响，并对海南50万椰农的生计构成直接威胁。棕榈科植物的棕榈油、棕榈糖、棕榈淀粉、棕榈纤维、棕榈果蔬以及棕榈的药用价值等都是正在开发的重要自然资源，经营海南特色食品为主导方向的企业也因椰心叶甲的危害而受影响。
椰心叶甲为害树梢叶心，防治难，因其为害而造成的损失连年提高。这几年，在政府的大力组织下，化学和生物防治措施均取得一定进展，疫情得到一定程度的控制，但疫情仍面临进一步爆发的严重威胁。生物防治椰心叶甲有一定成效，但高温高湿的气候不利于绿僵菌生长，姬小蜂、啮小蜂的生存和寄生率受生态状况影响较大。而目前的个别药剂因含有菊酯类、有机磷和氨基甲酸酯类药剂对环境和棕榈科产品的残留造成对人身健康的威胁。椰心叶甲的为害造成果农发愁，消费者恐慌。椰心叶甲如得不到安全、有效的控制，既危害海南发展和人身安全。
结合实际需求，因长期连续使用含有单一组分的杀菌杀虫剂，病原菌和寄生虫容易产生抗药性，已经远远不能满足防治农作物的保护需求，尤其是防治椰心叶甲。
发明内容
本发明的在于利用两种活性组分及助剂按一定比例混配成各种剂型，具有防治水稻、棉花、蔬菜、果树等上的害虫，特别是对棕榈科植物上发生的椰心叶甲更有特效。
本发明提供一种含有啶虫脒的防治椰心叶甲的组合物，包含有效组分I和组分II，所述组分I为啶虫脒，组分II为氟虫脲或甲氨基阿维菌素苯甲酸盐(下简称甲维盐)。
较佳地，所述组分I和组分II的重量比为1∶60～60∶1；
优选组分I和组分II的重量比为4∶1～20∶1；
较佳地，所述组分I和组分II的累积重量百分比占总重量的1％～80％；
优选组分I和组分II的累积重量百分比占总重量的3％～13％；
所述含有啶虫脒的防治椰心叶甲的组合物可制成不同的应用剂型，包括可湿性粉剂、可溶性粉剂和水分散粒剂。
较佳地，所述的含有啶虫脒的防治椰心叶甲的组合物，可用于防治水稻、棉花、蔬菜、果树等上的害虫，尤其是对棕榈科植物上发生的椰心叶甲。
本发明的有益效果是：不但有效的防治椰心叶甲，具有明显的增效作用，而且减少有效组分用药量，降低用药成本，支持特色农产品的无公害生产、有利于人身、环境及生态的安全；保障“绿色食品”及出口农产品的生产、加工和贸易，对促进海南及内地沿海省份的自然景观、生态环境、农林业经济发展、旅游业和海南特色食品产业起到积极的作用。
制备以下各种制剂所用的助剂、表面活性剂及载体均为本领域技术人员所公知的。
一、配制可湿性粉剂时可用的助剂
载体：有高岭土、活性白土、硅藻土、泥煤、轻质碳酸钙、白炭黑、叶蜡石、滑石粉、方解石等。可以选一种或多种的混合，用量按重量计占10～75％。
分散剂：有工业副产物和阴离子型分散剂，可用亚硫酸纸浆废液、木质素磺酸钠、木质素磺酸钙、非离子表面活性剂如聚氧乙烯聚氧丙烯基醚嵌段共聚物、烷基酚聚氧乙烯基磷酸酯。可以选一种或多种的混合，用量按重量计占4～35％。
润湿剂：有天然产物和阴离子型表面活性剂如茶枯粉、皂角粉、洗衣粉、无患子粉、蚕沙、月桂醇基硫酸钠、十二烷基磺酸钠、亚甲基双萘磺酸钠、拉开粉、农乳2000号系列、润湿渗透剂F。可以选一种或多种的混合，用量按重量计占3～35％。
二、配制可溶性粉剂时可用的助剂
载体：氯化钠、硫酸钠、硫酸铵等。可以是一种或多种的混合，10～75％。
分散剂：有工业副产物和阴离子型分散剂，可用亚硫酸纸浆废液、木质素磺酸钠、木质素磺酸钙、非离子表面活性剂如聚氧乙烯聚氧丙烯基醚嵌段共聚物、烷基酚聚氧乙烯基磷酸酯。可以选一种或多种的混合，用量按重量计占4～35％。
润湿剂：有天然产物和阴离子型表面活性剂如茶枯粉、皂角粉、洗衣粉、无患子粉、蚕沙、月桂醇基硫酸钠、十二烷基磺酸钠、拉开粉、农乳2000号系列、润湿渗透剂F。可以选一种或多种的混合，用量按重量计占3～90％。
三、配制水分散粒剂时所用的助剂
润湿剂：烷基苯磺酸钠、木质素磺酸钠、脂肪醇、烷基硫酸盐、烷基酚聚氧乙烯醚、亚硫酸纸浆废液、茶枯粉和皂角粉中的一种或多种，用量按重量计占5～30％。
粘结剂：有大豆卵磷脂、明胶、聚乙烯醇、聚乙二醇、大豆蛋白、糊精、松香、淀粉中的一种或多种，用量按重量计占1～10％
崩解剂：有膨润土、硫酸铵、尿素、氯化镁、氯化钠中的一种或多种，用量按重量计占5～20％。
载体：有高岭土、轻质碳酸钙、白炭黑、蒙脱石、硅藻土、生石灰、烟草、稻壳中的一种或多种，用量按重量计占10～90％。
具体实施方式
下面结合优选实施例对本发明作进一步说明，但本发明决不限于下述实施例。以下实施例中各组分百分含量均以重量比计。
制剂实施例一
10.5％啶虫脒·甲维盐可湿性粉剂各组分重量配比
啶虫脒 10％
甲维盐 0.5％
十二烷基硫酸钠 2％
木质素磺酸钠 6％
亚甲基双萘磺酸钠 8％
高岭土 至100％
该实例一中有效组分啶虫脒和甲维盐重量比为20∶1，将混合物进行超细粉碎后造粒、干燥、筛分既得产品。
制剂实施例二
12.5％啶虫脒·氟虫脲可溶性粉剂各组分重量配比
啶虫脒 10％
氟虫脲 2.5％
十二烷基硫酸钠 至100％
该实例二中有效组分啶虫脒和甲维盐重量比为4∶1，将混合物进行超细粉碎后造粒、干燥、筛分既得产品。
制剂实施例三
3.5％啶虫脒·甲维盐水分散粒剂各组分重量配比
啶虫脒 3％
甲维盐 0.5％
脂肪醇 6％
硫酸铵 5％
高岭土 至100％
该实例三中有效组分啶虫脒和甲维盐重量比为6∶1，将混合物进行超细粉碎后造粒、干燥、筛分既得产品。
生物测试实施例一
药剂对椰心叶甲的室内活性测定，试虫采用室内连代饲养的椰心叶甲，具体方法如下：
药剂配制：试验原药为厂家提供原药，由我公司产品开发中心制剂室制成需要的制剂。单剂、复配剂均为可溶性粉剂。试验前，根据不同配比方案配制成不同的浓度梯度，每药剂3个浓度(见表1)；
浸叶：将椰子心叶剪成长为4cm的叶段，分别放入不同浓度的药液中浸渍3s后取出，放吸水纸上晾干，放入9cm培养皿中；
浸虫：将大小一致的3龄中期幼虫在处理药液中浸渍3s，放滤纸上爬行以吸去多余药液，等晾干后放入装有有毒叶片的培养皿中，培养皿底铺有滤纸保湿；将处理好的培养皿置于培养箱(T：25℃，RH＝70～80％)培养；
调查统计：定时检查试虫的死亡情况，以毛笔轻触虫体，以完全不动者视为死亡。分别于24、48和72h统计死虫数，计算死亡率和校正死亡率(见表2)。
表1 几种药剂对椰心叶甲幼虫的供试浓度
注：药剂栏各组分百分含量均以重量比计
表2 几种药剂对椰心叶甲幼虫的杀虫活性
注：药剂栏各组分百分含量均以重量比计
分析上述数据：从表1、表2可以看出，在1ppm时，在药后24h～72h，与对照相比，复配剂12.5％啶虫脒·氟虫脲对试虫椰心叶甲的24h致死率为86.7％，而啶虫脒、氟虫脲对试虫的活性分别为71.7％和13.3％；药后48h，12.5％啶虫脒·氟虫脲对试虫的致死率为95％，而啶虫脒、氟虫脲对试虫的活性分别为76.7％和13.3％；药后72h，12.5％啶虫脒·氟虫脲对试虫的致死率为98.3％，而啶虫脒、氟虫脲对试虫的活性分别为91.7％和30.0％；
测定结果表明：12.5％啶虫脒·氟虫脲的活性明显较两单剂高；同样，复配剂10.5％啶虫脒·甲维盐对试虫的活性也较高，与甲维盐的活性相当，相同效果的成本明显降低，且该复配剂具甲维盐的触杀和胃毒效果、啶虫脒的内吸活性，杀虫谱拓宽。
生物测试实例二
药剂对椰心叶甲的田间防效
试验地点：海南省海口市灵山镇；
试验药剂：药剂全部由我公司产品开发中心制剂研究室提供；单剂、复配剂为可溶性粉剂；
基数调查：防治作物为椰子，树龄6～7年。喷药前调查基数并对树进行编号；
施药方法：采取喷雾法。采用手持式喷雾器进行喷雾，每药剂根据虫量可喷树多棵，喷药均匀周到。以喷清水为对照。
药效调查与统计：药后不同时间调查试虫存活情况，计算防效(见表3)。施药后5d均无降雨天气。
表3 几种药剂对椰心叶甲的田间防效
| 0.5％甲维盐 | 3000 | 88 | 12 | 88.4 | 15 | 85.5 |
| 5％氟虫脲 | 1000 | 63 | 15 | 79.7 | 12 | 83.8 |
| 12.5％啶虫脒·氟虫脲(啶虫脒+氟虫脲＝10+2.5) | 3000 | 79 | 2 | 97.8 | 3 | 96.8 |
| 10.5％啶虫脒·甲维盐(啶虫脒+甲维盐＝10+0.5) | 3000 | 67 | 3 | 96.2 | 5 | 93.6 |
| 清水对照 | - | 53 | 61 | - | 83 | - |
注：药剂栏各组分百分含量均以重量比计
分析上述数据：从表3可以看出，12.5％啶虫脒·氟虫脲在稀释3000倍后，对椰心叶甲的药后防效在97.8％以上，且在药后60d，防效仍达90％以上，而两单剂稀释1000倍后的药后7d防效不足90％。
测定结果表明：啶虫脒和氟虫脲复配后，效果提高，且按相同的防效计算，复配剂的成本明显降低；同样，对于10.5％啶虫脒·甲维盐，药后7d、60d效果较两单剂高。充分说明，啶虫脒与氟虫脲复配、啶虫脒与甲维盐复配对椰心叶甲具有增效作用。且啶虫脒、氟虫脲、甲维盐低毒，对环境和人身健康安全。鉴于该单剂防治效果及防治谱，除可防治逐渐成灾发生的害虫椰心叶甲外，12.5％啶虫脒·氟虫脲与10.5％啶虫脒·甲维盐复配剂也可有效防治农林业生产中的其它同翅目、鳞翅目害虫。在生产加工时，也可对采取不同的配比、挂药包法等进行防治，以达到更有效的防治。
综上所述，我公司发明的含有啶虫脒的防治椰心叶甲的组合物，该组合物药效试验说明，不论从实验数据或测试结果，都能说明本发明所混配的组合物农药使用效果明显优于单剂溴虫腈或丙溴磷的使用效果。
以上实施例具体说明本发明内容，但本发明并不局限于以上实施例。依本发明权利要求所作的等同变化，仍属于本发明所涵盖的范围。
Claims (3)
1.含有啶虫脒的防治椰心叶甲的组合物的用途，其特征在于组合物用于防治棕榈科植物上发生的椰心叶甲，组合物包含有效组分I和组分II，所述组分I为啶虫脒，组分II为氟虫脲，所述组分I和组分II的重量比为4∶1～20∶1，所述组分I和组分II的累积重量百分比占总重量的1％～80％。
2.根据权利要求1所述的用途，其特征在于：所述组分I和组分II的累积重量百分比占总重量的3％～13％。
3.根据权利要求1所述的用途，其特征在于：所述含有啶虫脒的防治椰心叶甲的组合物制成可溶性粉剂。
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| CN108576040A (zh) * | 2017-12-21 | 2018-09-28 | 浙江省农业科学院 | 一种树木注干液剂及其制备方法 |
| CN111084190A (zh) * | 2019-12-04 | 2020-05-01 | 河北威远生物化工有限公司 | 一种含甲氨基阿维菌素B2a苯甲酸盐的杀虫组合物及其应用 |
| CN111084032A (zh) * | 2019-12-29 | 2020-05-01 | 海南万钦森林病虫害防治有限公司 | 一种椰心叶甲幼虫多方式防治方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101518248A (zh) * | 2008-02-27 | 2009-09-02 | 潘贞德 | 以啶虫脒为原料的一组可溶性液剂杀虫剂 |
-
2010
- 2010-01-05 CN CN 201010003849 patent/CN102113505B/zh active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101518248A (zh) * | 2008-02-27 | 2009-09-02 | 潘贞德 | 以啶虫脒为原料的一组可溶性液剂杀虫剂 |
Non-Patent Citations (2)
| Title |
|---|
| 张华集等.转光驱虫聚乙烯农用薄膜的研究.《中国塑料》.2005,(第08期), * |
| 谢圣华等.36种杀虫制剂对椰心叶甲的毒力测定.《海南大学学报(自然科学版)》.2007,(第01期), * |
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