CN102108516A - Scale removing reagent and using method thereof - Google Patents

Scale removing reagent and using method thereof Download PDF

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Publication number
CN102108516A
CN102108516A CN 201010598723 CN201010598723A CN102108516A CN 102108516 A CN102108516 A CN 102108516A CN 201010598723 CN201010598723 CN 201010598723 CN 201010598723 A CN201010598723 A CN 201010598723A CN 102108516 A CN102108516 A CN 102108516A
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Prior art keywords
incrustation scale
reagent
scale
scale reagent
water
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CN 201010598723
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CN102108516B (en
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余媛媛
伍媚娜
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Rugao Wushan Bleach and Dyeing Co., Ltd.
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余媛媛
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Abstract

The invention relates to a scale removing reagent and a using method thereof. The scale removing reagent comprises the following components in percentage by weight: 2.0 to 6.5 percent of citric acid, 3.0 to 13.0 percent of sodium bicarbonate, 12.0 to 18.0 percent of sulfamic acid, 1.2 to 2.5 percent of hexamethylene tetramine, and 60.0 to 81.8 percent of water. The using method for the scale removing reagent can be changed according to the capacity and scale thickness of a utensil to be subjected to scale removal; the scale removing effect is good, harmful substances cannot be generated, and the utensil subjected to the scale removal cannot be harmfully corroded; and the scale removing reagent is safe and practical.

Description

A kind of removing incrustation scale reagent and using method thereof
Technical field
The present invention relates to a kind of scale remover, particularly a kind of removing incrustation scale reagent and using method thereof.
Background technology
Incrustation scale is a common objectionable impurities in production and the life, its main component is throw outs such as lime carbonate and magnesium hydroxide, the density of incrustation scale and thickness all can be because of the time of using and purposes and different, these incrustation scale clear water can't clean up, and present on the market the certain shortcoming of scale remover ubiquity on descale effect, even also have a lot of scale remover itself just to possess stronger corrodibility, also be worthless to being damaged very big like this by the life-span of scale removal utensil, especially industrial boiler, of many uses, the cost height when will guarantee features high scale-removing effect, also requires safe and reliable.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of removing incrustation scale reagent, the present invention also provides the using method of above-mentioned removing incrustation scale reagent, the present invention includes following materials of weight proportions composition: citric acid 2.0 ~ 6.5%, sodium bicarbonate 3.0 ~ 13.0%, thionamic acid 12.0 ~ 18.0%, hexamethylenetetramine 1.2 ~ 2.5%, remaining is a water; Wherein, at normal temperatures, as long as keeping dry, thionamic acid do not contact with water, the solid thionamic acid is non-hygroscopic, more stable, and the aqueous solution of thionamic acid has and hydrochloric acid, the strongly-acid that sulfuric acid etc. are equal, so another name is solid sulphuric acid again, it has non-volatile, no stink and the characteristics minimum to human toxicity, the thionamic acid aqueous solution is slower to the corrosion product effect of iron, can add a certain amount of citric acid, sodium bicarbonate and hexamethylenetetramine, thereby dissolved iron dirt effectively, the aqueous solution of above-mentioned removing incrustation scale reagent can be removed iron, steel, copper, the incrustation scale and the corrosion product of the equipment surface that materials such as stainless steel are made, in addition, thionamic acid still is unique acid that galvanized metal surfaces cleans that can be used as.
In the used raw material, hexamethylenetetramine is a kind of inhibiter commonly used, also is solubility promoter, is used to slow down Corrosion of Metallic Materials, is widely used in iron and steel, casting, prepare composite; Above-mentioned removing incrustation scale reagent descale effect is fine, does not produce deleterious material, can also can not injure HUMAN HEALTH to by the corrosion of damaging property of scale removal utensil, and is safe and practical.
In order further to realize removing incrustation scale reagent, comprise following materials of weight proportions composition: citric acid 3.0 ~ 5.5%, sodium bicarbonate 5.0 ~ 12.0%, thionamic acid 15.0 ~ 17.0%, hexamethylenetetramine 1.5 ~ 2.0%, remaining is a water, and this ratio can be removed the incrustation scale that produces in various lives and the production more apace.
To remove incrustation scale reagent in order further realizing, to comprise following materials of weight proportions composition: citric acid 4.5%, sodium bicarbonate 11.0%, thionamic acid 16.5%, hexamethylenetetramine 1.7%, remaining is a water, this ratio can fast and effeciently be removed the incrustation scale that produces in various lives and the production.
To remove incrustation scale reagent in order further realizing, to comprise following materials of weight proportions composition: citric acid 5.0%, sodium bicarbonate 11.5%, thionamic acid 16.8%, hexamethylenetetramine 1.5%, remaining is a water, this ratio can efficiently be removed the incrustation scale that produces in various lives and the production.
The present invention also provides the using method of described removing incrustation scale reagent, and as dirt thickness≤2.0mm, the weight that adds above-mentioned removing incrustation scale reagent is by 3.7 ~ 5.0% of the volumetric water weight of scale removal utensil; On this basis, the every increase of dirt thickness 0.5mm, the add-on of removing incrustation scale reagent increases by 1.0 ~ 2.1%.
Particularly, add according to the above ratio and remove after the incrustation scale reagent, stir and dip operation, described stirring velocity is 30r/min, and described soak time surpasses 200min; In the process of soaking, keeps specific stirring velocity can improve the efficient of scale removal, this rotating speed of 30r/min both can be fine scale removal, also can be to by the excessive pressure of scale removal utensil inwall generation; As the thickness of incrustation scale or density thickening, the rotating speed that can also stir according to the practical situation appropriate change and the time of immersion, again or increase the amount of removing incrustation scale reagent.
The invention provides the using method of described removing incrustation scale reagent, dirt thickness≤2.0mm, the weight that adds above-mentioned removing incrustation scale reagent is by 4.8% of the volumetric water weight of scale removal utensil; On this basis, the every increase of dirt thickness 0.5mm, the add-on of removing incrustation scale reagent increases by 1.8%.
Particularly, add according to the above ratio and remove after the incrustation scale reagent, stir and dip operation, described stirring velocity is 30r/min, and described soak time surpasses 200min; In the process of soaking, keeps specific stirring velocity can improve the efficient of scale removal, this rotating speed of 30r/min both can be fine scale removal, also can be to by the excessive pressure of scale removal utensil inwall generation; As the thickness of incrustation scale or density thickening, the rotating speed that can also stir according to the practical situation appropriate change and the time of immersion, again or increase the amount of removing incrustation scale reagent, even can increase operation such as the pressurization of heating, just can reach better descale effect like this.
The invention provides a kind of removing incrustation scale reagent and using method thereof, remove incrustation scale reagent and comprise following materials of weight proportions composition: citric acid 2.0 ~ 6.5%, sodium bicarbonate 3.0 ~ 13.0%, thionamic acid 12.0 ~ 18.0%, hexamethylenetetramine 1.2 ~ 2.5%, remaining is a water; The present invention can change its using method according to by the amount of capacity of scale removal utensil and incrustation scale thickness, and features high scale-removing effect can not produce objectionable impurities, can be to by the corrosion of damaging property of scale removal utensil, and safe and practical.
Description of drawings
There is not figure.
Embodiment
Embodiment 1:
With the 2.4kg citric acid, the 5.52kg sodium bicarbonate, the 8.06kg thionamic acid, the 0.72kg hexamethylenetetramine, 31.78kg water mixes, and obtains removing incrustation scale reagent 48kg of the present invention.
The boiler that capable of storing water is 1 ton, the thickness of its incrustation scale is about 2.0mm, the removing incrustation scale reagent of above-mentioned 48kg is joined in the boiler through the filler of boiler, fill with, make it to form uniform solution, start and stir and dip operation, the speed control that stirs is 30r/min, soaks 280min, discharges the material in the boiler, after measured, this method is removed incrustation scale above 95%.
Above content be in conjunction with concrete preferred implementation to further describing that the present invention did, can not assert that concrete enforcement of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.

Claims (7)

1. remove incrustation scale reagent for one kind, it is characterized in that, comprise following materials of weight proportions composition: citric acid 2.0 ~ 6.5%, sodium bicarbonate 3.0 ~ 13.0%, thionamic acid 12.0 ~ 18.0%, hexamethylenetetramine 1.2 ~ 2.5%, remaining is a water.
2. removing incrustation scale reagent according to claim 1 is characterized in that, comprises following materials of weight proportions composition: citric acid 3.0 ~ 5.5%, and sodium bicarbonate 5.0 ~ 12.0%, thionamic acid 15.0 ~ 17.0%, hexamethylenetetramine 1.5 ~ 2.0%, remaining is a water.
3. removing incrustation scale reagent according to claim 2 is characterized in that, comprises following materials of weight proportions composition: citric acid 4.5%, and sodium bicarbonate 11.0%, thionamic acid 16.5%, hexamethylenetetramine 1.7%, remaining is a water.
4. removing incrustation scale reagent according to claim 2 is characterized in that, comprises following materials of weight proportions composition: citric acid 5.0%, and sodium bicarbonate 11.5%, thionamic acid 16.8%, hexamethylenetetramine 1.5%, remaining is a water.
5. according to the using method of any described removing incrustation scale reagent of claim 1 ~ 4, it is characterized in that, dirt thickness≤2.0mm, the weight that adds above-mentioned removing incrustation scale reagent is by 3.7 ~ 5.0% of the volumetric water weight of scale removal utensil; On this basis, the every increase of dirt thickness 0.5mm, the add-on of removing incrustation scale reagent increases by 1.0 ~ 2.1%.
6. the using method of incrustation scale reagent is removed in use according to claim 5, it is characterized in that, and dirt thickness≤2.0mm, the weight that adds above-mentioned removing incrustation scale reagent is by 4.8% of the volumetric water weight of scale removal utensil; On this basis, the every increase of dirt thickness 0.5mm, the add-on of removing incrustation scale reagent increases by 1.8%.
7. the using method of incrustation scale reagent is removed in use according to claim 5, it is characterized in that, described removing incrustation scale reagent is added by behind the scale removal utensil, stir and dip operation, described stirring velocity is 30r/min, and described soak time surpasses 200min.
CN201010598723A 2010-12-21 2010-12-21 Scale removing reagent and using method thereof Active CN102108516B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277585A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Cleaning agent used for pretreatment in preparation of bioconversion film metal plate
CN103305853A (en) * 2012-03-09 2013-09-18 中国石油化工股份有限公司 Cleaning agent for automobile cooling system
CN103710718A (en) * 2013-12-11 2014-04-09 张啸 Oxide skin cleaning agent and application thereof
CN104607427A (en) * 2014-12-23 2015-05-13 长春轨道客车股份有限公司 Non-disassembling cleaning method for clear water tank in three-level maintenance project of CRH380B-series China railway high speed train
CN106635505A (en) * 2016-12-10 2017-05-10 钦州学院 Water scale cleaning agent and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1715452A (en) * 2004-06-29 2006-01-04 上海万森水处理有限公司 Detergent for cleaning metal surface
CN101294287B (en) * 2007-04-28 2010-09-22 佛山市顺德区汉达精密电子科技有限公司 Formula and technique for neutral rust remover for rust cleaning of sheet material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1715452A (en) * 2004-06-29 2006-01-04 上海万森水处理有限公司 Detergent for cleaning metal surface
CN101294287B (en) * 2007-04-28 2010-09-22 佛山市顺德区汉达精密电子科技有限公司 Formula and technique for neutral rust remover for rust cleaning of sheet material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《清洗世界》 20080131 李长海 锅炉清洗酸洗剂的选择及其应用 22-27 1-7 第24卷, 第1期 2 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102277585A (en) * 2011-08-22 2011-12-14 络力螯(昆山)生物科技研发中心有限公司 Cleaning agent used for pretreatment in preparation of bioconversion film metal plate
CN102277585B (en) * 2011-08-22 2013-04-17 络力螯(昆山)生物科技研发中心有限公司 Cleaning agent used for pretreatment in preparation of bioconversion film metal plate
CN103305853A (en) * 2012-03-09 2013-09-18 中国石油化工股份有限公司 Cleaning agent for automobile cooling system
CN103710718A (en) * 2013-12-11 2014-04-09 张啸 Oxide skin cleaning agent and application thereof
CN103710718B (en) * 2013-12-11 2016-01-06 北京中电龙源环保科技有限公司 A kind of oxide skin clean-out system and application thereof
CN104607427A (en) * 2014-12-23 2015-05-13 长春轨道客车股份有限公司 Non-disassembling cleaning method for clear water tank in three-level maintenance project of CRH380B-series China railway high speed train
CN106635505A (en) * 2016-12-10 2017-05-10 钦州学院 Water scale cleaning agent and preparation method thereof

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Inventor after: Luan Qiaomei

Inventor after: Zhang Xinyuan

Inventor after: Yu Yuanyuan

Inventor after: Wu Meina

Inventor before: Yu Yuanyuan

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Owner name: RUGAO CITY WUSHAN BLEACHING AND DYEING CO., LTD.

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Effective date: 20130906

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Effective date of registration: 20130906

Address after: 226500 No. 1, executive Road, Dong Chen Town, Jiangsu, Rugao

Patentee after: Rugao Wushan Bleach and Dyeing Co., Ltd.

Address before: 523000 Guangdong city of Dongguan province Changan Mayor Liang Mao Yi Road No. 703 building

Patentee before: Yu Yuanyuan